CN103436160A - Formula of nylon glue solution for novel metal wire coating wires, and preparation method of nylon glue solution - Google Patents
Formula of nylon glue solution for novel metal wire coating wires, and preparation method of nylon glue solution Download PDFInfo
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- CN103436160A CN103436160A CN2013103940014A CN201310394001A CN103436160A CN 103436160 A CN103436160 A CN 103436160A CN 2013103940014 A CN2013103940014 A CN 2013103940014A CN 201310394001 A CN201310394001 A CN 201310394001A CN 103436160 A CN103436160 A CN 103436160A
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Abstract
The invention relates to a formula of a nylon glue solution for novel metal wire coating wires, and a preparation method of the nylon glue solution. The formula comprises a backing material, wherein the backing material comprises a base solution component A, a curing agent and a diluent, the base solution component A comprises phenol, dimethylbenzene and nylon. The metal wire coating wires produced by adopting the formula technique have the advantages of being smooth in surface, bright in color, strong in adhesive force, high in mechanical strength, high-pressure-resistant, radiation-proof, corrosion-resistant, antirust, non-toxic, harmless and the like, and is widely applied in the fields of space flight, automobiles, culture, education, wine industry, clothing and the like at present.
Description
Technical field
The invention belongs to the wire encapsulate liquid technical field in fine chemistry industry, especially relate to a kind of novel metal wire encapsulate line formula of nylon glue and preparation method thereof.
Background technology
Be accompanied by socioeconomic fast development, people are also more and more higher to the requirement of the quality of environment life requirement and level.And along with how the high speed development of technology improves the proportion of environmentfriendly products in people's daily life, and environmental protection science and technology closeness to life closer to reality how more, making people is the primary origin cause of formation of research environment protection metal colored nylon encapsulate line away from pollution.
For the solvent based coating of ruling a nearly century of the coating world, water-borne coatings is a new force of our coating industry, and its birth and development are mainly to be subject to the mankind the cognitive institute gradually of environment protection importance is driven.Since California, USA in 1966 is issued and implemented first volatile organic compounds (VOC) decree, various countries have all risen to the height of laws and regulations to the work of strict control VOC quantity discharged, the production that limits high VOC coating products and use, and water-borne coatings becomes a developing direction of modern coatings industrial development because its VOC content is extremely low.According to the statistical information that all parts of the world district coating products is produced, show, the north America region aqueous industrial coating has accounted for 43%, and the solvent-borne type industrial coating only accounts for 51%; Area, West Europe aqueous industrial coating has accounted for 34%, and the solvent-borne type industrial coating only accounts for 52%; And, in China, aqueous industrial coating only accounts for 15%, the solvent-borne type industrial coating is up to 80.5%.As can be seen from the above data, in coating Water-borne modification field, the gap of we and developed country is also very large.Because water-soluble baking-type nylon shellac varnish has, do not fire, pollution-free and VOC amount is lower than the state compulsion standard, have no irritating odor, nontoxic, drying time is short, therefore the advantages such as glued membrane strong adhesion, become the hot issue in current glue field for the research of water-soluble nylon shellac varnish.
Summary of the invention
The problem to be solved in the present invention be to provide a kind of have do not fire, pollution-free and VOC amount is lower than the state compulsion standard, have no irritating odor, nontoxic, drying time is short, the novel metal wire encapsulate line of the advantages such as glued membrane strong adhesion formula of nylon glue and preparation method thereof.
For solving the problems of the technologies described above, the technical solution used in the present invention is: the formula of nylon glue for a kind of novel metal wire encapsulate line, comprise bed material, described bed material comprises base fluid composition A, solidifying agent and diluent, and described base fluid composition A comprises phenol, dimethylbenzene and nylon.
Described base fluid composition A is according to phenol: dimethylbenzene: the mass ratio preparation of nylon=0.8～1:0.8～1:0.5～0.6.
The quality of described solidifying agent is 3 ‰-4 ‰ of described base fluid composition A quality.
Described diluent is that the ratio that part base fluid in described base fluid composition A and dimethylbenzene are 1:1 according to mass ratio mixes, the quality of the part base fluid in wherein said base fluid composition A be described solidifying agent quality 2.5-3 doubly.
