CN103450597B - PVC processes auxiliary heat stabilizer - Google Patents
PVC processes auxiliary heat stabilizer Download PDFInfo
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- CN103450597B CN103450597B CN201310385589.7A CN201310385589A CN103450597B CN 103450597 B CN103450597 B CN 103450597B CN 201310385589 A CN201310385589 A CN 201310385589A CN 103450597 B CN103450597 B CN 103450597B
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- CN
- China
- Prior art keywords
- glycerine
- stablizer
- pvc
- heat stabilizer
- auxiliary heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000012760 heat stabilizer Substances 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 title claims abstract description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 32
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 235000011187 glycerol Nutrition 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000292 calcium oxide Substances 0.000 claims abstract description 10
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- 239000011701 zinc Substances 0.000 claims abstract description 9
- 239000002253 acid Substances 0.000 claims abstract description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 7
- -1 6-amino-2-mercapto phenyl Chemical group 0.000 claims abstract description 6
- 238000009413 insulation Methods 0.000 claims abstract description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 235000019260 propionic acid Nutrition 0.000 claims description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 3
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052725 zinc Inorganic materials 0.000 abstract description 4
- 230000000536 complexating effect Effects 0.000 abstract description 3
- 150000003751 zinc Chemical class 0.000 abstract description 3
- 150000001669 calcium Chemical class 0.000 abstract description 2
- 230000007547 defect Effects 0.000 abstract description 2
- 230000001629 suppression Effects 0.000 abstract description 2
- 238000001914 filtration Methods 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 description 11
- 229920000915 polyvinyl chloride Polymers 0.000 description 10
- 239000003381 stabilizer Substances 0.000 description 4
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 3
- 229960001545 hydrotalcite Drugs 0.000 description 3
- 229910001701 hydrotalcite Inorganic materials 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses PVC and process auxiliary heat stabilizer, it is in the system that organic carboxyl acid is catalyzer, and add calcium oxide, zinc oxide and glycerine reaction, the metallo-organic complex obtained is stablizer; Concrete reactions steps is as follows: get equimolar calcium oxide, zinc oxide, glycerine in organic carboxyl acid environment, be heated to 180 DEG C of reactions 200 minutes, question response system is cooled to 120 DEG C when becoming colorless transparent, total addition level and glycerine equimolar 6-amino-2-mercapto phenyl formic-pyrimidine-4-alcohol is dripped with 1 milliliter of speed per second, drip 80 DEG C of insulations 60 minutes completely, filtration, dries, pulverize, obtain stablizer.Lifting PVC is processed the zinc class component of thermally-stabilised initial performances together with the calcium class component complexing of suppression " zinc burning " by the present invention, has both solved the stablizer defect that primary stability is bad, and can directly use as stablizer separately again.
Description
Technical field
The present invention relates to stablizer, be specifically related to a kind of PVC and process auxiliary heat stabilizer.
Background technology
Polyvinyl chloride (PVC) resin also increased in the speed with annual 4% in recent years fast as its consumption of world's second largest synthetic resins, and the structures shape of PVC self its thermal destruction and easily aging feature, simultaneously its processing temperature (180 DEG C) is far above its decomposition temperature (120-130 DEG C), this just determines must add thermo-stabilizer in the machine-shaping process of PVC product, current stablizer, if lead, tin etc. are due to the limitation of its aspect such as performance and price, becomes clear day by day to the restriction of market and economic benefits.In order to satisfied society, market and economic requirement, the development of stablizer must towards nontoxic, efficient future development.
Hydrotalcite (metal A l in traditional PVC heat stabilizer, Mg, Ca complexing) series products is very common, but its primary stability of its structures shape is very poor, the good zinc class auxiliary stabilizer of primary stability generally can be introduced in order to address this problem, but have also been introduced " zinc burning " problem simultaneously, which forms a kind of contradiction situation, often need to add two or more auxiliary stabilizers to use, the synergistic effect of whole stabiliser system is so not only made to be deteriorated, operation increases with the X factor of result, also makes cost greatly promote.
Summary of the invention
The object of the invention is to: provide a kind of PVC to process auxiliary heat stabilizer, with hydrotalcite stablizer compound use, both the primary stability of hydrotalcite product had been promoted, solve again issuable " zinc burning " problem, in material, introduce analog structure again, the effect of the composite use of improving product simultaneously.
Technical solution of the present invention is: in the system that organic carboxyl acid is catalyzer, add calcium oxide, zinc oxide and glycerine reaction, the metallo-organic complex obtained is stablizer.
