CN103437200A - Manufacturing method of environment-friendly thermoplastic elastomer sporting glove leather - Google Patents
Manufacturing method of environment-friendly thermoplastic elastomer sporting glove leather Download PDFInfo
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- CN103437200A CN103437200A CN2013104091043A CN201310409104A CN103437200A CN 103437200 A CN103437200 A CN 103437200A CN 2013104091043 A CN2013104091043 A CN 2013104091043A CN 201310409104 A CN201310409104 A CN 201310409104A CN 103437200 A CN103437200 A CN 103437200A
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- leather
- base cloth
- thermoplastic elastomer
- game
- environmental protection
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- 239000010985 leather Substances 0.000 title claims abstract description 64
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 63
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 239000004744 fabric Substances 0.000 claims abstract description 66
- 238000000034 method Methods 0.000 claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 238000002844 melting Methods 0.000 claims abstract description 11
- 230000008018 melting Effects 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 230000007613 environmental effect Effects 0.000 claims description 39
- 238000012545 processing Methods 0.000 claims description 24
- 239000007864 aqueous solution Substances 0.000 claims description 16
- 239000004698 Polyethylene Substances 0.000 claims description 12
- 239000004743 Polypropylene Substances 0.000 claims description 12
- -1 polyethylene Polymers 0.000 claims description 12
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 10
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 9
- 238000004040 coloring Methods 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000003607 modifier Substances 0.000 claims description 9
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 9
- 239000002759 woven fabric Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 239000004952 Polyamide Substances 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 4
- 238000001035 drying Methods 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 2
- 238000003825 pressing Methods 0.000 abstract 2
- 239000003086 colorant Substances 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 30
- 238000005299 abrasion Methods 0.000 description 12
- 230000009172 bursting Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 239000002649 leather substitute Substances 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
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Abstract
The invention discloses a manufacturing method of environment-friendly thermoplastic elastomer sporting glove leather. The manufacturing method comprises the following steps: (1) immersing base cloth into a water solution containing a treating agent firstly, rolling the base cloth to dry, and then drying the base cloth through a drying oven of 70-130 DEG C; (2) adding a modifying agent and a coloring agent into a thermoplastic elastomer, melting and mixing all the components at the temperature of 150-350 DEG C, extruding the mixture to be meshy or point-shaped by using a die head through an extruding machine, pressing and compounding the mixture and the base cloth under the pressure of 0.1-0.8MPa, and pressing to strengthen anti-skid grains by using pair-rollers with grains; (3) removing a bottom treating layer in hot water of 60-110 DEG C, and squeezing to dry by using the pair-rollers, and then drying. The method disclosed by the invention is free of addition of solvents in the manufacturing process and clean in production; an obtained product is extremely good in wear resistance, low-temperature resistance and anti-skid performance, comparable with a pure leather product and low in maintenance cost, thus being ideal sporting glove leather.
Description
Technical field
The present invention relates to rubber and plastic manufacture field, synthetic leather field, be specifically related to a kind of manufacture method of environmental protection type thermoplastic elastomer gloves for game leather.
Background technology
Raising along with people's living standard; healthy health has become the emphasis of concern; different crowds selects different physical training styles, and people are also improving constantly the sense of self-protection in motion and requirement, and wherein the protected mode of gloves for game is exactly important one.Natural leather is the best material of gloves for game, yet, due to the reinforcement of the reinforcement, particularly environmental protection consciousness of the restriction that is subject to natural conditions and the countries in the world consciousness of watching for animals, the use of natural leather reduces year by year.Synthetic leather is the best substitute of natural leather.China is the big country of 1,300,000,000 populations, and according to incomplete reckoning, current domestic synthetic leather aggregate demand surpasses 800,000,000 m
2/ year, and keep ascendant trend, wherein to the annual requirement of the high-quality synthetic leather of high-performance, can reach 200,000,000 m
2above.The gloves for game leather is that still, the solvent of PU production use is very large to ambient influnence by the produced in conventional processes of PVC, PU slurry mostly at present, is a factor of restriction PU material gloves development.
