CN103450658A - Preparation method of anti-slipping agent for polyurethane package leather and anti-slipping polyurethane carpet - Google Patents
Preparation method of anti-slipping agent for polyurethane package leather and anti-slipping polyurethane carpet Download PDFInfo
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- CN103450658A CN103450658A CN2012101765181A CN201210176518A CN103450658A CN 103450658 A CN103450658 A CN 103450658A CN 2012101765181 A CN2012101765181 A CN 2012101765181A CN 201210176518 A CN201210176518 A CN 201210176518A CN 103450658 A CN103450658 A CN 103450658A
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- polyurethane
- slipping
- urethane
- agent
- carpet
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Abstract
The invention relates to a preparation method of an anti-slipping agent for polyurethane package leather and an anti-slipping polyurethane carpet. Abietate and polyurethane resin undergo a physical reaction, then dimethyl formamide (DMF) and a penetrating agent are added into the reaction product, and the mixture is heated to a temperature of about 70 DEG C to form the anti-slipping agent. The anti-slipping agent can be used as a polyurethane resin anti-slipping agent, can be used as an additive for slipping prevention of polyurethane package leather and an anti-slipping polyurethane carpet, and can improve blocking feel of the polyurethane package leather and the anti-slipping polyurethane carpet.
Description
The present invention relates to a kind of urethane packing leather and the urethane anti-slip carpet process of preparing with slipproofing agent.
The outer packaging of some products, except will being designed beautifully, also will have certain anti-skid, with the protection product, when some unforeseen circumstancess occur, is not damaged.Therefore, the Synthetic Leather that has anti-skid at packing external parcel last layer, increase the frictional force of surface of package, prevents the unexpected infringement product a kind of solution of can yet be regarded as that occurs.During rainy day, the doorways such as each emporium, hotel are often laid anti-slip carpet and are used for anti-skidding; Slipmat is also often laid in case on-slip is fallen in toilet at ordinary times.
The objective of the invention is to make urethane packing leather surface and the puckery sense of urethane anti-slip carpet to strengthen, increase the anti-skid of urethane packing leather and urethane anti-slip carpet.
Rosin ester is a kind of light yellow transparent solid through the height polymerization, and it has advantages of that softening temperature is high, viscosity is high and good in oxidation resistance, and under liquid state or in solution complete resistive connection crystalline substance.It can be for the synthesis of resin, rubber composition and various tackiness agent.Rosin ester adhesive industry for increasing viscosity, change tackiness agent hold viscosity, cohesive performance etc.
Urethane is a base polymer of contain-NHCOO-of main chain repeated structural unit, by vulcabond (monomer) and oxy-compound, is polymerized.Due to the carbamate groups containing strong polarity, be insoluble to non-polar group, there is the performances such as good elasticity, water tolerance, toughness, wear resistance, ageing resistance and binding property, can be made into the series product such as urethane foam, rubber, coating, tackiness agent, synthon, synthetic leather.Urethane resin is the special material of a kind of performance between plastics and rubber, there is the characteristics such as high strength, anti tear, wear-resisting, low temperature resistant, anti-solvent, anti-biological aging, therefore be widely used in fields such as industry, agricultural, military affairs, aviation, medical science, be in great demand.
Polyether glycol, polyester polyol are the main raw materials of synthesis of polyurethane resin, and the structure of polyvalent alcohol directly has influence on the performance of urethane resin.Utilize the rosin ester modification to make the polyester polyol of different types of structure, be applied to the synthetic and modification of urethane resin, the distinctive molecular structure of rosin ester is introduced in urethane resin, can effectively improve the performance of urethane resin.
Urethane packing leather of the present invention and urethane anti-slip carpet are in urethane resin, to add rosin ester, dimethyl formamide (DMF) and permeate agent to be heated to 70 ℃ by the principle of slipproofing agent, add urethane packing leather that this slipproofing agent makes and urethane anti-slip carpet in maintenance urethane resin superperformance, the performance that also has rosin ester, there is wear resistance, ageing resistance, water tolerance, binding property and anti-skid, meet the skid-resistance requirements of urethane packing leather goods and urethane anti-slip carpet.
