CN103450818B - Use the optical cement of transparent acrylic monomer - Google Patents
Use the optical cement of transparent acrylic monomer Download PDFInfo
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- CN103450818B CN103450818B CN201210182937.6A CN201210182937A CN103450818B CN 103450818 B CN103450818 B CN 103450818B CN 201210182937 A CN201210182937 A CN 201210182937A CN 103450818 B CN103450818 B CN 103450818B
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- transparent acrylic
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Abstract
The optical cement of use transparent acrylic monomer of the present invention, comprises the pre-synthesis transparent acrylic monomer composition of pre-synthesis step, and the sclerosis film-forming composition of sclerosis film formation step, and adds light initiator in addition; Wherein, the main component of pre-synthesis transparent acrylic monomer composition is stickiness monomer, modified monomer, interior poly-monomer and light initiator; The main component of sclerosis film-forming composition is thinner, linking agent and antioxidant.And obtain one and effectively can control product setting rate, and the optical cement constituent of use transparent acrylic monomer can effectively avoided product to go bad, turn to be yellow.
Description
Technical field
The present invention, about a kind of acryl optical cement constituent, refers to that one can effectively control product setting rate especially, and can effectively avoid product to go bad the optical cement of use transparent acrylic monomer of jaundice.
Background technology
In the information age now, the mankind grow with each passing day for the dependency of electronic product, the electronic products such as notebook computer, mobil phone, personal digital assistant device (personal digital assistant, PDA), digital walkman have become application tool indispensable in modern's life and work all.Above-mentioned electronic product, all except having an indicating meter, also must provide an operator-machine-interface simultaneously, and the built-in system of transmission user and electronic product is linked up.
Along with user is to the requirement of the display quality of indicating meter, convenience and friendly degree, display panel (display panel) arranges contact panel (touch panel), replace the conventional input devices such as button or mouse with contact panel, provide user and utilize finger or pointer etc. to carry out the approach of interactive input operation.
Generally speaking, touch control display panel is made up of contact panel and liquid crystal panel, most engagement means is based on gummed, that is after the prospective region of a slice plate is wherein coated with an optical cement (OCA), again another sheet plate correspondence is fitted with this plate being coated with optical cement, utilize UV-light that this optical cement is solidified subsequently, to complete the preparation of this touch control display panel.
Above-mentioned use optical cement forms the form of construction work of two plate laminatings, before optical cement not yet hardens, the trip edge between two plates all easily produces the glue that overflows, and must wiping in real time remove, in wiping process, optical cement still can continue to overflow, difficult treatment and quite consuming time; Especially, if optical cement is excessive and do not remove in real time, by more difficult removing after its sclerosis.Therefore, industry also uses one to make without base material by optics acryl glue, then at upper and lower bottom, the OCA optical adhesive tape of one deck release film of respectively fitting again, in order to form the comprehensive laminating of touch control screen, replace the mode of conventional mobile phone screen welt frame, effectively replace the gas cloud that must have because of welt frame, reach the effect improving screen contrast with physical property material.
In principle, similar OCA optical adhesive tape, in time making, after the acryl monomer be pre-mixed and film forming material mix and blend, then coordinates the irradiation of UV light and hardened forming; Only, when actual job, the acryl monomer that it is pre-mixed likely because store improper or the storage time is long, and rottenly even affects the follow-up light-struck setting rate of UV that accepts; Therefore, how to develop one and can effectively control product setting rate, and can effectively avoid product go bad jaundice curable composition, for industrial community and academia desire most ardently the problem of solution.
Summary of the invention
In view of this, namely the present invention is providing one can effectively control product setting rate, and the optical cement of use transparent acrylic monomer can effectively avoided product to go bad, turn to be yellow, and is its main purpose.