Summary of the invention
The object of the present invention is to provide a kind of manufacture method of the gloves for game leather that is main material, production process environmental protection, products obtained therefrom superior performance with the thermoplastic macromolecule material elastomer, change the manufacture method of conventional motion glove leather, with the above-mentioned technical problem existed in the manufacture method that overcomes existing gloves for game leather.
The invention provides a kind of manufacture method of environmental protection type thermoplastic elastomer gloves for game leather, comprise the steps:
(1) by base cloth by the aqueous solution that contains finishing agent, soak a bundle (first immerse the aqueous solution, then prick dry) through one, by baking oven, under 70-130 ℃, dry afterwards, stand-by;
(2) by 0.5-1 weight portion TPV TPV, 0.1-0.6 weight portion modifier, 0.01-0.05 weight portion colouring agent by extruder 140-350 ℃ of lower melting mixing, be squeezed into reticular membrane or point-like film through die head, before not yet cooling, with the base cloth that step (1) is made, under 0.1-0.8MPa pressure, suppressed compound, strengthen anti-skidding lines by the compacting of the pair roller with texture simultaneously, make elementary leather;
(3) the elementary leather of step (2) being made removes the processing layer of bottom in 60-110 ℃ of hot water, after extracting by two rollers, dries, and obtains environmental protection type thermoplastic elastomer gloves for game leather.
Preferably, the mixture that described modifier is following one or several: TPO POE, polyethylene from high pressure process PE, polyamide PA, polypropylene PP, styrene-rubbery copolymer ABS.Most preferably, described modifier is TPO POE.
Preferably, described colouring agent is Masterbatch or toner.Most preferably, described colouring agent is Masterbatch.
Preferably, described base cloth is knitted cloth or elasticity woven fabric.Most preferably, described base cloth is knitted cloth.
Preferably, described finishing agent is water-soluble poval or water-soluble poly ammoniacum.Most preferably, described base cloth is knitted cloth.
The environmental protection type thermoplastic elastomer gloves for game leather of making according to the inventive method, be respectively from the bottom to top base cloth layer, processing layer and thermoplastic elastomer, base cloth in base cloth layer is knitted cloth or elasticity woven fabric, processing layer is formed by finishing agent, thermoplastic elastomer is formed by the mixture of TPV TPV, modifier and colouring agent, and the thermoplastic elastomer outer surface has the anti-skidding lines of reinforcement.
The present invention is to be that main material adds modifier, colouring agent with the thermoplastic macromolecule material elastomer, through heating and melting, mixes, and utilizes transfer technique, a molding technology to manufacture a kind of environmental protection type thermoplastic elastomer gloves for game.The inventive method is solvent-free adding in manufacture process, cleaning production, and products obtained therefrom anti-wear performance, resistance to low temperature and Breathable anti-skidding superior performance, can match in excellence or beauty with the natural gum goods, and the maintaining expense is very low, it is leather for a kind of desirable gloves for game.
For above-mentioned purpose of the present invention, feature and advantage can be become apparent, preferred embodiment cited below particularly, and coordinate accompanying drawing, elaborate.
The accompanying drawing explanation
Fig. 1 is the manufacture method flow chart of environmental protection type thermoplastic elastomer gloves for game leather of the present invention.
Fig. 2 is the structural representation of environmental protection type thermoplastic elastomer gloves for game leather of the present invention.
The specific embodiment
The invention provides a kind of manufacture method of environmental protection type thermoplastic elastomer gloves for game leather, the method comprises: the selection of base cloth and processing; Thermoplastic elastomer (TPE) adds modifier and colouring agent, and melting mixing is squeezed into netted, point-like compound with the base cloth compacting by extruder by die head, and anti-skidding lines is strengthened in compacting; Processing layer bottom in hot water removes, and by two rollers, extracts post-drying.
