CN103480555A - Indoor spraying process for liquid photocatalyst spray - Google Patents

Indoor spraying process for liquid photocatalyst spray Download PDF

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Publication number
CN103480555A
CN103480555A CN201210195207.XA CN201210195207A CN103480555A CN 103480555 A CN103480555 A CN 103480555A CN 201210195207 A CN201210195207 A CN 201210195207A CN 103480555 A CN103480555 A CN 103480555A
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China
Prior art keywords
photocatalyst
spray
spraying
spray gun
hydrojet
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Pending
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CN201210195207.XA
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Chinese (zh)
Inventor
梁世超
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Beijing Wound Is Environmental Protection Technology Co Ltd All Over World
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Beijing Wound Is Environmental Protection Technology Co Ltd All Over World
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Priority to CN201210195207.XA priority Critical patent/CN103480555A/en
Publication of CN103480555A publication Critical patent/CN103480555A/en
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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention provides a method for preparing photocatalyst spray capable of effectively using visible light and stabilizing the long-term purifying effect, and a spraying process of the spray. The photocatalyst spray consists of 1-2 percent of modified nano-TiO2 photocatalyst, 0.5-1 percent of anti-bacterial agent, 30-35 percent of plant essence, 1-2 percent of chelating agent and 60-65 percent of water, wherein the modified nano-TiO2 photocatalyst is prepared by modifying doped precious metals. According to the photocatalyst spray, the photocatalytic performance continually plays a role in purifying under the condition of dark light source and even no illumination in a certain period of time due to doping of an appropriate quantity of noble metals. The construction process comprises the following steps: preserving noble wearable articles, moving to leave a vacant place, cleaning, shielding for protecting, high-temperature fumigation, spraying and ventilation. The adopted spraying process is suitable for spraying the photocatalyst spray onto the surfaces of different indoor articles, so that the problems of waste of the spray, damages to the articles and the like are solved.

