CN103451581A - Ageing heat treatment process of 3003 aluminium alloy electronic foil - Google Patents
Ageing heat treatment process of 3003 aluminium alloy electronic foil Download PDFInfo
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- CN103451581A CN103451581A CN2013104422205A CN201310442220A CN103451581A CN 103451581 A CN103451581 A CN 103451581A CN 2013104422205 A CN2013104422205 A CN 2013104422205A CN 201310442220 A CN201310442220 A CN 201310442220A CN 103451581 A CN103451581 A CN 103451581A
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Abstract
Provided is an ageing heat treatment process of a 3003 aluminium alloy electronic foil. When original hot rolling or cast rolling blank is rolled to be in the thickness of 5.0<+/-0.2>mm, high temperature homogenizing annealing treatment is used, the formation is well-closed, and segregation is weakened. Multi-pass cold rolling is continuously conducted after annealing, and when the thickness of 0.5<+/-0.05>mm is achieved, a complete annealing treatment process is conducted to weaken residual stress. The multi-pass cold rolling is continuously conducted until the thickness of 0.24<+/-0.01>mm is achieved, foil rolling is directly converted, when multi-pass foil rolling reaches the thickness of 0.09<+/-0.005>mm, ageing treatment of 80<+/-5> DEG C *3<+/-0.5> h is conducted, and the control over the morphology and the distribution of the second phase of the aluminium alloy electronic foil blank is achieved. The thickness of a finished product of 0.042mm - 0.038mm is achieved through multiple times of foil rolling after the ageing treatment. A specified heat treatment process is conducted on the 3003 aluminium alloy electronic foil blank, the control over the morphology and the distribution of second phase particles (MnAl6 phase) in the 3003 aluminium alloy is achieved, a large number of second phase particles are made to be dispersed and distributed evenly, the blank is used, the corrosion effect in the later period is good, the specific capacitance of the aluminium alloy electronic foil is improved, and 560-595 muF/cm<2> can be achieved.
Description
Technical field
Background technology
The various fields such as that aluminium foil is widely used in is electric, packing, building, and apply range along with the development in epoch and also strengthen, quality product is also had higher requirement.3003 aluminium alloy electronics paper tinsels are a kind of aluminium foils that are widely used in aluminium electrolutic capacitor.Due to complete electronic set, rapidly to short, little, light, thin future development, force aluminium electrolutic capacitor must accelerate miniaturization and microminiaturized process.The key of aluminum capacitor miniaturization is the gigantism of aluminum electrode foil effective surface area, this antianode aluminium foil has proposed to be strict with very much, also require its supporting cathode aluminum foil to possess excellent performance simultaneously, especially the specific capacitance of cathode aluminum foil, because cathode foil for aluminum electrolytic capacitors specific capacitance height affects the size of aluminium electrolutic capacitor volume equally.The aluminium alloy Cathode Foil valency a large amount of a large amount of high-specific capacitance supers of the annual import of China is large, has restricted to a great extent the development of China's electronic industry and the international competitiveness of aluminium processing enterprise.
In 3003 aluminium alloys containing Mn second-phase compound to separate out the alloy Effect on Mechanical Properties very little, but these are weak negative electrode phases containing the Mn precipitated phase for aluminum substrate, can produce the corrosion pit of " cavernous body " shape during chemical etching technology, effectively increase surface-area, be conducive to the raising of electronics paper tinsel specific capacitance.
The approach that improves the aluminum foil stock microstructure is improved the quality of electronics paper tinsel, and reasonably subsequent machining technology is these two.Although 3003 aluminium alloys belong to not heat-treatable strengthened alloy, usually do not carry out timeliness thermal treatment in actual production.
Summary of the invention
Purpose of the present invention: a kind of 3003 aluminium alloy electronics foil blank aging treatment process are provided, can Effective Regulation 3003 finished product aluminum foil stock second-phase forms, achieve evenly, disperse distributes; The 3003 aluminium alloy electronics foil blank corrosion by under this technique, realize the increase of specific capacitance.