For reaching above-mentioned purpose, the optical cement of use transparent acrylic monomer of the present invention, via pre-synthesis step and the synthesis of sclerosis film formation step; The optical cement of this use transparent acrylic monomer, includes: the pre-synthesis transparent acrylic monomer composition of the pre-synthesis step of predetermined proportion, and the sclerosis film-forming composition of the sclerosis film formation step of predetermined proportion, and adds light initiator in addition; Wherein, this pre-synthesis transparent acrylic monomer composition is made up of stickiness monomer, modified monomer, interior poly-monomer and light initiator; This sclerosis film-forming composition is made up of thinner, linking agent and antioxidant.
Art technical characteristic in utilization, the overall optical cement of transparent acrylic monomer that uses can utilize light initiator additional in the middle of sclerosis film-forming composition, compensate the light initiator loss in pre-synthesis transparent acrylic monomer composition storage process, reach and effectively control product setting rate; And, can sclerosis film-forming composition in antioxidant action under, reach effectively avoid product go bad jaundice object.
According to above-mentioned technical characteristics, described pre-synthesis transparent acrylic monomer composition by the ratio accounting for overall optical cement by: the stickiness monomer of 30 ~ 55wt%, the modified monomer of 15 ~ 35wt%, the interior poly-monomer of 10 ~ 20wt% and the light initiator of 0.1 ~ 0.2wt% are formed; This sclerosis film-forming composition by the ratio accounting for overall optical cement by: the antioxidant of the thinner of 10 ~ 20wt%, the linking agent of 1 ~ 2.5wt%, 0.1 ~ 0.3wt% and the light initiator of 0.3 ~ 0.5wt% are formed.
Described pre-synthesis transparent acrylic monomer composition by the ratio accounting for overall optical cement by: the 2-EHA (Isooctyl acrylate monomer) of 54.26wt%, 2-HEA (vinylformic acid 2-hydroxyl ethyl ester), the CHMA (2-cyclohexyl methacrylate) of 16.28wt% of 16.28wt% and the Photoinitiator 819 (light initiator) of 0.11wt% are formed, this sclerosis film-forming composition by the ratio accounting for overall optical cement is: the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 10.85wt%, the 23-EGMA (Polyethylene Glycol 1000 Dimethacrylate) of 0.60wt%, the TMPTMA (trimethylolpropane trimethacrylate) of 0.43wt%, the SR9035 ((15) ethoxyquin Viscoat 295) of 0.98wt%, the Irganox1076 (antioxidant) of 0.105wt%, the Irganox168 (antioxidant) of 0.105wt%, and the Photoinitiator 184 (light initiator) of additional 0.11wt%, the Photoinitiator 819 (light initiator) of 0.33wt% formed.
Described pre-synthesis transparent acrylic monomer composition by the ratio accounting for overall optical cement by: the 2-EHA (Isooctyl acrylate monomer) of 34.26wt%, the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 29.37wt%, the CHMA (2-cyclohexyl methacrylate) of 14.28wt%, the Photoinitiator 819 (light initiator) of 0.10wt% are formed, this sclerosis film-forming composition by the ratio accounting for overall optical cement is: the 2-EHA (Hydroxyethyl acrylate) of 14.68wt%, the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 4.89wt%, the 23-EGMA (Polyethylene Glycol 1000 Dimethacrylate) of 0.54wt%, the TMPTMA (trimethylolpropane trimethacrylate) of 0.39wt%, the SR9035 ((15) ethoxyquin Viscoat 295) of 0.88wt%, the Irganox1076 (antioxidant) of 0.105wt%, the Irganox168 (antioxidant) of 0.105wt%, and the Photoinitiator 184 (light initiator) of additional 0.098wt%, the Photoinitiator 819 (light initiator) of 0.294wt% formed.