Description

A kind of indoor spraying coating process of liquid photocatalyst hydrojet
Technical field
The present invention relates to a kind of spraying coating process of administering the liquid photocatalyst hydrojet of indoor environmental pollution
Background technology
Photocatalyst is a kind of versatile photochemical catalyst, powerful at aspects such as air cleaning, deodorizing, sterilization, antifouling, purification of water qualitys.This is, because photocatalyst can utilize luminous energy, water, oxygen molecule, organic substance is converted into to carbon dioxide.In this process, photocatalyst only plays catalytic action, and any variation does not occur for itself.Therefore, photocatalyst is material desirable in current indoor air purification.Photocatalyst is applied to indoor air purification and makes the organic substance that the photocatalyst hydrojet can be removed the generations such as interior decoration effectively, as formaldehyde, benzene, toluene etc.Current photocatalyst material mostly is the dissolved colloidal state photocatalyst, the photocatalyst of this form, and the crystalline structure of restive nano titanium oxide, photocatalysis performance is limited, is difficult to effectively adhere on various base materials, not too possesses long-term light stable catalytic capability; Some also has corrosiveness to base material, how not to possess long-term photocatalysis performance.Therefore, finding a kind of photocatalyst hydrojet that can be applicable to better Indoor Environment Treatment is the key that the application photocatalyst carries out indoor improvement.In addition, the clean-up effect of photocatalyst not only is subject to the impact of nature, also is subject to the impact of spray coating constructing technique.So, find a kind of spraying coating process of the hydrojet of photocatalyst preferably, can bring into play the effectiveness of photocatalyst aspect environmental improvement, can also improve the clean-up effect of air pollutants, thereby reach the purpose of administering indoor environmental pollution.
Summary of the invention:
The object of the present invention is to provide and a kind ofly can effectively utilize visible ray, stablize the preparation method of photocatalyst hydrojet of long-term clean-up effect and the spraying coating process of hydrojet, this technique adopts the spraying coating process that is applicable to different article surfaces to meet the purification requirement to different article surfaces by the mode of spray gun spraying.
For achieving the above object, the proportioning (mass percent) of the photocatalyst hydrojet of employing is as follows in the present invention:
Modified Nano TiO 2photocatalyst: 1-2%; Antiseptic: 0.5-1%; Plant essence liquid: 30-35%; Chelating agent: 1-2%; Water: 60-65%
Nano-TiO wherein 2photocatalyst raw material proportioning (mass percent) forms:
Pure nano-TiO 2: 20-30%; Precious metal powder: 2-10%; Water: 60-78%
Particularly precious metal powder is Ag, Au, Pt, Ru, Rh, Pd, one or more in Ir or Re.
For achieving the above object, the spraying coating process of the photocatalyst hydrojet of employing is as follows in the present invention:
(1) valuable fragile goods keeping: valuable fragile goods is deposited to keeping, appliance cut-off;
(2) displacement is soared: the article of furniture that will affect the scope of operation is slightly done to move with convenient construction, and the inner thing of various bins is removed to concentrate and place, and as the movable wardrobe back side, constructs and wardrobe must be moved away to distance more than metope 50cm so that back side construction;
(3) decontamination is clean: various scope of operations surface dirt is wiped with rag, and floating dust purges by the spray gun large tracts of land;
(4) block protection: various metal hinges, hinge, handle, metal finish, decorative object and cigarette sense etc. wrap up blocking sprayed product with protection things such as adhesive tape or newspapers, prevent direct contact; Valuables, electrical equipment, light fixture etc. and other do not need to administer article and block with the tarpaulin parcel, and lay the air compressor machine below need ground cushion protection etc.
(5) high temperature is stifling: use the high temperature gassing machine to be fumigated furniture, carpet etc.
(6) spraying: the photocatalyst hydrojet is placed in spray gun, spray gun should with kept vertical by sprayed surface, the spray gun moving parallel is in by sprayed surface.For wooden boards class article, spray gun should with kept the distance of 10-15cm by spray-coating surface, the speed that spray gun moves is 0.5m/s, quantity for spray is 30ml/m 2; The article that need the large tracts of land spraying for the article with high light outer surface and wallpaper, floor, cloth art etc., spray gun should with kept the distance of 30cm by spray-coating surface, the speed that spray gun moves is 1m/s, quantity for spray is 20ml/m 2.
(7) ventilation or forced ventilation: spraying finishes after 2 hours to carry out gravity-flow ventilation to eliminate product, strengthening regulation effect, and as poor as the gravity-flow ventilation condition (as basement or closed environment) can adopt the blower fan intensified ventilation in case of necessity.
