CN1034511C - Potassic Drilling mud - Google Patents
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- CN1034511C CN1034511C CN92105890A CN92105890A CN1034511C CN 1034511 C CN1034511 C CN 1034511C CN 92105890 A CN92105890 A CN 92105890A CN 92105890 A CN92105890 A CN 92105890A CN 1034511 C CN1034511 C CN 1034511C
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Abstract
An activated clay ground drilling method is by inhibiting the clay hydration around the drill holes. a drilling mud used in the method comprises (A) water and (B) a mixture composed of (a) a potassium salt of polyanionic cellulose, (b) at least one water-soluble potassium salt other than the potassium salt of polyanionic cellulose, and if necessary (c) (i) clay, (ii) one or more fluidizing agents selected from the group including tannin, alkali metal polyphosphate, and processed lignin and lignin iodate, (iii) one or more plugging agents in flaky, fibrous or granular form, (iv) one or more surfactants, (v) one or more weighting materials, (vi) one ore more lubricants or (vii) a combination thereof.
Description
The present invention relates to a kind of potassic Drilling mud.
Known that in drill-well operation the stability of boring is to determine one of most important factor that can drilling well achieve success.Cause the unsettled actual cause of boring to comprise the disperse of etch and formation rock stratum clay, the hole appears in the result, causes the card pipe so that boring is scrapped.To mud, can reduce drilling speed as the clay disperse in addition.
The adequate measure of avoiding this kind fault to take is to replenish sylvite to alleviate the hydration of clay in drilling mud.This moment, potassium ion can exchange with the sodium ion in the clay, owing to form special structure the trend of clay aquation is weakened, thereby stability strengthened.
Known this drilling mud can be by joining sylvite (normally Repone K or salt of wormwood) to contain clay, tackifier, fluid loss agents and an amount of liquid agent, an amount of weighting agent obtains in the based sols of an amount of plugging agent and an amount of surfactant.
Most widely used tackifier and/or fluid loss agents are Xylo-Mucines.Usually with the sodium salt of the TYLOSE 30000 of the polymerization degree in 500 to 1500 these scopes as tackifier, and when its polymerization degree is in 150 to 500 scope, be used as water retaining.
Obviously also should replenish polymkeric substance continuously when in drilling mud, using TYLOSE 30000.Because polymkeric substance is at machinery, Degradation can take place under the effect of heat and oxidation, make that Na ion concentration constantly increases and may equate with the concentration of potassium ion when using sodium salt, even surpass the concentration of potassium ion, this moment is stable with regard to what no longer can keep holing, recovers its optimum concn unless also replenish sylvite simultaneously continuously.
So when using Xylo-Mucine, must continuously replenish carboxymethyl cellulose and sylvite.
But need continuously drilling mud to be tested in carrying out said process, test not only relates to its viscosity and fluid loss, also relates to potassic concentration.
The applicant is surprised to find that the shortcoming of prior art can be by means of replacing the method for the sodium salt of sylvite and TYLOSE 30000 to overcome with carboxymethyl cellulose potassium (typically using the sylvite of TYLOSE 30000).
Use the sylvite of TYLOSE 30000 can prevent from drilling mud, to take place aforesaid sodium ion excess supply phenomenon out of control actually, the remarkable advantage of this method is to carry out relevant measurement to a kind of additive, relate to rheology and the dehydration characteristic of controlling mud, and the inhibition clay replaces the measurement respectively to cellulose polymer compound and sylvite.
The applicant also is surprised to find that the restraining effect that known potassium ion expands because of hydration clay, when promoting to some extent when using Repone K or salt of wormwood when the form with the salt of TYLOSE 30000 provides potassium ion.Promptly in same mud, potassium ion that from the sylvite of TYLOSE 30000, enters drilling mud and the potassium ion that from the mixture of the sodium salt of Repone K and TYLOSE 30000, enters drilling mud, under the identical situation of its quantity, the former has obviously higher inhibition effect than the latter concerning various clays.
The product composition that " TYLOSE 30000 " means its class can obtain by means of the hydroxyl group's of the dehydrated glucose unit in the carboxymethylated Mierocrystalline cellulose part or all of replacement.