Below by specific embodiment, technical scheme of the present invention is specifically described, but protection scope of the present invention is not limited to described embodiment.
A kind of manufacture method of environmental protection type thermoplastic elastomer gloves for game leather, manufacturing process as shown in Figure 1, carries out following step successively:
(1) using knitted cloth as base cloth, base cloth, by the aqueous solution that contains water-soluble poval, is soaked to a bundle (first immerse the aqueous solution, then prick dry) through one, dry under 90 ℃ by baking oven afterwards, stand-by;
(2) by 1000g TPV TPV, 200g TPO POE, 20g Masterbatch by extruder 140 ℃ of lower melting mixing, be squeezed into reticular membrane through die head, before not yet cooling, with the base cloth that step (1) is made, under 0.2MPa pressure, suppressed compound, strengthen anti-skidding lines by the compacting of the pair roller with texture simultaneously, make elementary leather;
(3) the elementary leather of step (2) being made removes the processing layer of bottom in 100 ℃ of hot water, after extracting by two rollers, dries, and obtains environmental protection type thermoplastic elastomer gloves for game leather.
The environmental protection type thermoplastic elastomer gloves for game leather of making, its structure as shown in Figure 2, be respectively from the bottom to top base cloth layer 1, processing layer 2 and thermoplastic elastomer 3, the base cloth of base cloth layer 1 is knitted cloth, processing layer 2 is formed by finishing agent, finishing agent is water-soluble poval, and thermoplastic elastomer 3 is formed by the mixture of TPV TPV, TPO POE and Masterbatch, and thermoplastic elastomer 3 outer surfaces also comprise strengthens anti-skidding lines.
The resulting environmental protection type thermoplastic elastomer gloves for game leather of the present embodiment is deflected to test, abrasion test, bursting strength test through abrasion test, low temperature, test its physical property, acquired results is as shown in table 1.
A kind of manufacture method of environmental protection type thermoplastic elastomer gloves for game leather, manufacturing process as shown in Figure 1, carries out following step successively:
(1) using the elasticity woven fabric as base cloth, base cloth, by the aqueous solution that contains the water-soluble poly ammoniacum, is soaked to a bundle (first immerse the aqueous solution, then prick dry) through one, dry under 130 ℃ by baking oven afterwards, stand-by;
(2) by 900g TPV TPV, 600g polyethylene from high pressure process PE, 50g toner by extruder 350 ℃ of lower melting mixing, be squeezed into the point-like film through die head, before not yet cooling, with the base cloth that step (1) is made, under 0.8MPa pressure, suppressed compound, strengthen anti-skidding lines by the compacting of the pair roller with texture simultaneously, make elementary leather;
(3) the elementary leather of step (2) being made removes the processing layer of bottom in 110 ℃ of hot water, after extracting by two rollers, dries, and obtains environmental protection type thermoplastic elastomer gloves for game leather.
The environmental protection type thermoplastic elastomer gloves for game leather of making, its structure as shown in Figure 2, be respectively from the bottom to top base cloth layer 1, processing layer 2 and thermoplastic elastomer 3, the base cloth of base cloth layer 1 is the elasticity woven fabric, processing layer 2 is formed by finishing agent, finishing agent is the water-soluble poly ammoniacum, and thermoplastic elastomer 3 is formed by the mixture of TPV TPV, polyethylene from high pressure process PE and toner, and thermoplastic elastomer 3 outer surfaces also comprise strengthens anti-skidding lines.
The resulting environmental protection type thermoplastic elastomer gloves for game leather of the present embodiment is deflected to test, abrasion test, bursting strength test through abrasion test, low temperature, test its physical property, acquired results is as shown in table 1.