The concrete proportioning of this urethane packing leather and urethane anti-slip carpet use slipproofing agent is as following table:
Raw material | Deal | Ratio % |
Urethane resin | 50 | 45.46 |
Rosin ester | 30 | 27.27 |
DMF | 20 | 18.18 |
Permeate agent | 10 | 9.09 |
Add up to | 110 | 100 |
For example:
The synthetic leather that adds this slipproofing agent 5% is compared as follows with the synthetic leather without adding:
Without the synthetic leather added | Add the synthetic leather of 5% slipproofing agent |
Without anti-skid | Anti-skid is good |
Without puckery sense | Puckery sense is strong |
Not wear-resisting | Wear resistance is good |
Claims (1)
1. the preparation method of urethane packing leather and urethane anti-slip carpet use slipproofing agent, it is characterized in that: by rosin ester, urethane resin, dimethyl formamide (DMF) and permeate agent, be heated to 70 ℃ and synthesize, add in the building-up process of urethane packing leather and urethane anti-slip carpet, synthetic urethane packing leather and the puckery sense of urethane anti-slip carpet are strengthened, increase the anti-skid of urethane packing leather and urethane anti-slip carpet.
Priority Applications (1)
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CN2012101765181A CN103450658A (en) | 2012-05-31 | 2012-05-31 | Preparation method of anti-slipping agent for polyurethane package leather and anti-slipping polyurethane carpet |
Applications Claiming Priority (1)
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CN2012101765181A CN103450658A (en) | 2012-05-31 | 2012-05-31 | Preparation method of anti-slipping agent for polyurethane package leather and anti-slipping polyurethane carpet |
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CN103450658A true CN103450658A (en) | 2013-12-18 |
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CN2012101765181A Pending CN103450658A (en) | 2012-05-31 | 2012-05-31 | Preparation method of anti-slipping agent for polyurethane package leather and anti-slipping polyurethane carpet |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108285524A (en) * | 2017-12-29 | 2018-07-17 | 浙江华峰新材料股份有限公司 | On-slip type polyurethane elastomer stoste and its preparation method and application |
CN111234510A (en) * | 2020-01-16 | 2020-06-05 | 上海汇得科技股份有限公司 | Polyurethane resin and preparation method and application thereof |
CN114805738A (en) * | 2022-06-07 | 2022-07-29 | 浙江华峰合成树脂有限公司 | Wet-process polyurethane resin and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101666042A (en) * | 2009-09-15 | 2010-03-10 | 烟台万华超纤股份有限公司 | Superfine basketball leather and preparation method thereof |
CN102168377A (en) * | 2010-12-02 | 2011-08-31 | 江苏宝泽高分子材料股份有限公司 | Matt-surface high-permeability moisture acerbity treating agent for synthetic leather and preparation method thereof |
CN102392364A (en) * | 2011-07-22 | 2012-03-28 | 烟台万华超纤股份有限公司 | Superfine fiber synthetic leather for basketball and preparation method thereof |
-
2012
- 2012-05-31 CN CN2012101765181A patent/CN103450658A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101666042A (en) * | 2009-09-15 | 2010-03-10 | 烟台万华超纤股份有限公司 | Superfine basketball leather and preparation method thereof |
CN102168377A (en) * | 2010-12-02 | 2011-08-31 | 江苏宝泽高分子材料股份有限公司 | Matt-surface high-permeability moisture acerbity treating agent for synthetic leather and preparation method thereof |
CN102392364A (en) * | 2011-07-22 | 2012-03-28 | 烟台万华超纤股份有限公司 | Superfine fiber synthetic leather for basketball and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108285524A (en) * | 2017-12-29 | 2018-07-17 | 浙江华峰新材料股份有限公司 | On-slip type polyurethane elastomer stoste and its preparation method and application |
CN111234510A (en) * | 2020-01-16 | 2020-06-05 | 上海汇得科技股份有限公司 | Polyurethane resin and preparation method and application thereof |
CN114805738A (en) * | 2022-06-07 | 2022-07-29 | 浙江华峰合成树脂有限公司 | Wet-process polyurethane resin and preparation method thereof |
CN114805738B (en) * | 2022-06-07 | 2024-01-23 | 浙江华峰合成树脂有限公司 | Wet polyurethane resin and preparation method thereof |
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Application publication date: 20131218 |