The typical polydispersion characteristic of the polymeric chain length of cellulose family and change the possibility of this polydispersion characteristic, the carboxymethyl substituting group is in (when the substituting group group on each dehydrated glucose unit is less than three really) on the sharp water glucose ring with along the possibility of changing on the polymeric chain and control distributes, and the chemical constitution of adjustment carboxymethylether (by means of introducing a spot of other substituting group along chain) makes the TYLOSE 30000 product have different effects to each other and make extensive diversified feature become possibility.
In the compound of TYLOSE 30000 class, usually said carboxymethyl cellulose (CMC) is known, and this compound has the high or low polymerization degree, or low or high replacement degree.Also has said Polyanionic Cellulose (PAC), this compound can demonstrate good rheological characteristics as the professional and technical personnel is known in solution, higher confining force, bigger ionogen tolerance limit and clay had stronger inhibition ability than the CMC series products of said acquisition.Difference between carboxymethyl cellulose and Polyanionic Cellulose, known as the professional and technical personnel, not only on its chemical major ingredient, and more find expression in the difference of its performance, this point will be illustrated in the example below.
As disclosed in the present invention, for the compound of all TYLOSE 30000 classes, it all is useful replacing (and need not) sodium salt with its sylvite.
The potassium drilling mud that contains of the present invention contains the sylvite of TYLOSE 30000 as previously mentioned, and this sylvite is selected come out from the sylvite of the sylvite of Polyanionic Cellulose and carboxymethyl cellulose.
With regard to the sylvite of Polyanionic Cellulose, this salt means the TYLOSE 30000 with following feature here:
A) have the characteristic (in the product of pure system, measuring) of potential resistance to electrolyte contamination, be expressed as and be higher than 0.9 ratio.Measuring respectively between 4% sodium chloride solution and distilled water is 0.6% viscosity by weight.
B) be applied in the most drilling mud, have the dehydration of falling ability during up to 150 ℃ in temperature.
And with regard to the sylvite of the carboxymethyl cellulose that is used for drilling mud, the substitution value that means its bottom line carboxymethyl is 0.8, and its anti-degree of ionization (by the regulation in the preamble) is lower than 0.9, and the common dehydration ability of falling is arranged.
The sylvite of TYLOSE 30000 has been known, this compound is to obtain by following process when being used in the present invention: at first Mierocrystalline cellulose is activated (potassium hydroxide and cellulosic weight ratio are within 0.1 to 1.6 scope) with potassium hydroxide when thinner (or not having) is arranged, use monochlor(in)ate acetic acid (or its esters) with the Mierocrystalline cellulose etherificate then.Monochlor(in)ate acetic acid (or its esters) is expressed as acid, to cellulosic weight ratio in 0.2 to 1.4 scope.
From prepared finished product, remove thinner (if having used) and grind to form required particulate state after the drying more in addition.
By product (Repone K and oxyacetic acid potassium) is still arranged except that the sylvite of TYLOSE 30000 in the product that is obtained, and oxyacetic acid potassium useable solvents extraction method is removed if necessary, preferably uses in reaction with same thinner, and this thinner is a water-alcohol mixture.
The analytical characteristics of product can be made by common technology, and its substitution value is determined when titre, the polymerization degree, viscosity all can be with product ionization in the aqueous solution (or unionization)
Evaluation to product property can (OCMA) draw with " API " standard and use model (Fann) family name viscometer (API) with reference to " oil company's materials association ".
Particularly (but and so non-limiting) is of the present invention is used for the preparation of the water base carboxymethyl cellulose potassium that contains the potassium drilling mud from Mierocrystalline cellulose.The step of preparation comprises: Mierocrystalline cellulose is done mechanical mill; Make the ground Mierocrystalline cellulose in hydration alcohol medium, disperse (is the best to adopt isopropanol water solution); Then the Mierocrystalline cellulose in the hydration alcohol medium is carried out chemical etching, carry out chemical reaction with potassium hydroxide in the aqueous solution earlier, the time is 0.5 to 2 hour.Then monochloroacetic acid solution (the sort of diluent solution in reacting in the above with monochlor(in)ate acetic acid is the best) and in 30 ℃ to 70 ℃ temperature range (preferably between 40 ℃ to 50 ℃) handled 2 to 6 hours, refilter the carboxymethyl cellulose potassium that obtains, carry out drying reaching under 120 ℃ the temperature then.
The sylvite of TYLOSE 30000 class is planted the raw product state of sylvite to be mixed with its, or refining or part purified product is when being used for drilling mud, and its concentration in these slurries is 0.1% to 5% (product weight and slurry weight relative percentage).
