CN103508597A - EWTS electrochemical sewage treatment method and system - Google Patents

EWTS electrochemical sewage treatment method and system Download PDF

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CN103508597A
CN103508597A CN201310412368.4A CN201310412368A CN103508597A CN 103508597 A CN103508597 A CN 103508597A CN 201310412368 A CN201310412368 A CN 201310412368A CN 103508597 A CN103508597 A CN 103508597A
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liquid
ewts
alloy electrode
treatment
sewage
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胡军
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SHENZHEN SANSHENG ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Abstract

The invention discloses an EWTS electrochemical sewage treatment method and system. The method comprises the following steps of: (1) storing a liquid to be treated in a raw water tank, and then allowing the liquid to flow from the raw water tank into a pH regulation tank; (2) allowing the liquid to enter an EWTS electrical process device for treatment, wherein the treatment process includes the steps of allowing the liquid to go through an interlayer between a positive alloy electrode plate and a negative alloy electrode plate, and charging the positive/negative alloy electrode plates with a high-frequency current, so that the alloy material molecules of the positive/negative alloy electrode plates are released at the same time into the liquid under the action of the high-frequency current, ionized and non-ionized pollutants in the liquid are adsorbed under the combined action of charges, electrolysis products and metal plate materials and discharged in the form of solid slurry; and (3) introducing the liquid resulting from the treatment with the EWTS electrical process device into an oxidation tank where inorganic and organic matters in the liquid are oxidized. The method provided by the invention has the advantages of low treatment cost, low slurry output, small floor area, high degree of automation and simplicity in management, and the capability of removing different types of pollutants at the same time.

Description

EWTS electrochemistry sewage water treatment method and system
Technical field
The present invention relates to sewage treatment area, relate in particular to a kind of EWTS electrochemistry sewage water treatment method and system.
Background technology
Prior art probably has several method to sewage water treatment method:
The first is biological process, by biological adsorption and the new cellular material of microorganism, synthesize and consume degraded, the method can be gone out COD 60% left and right, and running cost is lower, shortcoming is that floor space is large, invests high, be subject to waste water composition and concentration limit, the residence time is long, manageability not, and processing water can not reuse.
The second is chemical method, adds coagulating agent, reduces the operating range of electric charge and electrostatic double layer, by adsorption bridging, forms large floc sedimentation, COD can be gone out to 70% left and right, and shortcoming is that processing costs is high, and sludge quantity is large, and narrow application range is difficult up to standard.
The third is general chemical oxidization method, by conventional oxygenant decomposing organic matter, can make some organic oxygen compounds decompose, and the residence time is few, and oxygenant consumption is large, and only effective to some hardly degraded organic substance, the scope of application is narrow.
The various defects such as the 4th kind of method is common electrochemical appliance treatment process, and the method electrode easily corrodes, and work-ing life is short, easily produce bubble, reduced electrical method efficiency, the easy fouling of electrode, passivation, clean inconvenient, electrode need to adopt pickling, causes the pollution again to environment, and treatment capacity is little.
In several sewage water treatment methods, all there is weak point separately above.
Therefore, need that a kind of processing cost is low, sludge quantity is few, floor space is little, level of automation is high badly, manageability, can remove EWTS electrochemistry sewage water treatment method and the system of multiple pollutant simultaneously.
Summary of the invention
First object of the present invention is to provide that a kind of processing cost is low, sludge quantity is few, floor space is little, level of automation is high, manageability, can remove the EWTS electrochemistry sewage water treatment method of multiple pollutant simultaneously.
Second object of the present invention is to provide that a kind of processing cost is low, sludge quantity is few, floor space is little, level of automation is high, manageability, can remove the EWTS electrochemistry Sewage treatment systems of multiple pollutant simultaneously.
