CN103496905A - Antifreeze concrete and preparation method thereof - Google Patents

Antifreeze concrete and preparation method thereof Download PDF

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Publication number
CN103496905A
CN103496905A CN201310449451.9A CN201310449451A CN103496905A CN 103496905 A CN103496905 A CN 103496905A CN 201310449451 A CN201310449451 A CN 201310449451A CN 103496905 A CN103496905 A CN 103496905A
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CN
China
Prior art keywords
parts
frost
resistant concrete
frostproofer
lithium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201310449451.9A
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Chinese (zh)
Other versions
CN103496905B (en
Inventor
唐建军
杨支来
黄国平
顾永新
徐海彬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu TengXiang Concrete Co. Ltd.
Original Assignee
Zhangjiagang Shanmu New Material Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhangjiagang Shanmu New Material Technology Development Co Ltd filed Critical Zhangjiagang Shanmu New Material Technology Development Co Ltd
Priority to CN201310449451.9A priority Critical patent/CN103496905B/en
Publication of CN103496905A publication Critical patent/CN103496905A/en
Application granted granted Critical
Publication of CN103496905B publication Critical patent/CN103496905B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)
  • Revetment (AREA)

Abstract

The invention discloses antifreeze concrete and a preparation method thereof. The antifreeze concrete is prepared by mixing the following raw materials in parts by weight: 20-25 parts of cement, 20-45 parts of coal ash, 10-20 parts of water, 10-20 parts of river sands, 1-2 parts of polymer fibers, 4-6 parts of industrial aluminum sulfate and 15-20 parts of an antifreezing agent. A lithium base is introduced in the antifreezing agent, so that alkali-aggregate reaction can be effectively inhibited; the antifreeze concrete is simple in production process, low in cost, good in antifreezing effect and beneficial to industrial production.

Description

A kind of frost-resistant concrete and preparation method thereof
Technical field
The present invention relates to building material field, particularly a kind of frost-resistant concrete and preparation method thereof.
Background technology
In building operation, often can run into various atrocious weather environment, especially in the winter time, long-term low temperature has caused very large impact to concrete stirring, how just can prevent that concrete from freezing at low temperatures is the relatively problem of headache of engineering staff always.
Nitrate, the nitrite of adopting prevent that as antifreeze component concrete from freezing more on the market now, and still, this method makes the concrete alkalinity suddenly increase, and even occurs that the accumulation of salt in the surface soil is present, has had a strong impact on construction quality.
Summary of the invention
The present invention seeks to: propose a kind of frost-resistant concrete and preparation method thereof, it can resist the low temperature environment of subzero 15 ℃, and can effectively reduce the phenomenon of the accumulation of salt in the surface soil.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of frost-resistant concrete is formed by weight ratio by following raw material:
Cement 20-25 part;
Flyash 20-45 part;
Water 10-20 part;
River sand 10-20 part;
Polymer fiber 1-2 part;
Industrial aluminum sulphate 4-6 part;
Frostproofer 15-20 part.
Preferably, described polymer fiber adopts 2 parts.
Preferably, described polymer fiber is mixed by polyvinyl alcohol fiber and polypropylene fibre.
Preferably, the weight part proportioning of described polyvinyl alcohol fiber and described polypropylene fibre is 7:3.
Preferably, described industrial aluminum sulphate adopts 6 parts.
Preferably, described frostproofer is mixed and is formed by lithium acetate and sodium acetate.
Preferably, in described lithium acetate and described sodium acetate, the mol ratio of lithium and sodium is 0.3-0.5.
A kind of preparation method of frost-resistant concrete, comprise the steps:
Step (1): take following raw material mix and blend by weight ratio:
Cement 20-25 part;
Flyash 20-45 part;
Water 10-20 part;
River sand 10-20 part;
Industrial aluminum sulphate 4-6 part;
Step (2): take the polyvinyl alcohol fiber of 7 parts and the polypropylene fibre of 3 parts and mix rear the stirring 40 minutes, make polymer fiber;
Step (3): the polymer fiber that adds 2 parts of steps (2) to make in the mixture made in step (1), stir 1 hour;
Step (4): will after the proportioning mixing and stirring that be 0.3-0.5 by the mol ratio of lithium and sodium in lithium acetate and described sodium acetate, make frostproofer;
Step (5): by the frostproofer made in step (4), be added in the middle gained mixture of step (3), then stir 2-3 hour, can use.
 