Advantage of the present invention is:
1, the photocatalyst that the present invention adopts is the nano-TiO that adopts the catalysis material activation technique to prepare 2, the appropriate noble metal that adulterates, effectively shorten activation energy, extends the duration of load application in electronics and hole, guarantees photocatalysis performance in the situation that light source is dim, the unglazed photograph of certain hour section even, continues to bring into play its purification function.
2, the spraying method that the present invention adopts is applicable to the spraying of photocatalyst hydrojet to article surface in different chamber, has overcome the waste of hydrojet and to the problems such as infringement of article.
The specific embodiment:
The present invention is the photocatalyst hydrojet that can strengthen the illumination utilization rate that adopts the catalysis material activation technique to prepare, and has solved current dissolved colloidal state photocatalyst poor adhesive force, the light source utilization rate is low, the photocatalysis effect time is shorter problem.The spraying coating process adopted can adapt to the spraying of the different article surfaces such as article of the needs large tracts of land sprayings such as wooden boards class article, the article with high light outer surface and wallpaper, floor, cloth art.
Example 1
1) modified Nano TiO of the present invention 2the photocatalyst raw material is prepared burden by following mass percent: pure nano-TiO 2: 20%; Silver powder: 6%; Water: 74%
2) by 20% pure nano titanium oxide and 6% silver powder, add in 74% water, then the speed with 800~1000r/min stirs 30min, more than standing 2h, then by its oven dry.
3) by powder roasting 1h in the Muffle furnace of 500 ℃ of drying, be cooled to room temperature in stove.
4) by the powder after roasting through grinding or air-flow crushing, obtain the dopen Nano TiO after modification 2powder.
5) photocatalyst hydrojet raw material of the present invention is prepared burden by following mass percent: modified Nano TiO 2photocatalyst: 1%; Antiseptic: 1%; Plant essence liquid: 35%; Chelating agent: 1%; Water 62%
6) 1% antiseptic is added in 62% water, be mixed with the antimicrobial energy aqueous solution;
7) by the nano-TiO of antimicrobial energy water and 1% 2after photocatalyst and 1% chelating agent powder mix, inject mixer and carry out dispersed;
8) after homogenous disperse finishes, add 35% plant essence liquid to be mixed, be uniformly mixed liquid, discharging is the photocatalyst hydrojet.
The indoor furniture article are shifted soar, surface cleaning, high temperature stifling after, will in spray gun, add hydrojet by wooden boards class article, spray gun should with kept the distance of 10-15cm by spray-coating surface, the speed that spray gun moves is 0.5m/s, quantity for spray is 30ml/m 2; Having the article of high light outer surface and wallpaper, floor, cloth art etc. needs the article of large tracts of land spraying, spray gun should with kept the distance of 30cm by spray-coating surface, the speed that spray gun moves is 1m/s, quantity for spray is 20ml/m 2sprayed.Finally, to being ventilated through the indoor environment of administering.
Example 2
1) modified Nano TiO of the present invention 2the photocatalyst raw material is prepared burden by following mass percent: pure nano-TiO 2: 25%; Silver powder: 8%; Water: 67%
2) by 25% pure nano titanium oxide and 8% silver powder, add in 67% water, then the speed with 800~1000r/min stirs 30min, more than standing 2h, then by its oven dry.
3) by powder roasting 1h in the Muffle furnace of 500 ℃ of drying, be cooled to room temperature in stove.
4) by the powder after roasting through grinding or air-flow crushing, obtain the dopen Nano TiO after modification 2powder.
5) photocatalyst hydrojet raw material of the present invention is prepared burden by following mass percent: modified Nano TiO 2photocatalyst: 2%; Antiseptic: 0.5%; Plant essence liquid: 33.5%; Chelating agent: 1%; Water 63%
6) 0.5% antiseptic is added in 63% water, be mixed with the antimicrobial energy aqueous solution;
7) by the nano-TiO of antimicrobial energy water and 2% 2after photocatalyst and 1% chelating agent powder mix, inject mixer and carry out dispersed;
8) after homogenous disperse finishes, add 33.5% plant essence liquid to be mixed, be uniformly mixed liquid, discharging is the photocatalyst hydrojet.
The indoor furniture article are shifted soar, surface cleaning, high temperature stifling after, will in spray gun, add hydrojet by wooden boards class article, spray gun should with kept the distance of 10-15cm by spray-coating surface, the speed that spray gun moves is 0.5m/s, quantity for spray is 30ml/m 2; Having the article of high light outer surface and wallpaper, floor, cloth art etc. needs the article of large tracts of land spraying, spray gun should with kept the distance of 30cm by spray-coating surface, the speed that spray gun moves is 1m/s, quantity for spray is 20ml/m 2sprayed.Finally, to being ventilated through the indoor environment of administering.