Described pre-synthesis transparent acrylic monomer composition by the ratio accounting for overall optical cement by: the CHMA (2-cyclohexyl methacrylate) of the 2-EHA (Isooctyl acrylate monomer) of 43.41wt%, the 2-HEA (Hydroxyethyl acrylate) of 27.13wt%, 16.28wt%, the Photoinitiator819 (light initiator) of 0.11wt% are formed, this sclerosis film-forming composition by the ratio accounting for overall optical cement is: the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 10.85wt%, the 23-EGMA (Polyethylene Glycol 1000 Dimethacrylate) of 0.60wt%, the TMPTMA (trimethylolpropane trimethacrylate) of 0.43wt%, the SR9035 ((15) ethoxyquin Viscoat 295) of 0.98wt%, the Irganox1076 (antioxidant) of 0.105wt%, the Irganox168 (antioxidant) of 0.105wt%, and the Photoinitiator184 of additional 0.11wt% (light initiator), the Photoinitiator819 (light initiator) of 0.33wt% formed.
Specifically, the optical cement of the use transparent acrylic monomer disclosed by the present invention, has following advantages.
1. can effectively control product setting rate.
2. product effectively can be avoided to go bad, turn to be yellow.
3. be conducive to the slimming design of product.
4. its product can be taken care of at normal temperatures.
Accompanying drawing explanation
Fig. 1 is the original composition configuration diagram of the optical cement of this bright use transparent acrylic monomer.
Figure number illustrates:
The optical cement of 10 use transparent acrylic monomers
11 pre-synthesis transparent acrylic monomer compositions
12 sclerosis film-forming composition.
Embodiment
The present invention mainly provides one to have high transmission rate, is especially applicable to the optical cement of the use transparent acrylic monomer being processed into OCA optics rubber moulding.
The optical cement of use transparent acrylic monomer of the present invention is via pre-synthesis step and the synthesis of sclerosis film formation step; That is as shown in Figure 1, the optical cement 10 of use transparent acrylic monomer of the present invention, includes: the pre-synthesis transparent acrylic monomer composition 11 of predetermined proportion and the sclerosis film-forming composition 12 of predetermined proportion.
Wherein, this pre-synthesis transparent acrylic monomer composition 11 is made up of stickiness monomer, modified monomer, interior poly-monomer and light initiator; In time implementing, this transparent acrylic monomer composition 11 by the ratio accounting for overall optical cement by: the stickiness monomer of 30 ~ 55wt%, the modified monomer of 15 ~ 35wt%, the interior poly-monomer of 10 ~ 20wt% and the light initiator of 0.1 ~ 0.2wt% are formed.
This sclerosis film-forming composition 12 is made up of thinner, linking agent and antioxidant; In time implementing, this sclerosis film-forming composition 12 by the ratio accounting for overall optical cement by: the antioxidant of the thinner of 10 ~ 20wt%, the linking agent of 1 ~ 2.5wt%, 0.1 ~ 0.3wt% is formed, and adds the light initiator of 0.3 ~ 0.5wt% in addition.
In principle, pre-synthesis transparent acrylic monomer composition 11 in the middle of the present invention can in advance by the weight percent preparation accounting for overall optical cement respectively and form before using, stir primarily of stickiness monomer, modified monomer, interior poly-monomer and light initiator and form, and this pre-synthesis transparent acrylic monomer composition 11 is in stirring and in follow-up storage process, being good to control not being subject to the light-struck envrionment conditions of UV.Until use transparent acrylic monomer of the present invention optical cement 10 for use time, can by the pre-synthesis transparent acrylic monomer composition 11 of predetermined proportion and sclerosis film-forming composition 12 and additional light initiator be uniformly mixed the optical cement 10 becoming described use transparent acrylic monomer.
According to this, the optical cement of use transparent acrylic monomer of the present invention can utilize at the additional light initiator of sclerosis film-forming composition, compensates the light initiator loss in pre-synthesis transparent acrylic monomer composition storage process, reaches and effectively control product setting rate; And, can sclerosis film-forming composition in the middle of antioxidant action under, reach effectively avoid product go bad jaundice object.
