CN103449726A - Production method of freehand microcrystalline glass board - Google Patents
Production method of freehand microcrystalline glass board Download PDFInfo
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- CN103449726A CN103449726A CN2013103419968A CN201310341996A CN103449726A CN 103449726 A CN103449726 A CN 103449726A CN 2013103419968 A CN2013103419968 A CN 2013103419968A CN 201310341996 A CN201310341996 A CN 201310341996A CN 103449726 A CN103449726 A CN 103449726A
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Abstract
The invention relates to a production method of a freehand microcrystalline glass board. The production method comprises the following steps of respectively preparing seven microcrystalline glass aggregates with different colors, getting the microcrystalline glass aggregates with any two or more colors and uniformly scattering the microcrystalline glass aggregates with different colors in a stainless steel mould frame with a textured grating in sequence; moving a glass gate board at the bottom of the stainless steel mould frame for dropping the microcrystalline glass aggregates into a fireproof mould sprayed with an aluminum oxide sizing agent which is 1mm thick, and the fireproof mould carrying the microcrystalline glass aggregates enters a roller kiln; preheating, fusing the aggregates, crystallizing and preserving the heat at 1100 DEG C-1150 DEG C, cooling and discharging out of the kiln for firing a freehand microcrystalline glass board crude product with whole-body textures; and carrying out surface coarse-grinding, fine-grinding and polishing to obtain a freehand microcrystalline glass board finished product with clear texture patterns and board glossiness of over 90 degrees. The freehand microcrystalline glass board prepared by the production method disclosed by the invention has abundant colors, line textures from the inside to the outside, and physical and chemical performances better than those of a stone.
Description
Technical field
The present invention relates to a kind of production method of enjoyable crystallizing glass sheet material.
Background technology
Devitrified glass is a kind of glass of tool specific composition, and a kind of polycrystalline material obtained by crystallization control, have intensity high, and good weatherability can substitute high-grade stone material as building and ornament materials.
The assortment of current microcrystal glass plate section product are mainly solid colors, also do not reach the colourful decorative effect of lithotome.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of production method of enjoyable crystallizing glass sheet material, and enjoyable crystallizing glass sheet material color prepared by the present invention is abundant, and from outward appearance to inner essence, physicochemical property is more superior than stone material for the lines texture.
Enjoyable devitrified glass: the present invention is the pattern according to design by versicolor devitrified glass pellet, be added in fireproof die, through crystallizing and sintering, during high temperature, the devitrified glass pellet merges and flows mutually, the artistic effect that cooling rear formation is more smooth than the texture of lithotome, we are referred to as enjoyable devitrified glass.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: a kind of production method of enjoyable crystallizing glass sheet material comprises:
1) prepare respectively the devitrified glass pellet of seven kinds of different colours: get mine tailing 0-80 weight part, sandstone or quartz sand 40-100 weight part, calcite 40-60 weight part, zinc oxide 2-8 weight part, soda ash 10-12 weight part, barium carbonate 8-12 weight part, borax 1-3 weight part, copper powder 0-1 weight part, charcoal 0-2 weight part, weisspiessglanz 0.1-0.8 weight part, SODIUMNITRATE 1-3 weight part, chromic oxide 0-2 weight part, cupric oxide 0-2 part, cerium oxide 0-2 weight part, titanium oxide 0-2 weight part, after mixing, join in the glass furnace of 1500-1600 ℃, through within 10-15 hour, being fused into glass metal, glass metal flow in pond, chilling bursts, sieve out the following devitrified glass particle of 3mm, after the devitrified glass particle is dried, be broken into 10-100 purpose devitrified glass pellet, add the water that accounts for devitrified glass pellet weight 0-5%, obtain respectively the devitrified glass pellet of seven kinds of different colours,
2) get the devitrified glass pellet of two or more color arbitrarily, by the devitrified glass pellet of different colours successively be spread in uniform in framed with the stainless steel of texture grid in, the spreading thickness of every layer of devitrified glass pellet is 3-20mm, form at least three layers of devitrified glass pellet structure, the speed of dividing according to 5-10m/ is twitched the glass flashboard of the framed bottom of stainless steel, and the devitrified glass pellet is fallen in the fireproof die that has sprayed the thick alumina slurry of 1mm;
3) fireproof die is carrying the devitrified glass particulate material and is entering in roller kiln, through preheating, pellet merge, 1100-1150 ℃ crystallization insulation, cooling, after kiln discharge, fire as the enjoyable crystallizing glass sheet material crude product with the entire body texture;
4) the crystallizing glass sheet material crude product, after surface corase grind, fine grinding, polishing, obtains textured pattern clear, the above enjoyable crystallizing glass sheet material finished product of sheet material glossiness 90 degree;
The enjoyable crystallizing glass sheet material finished product of 7 kinds of colors prepared by the present invention is respectively white, black, redness, green, yellow, blueness, brown, and the formula that is β-wollastonite according to crystalline phase forms, and chemical composition is mainly SiO
255-65%, CaO 15-20%, Al
2o
35-10%, Na
2o 3-6%, ZnO 2-7%, BaO 3-7%, B
2o
30.3-1%.