In order to realize above-mentioned first object, technical scheme provided by the invention is: a kind of EWTS electrochemistry sewage water treatment method is provided, and it comprises, following steps:
(1) pending liquid storage Zhi Yuan pond, then flow into PH equalizing tank by described former pond;
(2) allowing liquid enter EWTS device processes, treating processes is to allow liquid pass through the interlayer between positive and negative alloy electrode plate, and by the logical upper high-frequency current of described positive and negative alloy electrode plate, allow the material molecule of alloy of described positive and negative alloy electrode plate be discharged in liquid under the effect of described high-frequency current simultaneously, ionization in liquid and unionized pollutent are adsorbed the acting in conjunction that is subject to electric charge, electrolysate and metallic sheet material, and discharge with the form of solid mud;
(3) liquid after processing by EWTS device is imported to oxidation pond, the inorganics in liquid, organism are carried out to oxide treatment.
Liquid through oxide treatment in step (3) is passed through to centrifugal settler, vertical baffling plate region, pressure filter, ultra-fine filter successively, obtain clear water and import clean water basin.
In described pH value equalizing tank, the pH value of sewage is detected, the PH data that then root detects are carried out PID analysis, then carry out PH proportioning by automatic liquid feeder.
In step (2), the data that described EWTS device can feed back by detection, the alloy electrode of automatic switchover different qualities, to coordinate liquid of different nature to process.
In step (2), the sewage after processing by EWTS device, the organic and inorganic pollution substance in liquid is carried out to redox reaction, and then cohesion, floating except pollutent is separated from water body, remove the Cr6 in waste water +, Zn2 +, Ni2 +, Cu2 +, Cd2 +heavy metal and CN, oil, phosphoric acid salt and COD, SS.
In step (3), described oxide treatment is for to carry out oxide treatment by ozone, by the free radical of ozone and pollutent in liquid: C==C, C ≡ C, aromatic compound, heterogeneous ring compound, isocyclic compound ,==N-N ,==S, C ≡ N, C-N, C-Si ,-OH ,-SH ,-NH2, ,-CHO ,-N==N-react.
In order to realize above-mentioned second object, technical scheme provided by the invention is: provide a kind of EWTS electrochemistry Sewage treatment systems it comprise:
Former pond and pH value equalizing tank, pending liquid is stored in described former pond, and liquid flows into described pH value equalizing tank by described former pond and carries out pH value adjusting;
EWTS device, described EWTS device comprises positive and negative alloy electrode, allow liquid pass through the interlayer between described positive and negative alloy electrode, and by the logical upper high-frequency current of described positive and negative alloy electrode plate, allow the material molecule of alloy of described positive and negative alloy electrode plate be discharged in liquid under the effect of described high-frequency current simultaneously, ionization in liquid and unionized pollutent are adsorbed the acting in conjunction that is subject to electric charge, electrolysate and metallic sheet material, and discharge with the form of solid mud;
Oxidation pond, imports oxidation pond by the liquid after processing by EWTS device, and described oxidation pond carries out oxide treatment by the inorganics in liquid, organism.
Also comprise centrifugal settler, vertical baffling plate region, pressure filter, ultra-fine filter, the liquid through oxide treatment is passed through to described centrifugal settler, vertical baffling plate region, pressure filter, ultra-fine filter successively, obtain clear water and import clean water basin.
In described pH value equalizing tank, be provided with the analytical equipment that PH data that proofing unit that the pH value of sewage is detected, root detect are carried out PID analysis, carry out the automatic liquid feeder of PH proportioning.
The data that described EWTS device can feed back by detection, the alloy electrode of automatic switchover different qualities, to coordinate liquid of different nature to process.
Sewage after processing by EWTS device, the organic and inorganic pollution substance in liquid is carried out to redox reaction, and then cohesion, floating except pollutent is separated from water body, remove the Cr6 in waste water +, Zn2 +, Ni2 +, Cu2 +, Cd2 +heavy metal and CN, oil, phosphoric acid salt and COD, SS.