As shown in appendix 1, the optical cement of use transparent acrylic monomer of the present invention, in time specifically implementing, this pre-synthesis transparent acrylic monomer composition by the ratio accounting for overall optical cement by: the 2-EHA (Isooctyl acrylate monomer) of 54.26wt%, 2-HEA (vinylformic acid 2-hydroxyl ethyl ester), the CHMA (2-cyclohexyl methacrylate) of 16.28wt% of 16.28wt% and the Photoinitiator 819 (light initiator) of 0.11wt% are formed; Wherein, this 2-EHA (Isooctyl acrylate monomer) is the stickiness monomer of optical cement, this 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) is the modified monomer of optical cement, and this CHMA (2-cyclohexyl methacrylate) is the interior poly-monomer of optical cement.
As for, this sclerosis film-forming composition by the ratio accounting for overall optical cement is: the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 10.85wt%, the 23-EGMA (Polyethylene Glycol 1000 Dimethacrylate) of 0.60wt%, the TMPTMA (trimethylolpropane trimethacrylate) of 0.43wt%, the SR9035 ((15) ethoxyquin Viscoat 295) of 0.98wt%, the Irganox1076 (antioxidant) of 0.105wt%, the Irganox168 (antioxidant) of 0.105wt% formed, and the Photoinitiator184 of additional 0.11wt% (light initiator), the Photoinitiator819 (light initiator) of 0.33wt%, wherein, this 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) is the thinner in the middle of sclerosis film-forming composition, and this 23-EGMA (Polyethylene Glycol 1000 Dimethacrylate), TMPTMA (trimethylolpropane trimethacrylate), SR9035 ((15) ethoxyquin Viscoat 295) are the linking agent in the middle of sclerosis film-forming composition.
Subordinate list 1.
The thickness of OCA blooming piece (adhesive tape) product utilizing the optical cement of the use transparent acrylic monomer of above-mentioned subordinate list 1 to complete can down to 200 μm, penetration (%) when completing can reach 100.83, mist degree (%) is 0.41, flavescence value is 0.461, and pulling force (glass) is 1.098kgf; Under the condition of 85 DEG C/85%RH 500hrs, its penetration (%) can reach 102.96, and mist degree (%) is 0, and flavescence value is-0.016.
As shown in subordinate list 2, the optical cement of use transparent acrylic monomer of the present invention, in time specifically implementing, this pre-synthesis transparent acrylic monomer composition by the ratio accounting for overall optical cement by: the 2-EHA (Isooctyl acrylate monomer) of 34.26wt%, the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 29.37wt%, the CHMA (2-cyclohexyl methacrylate) of 14.68wt%, the Photoinitiator819 (light initiator) of 0.10wt% are formed; Wherein, this 2-EHA (Isooctyl acrylate monomer) is the stickiness monomer of acryl optical cement, this 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) is the modified monomer of acryl optical cement, and this CHMA (2-cyclohexyl methacrylate) is the interior poly-monomer of acryl optical cement.
As for, this sclerosis film-forming composition by the ratio accounting for overall optical cement is: the 2-EHA (Hydroxyethyl acrylate) of 14.68wt%, the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 4.89wt%, the 23-EGMA (Polyethylene Glycol 1000 Dimethacrylate) of 0.54wt%, the TMPTMA (trimethylolpropane trimethacrylate) of 0.39wt%, the SR9035 ((15) ethoxyquin Viscoat 295) of 0.88wt%, the Irganox1076 (antioxidant) of 0.105wt%, the Irganox168 (antioxidant) of 0.105wt% formed, and the Photoinitiator184 of additional 0.098wt% (light initiator), the Photoinitiator819 (light initiator) of 0.294wt%, wherein, this 2-EHA (Hydroxyethyl acrylate), 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) are the thinner in the middle of sclerosis film-forming composition, and this 23-EGMA (Polyethylene Glycol 1000 Dimethacrylate), TMPTMA (trimethylolpropane trimethacrylate), SR9035 ((15) ethoxyquin Viscoat 295) are the linking agent in the middle of sclerosis film-forming composition.
