CN103467843B - A kind of PP antibiotic plastic - Google Patents
A kind of PP antibiotic plastic Download PDFInfo
- Publication number
- CN103467843B CN103467843B CN201310371759.6A CN201310371759A CN103467843B CN 103467843 B CN103467843 B CN 103467843B CN 201310371759 A CN201310371759 A CN 201310371759A CN 103467843 B CN103467843 B CN 103467843B
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- Prior art keywords
- mass parts
- antibiotic plastic
- zirconium phosphate
- plastic
- good
- Prior art date
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- 229920003023 plastic Polymers 0.000 title claims abstract description 24
- 239000004033 plastic Substances 0.000 title claims abstract description 24
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 15
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims abstract description 8
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims abstract description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052599 brucite Inorganic materials 0.000 claims abstract description 4
- 229910052802 copper Inorganic materials 0.000 claims abstract description 4
- 239000010949 copper Substances 0.000 claims abstract description 4
- 239000013078 crystal Substances 0.000 claims abstract description 4
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims abstract description 4
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims abstract description 4
- -1 phthalate anhydride Chemical class 0.000 claims abstract description 4
- 229910052709 silver Inorganic materials 0.000 claims abstract description 4
- 239000004332 silver Substances 0.000 claims abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 9
- 230000000845 anti-microbial effect Effects 0.000 abstract description 4
- 230000007774 longterm Effects 0.000 abstract description 2
- 230000002688 persistence Effects 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of PP antibiotic plastic, be made up of following weight parts component: 150-155 mass parts PP, 5-10 mass parts brucite, 10-20 mass parts GW-540,10-15 mass parts POE, 10-13 mass parts ferrocene, 7-9 mass parts phthalate anhydride, 10-15 mass parts melamine cyanurate, 7-9 mass parts silver-loaded zirconium phosphate, the copper-loaded zirconium phosphate of 10-15 mass parts, 10 mass parts potassium titanate crystal whiskers and 5-8 mass parts organotin.The PP antibiotic plastic that the present invention obtains has good antibacterial, and consumption seldom just obviously can play anti-microbial effect; To get well with the consistency of resin simultaneously, not move in plastics, do not separate out, be not extracted; Be easy in the plastic be uniformly dispersed, good weatherability, persistence is good, makes plastics have long-term germ resistance.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of PP antibiotic plastic.
Technical background
Along with the development and progress of society and the raising day by day of living standard, people are to life, Working environment, and especially the requirement of hygienic condition is more and more higher.Because plastics have the advantages such as light weight, not corrosion, good insulating, so will plastics be used in a lot of links of household electrical appliances production.Such as, but in daily life, quite a few unwanted bacteria exists on the surface of plastics and breeds, and: phone, washing machine, computer, refrigerator, electric switch etc., and causes various disease by contacting; Therefore, in life, people inevitably will touch the microorganisms such as each bacterioid, mould, all can become bacterial contamination source and pathophoresis source.But along with people are to continuous enhancing that is healthy and environmental consciousness, to the demand contacting household electrical appliance plastic components frequently in daily life and propose " antibacterial, sterilization ", the various household appliances used during this just requires us to live have effect of antibacterial and mouldproof.
Also there is no antibiotic plastic PP Pipe Compound at present, household electric appliances are all add antiseptic-germicide in the feed to prepare antibiotic plastic, its anti-microbial effect is formed by the slow releasing of antiseptic-germicide, along with the release of antiseptic-germicide, anti-microbial activity is more and more less, antiseptic-germicide easily lost efficacy and did not reach antibacterial object, and antibacterial release can cause the pollution of environment.Product cost obtained is like this high, quality is unstable, although have antibacterial, antibacterial range is little, the time length is short and do not have mildew-resistant effect.
Household electrical appliances antibiotic plastic has a good application prospect, along with the formal appearance of relative national standards GB21551.2-2010 " particular requirement of antibacterial, degerming, the purification function anti-biotic material of family expenses and similar applications electrical equipment ", antibiotic plastic also will be more wide in the prospect of household electrical appliances market.
Summary of the invention
For above shortcomings in prior art, the object of the invention is to provide a kind of PP antibiotic plastic.
The object of the invention is to be achieved through the following technical solutions: a kind of PP antibiotic plastic, is made up of following weight parts component: 150-155 mass parts PP, 5-10 mass parts brucite, 10-20 mass parts GW-540,10-15 mass parts POE, 10-13 mass parts ferrocene, 7-9 mass parts phthalate anhydride, 10-15 mass parts melamine cyanurate, 7-9 mass parts silver-loaded zirconium phosphate, the copper-loaded zirconium phosphate of 10-15 mass parts, 10 mass parts potassium titanate crystal whiskers and 5-8 mass parts organotin.
The beneficial effect that the present invention has: the PP antibiotic plastic that the present invention obtains has good antibacterial, consumption seldom just obviously can play anti-microbial effect; To get well with the consistency of resin simultaneously, not move in plastics, do not separate out, be not extracted; Be easy in the plastic be uniformly dispersed, good weatherability, persistence is good, makes plastics have long-term germ resistance.