Wherein, concrete reactions steps is as follows: get equimolar calcium oxide, zinc oxide, glycerine in organic carboxyl acid environment, be heated to 180 DEG C of reactions 200 minutes, question response system is cooled to 120 DEG C when becoming colorless transparent, drips total addition level and glycerine equimolar 6-amino-2-mercapto phenyl formic-pyrimidine-4-alcohol with 1 milliliter of speed per second, drips completely 80 DEG C of insulations 60 minutes, filter, dry, pulverize, obtain stablizer.
Wherein, the pure calcium content of calcium oxide is higher than 60%, and the pure Zn content of zinc oxide is not less than 50%, the purity more than 90% of glycerine.
Wherein, organic carboxyl acid is formic acid, acetic acid or propionic acid.
The contrast of the present invention and prior art: processing the zinc class component of thermally-stabilised initial performances together with the calcium class component complexing of suppression " zinc burns " by promoting PVC, both having solved the stablizer defect that primary stability is bad, and can directly use as stablizer separately again.
Accompanying drawing explanation
Fig. 1 is the photo comparison figure that stablizer is processed for PVC.
Embodiment
Further illustrate technical solution of the present invention below in conjunction with specific embodiment, such embodiment can not be interpreted as it is restriction to technical scheme.
Embodiment 1: get equimolar pure calcium content and be not less than 50% zinc oxide, purity more than 90% glycerine in formic acid environment higher than 60% calcium oxide, pure Zn content, be heated to 180 DEG C of reactions 200 minutes, question response system is cooled to 120 DEG C when becoming colorless transparent, total addition level and glycerine equimolar 6-amino-2-mercapto phenyl formic-pyrimidine-4-alcohol is dripped with 1 milliliter of speed per second, 80 DEG C of insulations 60 minutes after dropping, filter, dry, pulverize, obtain stablizer.
Embodiment 2: get equimolar pure calcium content and be not less than 50% zinc oxide, purity more than 90% glycerine in acetic environment higher than 60% calcium oxide, pure Zn content, be heated to 180 DEG C of reactions 200 minutes, question response system is cooled to 120 DEG C when becoming colorless transparent, total addition level and glycerine equimolar 6-amino-2-mercapto phenyl formic-pyrimidine-4-alcohol is dripped with 1 milliliter of speed per second, 80 DEG C of insulations 60 minutes after dropping, filter, dry, pulverize, obtain stablizer.
Embodiment 3: get equimolar pure calcium content and be not less than 50% zinc oxide, purity more than 90% glycerine in propionic acid environment higher than 60% calcium oxide, pure Zn content, be heated to 180 DEG C of reactions 200 minutes, question response system is cooled to 120 DEG C when becoming colorless transparent, total addition level and glycerine equimolar 6-amino-2-mercapto phenyl formic-pyrimidine-4-alcohol is dripped with 1 milliliter of speed per second, 80 DEG C of insulations 60 minutes after dropping, filter, dry, pulverize, obtain stablizer.
The stablizer of embodiment 1-2 gained is used for PVC processing, and the photo of PVC product as shown in Figure 1.
Claims (3)
1.PVC processes auxiliary heat stabilizer, it is characterized in that concrete reactions steps is as follows: get equimolar calcium oxide, zinc oxide, glycerine in organic carboxyl acid environment, be heated to 180 DEG C of reactions 200 minutes, question response system is cooled to 120 DEG C when becoming colorless transparent, drips total addition level and glycerine equimolar 6-amino-2-mercapto phenyl formic-pyrimidine-4-alcohol with 1 milliliter of speed per second, drips completely 80 DEG C of insulations 60 minutes, filter, dry, pulverize, obtain stablizer.
2. PVC according to claim 1 processes auxiliary heat stabilizer, it is characterized in that: the pure calcium content of calcium oxide is higher than 60%, and the pure Zn content of zinc oxide is not less than 50%, the purity more than 90% of glycerine.