Subordinate list 2.
The thickness of OCA blooming piece (adhesive tape) product utilizing the optical cement of the use transparent acrylic monomer of above-mentioned subordinate list 2 to complete can down to 200 μm, penetration (%) when completing can reach 102.59, mist degree (%) is 0.5, flavescence value is 0.352, and pulling force (glass) is 0.774kgf; Under the condition of 85 DEG C/85%RH 500hrs, its penetration (%) can reach 101.42, and mist degree (%) is 0.98, and flavescence value is 0.407.
As shown in subordinate list 3, the optical cement of use transparent acrylic monomer of the present invention, in time specifically implementing, this pre-synthesis transparent acrylic monomer composition by the ratio accounting for overall optical cement by: the CHMA (2-cyclohexyl methacrylate) of the 2-EHA (Isooctyl acrylate monomer) of 43.41wt%, the 2-HEA (Hydroxyethyl acrylate) of 27.13wt%, 16.28wt%, the Photoinitiator819 (light initiator) of 0.11wt% are formed; Wherein, this 2-EHA (Isooctyl acrylate monomer) is the stickiness monomer of acryl optical cement, this 2-HEA (Hydroxyethyl acrylate) is the modified monomer of acryl optical cement, and this CHMA (2-cyclohexyl methacrylate) is the interior poly-monomer of acryl optical cement.
As for, this sclerosis film-forming composition by the ratio accounting for overall optical cement is: the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 10.85wt%, the 23-EGMA (Polyethylene Glycol 1000 Dimethacrylate) of 0.60wt%, the TMPTMA (trimethylolpropane trimethacrylate) of 0.43wt%, the SR9035 ((15) ethoxyquin Viscoat 295) of 0.98wt%, the Irganox1076 (antioxidant) of 0.105wt%, the Irganox168 (antioxidant) of 0.105wt% formed, and the Photoinitiator 184 (light initiator) of additional 0.11wt%, the Photoinitiator819 (light initiator) of 0.33wt%, wherein, this 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) is the thinner in the middle of sclerosis film-forming composition, and this 23-EGMA (Polyethylene Glycol 1000 Dimethacrylate), TMPTMA (trimethylolpropane trimethacrylate), SR9035 ((15) ethoxyquin Viscoat 295) are the linking agent in the middle of sclerosis film-forming composition.
Subordinate list 3.
Namely intention of the present invention is that createing one can effectively control product setting rate, and can effectively avoid product to go bad the optical cement of use transparent acrylic monomer of jaundice, create in the process of design whole, and the character that cannot can be possessed by single composition easily, and must at the loaded down with trivial details manufacturing processed (processing procedure of mixture, standby journey) in assessment learn, mat constantly becomes different gradually and has the composition of difference in functionality, exploration may have required characteristic, and then determine whether the character of each composition can enable final acryl optical cement produce and can effectively control product setting rate, product can be effectively avoided to go bad, jaundice, be conducive to the slimming design of product, with and products thereof the effect such as can to take care of at normal temperatures.
Claims (3)
1. use an optical cement for transparent acrylic monomer, it is characterized in that, via pre-synthesis step and the synthesis of sclerosis film formation step; The optical cement of this use transparent acrylic monomer, includes: the pre-synthesis transparent acrylic monomer composition of the pre-synthesis step of predetermined proportion, and the sclerosis film-forming composition of the sclerosis film formation step of predetermined proportion, and adds light initiator in addition; Wherein:
This pre-synthesis transparent acrylic monomer composition is made up of stickiness monomer, modified monomer, interior poly-monomer and light initiator;
This sclerosis film-forming composition is made up of thinner, linking agent, antioxidant;
This pre-synthesis transparent acrylic monomer composition by the ratio accounting for overall optical cement by: the 2-EHA (Isooctyl acrylate monomer) of 54.26wt%, 2-HEA (vinylformic acid 2-hydroxyl ethyl ester), the CHMA (2-cyclohexyl methacrylate) of 16.28wt% of 16.28wt% and the light initiator Photoinitiator 819 of 0.11wt% are formed, this sclerosis film-forming composition by the ratio accounting for overall optical cement is: the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 10.85wt%, the 23-EGMA of 0.60wt%, the TMPTMA (trimethylolpropane trimethacrylate) of 0.43wt%, the SR9035 of 0.98wt%, the antioxidant Irganox1076 of 0.105wt%, the antioxidant Irganox168 of 0.105wt% and the light initiator Photoinitiator184 of additional 0.11wt%, the light initiator Photoinitiator819 of 0.33wt% formed.