A kind of manufacture method of environmental protection type thermoplastic elastomer gloves for game leather, manufacturing process as shown in Figure 1, carries out following step successively:
(1) using knitted cloth as base cloth, base cloth, by the aqueous solution that contains water-soluble poval, is soaked to a bundle (first immerse the aqueous solution, then prick dry) through one, dry under 70 ℃ by baking oven afterwards, stand-by;
(2) by 500g TPV TPV, 600g polyamide PA, 10g toner by extruder 200 ℃ of lower melting mixing, be squeezed into reticular membrane through die head, before not yet cooling, with the base cloth that step (1) is made, under 0.1MPa pressure, suppressed compound, strengthen anti-skidding lines by the compacting of the pair roller with texture simultaneously, make elementary leather;
(3) the elementary leather of step (2) being made removes the processing layer of bottom in 80 ℃ of hot water, after extracting by two rollers, dries, and obtains environmental protection type thermoplastic elastomer gloves for game leather.
The environmental protection type thermoplastic elastomer gloves for game leather of making, its structure as shown in Figure 2, be respectively from the bottom to top base cloth layer 1, processing layer 2 and thermoplastic elastomer, base cloth in base cloth layer 1 is knitted cloth, processing layer 2 is formed by finishing agent, finishing agent is water-soluble poval, and thermoplastic elastomer 3 is formed by the mixture of TPV TPV, polyamide PA and toner, and thermoplastic elastomer 3 outer surfaces also comprise strengthens anti-skidding lines.
The resulting environmental protection type thermoplastic elastomer gloves for game leather of the present embodiment is deflected to test, abrasion test, bursting strength test through abrasion test, low temperature, test its physical property, acquired results is as shown in table 1.
Embodiment 4
A kind of manufacture method of environmental protection type thermoplastic elastomer gloves for game leather, manufacturing process as shown in Figure 1, carries out following step successively:
(1) using the elasticity woven fabric as base cloth, base cloth, by the aqueous solution that contains the water-soluble poly ammoniacum, is soaked to a bundle (first immerse the aqueous solution, then prick dry) through one, dry under 100 ℃ by baking oven afterwards, stand-by;
(2) by 1000g TPV TPV, 100g polypropylene PP and polyethylene from high pressure process PE mixture, 50g Masterbatch by extruder 240 ℃ of lower melting mixing, be squeezed into the point-like film through die head, before not yet cooling, with the base cloth that step (1) is made, under 0.4MPa pressure, suppressed compound, strengthen anti-skidding lines by the compacting of the pair roller with texture simultaneously, make elementary leather;
(3) the elementary leather of step (2) being made removes the processing layer of bottom in 90 ℃ of hot water, after extracting by two rollers, dries, and obtains environmental protection type thermoplastic elastomer gloves for game leather.
The environmental protection type thermoplastic elastomer gloves for game leather of making, its structure as shown in Figure 2, be respectively from the bottom to top base cloth layer 1, processing layer 2 and thermoplastic elastomer 3, base cloth in base cloth layer 1 is the elasticity woven fabric, processing layer 2 is formed by finishing agent, finishing agent is the water-soluble poly ammoniacum, and thermoplastic elastomer 3 is formed by the mixture of TPV TPV, polypropylene PP, polyethylene from high pressure process PE and Masterbatch, and thermoplastic elastomer 3 outer surfaces also comprise strengthens anti-skidding lines.
The resulting environmental protection type thermoplastic elastomer gloves for game leather of the present embodiment is deflected to test, abrasion test, bursting strength test through abrasion test, low temperature, test its physical property, acquired results is as shown in table 1.
Embodiment 5
A kind of manufacture method of environmental protection type thermoplastic elastomer gloves for game leather, manufacturing process as shown in Figure 1, carries out following step successively:
(1) using knitted cloth as base cloth, base cloth, by the aqueous solution that contains water-soluble poval, is soaked to a bundle (first immerse the aqueous solution, then prick dry) through one, dry under 110 ℃ by baking oven afterwards, stand-by;
(2) by 600g TPV TPV, 400g styrene-rubbery copolymer ABS, 30g toner by extruder 280 ℃ of lower melting mixing, be squeezed into reticular membrane through die head, before not yet cooling, with the base cloth that step (1) is made, under 0.6MPa pressure, suppressed compound, strengthen anti-skidding lines by the compacting of the pair roller with texture simultaneously, make elementary leather;
(3) the elementary leather of step (2) being made removes the processing layer of bottom in 70 ℃ of hot water, after extracting by two rollers, dries, and obtains environmental protection type thermoplastic elastomer gloves for game leather.