On the basis of technique scheme, the present invention can also do following improvement.
Further, 1) in, described mine tailing is alumina laterite, iron ore mine, golden mine tailing, copper mining tailing or cobalt nickel minerals mine tailing;
Further, 1) in, alumina laterite 60 weight parts, quartz sand 60 weight parts, calcite 55 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part;
Further, 1) in, quartz sand 100 weight parts, calcite 55 weight parts, soda ash 12 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part;
Further, 1) in, iron ore mine 70 weight parts, quartz sand 40 weight parts, calcite 50 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part;
Further, 1) in, quartz sand 100 weight parts, calcite 55 weight parts, soda ash 12 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, cerium oxide 2 weight parts, titanium oxide 2 weight parts;
Further, 1) in, copper mining tailing 70 weight parts, quartz sand 40 weight parts, calcite 50 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, copper powder 1 weight, charcoal 2 weight parts, weisspiessglanz 0.5 weight part;
Further, 1) in, quartz sand 100 weight parts, calcite 55 weight parts, soda ash 12 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, chromic oxide 2 weight parts, cupric oxide 1 weight part;
Further, 1) in, cobalt nickel minerals mine tailing 40 weight parts, quartz sand 60 weight parts, calcite 45 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part;
Further, 1) in, golden mine tailing 70 weight parts, quartz sand 40 weight parts, calcite 50 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part;
Further, 3) in, described roller kiln can be substituted by shuttle kiln or tunnel furnace.
The beneficial effect that adopts above-mentioned further scheme is the range of application that has enlarged enjoyable crystallizing glass sheet material production method.
The invention has the beneficial effects as follows:
Enjoyable crystallizing glass sheet material color prepared by production method of the present invention is abundant, and from outward appearance to inner essence, form is true to nature for the lines texture.Have more the colourful decorative effect of the textured pattern of lithotome than common crystallizing glass sheet material.
The production method of the enjoyable crystallizing glass sheet material of the present invention can be used the devitrified glass pellet of different colours, coordinates the lines texture of design in advance to produce colourful devitrified glass assortment.
Embodiment
Below principle of the present invention and feature are described, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1
Get alumina laterite 60 weight parts, quartz sand 60 weight parts, calcite 55 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, after mixing, add in 1550 ℃ of glass furnaces, through within 12 hours, being fused into glass metal, by the material road, flow out in pond, chilling bursts, sieve out the following black glass ceramic particle of 3mm, after the devitrified glass particle is dried, use crusher to be broken into respectively 10-100 purpose devitrified glass pellet, add and account for devitrified glass pellet weight 2% water.
Get quartz sand 100 weight parts, calcite 55 weight parts, soda ash 12 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, after mixing, add in 1550 ℃ of glass furnaces, through within 12 hours, being fused into glass metal, by the material road, flow out in pond, chilling bursts, sieve out the following white micro-crystals glass particle of 3mm, after the devitrified glass particle is dried, use crusher to be broken into respectively 10-100 purpose devitrified glass pellet, add and account for devitrified glass pellet weight 2% water.
By white micro-crystals glass pellet be spread in uniform in framed with the stainless steel of waviness texture grid in, the framed 1250*2750*40mm that is of a size of of stainless steel, the thickness of spreading is 20mm.The black glass ceramic pellet is spread in uniform on the framed interior white micro-crystals glass pellet face of stainless steel, the thickness of spreading is 10mm again.Finally white micro-crystals glass pellet is spread in uniform on the framed interior black glass ceramic pellet face of stainless steel, the thickness of spreading is 10mm again, forms the devitrified glass pellet structure of thriple decker sandwich's shape.
After the framed bottom glass flashboard of stainless steel is according to 5 m/mins of extractions, the strip and block of three layers of devitrified glass pellet formation overturns or directly drops into and falls in the fireproof die that has sprayed 1mm thickness alumina slurry, form the devitrified glass pellet accumulation body of white background black line, in fireproof die, sky is of a size of 1250*2750*50mm.