2. use an optical cement for transparent acrylic monomer, it is characterized in that, via pre-synthesis step and the synthesis of sclerosis film formation step; The optical cement of this use transparent acrylic monomer, includes: the pre-synthesis transparent acrylic monomer composition of the pre-synthesis step of predetermined proportion, and the sclerosis film-forming composition of the sclerosis film formation step of predetermined proportion, and adds light initiator in addition; Wherein:
This pre-synthesis transparent acrylic monomer composition is made up of stickiness monomer, modified monomer, interior poly-monomer and light initiator;
This sclerosis film-forming composition is made up of thinner, linking agent, antioxidant;
This pre-synthesis transparent acrylic monomer composition by the ratio accounting for overall optical cement by: the 2-EHA (Isooctyl acrylate monomer) of 34.26wt%, the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 29.37wt%, the CHMA (2-cyclohexyl methacrylate) of 14.68wt%, the light initiator Photoinitiator819 of 0.10wt% are formed, this sclerosis film-forming composition by the ratio accounting for overall optical cement is: the 2-EHA (Hydroxyethyl acrylate) of 14.68wt%, the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 4.89wt%, the 23-EGMA of 0.54wt%, the TMPTMA (trimethylolpropane trimethacrylate) of 0.39wt%, the SR9035 of 0.88wt%, the antioxidant Irganox1076 of 0.105wt%, the antioxidant Irganox168 of 0.105wt% and the light initiator Photoinitiator184 of additional 0.098wt%, the light initiator Photoinitiator819 of 0.294wt% formed.
3. use an optical cement for transparent acrylic monomer, it is characterized in that, via pre-synthesis step and the synthesis of sclerosis film formation step; The optical cement of this use transparent acrylic monomer, includes: the pre-synthesis transparent acrylic monomer composition of the pre-synthesis step of predetermined proportion, and the sclerosis film-forming composition of the sclerosis film formation step of predetermined proportion, and adds light initiator in addition; Wherein:
This pre-synthesis transparent acrylic monomer composition is made up of stickiness monomer, modified monomer, interior poly-monomer and light initiator;
This sclerosis film-forming composition is made up of thinner, linking agent, antioxidant;
This pre-synthesis transparent acrylic monomer composition by the ratio accounting for overall optical cement by: the CHMA (2-cyclohexyl methacrylate) of the 2-EHA (Isooctyl acrylate monomer) of 43.41wt%, the 2-HEA (Hydroxyethyl acrylate) of 27.13wt%, 16.28wt%, the light initiator Photoinitiator819 of 0.11wt% are formed, this sclerosis film-forming composition by the ratio accounting for overall optical cement is: the 2-HEA (vinylformic acid 2-hydroxyl ethyl ester) of 10.85wt%, the 23-EGMA of 0.60wt%, the TMPTMA (trimethylolpropane trimethacrylate) of 0.43wt%, the SR9035 of 0.98wt%, the antioxidant Irganox1076 of 0.105wt%, the antioxidant Irganox168 of 0.105wt% and the light initiator Photoinitiator184 of additional 0.11wt%, the light initiator Photoinitiator819 of 0.33wt% formed.
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