The environmental protection type thermoplastic elastomer gloves for game leather of making, its structure as shown in Figure 2, be respectively from the bottom to top base cloth layer 1, processing layer 2 and thermoplastic elastomer 3, base cloth in base cloth layer 1 is knitted cloth, processing layer 2 is formed by finishing agent, finishing agent is water-soluble poval, and thermoplastic elastomer 3 is formed by the mixture of TPV TPV, styrene-rubbery copolymer ABS and toner, and thermoplastic elastomer 3 outer surfaces also comprise strengthens anti-skidding lines.
The resulting environmental protection type thermoplastic elastomer gloves for game leather of the present embodiment is deflected to test, abrasion test, bursting strength test through abrasion test, low temperature, test its physical property, acquired results is as shown in table 1.
Embodiment 6
A kind of manufacture method of environmental protection type thermoplastic elastomer gloves for game leather, manufacturing process as shown in Figure 1, carries out following step successively:
(1) using the elasticity woven fabric as base cloth, base cloth, by the aqueous solution that contains the water-soluble poly ammoniacum, is soaked to a bundle (first immerse the aqueous solution, then prick dry) through one, dry under 120 ℃ by baking oven afterwards, stand-by;
(2) by 800g TPV TPV, 200g polyamide PA and polypropylene PP mixture, 40g Masterbatch by extruder 310 ℃ of lower melting mixing, be squeezed into the point-like film through die head, before not yet cooling, with the base cloth that step (1) is made, under 0.7MPa pressure, suppressed compound, strengthen anti-skidding lines by the compacting of the pair roller with texture simultaneously, make elementary leather;
(3) the elementary leather of step (2) being made removes the processing layer of bottom in 60 ℃ of hot water, after extracting by two rollers, dries, and obtains environmental protection type thermoplastic elastomer gloves for game leather.
The environmental protection type thermoplastic elastomer gloves for game leather of making, its structure as shown in Figure 2, be respectively from the bottom to top base cloth layer 1, processing layer 2 and thermoplastic elastomer 3, base cloth in base cloth layer 1 is the elasticity woven fabric, processing layer 2 is formed by finishing agent, finishing agent is the water-soluble poly ammoniacum, and thermoplastic elastomer 3 is formed by the mixture of TPV TPV, polyamide PA, polypropylene PP and Masterbatch, and thermoplastic elastomer 3 outer surfaces also comprise strengthens anti-skidding lines.
The resulting environmental protection type thermoplastic elastomer gloves for game leather of the present embodiment is deflected to test, abrasion test, bursting strength test through abrasion test, low temperature, test its physical property, acquired results is as shown in table 1.
The list of table 1 environmental protection type thermoplastic elastomer gloves for game leather performance
Known according to table 1, as to utilize the inventive method to manufacture environmental protection type thermoplastic elastomer gloves for game leather, wear-resisting, scratch resistance, low temperature resistant, non-skid property is splendid.
Above-described is only the preferred embodiments of the invention mode.Should be understood that for the person of ordinary skill of the art; can also make some distortion and improvement under the prerequisite that does not break away from principle of the present invention; step sectional set forth in the present invention completes, and also can complete continuously, and all these is considered as belonging to protection of the present invention.