Fireproof die is carrying the devitrified glass pellet and is entering in roller kiln, through preheating, pellet merge, after 1120 ℃ of crystallization insulations, the cooling process of 12 hours, after kiln discharge, fire as the enjoyable crystallizing glass sheet material crude product of white background with entire body black line texture, after surface corase grind, fine grinding, polishing, obtain textured pattern clear, more than the sheet material glossiness reaches 90 degree, be similar to the enjoyable crystallizing glass sheet material finished product of white black line of the marmorean pattern texture effect of Italian Snow Flower White.
Embodiment 2
Get iron ore mine 70 weight parts, quartz sand 40 weight parts, calcite 50 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, after mixing, add in 1550 ℃ of glass furnaces, through within 12 hours, being fused into glass metal, by the material road, flow out in pond, chilling bursts, sieve out the following black glass ceramic particle of 3mm, after the devitrified glass particle is dried, use crusher to be broken into respectively 10-100 purpose black glass ceramic pellet, add and account for devitrified glass pellet weight 2% water.
Get quartz sand 100 weight parts, calcite 55 weight parts, soda ash 12 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, cerium oxide 2 weight parts, titanium oxide 2 weight parts, after mixing, add in 1550 ℃ of glass furnaces, through within 12 hours, being fused into glass metal, by the material road, flow out in pond, chilling bursts, sieve out the following yellow devitrified glass particle of 3mm, after the devitrified glass particle is dried, use crusher to be broken into respectively 10-100 purpose devitrified glass pellet, add and account for devitrified glass pellet weight 2% water.
By the black glass ceramic pellet be spread in uniform in framed with the stainless steel of waviness texture grid in, the framed 1250*2750*40mm that is of a size of of stainless steel, the thickness of spreading is 15mm.Yellow devitrified glass pellet is spread in uniform on the framed interior black glass ceramic pellet face of stainless steel, the thickness of spreading is 10mm again.Finally white micro-crystals glass pellet is spread in uniform on the framed interior black glass ceramic pellet face of stainless steel, the thickness of spreading is 15mm again, forms three layers of devitrified glass pellet structure of sandwich shape.
After the framed bottom glass flashboard of stainless steel is according to 10 m/mins of extractions, the strip and block of three layers of devitrified glass pellet formation overturns or directly drops into and falls in the fireproof die that has sprayed 1mm thickness alumina slurry, form the devitrified glass pellet accumulation body of black matrix yellow line bar, in fireproof die, sky is of a size of 1250*2750*50mm.
Fireproof die is carrying the devitrified glass pellet and is entering in roller kiln, through preheating, pellet merge, after 1100 ℃ of crystallization insulations, the cooling process of 10 hours, after kiln discharge, fire as the enjoyable crystallizing glass sheet material crude product of black matrix with entire body yellow line texture, after surface corase grind, fine grinding, polishing, obtain textured pattern clear, more than the sheet material glossiness reaches 90 degree, the enjoyable crystallizing glass sheet material finished product of the black yellow line of the marmorean pattern texture effect of likeness in form Portoro.
Embodiment 3
Get copper mining tailing 70 weight parts, quartz sand 40 weight parts, calcite 50 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, copper powder 1 weight part, charcoal 2 weight parts, weisspiessglanz 0.5 weight part, after mixing, add in 1550 ℃ of glass furnaces, through within 12 hours, being fused into glass metal, by the material road, flow out in pond, chilling bursts, sieve out the following red microcrystalline glass particle of 3mm, after the devitrified glass particle is dried, use crusher to be broken into respectively 10-100 purpose red microcrystalline glass pellet, add and account for devitrified glass pellet weight 2% water.
Get quartz sand 100 weight parts, calcite 55 weight parts, soda ash 12 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, chromic oxide 2 weight parts, 1 part of cupric oxide, after mixing, add in 1550 ℃ of glass furnaces, through within 12 hours, being fused into glass metal, by the material road, flow out in pond, chilling bursts, sieve out the following green glass-ceramic particle of 3mm, after the devitrified glass particle is dried, use crusher to be broken into respectively 10-100 purpose devitrified glass pellet, add and account for devitrified glass pellet weight 2% water.
