CN103451993A - Attapulgite clay papermaking additive and preparation method of same - Google Patents
Attapulgite clay papermaking additive and preparation method of same Download PDFInfo
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- CN103451993A CN103451993A CN2013103305276A CN201310330527A CN103451993A CN 103451993 A CN103451993 A CN 103451993A CN 2013103305276 A CN2013103305276 A CN 2013103305276A CN 201310330527 A CN201310330527 A CN 201310330527A CN 103451993 A CN103451993 A CN 103451993A
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- attapulgite
- attapulgite clay
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Abstract
The invention discloses an attapulgite clay papermaking additive and a preparation method of the same. The attapulgite clay papermaking additive is prepared from the following raw materials in parts by weight: 30-50 parts of attapulgite, 15-20 parts of kaolin, 5-10 parts of calcium lignosulphonate, 4-8 parts of triethanolamine, 1-2 parts of Bis(P,P-bis-ethylhexyl diphosphato)ethanediolato titanate, 10-15 parts of polyacrylamide, 2-3 parts of emulgator MS-903, 3-4 parts of carboxymethylcellulose, 1-3 parts of sodium dodecyl benzene sulfonate, 1-2 parts of urotropin, 3-5 parts of sodium hexametaphosphate, 2-3 parts of dodecyl dimethyl benzyl ammonium chloride, 1-2 parts of N, N'-ethylene bis stearamide, 0.5-1 part of dicyclohexylamine nitrite, 2-3 parts of tributyl phosphate, 5-10 parts of aluminum polychloride and 1-2 parts of 2-bromo-2-nitro-1, 3-propanediol. The papermaking additive provided by the invention can improve the viscosity of paper pulp raw material, reduce the use amount of the paper pulp, improve the fiber structure of the paper pulp and increase the tensile strength, the glossiness, the softness, the whiteness and the smoothness, and can effectively solve the phenomena of hair shedding and fluffing during the use process.
Description
Technical field
The present invention relates to a kind of attapulgite clay paper making additive and preparation method thereof, belong to the papermaking chemical product technical field.
Background technology
Paper industry is a kind of chemical process industry (CPI) that string is main raw material of take, the paper pulp raw material adhesion strength of being made by natural plant fibre is poor, the paper made easily falls hair, fluffing, therefore need to add the deficiency that appropriate paper making additive makes up natural fabric in paper production, meet the requirement of people to the many-sided performance of paper.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of attapulgite clay paper making additive and preparation method thereof, this auxiliary agent can improve paper pulp raw material viscosity, improves the fibre structure of paper pulp.
The technical solution used in the present invention is as follows:
A kind of attapulgite clay paper making additive, its raw material by following weight portion is made: attapulgite 30-50, kaolin 15-20, calcium lignosulfonate 5-10, triethanolamine 4-8, Di(dioctylpyrophosphato) ethylene titanate 1-2, polyacrylamide 10-15, emulsifying agent MS-903 2-3, carboxymethyl cellulose 3-4, neopelex 1-3, methenamine 1-2, calgon 3-5, dodecyl benzyl dimethyl ammonium chloride 2-3, N, N'-ethylene bis stearamide 1-2, nitrous acid bicyclohexylamine 0.5-1, tributyl phosphate 2-3, aluminium polychloride 5-10, the bromo-2-nitro-1 of 2-, ammediol 1-2.
The preparation method of attapulgite clay paper making additive, comprise the steps:
(1) getting attapulgite, kaolin, calcium lignosulfonate, triethanolamine, Di(dioctylpyrophosphato) ethylene titanate mixes, 4000-5000rpm speed lapping 10-15min, dry, then add the water making beating and make the slurries that concentration is 30-40%, add polyacrylamide, emulsifying agent MS-903, carboxymethyl cellulose, neopelex, methenamine, calgon and dodecyl benzyl dimethyl ammonium chloride, stir 20-30min under 1000-1500rpm speed, be spray dried to powder;
(2) the above-mentioned powder made is mixed with remaining raw material, ground the 200-300 mesh sieve, packing gets final product.