Oxide treatment in described oxidation pond is for to carry out oxide treatment by ozone, by the free radical of ozone and pollutent in liquid: C==C, C ≡ C, aromatic compound, heterogeneous ring compound, isocyclic compound ,==N-N ,==S, C ≡ N, C-N, C-Si ,-OH ,-SH ,-NH2, ,-CHO ,-N==N-react.
Compared with prior art, EWTS electrochemistry sewage water treatment method of the present invention and system are that a kind of processing cost is low, sludge quantity is few, floor space is little, level of automation is high, manageability, can remove EWTS electrochemistry sewage water treatment method and the system of multiple pollutant simultaneously.
By following description also by reference to the accompanying drawings, it is more clear that the present invention will become, and these accompanying drawings are used for explaining embodiments of the invention.
Accompanying drawing explanation
Fig. 1 is the system chart of EWTS electrochemistry Sewage treatment systems of the present invention.
Embodiment
With reference now to accompanying drawing, describe embodiments of the invention, in accompanying drawing, similarly element numbers represents similar element.As mentioned above, as shown in Figure 1, provided by the inventionly provide a kind of EWTS electrochemistry sewage water treatment method, it comprises, following steps:
(1) pending liquid storage Zhi Yuan pond 10, then flow into PH equalizing tank 20 by described former pond 10, wherein by liquid Cong Yuan pond 10, entering PH equalizing tank is to inject by water pump 30;
(2) allowing liquid enter EWTS device 40 processes, treating processes is to allow liquid pass through the interlayer between positive and negative alloy electrode plate, and by the logical upper high-frequency current of described positive and negative alloy electrode plate, allow the material molecule of alloy of described positive and negative alloy electrode plate be discharged in liquid under the effect of described high-frequency current simultaneously, ionization in liquid and unionized pollutent are adsorbed the acting in conjunction that is subject to electric charge, electrolysate and metallic sheet material, and discharge with the form of solid mud;
(3) liquid after processing by EWTS device 40 is imported to oxidation pond 50, the inorganics in liquid, organism are carried out to oxide treatment.
Liquid through oxide treatment in step (3) is passed through to centrifugal settler 60, vertical baffling plate region (not showing on figure), pressure filter 70, medium filter 80, ultra-fine filter 90 successively, obtain clear water and import clean water basin 100.
In described pH value equalizing tank 20, the pH value of sewage is detected, the PH data that then root detects are carried out PID analysis, then carry out PH proportioning by automatic liquid feeder.
In step (2), the data that described EWTS device 40 can feed back by detection, the alloy electrode of automatic switchover different qualities, to coordinate liquid of different nature to process.
In step (2), sewage after processing by EWTS device 40, the organic and inorganic pollution substance in liquid is carried out to redox reaction, and then cohesion, floating except pollutent is separated from water body, remove Cr6+, Zn2+, Ni2+, Cu2+, Cd2+ heavy metal and CN, oil, phosphoric acid salt and COD, SS in waste water.
In step (3), described oxide treatment is for to carry out oxide treatment by ozone, by the free radical of ozone and pollutent in liquid: C==C, C ≡ C, aromatic compound, heterogeneous ring compound, isocyclic compound ,==N-N ,==S, C ≡ N, C-N, C-Si ,-OH ,-SH ,-NH2, ,-CHO ,-N==N-react.
In order to realize above-mentioned second object, as shown in Figure 1, technical scheme provided by the invention is: provide a kind of EWTS electrochemistry Sewage treatment systems 200 it comprise:
Former pond 10 and pH value equalizing tank 20, pending liquid is stored in described former pond 10, and liquid flows into described pH value equalizing tank 20 by described former pond 10 and carries out pH value adjusting;
EWTS device 20, described EWTS device 40 comprises positive and negative alloy electrode, allow liquid pass through the interlayer between described positive and negative alloy electrode, and by the logical upper high-frequency current of described positive and negative alloy electrode plate, allow the material molecule of alloy of described positive and negative alloy electrode plate be discharged in liquid under the effect of described high-frequency current simultaneously, ionization in liquid and unionized pollutent are adsorbed the acting in conjunction that is subject to electric charge, electrolysate and metallic sheet material, and discharge with the form of solid mud;
Oxidation pond 50, imports oxidation pond 50 by the liquid after processing by EWTS device 20, and described oxidation pond 50 carries out oxide treatment by the inorganics in liquid, organism.
