CN103493238A - Vacuum-tube type dye-sensitized solar cells - Google Patents
Vacuum-tube type dye-sensitized solar cells Download PDFInfo
- Publication number
- CN103493238A CN103493238A CN201280018276.1A CN201280018276A CN103493238A CN 103493238 A CN103493238 A CN 103493238A CN 201280018276 A CN201280018276 A CN 201280018276A CN 103493238 A CN103493238 A CN 103493238A
- Authority
- CN
- China
- Prior art keywords
- heat
- vacuum tube
- vacuum
- dssc
- sensitized solar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000694 effects Effects 0.000 claims abstract description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229920002521 macromolecule Polymers 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 abstract 1
- 206010070834 Sensitisation Diseases 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 230000008313 sensitization Effects 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 230000005611 electricity Effects 0.000 description 6
- 238000010248 power generation Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2004—Light-sensitive devices characterised by the electrolyte, e.g. comprising an organic electrolyte
- H01G9/2009—Solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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- Power Engineering (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- General Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
Abstract
The present invention relates to a vacuum-tube type dye-sensitized solar cell, and is characterized by the effect of achieving heated water and energy generation in a single tube with a combination vacuum-tube type dye-sensitized solar cell, whereas up to the present, separate manufacture and operations were required for separate water heating in a vacuum tube and energy generation with a dye-sensitized solar cell. Thus, the area required per unit is reduced, which maximizes efficiency and simplifies the structure of facilities.
Description
Technical field
The present invention relates to a kind of DSSC, more specifically, relate to a kind of in conjunction with solar heat vacuum tube heat collector and DSSC the electron tubes type DSSC with the generating effect that can obtain solar heat and DSSC simultaneously.
Background technology
Usually, use plate or vacuum tube type in order to assemble solar heat, but, because the heat efficiency of vacuum tube type is higher, therefore generally use vacuum tube type.
The universal silicon solar cell module in order to utilize solar power generation, but the cheap and convenient DSSC of manufacturing in research how, simultaneously, the high product of various efficiency is in city's mid-sales.
In order to apply flexibly described technology, described product needed is exposed under sunlight, and therefore certain limitation is arranged.The silicon module needs ground, wide field, and cost of equipment is also high.But generating efficiency only has 12%～14% and efficiency is low.Although its efficiency of solar heat vacuum tube, up to more than 90%, is difficult to accumulation of heat, and can not generate electricity.
Therefore, in order to obtain the highest efficiency in the environment limited and unit are, need to assemble solar heat and for the device of the mixed type of solar power generation.
Summary of the invention
The object of the invention is to, effectively utilize solar heat and sunlight, thereby can obtain the thermal effect of the vacuum tube that the heat efficiency is high and the generating effect of DSSC simultaneously.
The generating efficiency of unit are inner dye sensitization solar battery is 10% left and right, but the heat efficiency of solar heat vacuum tube surpasses 90%.Therefore, preferably, can obtain the heat of electric power and the vacuum tube of DSSC simultaneously.
For this reason, provide a kind of and paste DSSC and obtain the generating effect at vacuum tube, obtain the method for the thermal effect of vacuum tube simultaneously.
The object of the invention is to, obtain the generating effect of DSSC and the thermal effect of vacuum tube in unit are simultaneously.
Smear dye sensitization coating (TiO2) at the existing carbon coating of the inner replacement of vacuum tube, thereby obtain first the generating effect.
The generating efficiency of DSSC, wherein 10% left and right is for being obtained by visible light, and residue is stayed the inside of vacuum tube with infrared heat, therefore, can be used as the thermal source of hot water or heat pipe and use.
DSSC comprises: in thermal endurance, chemical resistance and transparency, high macromolecule mantle is smeared the nanometer platinum that transparency is high and is manufactured the step of one-time electrode; Smear dye sensitization coating (TiO2), then smear polymer solid electrolyte and platinum and manufacture the step of second electrode.Then, the light (infrared ray) of smearing carbon advance so that see through vacuum tube on second electrode is converted to heat, then, smears the macromolecule mantle.
By the thin film fabrication of the DSSC of manufacture, be the circular inside that sticks on vacuum tube with bonding agent.
Only there is the generating efficiency of 10% left and right in the past, but by the present invention, at a vacuum tube, can to obtain solar heat and solar power generation effect simultaneously, to use wide area in order generating electricity, heat can be in unit are, also obtained simultaneously, thereby the efficiency of sunlight and solar heat can be greatly improved.
By the double effects of solar heat and solar power generation, can simplified apparatus, save producing cost and cost of equipment simultaneously, thereby can reduce the financial burden.
The accompanying drawing explanation
Fig. 1 is the structural map at the state of heat pipe type vacuum tube combination dye sensitization solar battery.
Fig. 2 is the top structural map of vacuum tube.
Fig. 3 is the structural map of DSSC.
In figure:
100: positive electricity pond, dye sensitization sky, 200: vacuum tube, 300: heat pipe heat radiation section, 301: the heat collector tube wing.
Embodiment
Present invention will be described in detail with reference to the accompanying.