Embodiment
Example of the present invention can not limit the present invention to explanation of the present invention, and any change in the implication suitable with the present invention and scope and adjustment, all should think within the scope of the invention.
embodiment 1
The preparation of PP antibiotic plastic: 150-155 mass parts PP, 5-10 mass parts brucite, 10-20 mass parts GW-540, 10-15 mass parts POE, 10-13 mass parts ferrocene, 7-9 mass parts phthalate anhydride, 10-15 mass parts melamine cyanurate, 7-9 mass parts silver-loaded zirconium phosphate, the copper-loaded zirconium phosphate of 10-15 mass parts, stirrer is put in 10 mass parts potassium titanate crystal whiskers and the mixing of 5-8 mass parts organotin, put into twin screw extruder after stirring and plastify granulation, temperature is 195 DEG C, 200 DEG C, 205 DEG C, 210 DEG C, 205 DEG C, screw speed is 70r/min, pellet injection moulding process machine-shaping batten, temperature is 170 DEG C, 185 DEG C, 195 DEG C, 190 DEG C.The salient features of the material that the present embodiment is prepared is as follows: tensile strength MPa(GB/T1040-2006): 35-36, elongation at break %(GB/T1040-2006): 11-13; Shock strength kJ/m
2(GB/T1043-2008): 12.0; Flexural strength MPa(GB/T9341-2000): 42-45; Detect through the experiment of industry internal standard, result is as follows: reach 97.6% to colibacillary 24 hours sterilizing rates; 98.9% is reached to 24 hours sterilizing rates of streptococcus aureus.
Claims (1)
1. a PP antibiotic plastic, is characterized in that being made up of following weight parts component: 150-155 mass parts PP, 5-10 mass parts brucite, 10-20 mass parts GW-540,10-15 mass parts POE, 10-13 mass parts ferrocene, 7-9 mass parts phthalate anhydride, 10-15 mass parts melamine cyanurate, 7-9 mass parts silver-loaded zirconium phosphate, the copper-loaded zirconium phosphate of 10-15 mass parts, 10 mass parts potassium titanate crystal whiskers and 5-8 mass parts organotin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310371759.6A CN103467843B (en) | 2013-08-23 | 2013-08-23 | A kind of PP antibiotic plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310371759.6A CN103467843B (en) | 2013-08-23 | 2013-08-23 | A kind of PP antibiotic plastic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103467843A CN103467843A (en) | 2013-12-25 |
| CN103467843B true CN103467843B (en) | 2016-02-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310371759.6A Active CN103467843B (en) | 2013-08-23 | 2013-08-23 | A kind of PP antibiotic plastic |
Country Status (1)
| Country | Link |
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| CN (1) | CN103467843B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103897268B (en) * | 2014-03-13 | 2016-08-17 | 江苏康非特动力科技有限公司 | Medical antibacterial toughness reinforcing antistatic PP composite material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101108906A (en) * | 2007-08-22 | 2008-01-23 | 上海景鹏日用品有限公司 | Polypropylene plastics and manufacturing method thereof |
| CN103012939A (en) * | 2012-09-29 | 2013-04-03 | 深圳市沃尔核材股份有限公司 | Ultraviolet light cross-linking heat-shrinkage pipe material and method for producing ultraviolet light cross-linking heat-shrinkage pipe |
-
2013
- 2013-08-23 CN CN201310371759.6A patent/CN103467843B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101108906A (en) * | 2007-08-22 | 2008-01-23 | 上海景鹏日用品有限公司 | Polypropylene plastics and manufacturing method thereof |
| CN103012939A (en) * | 2012-09-29 | 2013-04-03 | 深圳市沃尔核材股份有限公司 | Ultraviolet light cross-linking heat-shrinkage pipe material and method for producing ultraviolet light cross-linking heat-shrinkage pipe |
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| Publication number | Publication date |
|---|---|
| CN103467843A (en) | 2013-12-25 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Xu Wenjie Inventor after: Xu Youjiang Inventor before: Xiao Weirong |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151224 Address after: 362241 Fujian city of Jinjiang province Longhu Zhen Wu Keng Industrial Zone No. 301 Applicant after: Tian Yongmao Address before: Wujiang District of Suzhou City, Jiangsu province 215212 Lili Town Industrial Park of arch bridge Applicant before: Wujiang Tianyuan Plastic Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170215 Address after: 362241 Jinjiang, China Town, Longhu, China pit Industrial Zone Patentee after: Jinjiang Hengsheng Toy Co., Ltd. Address before: 362241 Fujian city of Jinjiang province Longhu Zhen Wu Keng Industrial Zone No. 301 Patentee before: Tian Yongmao |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170407 Address after: 362200 Quanzhou, Fujian, Longhu Town, Wu Hang Industrial Zone, No. 301 Patentee after: Tian Yongmao Address before: 362241 Jinjiang, China Town, Longhu, China pit Industrial Zone Patentee before: Jinjiang Hengsheng Toy Co., Ltd. |