The invention has the beneficial effects as follows: the present invention has introduced the lithium base in frostproofer, can effectively suppress alkali-aggregate reaction, and production process of the present invention is simple, and cost is low, and good freezing protection effect, more is conducive to suitability for industrialized production.
Embodiment
What below show is one of preferred embodiment of the present invention, for the enforcement personnel as a reference.
Embodiment 1: a kind of frost-resistant concrete is formed by weight ratio by following raw material:
25 parts of cement;
20 parts, flyash;
20 parts, water
15 parts of river sands;
2 parts of polymer fibers;
6 parts of industrial aluminum sulphates;
12 parts of frostproofers.
Preferably, described polymer fiber is mixed by polyvinyl alcohol fiber and polypropylene fibre.
Preferably, the weight part proportioning of described polyvinyl alcohol fiber and described polypropylene fibre is 7:3.
Preferably, described frostproofer is mixed and is formed by lithium acetate and sodium acetate.
Preferably, in described lithium acetate and described sodium acetate, the mol ratio of lithium and sodium is 0.3-0.5.
The preparation method of this product is as follows:
Step (1): take following raw material mix and blend by weight ratio:
25 parts of cement;
20 parts, flyash;
20 parts, water
15 parts of river sands;
6 parts of industrial aluminum sulphates;
Step (2): take the polyvinyl alcohol fiber of 7 parts and the polypropylene fibre of 3 parts and mix rear the stirring 40 minutes, make polymer fiber;
Step (3): the polymer fiber that adds 2 parts of steps (2) to make in the mixture made in step (1), stir 1 hour;
Step (4): will after the proportioning mixing and stirring that be 0.3-0.5 by the mol ratio of lithium and sodium in lithium acetate and described sodium acetate, make frostproofer;
Step (5): by the frostproofer made in step (4), be added in the middle gained mixture of step (3), then stir 2 hours, can use.
Experiment showed, that through the contriver concrete that present method makes can effectively resist the low temperature environment of-15 ℃, and can be under the subzero temperature environment maintenance about 7 days, then transfer the curing strength standard of normal curing 28 to.

Claims (8)

1. a frost-resistant concrete, is characterized in that, by following raw material, formed by weight ratio:
Cement 20-25 part;
Flyash 20-45 part;
Water 10-20 part
River sand 10-20 part;
Polymer fiber 1-2 part;
Industrial aluminum sulphate 4-6 part;
Frostproofer 15-20 part.
2. a kind of frost-resistant concrete as claimed in claim 1, is characterized in that, described polymer fiber adopts 2 parts.
3. a kind of frost-resistant concrete as claimed in claim 2, is characterized in that, described polymer fiber is mixed by polyvinyl alcohol fiber and polypropylene fibre.
4. a kind of frost-resistant concrete as claimed in claim 3, is characterized in that, the weight part proportioning of described polyvinyl alcohol fiber and described polypropylene fibre is 7:3.
5. a kind of frost-resistant concrete as claimed in claim 1, is characterized in that, described industrial aluminum sulphate adopts 6 parts.
6. a kind of frost-resistant concrete as claimed in claim 1, is characterized in that, described frostproofer is mixed and formed by lithium acetate and sodium acetate.
7. a kind of frost-resistant concrete as claimed in claim 6, is characterized in that, in described lithium acetate and described sodium acetate, the mol ratio of lithium and sodium is 0.3-0.5.
8. the preparation method of a frost-resistant concrete, is characterized in that, comprises the steps:
Step (1): take following raw material mix and blend by weight ratio:
Cement 20-25 part;
Flyash 20-45 part;
Water 10-20 part
River sand 10-20 part;
Industrial aluminum sulphate 4-6 part;
Step (2): take the polyvinyl alcohol fiber of 7 parts and the polypropylene fibre of 3 parts and mix rear the stirring 40 minutes, make polymer fiber;
Step (3): the polymer fiber that adds 2 parts of steps (2) to make in the mixture made in step (1), stir 1 hour;
Step (4): will after the proportioning mixing and stirring that be 0.3-0.5 by the mol ratio of lithium and sodium in lithium acetate and described sodium acetate, make frostproofer;
Step (5): by the frostproofer made in step (4), be added in the middle gained mixture of step (3), then stir 2-3 hour, can use.
CN201310449451.9A 2013-09-29 2013-09-29 A kind of frost-resistant concrete and preparation method thereof Expired - Fee Related CN103496905B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310449451.9A CN103496905B (en) 2013-09-29 2013-09-29 A kind of frost-resistant concrete and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310449451.9A CN103496905B (en) 2013-09-29 2013-09-29 A kind of frost-resistant concrete and preparation method thereof