Also include an amount of byproduct water of the present invention containing except that the sylvite that contains TYLOSE 30000 in the potassium drilling mud, and contain the various components of following concentration:
---clay, content are 2 to 8% by weight;
-an amount of liquid agent, content are 0.05% to 2% by weight
---an amount of plugging agent, content are 5% to 30% by weight
---an amount of tensio-active agent, content are 0.5% to 2% by weight,
---an amount of weighting agent,
---proper amount of lubricating agent,
All per-cent all is the gross weight of relative drilling mud.
Must notice in particular cases that the clay-based slurry can at some.
Carboxymethyl cellulose potassium is identical with the polymerization degree of aforesaid cellulose sodium carboxymethyl.
Can be selected from wilkinite for clay composition, attapulgite and sepiolite (can take from wherein any or its mixture).
For liquid agent, can be selected from tannin, alkali metal polysilicate phosphoric acid salt, the xylogen of handling, sulfonated lignin is sulfonated lignin iron and sulfonated lignin chromium especially.
Can select barium oxide for use for weighting agent, Wingdale, red iron sand, magnetite and spathic iron ore.
Can select mineral or plant oil, emulsion, tensio-active agent for use for lubricant.
Plugging agent can be laminar, and be the best to select glassine paper mica and vermiculite for use this moment.Also can be particulate state, this moment, gilsonite or apricot shell be best to select Wingdale for use.Can also adopt fiber at last, this moment, straw stem and vegetable fibre were best to select asbestos for use.
Some examples that provide below propose for the present invention is made better explanation, but should notice that content of the present invention is not limited in this several examples.
Example 1:
With 100 gram length and width is that the Mierocrystalline cellulose of 1mm is inserted the rotating paddle kneader with the anhydrous methanol of 500CC for 5mm thickness respectively.
After mentioned component is mediated evenly, use G3 gooch's filter (Gooch G3) under the pump vacuum condition, Mierocrystalline cellulose is pressed into filters, remove methyl alcohol wherein as far as possible fully.
From strainer, take out Mierocrystalline cellulose and insert in the baking oven, carry out drying with 80 ℃ temperature in a vacuum.
Dried Mierocrystalline cellulose charges into flask in nitrogen gas stream, add the dispersion agent of forming by the water of 819 gram Virahols and 145 grams again, add 50% (by weight) potassium hydroxide aqueous solution of forming by 48.2 gram potassium hydroxide and 48.2 gram water again and also stir continuously.Reaction is at room temperature carried out just having obtained a kind of uniform block product after about one hour.
Add the alcoholic solution of forming by the monochlor(in)ate acetic acid of 38.8 grams and 62.4 Virahols that restrain with time of 30 minutes then.Interpolation begins to carry out during from room temperature, attaches when finishing at monochlor(in)ate acetic acid, and temperature rises to 40 ℃.
Carried out when being reflected at 40 ℃ one hour, and reactant was heated to 65 ℃ again.
Said temperature was kept two hours, and cooling is close to 50 ℃ then, continues two hours.
Stop then stirring, post reaction mixture is kept somewhere a night.
Filter reactant next day in gooch's filter, the carboxymethyl cellulose potassium that obtains is inserted baking oven and carried out drying under 110 ℃ the temperature in a vacuum.
When being compared with available Xylo-Mucine on the market, the carboxymethyl cellulose that makes by disclosed aforesaid method finds that the former is except that providing the performance of potassium ion under the situation that no longer inserts sylvite, also have higher apparent viscosity, susceptible of proof has lower degree of depolymerizaton with the Mierocrystalline cellulose that is raw material.
Example 2:
The preparation method of the sylvite of TYLOSE 30000 is further disclosed in this example.
Be fed in Mierocrystalline cellulose in the liquid phase after the segmentation of 10 kilograms of wood celluloses cut and use and to obtain homodisperse reactor, add the azeotropic mixture of 50 liters of Virahols and water and 90% potassium hydroxide in the 8.6 public Rooms again.
After stirring one and a half hours under 20 ℃ the temperature, add 7.3 kilograms of monochlor(in)ate acetic acid again, it is dissolved in 8 liters of aqueous isopropanols.Temperature during interpolation can not be above 45 ℃.Temperature increase to 70 ℃ and keep this temperature and stirred simultaneously in one hour after one hour.
The resultant of reaction cooling is also become solid phase after filtration, obtain the sylvite (K-CMC/LV) of 20.5 kilograms of low-molecular-weight carboxymethyl celluloses after drying.