Also comprise centrifugal settler 60, vertical baffling plate region, pressure filter 70, medium filter 80, ultra-fine filter 90, liquid through oxide treatment is passed through to described centrifugal settler 60, vertical baffling plate region, pressure filter 70, ultra-fine filter 90 successively, obtain clear water and import clean water basin 100.
In described pH value equalizing tank 20, be provided with the analytical equipment that PH data that proofing unit that the pH value of sewage is detected, root detect are carried out PID analysis, carry out the automatic liquid feeder of PH proportioning.
The data that described EWTS device 40 can feed back by detection, the alloy electrode of automatic switchover different qualities, to coordinate liquid of different nature to process.
Sewage after processing by EWTS device 40, the organic and inorganic pollution substance in liquid is carried out to redox reaction, and then cohesion, floating except pollutent is separated from water body, remove Cr6+, Zn2+, Ni2+, Cu2+, Cd2+ heavy metal and CN, oil, phosphoric acid salt and COD, SS in waste water.
Oxide treatment in described oxidation pond 50 is for to carry out oxide treatment by ozone, by the free radical of ozone and pollutent in liquid: C==C, C ≡ C, aromatic compound, heterogeneous ring compound, isocyclic compound ,==N-N ,==S, C ≡ N, C-N, C-Si ,-OH ,-SH ,-NH2, ,-CHO ,-N==N-react.
The key technical indexes reference when EWTS electrical method sewage water treatment method of the present invention and system treating part industry waste water:
By lower list 1 and table 2, can find out, EWTS method has good effect when processing these industry waste water.
Table 1
Figure BSA0000095054860000061
Remarks: all test results are all to take mg/l as unit.
Table 2
Figure BSA0000095054860000062
Figure BSA0000095054860000071
In conjunction with Fig. 1, table 1 and table 2, EWTS electrochemistry sewage water treatment method of the present invention and system are that a kind of processing cost is low, sludge quantity is few, floor space is little, level of automation is high, manageability, can remove EWTS electrochemistry sewage water treatment method and the system of multiple pollutant simultaneously.Above disclosed is only the preferred embodiments of the present invention, certainly can not limit with this interest field of the present invention, and the equivalent variations of therefore doing according to the present patent application the scope of the claims, still belongs to the scope that the present invention is contained.

Claims (12)

1. an EWTS electrochemistry sewage water treatment method, is characterized in that, comprises following steps:
(1) pending liquid storage Zhi Yuan pond, then flow into PH equalizing tank by described former pond;
(2) allowing liquid enter EWTS device processes, treating processes is to allow liquid pass through the interlayer between positive and negative alloy electrode plate, and by the logical upper high-frequency current of described positive and negative alloy electrode plate, allow the material molecule of alloy of described positive and negative alloy electrode plate be discharged in liquid under the effect of described high-frequency current simultaneously, ionization in liquid and unionized pollutent are adsorbed the acting in conjunction that is subject to electric charge, electrolysate and metallic sheet material, and discharge with the form of solid mud;
(3) liquid after processing by EWTS device is imported to oxidation pond, the inorganics in liquid, organism are carried out to oxide treatment.
2. EWTS electrochemistry sewage water treatment method as claimed in claim 1, it is characterized in that: the liquid through oxide treatment in step (3) is passed through to centrifugal settler, vertical baffling plate region, pressure filter, ultra-fine filter successively, obtain clear water and import clean water basin.
3. EWTS electrochemistry sewage water treatment method as claimed in claim 1, is characterized in that: in described pH value equalizing tank, the pH value of sewage is detected, the PH data that then root detects are carried out PID analysis, then carry out PH proportioning by automatic liquid feeder.