Fig. 1 is the structural map at vacuum tube 200 combination dye sensitization solar batteries 100.Existing vacuum tube 200 is coated with carbon in inside, when the infrared ray of solar heat sees through vacuum tube 200 when interior from outside, and contact carbon film and be converted to heat, now, heat can not be discharged into the outside of vacuum tube 200.Thereby can pass through hot media (water, salt solution, heat pipe etc.) and utilize heat.
The bonding DSSC 100 in the inside of vacuum tube 200.
DSSC 100 comprises: the mantle 103 in permeability, thermal endurance, chemical resistance in strong macromolecule mantle 103,109 is smeared the platinum of transparent nano molecular and is manufactured the step of one-time electrode terminal 101; Smear the dye sensitization coating 105(TiO2 of nano-scale on described primary electron terminal), the step of then smearing polymer solid electrolyte 106; And smear platinum and manufacture the step of second electrode 107 on polymer solid electrolyte.Smear carbon 108 on second electrode 107, thereby make the light advanced through vacuum tube be converted to heat.The heat collection function of the vacuum tube by water-tube or heat pipe type utilizes described heat.
The electricity sent from DSSC is connected in transducer etc. by one-time electrode terminal 101 and second electrode terminal 102, thereby produces electricity.
Can obtain hot water effect and the generating effect of solar heat at vacuum tube 200 combination dye sensitization solar batteries 100 simultaneously in identical unit are, thereby reduce the area of equipment, save cost of equipment.
The industrial utilization possibility
The generating efficiency of in the past only having 10% left and right, but by the present invention, at a vacuum tube, can to obtain solar heat and solar power generation effect simultaneously, to use wide area in order generating electricity, heat can be in unit are, also obtained simultaneously, thereby the efficiency of sunlight and solar heat can be greatly improved.
By the double effects of solar heat and solar power generation, can simplified apparatus, save producing cost and cost of equipment simultaneously, thereby can reduce the financial burden.
Claims (2)
1. a vacuum tube type DSSC, it is characterized in that, make DSSC and stick on the inside of vacuum tube (200) with circle on macromolecule membrane, thereby can obtain by the generating effect of visible light with by ultrared Heat-collecting effect simultaneously.
2. vacuum tube type DSSC according to claim 1, is characterized in that, is coated with carbon film (108) and the infrared ray of sunlight is converted to heat on second electrode, thereby can pass through hot media or heat collector tube.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020110021721A KR101074942B1 (en) | 2011-03-11 | 2011-03-11 | Vacuum-tube type dye-sensitized solar cell |
| KR10-2011-0021721 | 2011-03-11 | ||
| PCT/KR2012/001280 WO2012124906A2 (en) | 2011-03-11 | 2012-02-20 | Vacuum-tube type dye-sensitized solar cells |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103493238A true CN103493238A (en) | 2014-01-01 |
Family
ID=45033057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280018276.1A Pending CN103493238A (en) | 2011-03-11 | 2012-02-20 | Vacuum-tube type dye-sensitized solar cells |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR101074942B1 (en) |
| CN (1) | CN103493238A (en) |
| WO (1) | WO2012124906A2 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101728996A (en) * | 2009-11-06 | 2010-06-09 | 电子科技大学 | Composite power source device based on solar battery and thermobattery |
| KR20100098224A (en) * | 2009-02-27 | 2010-09-06 | 경상대학교산학협력단 | Solar battery, battery using the same, and method for manufacturing solar battery |
| CN201589441U (en) * | 2009-11-16 | 2010-09-22 | 索尼株式会社 | Vacuum tube type heat collection power generation unit and solar water heater |
| KR20110014447A (en) * | 2009-08-05 | 2011-02-11 | 삼성전자주식회사 | Solar energy utilizing apparatus and method of manufacturing the same |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100368135B1 (en) | 2000-08-12 | 2003-01-15 | 한국에너지기술연구원 | Evacuated tube solar collector for industry use |
| KR100755505B1 (en) | 2005-06-29 | 2007-09-04 | 황우성 | Photovoltaic-Thermal Energy Cogeneration System |
| KR101066230B1 (en) * | 2009-10-12 | 2011-09-21 | 주식회사 티지에너지 | A Preparation Method of DSSC |
-
2011
- 2011-03-11 KR KR1020110021721A patent/KR101074942B1/en not_active IP Right Cessation
-
2012
- 2012-02-20 WO PCT/KR2012/001280 patent/WO2012124906A2/en active Application Filing
- 2012-02-20 CN CN201280018276.1A patent/CN103493238A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20100098224A (en) * | 2009-02-27 | 2010-09-06 | 경상대학교산학협력단 | Solar battery, battery using the same, and method for manufacturing solar battery |
| KR20110014447A (en) * | 2009-08-05 | 2011-02-11 | 삼성전자주식회사 | Solar energy utilizing apparatus and method of manufacturing the same |
| CN101728996A (en) * | 2009-11-06 | 2010-06-09 | 电子科技大学 | Composite power source device based on solar battery and thermobattery |
| CN201589441U (en) * | 2009-11-16 | 2010-09-22 | 索尼株式会社 | Vacuum tube type heat collection power generation unit and solar water heater |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012124906A9 (en) | 2013-03-14 |
| KR101074942B1 (en) | 2011-10-18 |
| WO2012124906A3 (en) | 2012-12-27 |
| WO2012124906A2 (en) | 2012-09-20 |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140101 |