The specificity analysis of this product sees below.
Above-mentioned preparation method replaces wood cellulose as repeating with lint cellulose when beginning, then resultant has higher molecular weight.
This resultant represents that with code name K-CMC/HV the condition of its preparation is identical.
The method of purification of K-CMC/HV is as follows:
1 public Room K-CMC/HV is disperseed to add in the constant boiling mixture of 7 liters of Virahol one water.Its dispersion is stirred half an hour, and salt wherein extracts the byproduct as reaction.
Resultant is filtered, and with above-mentioned same operation steps, and the resulting wet solids of time enough is arranged after drying, and its finished product titre is 98.0% (for dry thing)
This product is represented with code name K-CMC/HV/P.
Analytical characteristics to products therefrom is listed as follows:
K-CMC/LV K-CMC/HV K-CMC/HV/P carboxymethyl degree of exchange: the long standpipe of 0.85 0.9 0.9 Brookfield (Brookfield) viscosity, 20 ℃, 60 rev/mins of K-CMC/LV K-CMC/HV K-CMC/H/P
Concentration is 2%, centipoise: 23 2500
Concentration is 1%.Centipoise: 2000
Titre 61.0 60.4 98.0
Example 3:
The Mierocrystalline cellulose use that is fed in the liquid phase after 10 kilograms the linters segmentation can be obtained homodisperse reactor, add the constant boiling mixture of 60 liters of Virahols and water and 11.5 kilograms 90% potassium hydroxide again.
After stirring one and a half hours under 20 ℃ the temperature, add 4.9 kilograms of monochlor(in)ate acetic acid again, it is dissolved in the solution of 5 liters of azeotropic Virahols.Temperature during interpolation can not be above 40 ℃.Then with temperature increase to 50 ℃, and kept this temperature 1 hour.
Then make the reaction mixture cooling, and continuation adds 4.8 kilograms of monochlor(in)ate acid, in the solution of its dissolving and 5 liters of azeotropic Virahols formation, in 1 hour, temperature is increased to 70～75 ℃ then, kept this temperature again 1 hour and stirring constantly, resultant of reaction is cooled off also recovery after filtration obtain solid product, obtain the sylvite of 23 kilograms of TYLOSE 30000 more after drying.
The rheological characteristics of this product makes it can range Polyanionic Cellulose (K-PAC/1) to see example 5
The specificity analysis of this product will be narrated below.
For the another kind of working method that obtains high performance TYLOSE 30000 as follows:
Undertaken by program recited above, the reactor inner face is answered strict seal and can anti-10 barometric absolute pressures.Use linters and use 4.5 kilograms of monochlor(in)ate acetic acid in the additive, when the reaction with monochlor(in)ate acetic acid finishes, in reactor, add 0.3 kg ethylene oxide, reactant is stirred until surplus pressure disappear then in the second time.With 0.2 kilogram of acetic acid neutralization reaction resultant, to proceed mode identical with the example of front for program then, and resulting resultant code name is K-PAC/2.
The product performance that obtains is as follows:
K-PAC/1 K-PAC/2 carboxymethyl degree of exchange: the mol degree of exchange of 1.1 1.05 pairs of oxyethane :-0.6 Fan Shi apparent viscosity 1%, 20 ℃ 600 rev/mins, centipoise: 60 55 titre (%): 59.0 57.5
Example 4:
Openly use the comparative result (under the situation that titre equates, comparing) of rheological characteristics with the characteristic of the mud of the sodium salt gained that adopts CMC of the resulting mud of K-CMC/LV in this example
Put into the water of 1000 milliliters of deionizing with 40 gram bentonite in powder (also claiming Magcogel) and make bentonite suspension.
This suspension leaves standstill a night.
Make base fluid with 416 these suspension of gram and add 8 gram Repone K, stir simultaneously, dissolve the back fully to Repone K and add 0.4 gram potassium hydroxide.Add TYLOSE 30000 in the aforesaid liquid with aequum.The rheological characteristics of this filtrate can at room temperature be checked through 16 hours timeliness and stir 5 minutes in install than strange (HamiHon Beach) Hamilton after.
This mud is taken out directly importing timeliness groove, in mud, be blown into 15 minutes nitrogen again, deliver in the rotary oven under 121 ℃ temperature again timeliness 16 hours in the steel tank of packing into then.