4. EWTS electrochemistry sewage water treatment method as claimed in claim 1, it is characterized in that: in step (2), the data that described EWTS device can feed back by detection, the alloy electrode of automatic switchover different qualities, to coordinate liquid of different nature to process.
5. EWTS electrochemistry sewage water treatment method as claimed in claim 1, it is characterized in that: in step (2), sewage after processing by EWTS device, the organic and inorganic pollution substance in liquid is carried out to redox reaction, and then cohesion, floating except pollutent is separated from water body, remove the Cr6 in waste water +, Zn2 +, Ni2 +, Cu2 +, Cd2 +heavy metal and CN, oil, phosphoric acid salt and COD, SS.
6. EWTS electrochemistry sewage water treatment method as claimed in claim 1, it is characterized in that: in step (3), described oxide treatment is for to carry out oxide treatment by ozone, by the free radical of ozone and pollutent in liquid: C==C, C ≡ C, aromatic compound, heterogeneous ring compound, isocyclic compound ,==N-N ,==S, C ≡ N, C-N, C-Si ,-OH ,-SH ,-NH2, ,-CHO ,-N==N-react.
7. an EWTS electrochemistry Sewage treatment systems, is characterized in that, comprising:
Former pond and pH value equalizing tank, pending liquid is stored in described former pond, and liquid flows into described pH value equalizing tank by described former pond and carries out pH value adjusting;
EWTS device, described EWTS device comprises positive and negative alloy electrode, allow liquid pass through the interlayer between described positive and negative alloy electrode, and by the logical upper high-frequency current of described positive and negative alloy electrode plate, allow the material molecule of alloy of described positive and negative alloy electrode plate be discharged in liquid under the effect of described high-frequency current simultaneously, ionization in liquid and unionized pollutent are adsorbed the acting in conjunction that is subject to electric charge, electrolysate and metallic sheet material, and discharge with the form of solid mud;
Oxidation pond, imports oxidation pond by the liquid after processing by EWTS device, and described oxidation pond carries out oxide treatment by the inorganics in liquid, organism.
8. EWTS electrochemistry Sewage treatment systems as claimed in claim 7, it is characterized in that, also comprise centrifugal settler, vertical baffling plate region, pressure filter, ultra-fine filter, liquid through oxide treatment is passed through to described centrifugal settler, vertical baffling plate region, pressure filter, ultra-fine filter successively, obtain clear water and import clean water basin.
9. EWTS electrochemistry Sewage treatment systems as claimed in claim 7, it is characterized in that, in described pH value equalizing tank, be provided with the analytical equipment that PH data that proofing unit that the pH value of sewage is detected, root detect are carried out PID analysis, carry out the automatic liquid feeder of PH proportioning.
10. EWTS electrochemistry Sewage treatment systems as claimed in claim 7, is characterized in that, the data that described EWTS device can feed back by detection, and the alloy electrode of automatic switchover different qualities, to coordinate liquid of different nature to process.
11. EWTS electrochemistry Sewage treatment systemss as claimed in claim 7, it is characterized in that, sewage after processing by EWTS device, the organic and inorganic pollution substance in liquid is carried out to redox reaction, and then cohesion, floating except pollutent is separated from water body, remove the Cr6 in waste water +, Zn2 +, Ni2 +, Cu2 +, Cd2 +heavy metal and CN, oil, phosphoric acid salt and COD, SS.
12. EWTS electrochemistry Sewage treatment systemss as claimed in claim 7, it is characterized in that, oxide treatment in described oxidation pond is for to carry out oxide treatment by ozone, by the free radical of ozone and pollutent in liquid: C==C, C ≡ C, aromatic compound, heterogeneous ring compound, isocyclic compound ,==N-N ,==S, C ≡ N, C-N, C-Si ,-OH ,-SH ,-NH2, ,-CHO ,-N==N-react.
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