By the green glass-ceramic pellet be spread in uniform in framed with the stainless steel of waviness texture grid in, the framed 1250*2750*40mm that is of a size of of stainless steel, the thickness of spreading is 15mm.Yellow devitrified glass pellet is spread in uniform on the framed interior green glass-ceramic pellet face of stainless steel, the thickness of spreading is 10mm again.Finally white micro-crystals glass pellet is spread in uniform on the framed interior red microcrystalline glass pellet face of stainless steel, the thickness of spreading is 15mm again, forms three layers of devitrified glass pellet structure of sandwich shape.
After the framed bottom glass flashboard of stainless steel is according to 10 m/mins of extractions, the strip and block of three layers of devitrified glass pellet formation overturns or directly drops into and falls in the fireproof die that has sprayed 1mm thickness alumina slurry, form the devitrified glass pellet accumulation body of green line bar of the red end, in fireproof die, sky is of a size of 1250*2750*50mm.
Fireproof die is carrying the devitrified glass pellet and is entering in roller kiln, through preheating, pellet merge, after 1100 ℃ of crystallization insulations, the cooling process of 10 hours, fire the enjoyable crystallizing glass sheet material crude product that entire body green line texture is arranged for red tail band after kiln discharge, after surface corase grind, fine grinding, polishing, obtain textured pattern clear, more than the sheet material glossiness reaches 90 degree, the enjoyable crystallizing glass sheet material finished product of the red green line of the pattern texture effect that the likeness in form cuckoo is red.
Embodiment 4
Get cobalt nickel minerals mine tailing 40 weight parts, quartz sand 60 weight parts, calcite 45 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, after mixing, add in 1550 ℃ of glass furnaces, through within 12 hours, being fused into glass metal, by the material road, flow out in pond, chilling bursts, sieve out the following blue glass ceramics particle of 3mm, after the devitrified glass particle is dried, use crusher to be broken into respectively 10-100 purpose blue glass ceramics pellet, add water 2%.
Get golden mine tailing 70 weight parts, quartz sand 40 weight parts, calcite 50 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, after mixing, add in 1550 ℃ of glass furnaces, through within 12 hours, being fused into glass metal, by the material road, flow out in pond, chilling bursts, sieve out the following brown devitrified glass particle of 3mm, after the devitrified glass particle is dried, use crusher to be broken into respectively 10-100 purpose devitrified glass pellet, add water 2%.
By brown devitrified glass pellet be spread in uniform in framed with the stainless steel of waviness texture grid in, the framed 1250*2750*40mm that is of a size of of stainless steel, the thickness of spreading is 15mm.The blue glass ceramics pellet is spread in uniform on the framed interior black glass ceramic pellet face of stainless steel, the thickness of spreading is 10mm again.Finally browner devitrified glass pellet is spread in uniform on the framed interior blue glass ceramics pellet face of stainless steel, the thickness of spreading is 15mm, forms three layers of devitrified glass pellet structure of sandwich shape.
After the framed bottom glass flashboard of stainless steel is according to 10 m/mins of extractions, the strip and block of three layers of devitrified glass pellet formation overturns or directly drops into and falls in the fireproof die that has sprayed 1mm thickness alumina slurry, form the devitrified glass pellet accumulation body of palm fibre end blue line bar, in fireproof die, sky is of a size of 1250*2750*50mm.
Fireproof die is carrying the devitrified glass pellet and is entering in roller kiln, through preheating, pellet merge, after 1100 ℃ of crystallization insulations, the cooling process of 10 hours, fire the enjoyable crystallizing glass sheet material crude product that the blue lines texture of entire body is arranged for brown tail band after kiln discharge, after surface corase grind, fine grinding, polishing, obtain textured pattern clear, more than the sheet material glossiness reaches 90 degree, the enjoyable crystallizing glass sheet material finished product of the brown blue line of the granitic pattern texture effect of likeness in form coffee net.
Enjoyable crystallizing glass sheet material prepared by embodiment of the present invention 1-4 has carried out specification deviation, flatness tolerance, visual appearance, mirror surface luster, Mohs' hardness, flexural strength, anti-rapid heat cycle, acid resistance, ten checks of alkali resistance by the JC/T872-2000 standard, and assay meets the technical requirements in the JC/T872-2000 standard.