At room temperature make an appraisal by Fann viscosimeter (FANN mad.35SA/SR12) viscometer by common program.
The result of timeliness after 16 hours at room temperature:
Mierocrystalline cellulose:
Ether Na-CMC K-CMC/LV (concentration (restraining/100 milliliters)) AV PV YP FL AV PV YP FL
- 26 5 42 59 26 5 42 59
0.2 8 5 6 18.2?10 5 10 15.5
0.4 6 5 2 11.7?9 7 4 10.8
0.6 8 8 0 9.5 12 10 4 7.6
0.8 10 9 2 7.8 15 12 6 6.8
1.0 12 10 4 6.6 18 14 8 6.1
1.2 14 12 4 6.5 22 16 12 5.7
The result after 16 hours during timeliness under 121 ℃ of temperature
Mierocrystalline cellulose:
Ether Na-CMC K-CMC/LV
(concentration (restraining/100 milliliters)) AV PV YP FL AV PV YP FL
0.6 13 8 10 11.3 19 8 22 10.0
0.8 12 8 8 12.4 17 11 12 8.1
1.0 11 8 6 8.8 - - -
12 12 10 4 7.2 20?14 12 6.0
The implication of abbreviation is explained in the last table:
AV-apparent viscosity (centipoise)
PV-plastic viscosity (centipoise)
The mobile threshold value of YP-(* 0.48Pa (pound/100 square feet))
FL-fluid loss (by American Petroleum Institute (API) (PPI))
Example 5:
Make bentonite suspension in the water with 1000 milliliters of deionizing of 40 gram former times Ni Kela (Cinicola) wilkinites addings.This suspension is left standstill a night.
In 416 restrain as this suspension of base fluid, add 16 gram Repone K and stirring, after Repone K dissolves fully, add 0.6 again and restrain potassium hydroxide.In above-mentioned suspension, add the K-CMC/LV of 2.8 grams (0.7%) and the K-PAC/1 of variable quantity again.Suspension, is measured the rheology and the control characteristic of this filtrate than after stirring 20 minutes in very installing in the Hamilton.Also filtrate like another category is tested simultaneously, adding in this liquid is the K-CMC/LV of 2.8 grams and the K-CMC/HV of variable quantity.
The result shows that K-PAC has rheological characteristics preferably with respect to full-bodied K-CMC.
K-PAC/1 K-CMC/HV
Concentration (restraining/100 milliliters) AV PV YP FL AV PV YP FL
0.3 20 13 14 7.1 - - - -
0.5 29 19 20 5.8 26 18 16 6.4
0.7 42 27 30 5.0 37 27 21 6.1
0.9 - - - - 49 33 32 6.5
About code name AV, PV, YP, and the implication of FL referring to aforesaid example 5.
Example 6:
Stability when the example of example 6 and back has been described relevant clay and contacted with the aqueous solution, the series of advantages that is derived when being the sylvite with TYLOSE 30000.
This routine process is as follows:
A) preparation mud: in 400 milliliters of tap water, add 8 gram sodium bentonites and also stir with 9000 rev/mins rotating speed with Hamilton, the strange device of ratio.Stir and continued 20 minutes, add the CMC/LV of 3.2 grams and the CMC/HV of 1.6 grams then; Restir 5 minutes; Add 0.2 gram potassium hydroxide; Again this mixture was stirred 20 minutes.The mud steel tank of packing into, steel tank is inserted in the rotary oven then, and under 66 ℃ temperature timeliness 16 hours.
B) preparation clay chip: the clay sample that will test usefulness pulverizes and sieves, and isolates and can reclaim by the clay particle of 10 to 20 meshes (1340-3460 μ) (ASTM (American society for testing materials) (ASTM) standard).Clay is placed a night in atmosphere.
C) restraining effect test is encased in steel tank by above-mentioned (a) method made mud after timeliness and 20 grams by the made clay of above-mentioned (b) method with 350 milliliters.Pack into this steel tank in the rotating cylinder and keep 104 ℃ temperature 3 hours.After making steel tank cooling, its content is poured onto on the sieve of 267 μ (ASTM) standard and sieves.Use the Virahol wash residue, heated 3 hours with the temperature of baking oven again with 70 ℃.The chip of gained uses the sieve of 267 μ (ASTM) to sift out again, at room temperature places a night then.The clay amount (a) (weighing) that reclaims is compared the per-cent that can calculate the rate of recovery with original bulk (b).