The technical solution used in the present invention: aluminum foil stock is realized in the operation of rolling to the combination of high-temperature annealing process, middle Full Annealing technique and timeliness thermal treatment process; In the artificial aging thermal treatment process that the rolling later stage carries out, realized in the 3003 alloy foil operations of rolling control to second-phase form and distribution.
1) by hot rolling blank (cast-rolling stock), be hot-rolled down to
, carry out homogenizing annealing at this thickness, mechanism of anneal is
.
2) through the multi-pass cold-rolling process, roll
during thickness, carry out
full Annealing technique.
3) continue to be cold-rolled to
, then transfer paper tinsel to and roll, produce through multi-pass paper tinsel roll process,
during thickness, carry out
artificial aging is processed, and makes second-phase separate out in a large number, and disperse is uniformly distributed.
4), after multi-pass paper tinsel roll process, select to generate
the aluminium foil of different thickness in scope, generate finished product aluminium alloy electronics foil blank, and this finished product electronics paper tinsel is carried out
the finished product aging treatment process.
By this 3003 aluminium alloy electronics foil blank is implemented to specific thermal treatment process, the present invention realized to the second phase particles in 3003 aluminium alloys (
phase) control of form and distribution, be uniformly distributed its a large amount of disperses, and by using this blank, the later stage corrosive effect is good, improves this aluminium alloy electronics paper tinsel specific capacitance, can reach
.
Embodiment
embodiment1 3003 hot rolling blank schemes:
1) by hot rolling blank, be hot-rolled down to
, carry out homogenizing annealing at this thickness, mechanism of anneal is
.
2) through four times, cold rollingly (after the first passage is cold rolling, be
, after the second passage is cold rolling, be
, after the 3rd passage is cold rolling, be
, after four-pass is cold rolling, be
) technique,
during thickness, carry out
full Annealing technique.
3) continue to be cold-rolled to
, then transfer paper tinsel to and roll production, roll through three paper tinsels that (paper tinsel after rolling is for the first time
, paper tinsel after rolling is for the second time
, paper tinsel after rolling is for the third time
) technique,
during thickness, carry out
artificial aging is processed.
4) roll through three passage paper tinsels that (paper tinsel after rolling is for the first time
, paper tinsel after rolling is for the second time
, paper tinsel rolls and can, according to real needs, select to generate for the third time
the aluminium foil of different thickness in scope) generate finished product aluminium alloy electronics foil blank after technique, this finished product electronics paper tinsel is carried out
the finished product aging treatment process.
5) finished product paper tinsel ageing treatment is cut later, and qualified rear packing is dispatched from the factory on inspection.
The 3003 aluminium alloy electronics foil blanks that use above-mentioned hot rolling blank to produce, corrode operation, can be so that than electricity
Embodiment 2 3003 cast-rolling stock schemes:
1) by cast-rolling stock, be hot-rolled down to
, carry out homogenizing annealing at this thickness, make its homogeneous microstructure, reduce segregation, mechanism of anneal is
.
2) cold rollingly through five passages (after the first passage is cold rolling, be
, after the second passage is cold rolling, be
, after the 3rd passage is cold rolling, be
, after four-pass is cold rolling, be
, after the 5th passage is cold rolling, be
) technique,
during thickness, carry out
full Annealing technique, alleviate and organize unrelieved stress.
3) continue to be cold-rolled to
, then transfer paper tinsel to and roll production, roll through twice paper tinsel that (paper tinsel after rolling is for the first time
, paper tinsel after rolling is for the second time
) technique,
during thickness, carry out
artificial aging is processed.
4) roll through three passage paper tinsels that (paper tinsel after rolling is for the first time
, paper tinsel after rolling is for the second time
, paper tinsel rolls and can, according to real needs, select to generate for the third time
the aluminium foil of different thickness in scope) generate finished product aluminium alloy electronics foil blank after technique, this finished product electronics paper tinsel is carried out
the finished product aging treatment process.
5) finished product paper tinsel ageing treatment is cut later, and qualified rear packing is dispatched from the factory on inspection.