Claims (9)
1. the manufacture method of an environmental protection type thermoplastic elastomer gloves for game leather, is characterized in that, comprises the steps:
(1) by base cloth by the aqueous solution that contains finishing agent, soak a bundle through one, first immerse the aqueous solution, then prick dryly, by baking oven, under 70-130 ℃, dry afterwards, stand-by;
(2) by 0.5-1 weight portion TPV TPV, 0.1-0.6 weight portion modifier, 0.01-0.05 weight portion colouring agent by extruder 140-350 ℃ of lower melting mixing, be squeezed into reticular membrane or point-like film through die head, before not yet cooling, with the base cloth that step (1) is made, under 0.1-0.8MPa pressure, suppressed compound, strengthen anti-skidding lines by the compacting of the pair roller with texture simultaneously, make elementary leather;
(3) the elementary leather of step (2) being made removes the processing layer of bottom in 60-110 ℃ of hot water, after extracting by two rollers, dries, and obtains environmental protection type thermoplastic elastomer gloves for game leather.
2. method according to claim 1, it is characterized in that the mixture that the modifier described in step (2) is following one or several: TPO POE, polyethylene from high pressure process PE, polyamide PA, polypropylene PP, styrene-rubbery copolymer ABS.
3. method according to claim 2, is characterized in that, the modifier described in step (2) is TPO POE.
4. method according to claim 1, is characterized in that, the colouring agent described in step (2) is Masterbatch or toner.
5. method according to claim 4, is characterized in that, the colouring agent described in step (2) is Masterbatch.
6. method according to claim 1, is characterized in that, the described base cloth of step (1) is knitted cloth or elasticity woven fabric.
7. method according to claim 6, is characterized in that, the described base cloth of step (1) is knitted cloth.
8. method according to claim 1, is characterized in that, the described finishing agent of step (1) is water-soluble poval or water-soluble poly ammoniacum.
9. method according to claim 8, it is characterized in that: it is characterized in that, the described finishing agent of step (1) is water-soluble poval.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103437201A (en) * | 2013-09-10 | 2013-12-11 | 华伦皮塑（苏州）有限公司 | Manufacturing method of environment-friendly thermoplastic elastomer golf glove leather |
| CN103770344A (en) * | 2014-01-03 | 2014-05-07 | 安吉藤仓橡胶有限公司 | Base cloth paste leading treatment technology |
| CN104233847A (en) * | 2014-10-08 | 2014-12-24 | 上海华峰超纤材料股份有限公司 | Dripping plastic superfine fiber synthetic leather and production method thereof |
| CN114908580A (en) * | 2022-04-15 | 2022-08-16 | 广东柏拉图塑胶有限公司 | Military light covering cloth and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102561049A (en) * | 2011-12-31 | 2012-07-11 | 华伦皮塑（苏州）有限公司 | Production method of zero-emission and full-environment-friendly synthetic leather |
| CN102717533A (en) * | 2012-07-09 | 2012-10-10 | 华伦皮塑（苏州）有限公司 | Method for preparing environment-friendly outdoor sofa leather |
-
2013
- 2013-09-10 CN CN201310409104.3A patent/CN103437200B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102561049A (en) * | 2011-12-31 | 2012-07-11 | 华伦皮塑（苏州）有限公司 | Production method of zero-emission and full-environment-friendly synthetic leather |
| CN102717533A (en) * | 2012-07-09 | 2012-10-10 | 华伦皮塑（苏州）有限公司 | Method for preparing environment-friendly outdoor sofa leather |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103437201A (en) * | 2013-09-10 | 2013-12-11 | 华伦皮塑（苏州）有限公司 | Manufacturing method of environment-friendly thermoplastic elastomer golf glove leather |
| CN103770344A (en) * | 2014-01-03 | 2014-05-07 | 安吉藤仓橡胶有限公司 | Base cloth paste leading treatment technology |
| CN104233847A (en) * | 2014-10-08 | 2014-12-24 | 上海华峰超纤材料股份有限公司 | Dripping plastic superfine fiber synthetic leather and production method thereof |
| CN114908580A (en) * | 2022-04-15 | 2022-08-16 | 广东柏拉图塑胶有限公司 | Military light covering cloth and preparation method thereof |
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| CN103437200B (en) | 2015-09-09 |
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