By top disclosed operating process, can be compared the sylvite of CMC and two kinds of mud of sodium salt (LV+HV) are housed respectively.Used clay is the quartzose clay, and contains more a spot of kaolinite and montmorillonite.
To use the rate of recovery after the sieve screening of 267 μ (ASTM) be 70% sylvite to 10% sodium salt.
Example 7:
Make comparisons the Repone K (/ 400 milliliters of 2.0,2.5,3 grams) that adds variable quantity among the K-CMC (LV+HV) and Na-CMC (LV+HV) latter is housed respectively by disclosed working method in the example 6.So do, can draw following inference, be i.e. the concentration characteristic of Repone K and all potassium ion equivalences that are included in K-CMC mud (/ 400 milliliters of 2.3 grams) with interpolation technique.
It constitutes the result who analyzes with X-ray diffractometer used A type clay, contains quartz and kaolinite, and a spot of illite, chlorite, calcite are arranged.
The gained result is as follows:
The rate of recovery (%)
K-CMC mud 90.0 (three value mean value)
Na-CMC+ potassium chloride mud 85.7
Shown in above, except using a kind of additive is that the fact that another part makes us feeling surprised is that the potassium ion of result in the sylvite of CMC of this method can more effectively suppress clay under normal conditions than the potassium ion in the Repone K the rheological characteristics and this advantage of control clay of may command mud.
Example 8:
The class of operation of carrying out of this test is similar to example 6, and the clay of use (Type B) is made up of with quartzy illite, has more a spot of kaolinite and montmorillonite.Different only replace in the examples 6 104 ℃ with 66 ℃ for the aging temp of the mud that contains clay.
Its result further confirms the conclusion of example 7
Rate of recovery %
K-CMC mud 76.7
Na-CMC+ potassium chloride mud 70.0
Example 9:
This test carry out similar example 6, the base stock of used (D type) clay is a montmorillonite.
The result is as follows:
Rate of recovery %
K—CMC 90.0
Na-CMC+ Repone K 83.0
The result has reconfirmed the following beyond thought fact, and the potassium ion of same quantity can show different performances in the promptly similar mud, when its respectively from the sylvite of CMC and Repone K in the time, when the previous case, have certain superiority.
Example 10:
The similar example 6 of this process of the test, but used clay (C type) is by montmorillonite, quartz, kaolinite is formed with illite, effectively the characteristic of montmorillonite.
The result is as follows:
Rate of recovery %
K—CMC 60.0
Na-CMC+ Repone K 58.0
Example 11:
1.4 the potassium-CMC/HV (purify to titre 98.0% provide with dry substance) of gram is dissolved in the water of 400 milliliters of deionizing, stirs 20 minutes in the Hamilton, than strange device.The Fan Shi apparent viscosity is 28 centipoises in the time of 25 ℃.Be produced in addition and add the solution that 1.24 gram high viscosity-CMC (being purified to titre is 98.2%) are formed in the water of 400 milliliters of deionizing, this solution is made three parts (promptly containing three parts of solution of sodium-CMC) and is added 0,0.3 and 0.4 respectively and restrain Repone K.The Fan Shi apparent viscosity is respectively 29.5 centipoises in the time of 25 ℃, 20.0 centipoises, 19.0 centipoises.Again according to (b) in the example 6 with (c) operate.But the solution with above-mentioned preparation replaces mud, to carry out the test of clay restraining effect.The matrix of (D type) clay that uses is polynite.
The result is as follows:
Rate of recovery %
K-the CMC/HV 79.0 that purifies
Na-the CMC/HV 3.0 that purifies
The Na that purifies-CMC/HV+0.3 gram
Repone K/400 milliliters 7.5
The Na that purifies-CMC/HV+0.4 gram
Repone K/400 milliliters 11.0
Be equivalent to 0.35 gram Repone K/400 milliliter owing in K-CMC/HV solution, contain the potassium total amount, so the advantage that sylvite produced of use TYLOSE 30000 is very tangible.
Example 12:
Employing is by water, wilkinite (weight ratio 3%) K-CMC/LV (weight ratio 1%) K-CMC/HV (weight ratio 0.5%), potassium hydroxide (weight ratio 0.2) drilling mud of Zu Chenging its maximum drilling depth when international candle (Candela) drilling well that Italian Fu Jiya economizes reaches 1.672 meters.