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CN103496905A true CN103496905A (en) 2014-01-08
CN103496905B CN103496905B (en) 2016-02-03

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105174831A (en) * 2015-07-29 2015-12-23 安徽砼宇特构科技有限公司 Antifreezing concrete and preparation method therefor
CN107382220A (en) * 2017-09-06 2017-11-24 陈毅忠 A kind of frost-resistant concrete
CN107473650A (en) * 2017-08-11 2017-12-15 汤始建华建材(苏州)有限公司 A kind of anti-freezing type concrete

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101200364A (en) * 2007-12-21 2008-06-18 大连理工大学 Chlorine-free highly effective composite enhanced solid cement grinding aids and production method
CN102219452A (en) * 2011-04-13 2011-10-19 河北建筑工程学院 Pumice straw lightweight aggregate concrete and preparation method thereof
CN102786246A (en) * 2012-08-31 2012-11-21 句容宁武高新技术发展有限公司 Concrete antifreezer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101200364A (en) * 2007-12-21 2008-06-18 大连理工大学 Chlorine-free highly effective composite enhanced solid cement grinding aids and production method
CN102219452A (en) * 2011-04-13 2011-10-19 河北建筑工程学院 Pumice straw lightweight aggregate concrete and preparation method thereof
CN102786246A (en) * 2012-08-31 2012-11-21 句容宁武高新技术发展有限公司 Concrete antifreezer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105174831A (en) * 2015-07-29 2015-12-23 安徽砼宇特构科技有限公司 Antifreezing concrete and preparation method therefor
CN107473650A (en) * 2017-08-11 2017-12-15 汤始建华建材(苏州)有限公司 A kind of anti-freezing type concrete
CN107382220A (en) * 2017-09-06 2017-11-24 陈毅忠 A kind of frost-resistant concrete

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C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C41 Transfer of patent application or patent right or utility model
CB03 Change of inventor or designer information

Inventor after: Mu Xiaojun

Inventor before: Tang Jianjun

Inventor before: Yang Zhilai

Inventor before: Huang Guoping

Inventor before: Gu Yongxin

Inventor before: Xu Haibin

COR Change of bibliographic data
TR01 Transfer of patent right

Effective date of registration: 20160420

Address after: 212216 Jiangsu province Yangzhong Youfang Town Industrial Park of new materials

Patentee after: Jiangsu TengXiang Concrete Co. Ltd.

Address before: Suzhou City, Jiangsu province 215600 Zhangjiagang City Jin Fengzhen Hexing Street Village red audio-visual company in Mars

Patentee before: Shan Mu new material technology development corporation, Ltd. of Zhangjagang City

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160203

Termination date: 20170929

CF01 Termination of patent right due to non-payment of annual fee