The 3003 aluminium alloy electronics foil blanks that use above-mentioned cast-rolling stock to produce, corrode operation, can be so that than electricity
Claims (2)
1. an aluminium alloy electronics foil blank aging thermal treating process, first heat-treat blank, more respectively aluminum foil stock is carried out the thermal treatment process of different heat treatment system in the Rolling Production process, it is characterized in that concrete production technique is:
By blank material hot-rolled extremely
, carry out homogenizing annealing at this thickness, mechanism of anneal is
;
Through the multi-pass cold-rolling process, roll
during thickness, carry out
full Annealing technique;
Continue to be cold-rolled to
, then transfer paper tinsel to and roll, through multi-pass paper tinsel roll process,
during thickness, carry out
artificial aging is processed;
2. 1 described 3003 aluminium alloy electronics foil blank aging thermal treating process as requested, it is characterized in that: described blank is hot rolling blank or cast-rolling stock.
Priority Applications (1)
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CN201310442220.5A CN103451581B (en) | 2013-09-26 | 2013-09-26 | A kind of aging thermal treating process of 3003 aluminium alloy electronics paper tinsels |
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---|---|---|---|
CN201310442220.5A CN103451581B (en) | 2013-09-26 | 2013-09-26 | A kind of aging thermal treating process of 3003 aluminium alloy electronics paper tinsels |
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Publication Number | Publication Date |
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CN103451581A true CN103451581A (en) | 2013-12-18 |
CN103451581B CN103451581B (en) | 2016-05-04 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104624647A (en) * | 2014-12-31 | 2015-05-20 | 中铝西南铝冷连轧板带有限公司 | Production method for cast rolling 1100 alloy aluminum foil for mobile-phone battery shell |
CN110711773A (en) * | 2019-10-12 | 2020-01-21 | 江苏鼎胜新能源材料股份有限公司 | Preparation method of aluminum foil with high heat seal strength |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11217656A (en) * | 1998-01-29 | 1999-08-10 | Furukawa Electric Co Ltd:The | Production of aluminum alloy foil excellent in foil rollability |
CN102719771A (en) * | 2012-07-12 | 2012-10-10 | 中南大学 | Thermal treatment process of aluminum foil stock |
CN102912191A (en) * | 2011-08-01 | 2013-02-06 | 江阴新仁科技有限公司 | 3003 reflective foil aluminum alloy |
-
2013
- 2013-09-26 CN CN201310442220.5A patent/CN103451581B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11217656A (en) * | 1998-01-29 | 1999-08-10 | Furukawa Electric Co Ltd:The | Production of aluminum alloy foil excellent in foil rollability |
CN102912191A (en) * | 2011-08-01 | 2013-02-06 | 江阴新仁科技有限公司 | 3003 reflective foil aluminum alloy |
CN102719771A (en) * | 2012-07-12 | 2012-10-10 | 中南大学 | Thermal treatment process of aluminum foil stock |
Non-Patent Citations (1)
Title |
---|
黄元春,朱弘源,肖政兵: "时效工艺对3003铝合金阴极箔组织、比电容和表面腐蚀形貌的影响", 《机械工程材料》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104624647A (en) * | 2014-12-31 | 2015-05-20 | 中铝西南铝冷连轧板带有限公司 | Production method for cast rolling 1100 alloy aluminum foil for mobile-phone battery shell |
CN104624647B (en) * | 2014-12-31 | 2017-01-11 | 中铝西南铝冷连轧板带有限公司 | Production method for cast rolling 1100 alloy aluminum foil for mobile-phone battery shell |
CN110711773A (en) * | 2019-10-12 | 2020-01-21 | 江苏鼎胜新能源材料股份有限公司 | Preparation method of aluminum foil with high heat seal strength |
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CN103451581B (en) | 2016-05-04 |
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Effective date of registration: 20170523 Address after: 264200 No. 1 middle Shenyang Road, Zhang Cun town, Weihai, Shandong Patentee after: Weihai Haixin New Material Co., Ltd. Address before: Yuelu District City, Hunan province 410083 Changsha left ridge Lushan Road No. 932 Patentee before: Central South University |