From 214 meters to 940 meters this stage, drilling well is passed from the maximum sand content of one deck is 20% lightweight ash clay at drilling depth.
This stage boring is passed during being mingled with the grey powdered clay of sand or sandstone from 940 meters to 1485 meters.
Muddy limestone---powdered clay layer (wherein containing a spot of sand) is passed in this stage boring from 1485 meters to 1672 meters.
4.11% deviation has appearred in the capacity of the well of diameter 21.6cm and theoretical capacity.
Creep into the drilling mud that uses with reference to well flatly at areal and comprise weight ratio 3% wilkinite, weight ratio 1% low viscosity Na-CMC, weight ratio 0.5% high viscosity Na-CMC, weight ratio 0.2% sodium hydroxide and weight ratio 1% sulfonated lignin, when the shaft bottom drilling depth reaches 1615 meters, its well head capacity of the diameter value of this well (21.6cm) is greater than theoretical value, and the result is 46.64% deviation.
Like this, the excellent properties of the sylvite of TYLOSE 30000 of the present invention has obtained confirmation.
Claims (1)
1. potassic Drilling mud, comprise and stop boring clay hydration on every side, wherein adopt drilling mud, comprising: (A) water and (B) a kind of mixture, comprise sylvite of (a) TYLOSE 30000 and at least a sylvite that (b) is selected from Repone K and oxyacetic acid potassium, (a) and (b) concentration in drilling mud is 0.1%-5% weight, and in case of necessity (c) is in (i) 2-8% clay of drilling mud gross weight, (ii) one or more liquid agents of 0.05-2%, be selected from tannin, alkali metal polysilicate phosphoric acid salt, xylogen of handling and sulfonated lignin, (iii) one or more are laminar for 5-30%, fibrous or granular plugging agent, be selected from glassine paper, mica, vermiculite, asbestos, straw stem and vegetable fibre, Wingdale, gilsonite and apricot shell, (iv) one or more tensio-active agents of 0.5-2%, (v) one or more weighted material, be selected from barium oxide, Wingdale, red iron sand, magnetite and spathic iron ore, (vi) one or more lubricants are selected from mineral and plant oil, emulsion and tensio-active agent.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT20682A/86 | 1986-06-05 | ||
| IT20682/86A IT1190037B (en) | 1986-06-05 | 1986-06-05 | POTASSIC PERFORATION FLUID |
| CN87105729A CN1025627C (en) | 1986-06-05 | 1987-06-05 | Potassic drilling mud |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN87105729A Division CN1025627C (en) | 1986-06-05 | 1987-06-05 | Potassic drilling mud |
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| CN1069050A CN1069050A (en) | 1993-02-17 |
| CN1034511C true CN1034511C (en) | 1997-04-09 |
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| CN92105890A Expired - Lifetime CN1034511C (en) | 1986-06-05 | 1992-07-18 | Potassic Drilling mud |
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| WO2020060525A1 (en) * | 2018-09-17 | 2020-03-26 | Halliburton Energy Services, Inc. | Water-soluble polymer shale inhibitors |
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|---|---|---|---|---|
| CN104295249A (en) * | 2014-09-17 | 2015-01-21 | 深圳市建业建筑工程有限公司 | Method for estimating usage of wall protection mud for flowing water sand layer pipeline drilling and mud formula |
| CN104860581A (en) * | 2015-01-30 | 2015-08-26 | 武汉地网非开挖科技有限公司 | Bentonite for trenchless horizontal directional crossing construction, and production method thereof |
| CN109337658A (en) * | 2018-12-03 | 2019-02-15 | 重庆力宏精细化工有限公司 | A kind of water-based drilling solution additive and its drilling fluid and preparation method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4110226A (en) * | 1977-02-02 | 1978-08-29 | Phillips Petroleum Company | Stabilized aqueous gels and uses thereof |
-
1992
- 1992-07-18 CN CN92105890A patent/CN1034511C/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4110226A (en) * | 1977-02-02 | 1978-08-29 | Phillips Petroleum Company | Stabilized aqueous gels and uses thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020060525A1 (en) * | 2018-09-17 | 2020-03-26 | Halliburton Energy Services, Inc. | Water-soluble polymer shale inhibitors |
| US11066590B2 (en) | 2018-09-17 | 2021-07-20 | Halliburton Energy Services, Inc. | Water-soluble polymer shale inhibitors |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1069050A (en) | 1993-02-17 |
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