The foregoing is only preferred embodiment of the present invention, in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (10)
1. the production method of an enjoyable crystallizing glass sheet material, is characterized in that, comprising:
1) prepare respectively the devitrified glass pellet of seven kinds of different colours: get mine tailing 0-80 weight part, sandstone or quartz sand 40-100 weight part, calcite 40-60 weight part, zinc oxide 2-8 weight part, soda ash 10-12 weight part, barium carbonate 8-12 weight part, borax 1-3 weight part, copper powder 0-1 weight part, charcoal 0-2 weight part, weisspiessglanz 0.1-0.8 weight part, SODIUMNITRATE 1-3 weight part, chromic oxide 0-2 weight part, cupric oxide 0-2 part, cerium oxide 0-2 weight part, titanium oxide 0-2 weight part, after mixing, join in the glass furnace of 1500-1600 ℃, through within 10-15 hour, being fused into glass metal, glass metal flow in pond, chilling bursts, sieve out the following devitrified glass particle of 3mm, after the devitrified glass particle is dried, be broken into 10-100 purpose devitrified glass pellet, add the water that accounts for devitrified glass pellet weight 0-5%, obtain respectively the devitrified glass pellet of seven kinds of different colours,
2) get the devitrified glass pellet of two or more color arbitrarily, by the devitrified glass pellet of different colours successively be spread in uniform in framed with the stainless steel of texture grid in, the spreading thickness of every layer of devitrified glass pellet is 3-20mm, form at least three layers of devitrified glass pellet structure, the speed of dividing according to 5-10m/ is twitched the glass flashboard of the framed bottom of stainless steel, and the devitrified glass pellet is fallen in the fireproof die that has sprayed the thick alumina slurry of 1mm;
3) fireproof die is carrying the devitrified glass particulate material and is entering in roller kiln, through preheating, pellet merge, 1100-1150 ℃ crystallization insulation, cooling, after kiln discharge, fire as the enjoyable crystallizing glass sheet material crude product with the entire body texture;
4) the crystallizing glass sheet material crude product, after surface corase grind, fine grinding, polishing, obtains textured pattern clear, the above enjoyable crystallizing glass sheet material finished product of sheet material glossiness 90 degree.
2. production method according to claim 1, it is characterized in that, 1) in, alumina laterite 60 weight parts, quartz sand 60 weight parts, calcite 55 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part.
3. production method according to claim 1, it is characterized in that, 1) in, quartz sand 100 weight parts, calcite 55 weight parts, soda ash 12 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part.
4. production method according to claim 1, it is characterized in that, 1) in, iron ore mine 70 weight parts, quartz sand 40 weight parts, calcite 50 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part.
5. production method according to claim 1, it is characterized in that, 1) in, quartz sand 100 weight parts, calcite 55 weight parts, soda ash 12 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, cerium oxide 2 weight parts, titanium oxide 2 weight parts.
6. production method according to claim 1, it is characterized in that, 1) in, copper mining tailing 70 weight parts, quartz sand 40 weight parts, calcite 50 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, copper powder 1 weight, charcoal 2 weight parts, weisspiessglanz 0.5 weight part.
7. production method according to claim 1, it is characterized in that, 1) in, quartz sand 100 weight parts, calcite 55 weight parts, soda ash 12 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part, chromic oxide 2 weight parts, cupric oxide 1 weight part.
8. production method according to claim 1, it is characterized in that, 1) in, cobalt nickel minerals mine tailing 40 weight parts, quartz sand 60 weight parts, calcite 45 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part.
9. production method according to claim 1, it is characterized in that, 1) in, golden mine tailing 70 weight parts, quartz sand 40 weight parts, calcite 50 weight parts, soda ash 10 weight parts, zinc oxide 6 weight parts, barium carbonate 10 weight parts, borax 2 weight parts, SODIUMNITRATE 2 weight parts, weisspiessglanz 0.5 weight part.
10. production method according to claim 1, is characterized in that, 3) in, described roller kiln can be substituted by shuttle kiln or tunnel furnace.
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| CN103819077A (en) * | 2014-03-03 | 2014-05-28 | 北京工业大学 | Distribution method of mixed batch for foam glass |
| CN103864307A (en) * | 2014-01-17 | 2014-06-18 | 承德华富玻璃技术工程有限公司 | Method for preparing crystallized building materials from tailings |
| CN103922585A (en) * | 2014-03-18 | 2014-07-16 | 山西晶玉建材有限公司 | Method for producing multi-color micro-crystal glass granular material by using alumina red mud |
| CN110937815A (en) * | 2019-12-18 | 2020-03-31 | 中郡庄艺(泉州)新材料有限公司 | Preparation method of black glass ceramics by taking waste cement blocks as raw materials |
| CN112408800A (en) * | 2020-11-25 | 2021-02-26 | 江西璞晶新材料股份有限公司 | Method for preparing marble-like colored microcrystalline glass by using ceramic pigment |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103449726B (en) | 2015-05-27 |
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