Claims (5)

1. the spraying coating process of a photocatalyst hydrojet, it is characterized in that: it is comprised of following steps:
(1) valuable fragile goods keeping: valuable fragile goods is deposited to keeping, appliance cut-off;
(2) displacement is soared: the article of furniture that will affect the scope of operation is slightly done to move with convenient construction, and the inner thing of various bins is removed to concentrate and place, and constructs and wardrobe must be moved away to distance more than metope 50cm so that back side construction in the movable wardrobe back side;
(3) decontamination is clean: various scope of operations surface dirt is wiped with rag, and floating dust purges by the spray gun large tracts of land;
(4) block protection: various metal hinges, hinge, handle, metal finish, decorative object and cigarette sense etc. wrap up blocking sprayed product with protection things such as adhesive tape or newspapers, prevent direct contact; Valuables, electrical equipment, light fixture etc. and other do not need to administer article and block with the tarpaulin parcel, and lay the air compressor machine below need ground cushion protection etc.
(5) high temperature is stifling: use the high temperature gassing machine to be fumigated furniture, carpet etc.
(6) spraying: the photocatalyst hydrojet is placed in spray gun, spray gun should with kept vertical by sprayed surface, the spray gun moving parallel is in by sprayed surface.
(7) ventilation or forced ventilation: spraying finishes after 2 hours to carry out gravity-flow ventilation to eliminate product, strengthening regulation effect, and as poor as the gravity-flow ventilation condition (as basement or closed environment) can adopt the blower fan intensified ventilation in case of necessity.
2. the spraying coating process of photocatalyst hydrojet as claimed in claim 1, it is characterized in that described step (6) spraying: for wooden boards class article, spray gun should with kept the distance of 10-15cm by spray-coating surface, the speed that spray gun moves is 0.5m/s, quantity for spray is 30ml/m 2; . need the article of large tracts of land spraying for the article with high light outer surface and wallpaper, floor, cloth art etc., spray gun should with kept the distance of 30cm by spray-coating surface, the speed that spray gun moves is 1m/s, quantity for spray is 20ml/m 2.
3. the spraying coating process of photocatalyst hydrojet as claimed in claim 1, is characterized in that described step (6) spraying, and the raw material percentage (mass percent) of described photocatalyst hydrojet is: modified Nano TiO 2photocatalyst: 1-2%; Antiseptic: 0.5-1%; Plant essence liquid: 30-35%; Chelating agent: 1-2%; Water: 60-65%.
4. modified Nano TiO as claimed in claim 2 2photocatalyst, is characterized in that described raw material percentage (mass percent) is: pure nano-TiO 2: 20-30%; Precious metal powder: 2-10%; Water: 60-78%.
5. noble metal as claimed in claim 3, is characterized in that described noble metal refers to as Ag, Au, Pt, Ru, Rh, Pd, one or more in Ir or Re.
CN201210195207.XA 2012-06-14 2012-06-14 Indoor spraying process for liquid photocatalyst spray Pending CN103480555A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104957806A (en) * 2015-07-13 2015-10-07 鞍山瀚盛科技有限公司 Sterilizing anti-viral odor-removing reusable medical photocatalyst protective mask
CN105733321A (en) * 2015-10-10 2016-07-06 杭州职业技术学院 Multimode nano-photocatalyst spray coating agent and production method thereof
CN106189390A (en) * 2016-07-20 2016-12-07 王玲 A kind of photocatalyst of titanium dioxide coating and film thereof, and preparation method
CN106733569A (en) * 2015-11-20 2017-05-31 深圳市格绿丝纳米科技有限公司 A kind of photocatalyst global field automatic spraying technique
CN110592934A (en) * 2019-09-25 2019-12-20 株洲市美力迪实业有限公司 Photocatalyst product and preparation method thereof
CN114904389A (en) * 2022-05-13 2022-08-16 成都金螺科技有限公司 Modern indoor air pollution treatment method

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104957806A (en) * 2015-07-13 2015-10-07 鞍山瀚盛科技有限公司 Sterilizing anti-viral odor-removing reusable medical photocatalyst protective mask
CN105733321A (en) * 2015-10-10 2016-07-06 杭州职业技术学院 Multimode nano-photocatalyst spray coating agent and production method thereof
CN105733321B (en) * 2015-10-10 2017-12-26 杭州职业技术学院 Multi-mode nano photo-catalytic spray liniment and its production method
CN106733569A (en) * 2015-11-20 2017-05-31 深圳市格绿丝纳米科技有限公司 A kind of photocatalyst global field automatic spraying technique
CN106189390A (en) * 2016-07-20 2016-12-07 王玲 A kind of photocatalyst of titanium dioxide coating and film thereof, and preparation method
CN106189390B (en) * 2016-07-20 2019-05-10 王玲 A kind of photocatalyst of titanium dioxide coating and its film and preparation method
CN110592934A (en) * 2019-09-25 2019-12-20 株洲市美力迪实业有限公司 Photocatalyst product and preparation method thereof
CN114904389A (en) * 2022-05-13 2022-08-16 成都金螺科技有限公司 Modern indoor air pollution treatment method

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Application publication date: 20140101