3. PVC according to claim 1 processes auxiliary heat stabilizer, it is characterized in that: organic carboxyl acid is formic acid, acetic acid or propionic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310385589.7A CN103450597B (en) | 2013-08-30 | 2013-08-30 | PVC processes auxiliary heat stabilizer |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310385589.7A CN103450597B (en) | 2013-08-30 | 2013-08-30 | PVC processes auxiliary heat stabilizer |
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| Publication Number | Publication Date |
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| CN103450597A CN103450597A (en) | 2013-12-18 |
| CN103450597B true CN103450597B (en) | 2015-09-09 |
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| CN201310385589.7A Active CN103450597B (en) | 2013-08-30 | 2013-08-30 | PVC processes auxiliary heat stabilizer |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103804144B (en) * | 2014-01-16 | 2015-10-28 | 东南大学 | A kind of method of Homogeneous synthesis glycerine calcium |
| CN106188944B (en) * | 2016-07-19 | 2018-02-09 | 大连宝蓝科技有限公司 | A kind of PVC stabilizers |
| CN109942886A (en) * | 2019-02-21 | 2019-06-28 | 福建致尚生物质材料发展有限公司 | The preparation method of polyvinyl-chloride use glycerol Ca-Zn composite heat stabilizer |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB934644A (en) * | 1961-05-10 | 1963-08-21 | Argus Chem | Polyvinyl chloride stabiliser combinations and polyvinyl chloride resins stabilised thereby |
| EP0623648B1 (en) * | 1993-05-05 | 2000-07-05 | Morton International, Inc. | A combination heat stabilizer/lubricant for PVC processing and method for producing the same |
| CN101486805A (en) * | 2008-11-20 | 2009-07-22 | 靖江旭光塑胶有限公司 | Preparation of calcium zinc composite stabilizer for processing plastic |
| CN101704721A (en) * | 2009-10-27 | 2010-05-12 | 中南民族大学 | Method for preparing glycerin zinc |
| CN102336985A (en) * | 2011-07-06 | 2012-02-01 | 江南大学 | Glyceryl calcium/zinc composite heat stabilizer for polyvinyl chloride |
| CN103183644A (en) * | 2011-12-31 | 2013-07-03 | 深圳市志海实业有限公司 | Uracil zinc salt and application thereof as heat stabilizer for PVC |
-
2013
- 2013-08-30 CN CN201310385589.7A patent/CN103450597B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB934644A (en) * | 1961-05-10 | 1963-08-21 | Argus Chem | Polyvinyl chloride stabiliser combinations and polyvinyl chloride resins stabilised thereby |
| EP0623648B1 (en) * | 1993-05-05 | 2000-07-05 | Morton International, Inc. | A combination heat stabilizer/lubricant for PVC processing and method for producing the same |
| CN101486805A (en) * | 2008-11-20 | 2009-07-22 | 靖江旭光塑胶有限公司 | Preparation of calcium zinc composite stabilizer for processing plastic |
| CN101704721A (en) * | 2009-10-27 | 2010-05-12 | 中南民族大学 | Method for preparing glycerin zinc |
| CN102336985A (en) * | 2011-07-06 | 2012-02-01 | 江南大学 | Glyceryl calcium/zinc composite heat stabilizer for polyvinyl chloride |
| CN103183644A (en) * | 2011-12-31 | 2013-07-03 | 深圳市志海实业有限公司 | Uracil zinc salt and application thereof as heat stabilizer for PVC |
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| CN103450597A (en) | 2013-12-18 |
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| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: Hong Road salt Hongze salt chemical industry district of Huaian city in 223100 Jiangsu County of Hongze Province, North East of Lee Wan Lu Applicant after: Mei Ke (Huaian) Chemical Co. Ltd. Address before: 223100, Hongze District, Jiangsu County, Huaian province Huaian salt chemical industry zone (east area) Hongze area Applicant before: Huai'an Feixiang Liquid Crystal Materials Co., Ltd. |
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| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: HUAI AN FEIXIANG LIQUID CRYSTAL MATERIALS CO., LTD. TO: MATRIX (HUAI'AN) CHEMICAL CO., LTD. |
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| C14 | Grant of patent or utility model | ||
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Effective date of registration: 20191118 Address after: 511356 No.4 Xin'an Road, Yonghe Economic Zone, Guangzhou Economic and Technological Development Zone, Huangpu District, Guangzhou City, Guangdong Province Patentee after: Meiyi (Guangzhou) Chemical Co., Ltd. Address before: Hong Road salt Hongze salt chemical industry district of Huaian city in 223100 Jiangsu County of Hongze Province, North East of Lee Wan Lu Patentee before: Meiyi (Huai'an) Chemistry Co., Ltd. |
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| TR01 | Transfer of patent right | ||
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Address after: 511356 No. 4 Xin'an Road, Yonghe Economic Zone, Guangzhou Economic and Technological Development Zone, Huangpu District, Guangzhou City, Guangdong Province Patentee after: Meike (Guangzhou) new material Co.,Ltd. Address before: No.4 Xin'an Road, Yonghe Economic Zone, Guangzhou Economic and Technological Development Zone, Huangpu District, Guangzhou, Guangdong 511356 Patentee before: MATRIX GUANGZHOU CHEMICALS Corp. |