Beneficial effect of the present invention:
Paper making additive of the present invention be integrate wet strong, brighten, the papermaking chemical product composition of the functions such as retention, drainage, antibiotic, mildew-resistant, it can improve paper pulp raw material viscosity, reduce the paper pulp consumption, improve the fibre structure of paper pulp, increase tensile strength, glossiness, pliability and whiteness, planarization.Effectively hair, fluffiness are in use fallen in solution.
The specific embodiment
a kind of attapulgite clay paper making additive, its raw material by following weight (kg) is made: attapulgite 40, kaolin 18, calcium lignosulfonate 6, triethanolamine 5, Di(dioctylpyrophosphato) ethylene titanate 1.5, polyacrylamide 12, emulsifying agent MS-9032, carboxymethyl cellulose 3, neopelex 2, methenamine 1.5, calgon 4, dodecyl benzyl dimethyl ammonium chloride 2, N, N'-ethylene bis stearamide 1.5, nitrous acid bicyclohexylamine 0.8, tributyl phosphate 2, aluminium polychloride 8, the bromo-2-nitro-1 of 2-, ammediol 1.
The preparation method of attapulgite clay paper making additive, comprise the steps:
(1) getting attapulgite, kaolin, calcium lignosulfonate, triethanolamine, Di(dioctylpyrophosphato) ethylene titanate mixes, 5000rpm speed lapping 10min, dry, then add the water making beating and make the slurries that concentration is 40%, add polyacrylamide, emulsifying agent MS-903, carboxymethyl cellulose, neopelex, methenamine, calgon and dodecyl benzyl dimethyl ammonium chloride, stir 20min under 1500rpm speed, be spray dried to powder;
(2) the above-mentioned powder made is mixed with remaining raw material, ground 300 mesh sieves, packing gets final product.
In the production paper process, paper making additive of the present invention is added to 3-5 water dilution doubly, evenly add paper pulp, the paper made is more as shown in the table with the Performance Ratio of the paper of adding assistant not:
| Project | Add the paper of auxiliary agent of the present invention | Do not add the paper of auxiliary agent of the present invention |
| Whiteness (%) | 82.6 | 88.9 |
| Tensile strength (N/m) | 9.5 | 13.2 |
| Pliability (mN) | 65 | 8 |
| Eye (individual/m 2） | 8 | 3 |
| Dirt count (individual/m 2） | 62 | 35 |
Claims (2)
1. an attapulgite clay paper making additive, it is characterized in that, raw material by following weight portion is made: attapulgite 30-50, kaolin 15-20, calcium lignosulfonate 5-10, triethanolamine 4-8, Di(dioctylpyrophosphato) ethylene titanate 1-2, polyacrylamide 10-15, emulsifying agent MS-903 2-3, carboxymethyl cellulose 3-4, neopelex 1-3, methenamine 1-2, calgon 3-5, dodecyl benzyl dimethyl ammonium chloride 2-3, N, N'-ethylene bis stearamide 1-2, nitrous acid bicyclohexylamine 0.5-1, tributyl phosphate 2-3, aluminium polychloride 5-10, the bromo-2-nitro-1 of 2-, ammediol 1-2.
2. the preparation method of attapulgite clay paper making additive as claimed in claim 1, is characterized in that comprising the steps:
(1) getting attapulgite, kaolin, calcium lignosulfonate, triethanolamine, Di(dioctylpyrophosphato) ethylene titanate mixes, 4000-5000rpm speed lapping 10-15min, dry, then add the water making beating and make the slurries that concentration is 30-40%, add polyacrylamide, emulsifying agent MS-903, carboxymethyl cellulose, neopelex, methenamine, calgon and dodecyl benzyl dimethyl ammonium chloride, stir 20-30min under 1000-1500rpm speed, be spray dried to powder;
(2) the above-mentioned powder made is mixed with remaining raw material, ground the 200-300 mesh sieve, packing gets final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310330527.6A CN103451993B (en) | 2013-08-01 | 2013-08-01 | A kind of attapulgite clay paper making additive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310330527.6A CN103451993B (en) | 2013-08-01 | 2013-08-01 | A kind of attapulgite clay paper making additive and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103451993A true CN103451993A (en) | 2013-12-18 |
| CN103451993B CN103451993B (en) | 2015-10-28 |
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| CN201310330527.6A Active CN103451993B (en) | 2013-08-01 | 2013-08-01 | A kind of attapulgite clay paper making additive and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104343051A (en) * | 2014-09-29 | 2015-02-11 | 安徽博硕科技有限公司 | Attapulgite-level paper-making additive |
| CN106638137A (en) * | 2016-12-09 | 2017-05-10 | 苏州艾博迈尔新材料有限公司 | Compound papermaking filtering aid and preparation method thereof |
| CN106988154A (en) * | 2017-04-11 | 2017-07-28 | 安徽省明美矿物化工有限公司 | A kind of attapulgite clay paper making additive and preparation method thereof |
| CN108035180A (en) * | 2017-11-28 | 2018-05-15 | 安徽比伦生活用纸有限公司 | A kind of method of papermaking magma mashing |
| CN112663385A (en) * | 2020-12-28 | 2021-04-16 | 冠宏化工（扬州）有限公司 | Paper pulp papermaking auxiliary agent and preparation method thereof |
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| US20090229775A1 (en) * | 2008-03-15 | 2009-09-17 | Fushan Zhang | Clay slurries and use thereof in pulp and papermaking applications |
| CN102041153A (en) * | 2010-09-29 | 2011-05-04 | 上海东升新材料有限公司 | Preparation method for coating lubricant |
| CN102816461A (en) * | 2012-08-27 | 2012-12-12 | 暨南大学 | Quaternary ammonium cation and quaternary phosphonium cation-containing modified clay, its preparation and application |
| CN102921387A (en) * | 2012-10-26 | 2013-02-13 | 浙江海亮环境材料有限公司 | Particle retention and filtration aid agent for papermaking |
| CN102995495A (en) * | 2012-10-31 | 2013-03-27 | 蚌埠首创滤清器有限公司 | Modified attapulgite-containing filter paper and preparation method thereof |
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2013
- 2013-08-01 CN CN201310330527.6A patent/CN103451993B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090229775A1 (en) * | 2008-03-15 | 2009-09-17 | Fushan Zhang | Clay slurries and use thereof in pulp and papermaking applications |
| CN102041153A (en) * | 2010-09-29 | 2011-05-04 | 上海东升新材料有限公司 | Preparation method for coating lubricant |
| CN102816461A (en) * | 2012-08-27 | 2012-12-12 | 暨南大学 | Quaternary ammonium cation and quaternary phosphonium cation-containing modified clay, its preparation and application |
| CN102921387A (en) * | 2012-10-26 | 2013-02-13 | 浙江海亮环境材料有限公司 | Particle retention and filtration aid agent for papermaking |
| CN102995495A (en) * | 2012-10-31 | 2013-03-27 | 蚌埠首创滤清器有限公司 | Modified attapulgite-containing filter paper and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104343051A (en) * | 2014-09-29 | 2015-02-11 | 安徽博硕科技有限公司 | Attapulgite-level paper-making additive |
| CN106638137A (en) * | 2016-12-09 | 2017-05-10 | 苏州艾博迈尔新材料有限公司 | Compound papermaking filtering aid and preparation method thereof |
| CN106988154A (en) * | 2017-04-11 | 2017-07-28 | 安徽省明美矿物化工有限公司 | A kind of attapulgite clay paper making additive and preparation method thereof |
| CN108035180A (en) * | 2017-11-28 | 2018-05-15 | 安徽比伦生活用纸有限公司 | A kind of method of papermaking magma mashing |
| CN112663385A (en) * | 2020-12-28 | 2021-04-16 | 冠宏化工（扬州）有限公司 | Paper pulp papermaking auxiliary agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103451993B (en) | 2015-10-28 |
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Address after: 239400 Industrial Park, Mingdong sub district office, Mingguang City, Chuzhou City, Anhui Province Patentee after: Anhui Anbang Minerals Co.,Ltd. Address before: 239400 Industrial Park, Mingdong sub district office, Mingguang City, Chuzhou City, Anhui Province Patentee before: ANHUI ANBANG MINERAL Co.,Ltd. |