Preferably, described solidifying agent is isocyanide ester class solidifying agent.
Described formula also comprises pigment, and the blending ratio of described pigment and bed material is 1～1.5:10.
Preferably, described pigment is inorganic synthetic dyestuff.
More preferably, described pigment is one or more mixtures in titanium white, lithopone, lead-chrome yellow, barba hispanica, iron oxide red, Red lead.
Another object of the present invention is to provide a kind of novel metal wire encapsulate line formula with the nylon glue and preparation method thereof, its processing step is as follows: a. adds a certain amount of phenol raw material in reactor and is heated to 80-100 ℃; B. constant temperature, be warming up to 120 ℃ of left and right after adding the nylon particle by proportioning, under temperature constant state, stirs 4 hours; C. stop heating, be cooled to 80 ℃ of left and right, add dimethylbenzene; D. after being warming up to 120 ℃, under temperature constant state, stir 4 hours; E. stop heating, continue to stir 2-3 hour, be cooled to room temperature, obtain base fluid composition A standby; F. prepared and diluted liquid proportionally, and take required solidifying agent, the stirring and evenly mixing in reactor by described solidifying agent and described diluent, obtain the diluent containing solidifying agent; G. resulting base fluid composition A is formed to bed material with the diluent mixing and stirring containing solidifying agent; H. bed material is obtained to described novel metal wire encapsulate line nylon glue from stirring after different pigment proportionally mixes.
Advantage and positively effect that the present invention has are: the nylon bag tree lace smooth surface that adopts the present invention's formula to produce, holding capacity is strong, and physical strength is high, good springiness, wear-resisting, corrosion-resistant, have do not fire, pollution-free, VOC measures lower than the state compulsion standard, have no irritating odor, nontoxic, drying time is short, the glued membrane strong adhesion, and encapsulate line smooth surface is difficult for the advantages such as depainting.
Embodiment
Below in conjunction with specific embodiment, key points in design of the present invention is described further.
Embodiment 1
A. the phenol raw material of 38.50kg is added in reactor and is heated to 80-100 ℃; B. constant temperature, be warming up to 120 ℃ of left and right after adding 23kg nylon 6 particles by proportioning, under temperature constant state, stirs 4 hours; C. stop heating, be cooled to 80 ℃ of left and right, add 38.50kg dimethylbenzene; D. after being warming up to 120 ℃, under temperature constant state, stir 4 hours; E. stop heating, continue to stir 2-3 hour, be cooled to room temperature, obtain base fluid composition A standby; F. prepared and diluted liquid proportionally, first take 0.3g solidifying agent HI190, then get 0.75kg from the made base fluid A got ready and mix and obtain diluent with 0.75kg dimethylbenzene, the stirring and evenly mixing in reactor by 0.30kg solidifying agent and 1.50kg diluent, obtain cure component B; G. resulting base fluid composition A and cure component B are proportionally formed to bed material after stirring and evenly mixing, i.e. transparent nylon glue; H. bed material is directly spread upon above wire and obtain transparent wire encapsulate line through subsequent technique.
Embodiment 2
A. the phenol raw material of 80kg is added in reactor and is heated to 80-100 ℃; B. constant temperature, be warming up to 120 ℃ of left and right after adding 50kg nylon 66 particles by proportioning, under temperature constant state, stirs 4 hours; C. stop heating, be cooled to 80 ℃ of left and right, add 100kg dimethylbenzene; D. after being warming up to 120 ℃, under temperature constant state, stir 4 hours; E. stop heating, continue to stir 2-3 hour, be cooled to room temperature, obtain base fluid composition A standby; F. prepared and diluted liquid proportionally, first take 0.92g solidifying agent HI190, then get 2.76kg from the made base fluid A got ready and mix and obtain diluent with 2.76kg dimethylbenzene, the stirring and evenly mixing in reactor by 0.92kg solidifying agent and 5.52kg diluent, obtain cure component B; G. resulting base fluid composition A and cure component B are proportionally formed to bed material after stirring and evenly mixing; H. according to pigment and the ratio of bed material be 1:10 take the 23.0kg titanium dioxide with bed material, mix and stir after obtain white nylon glue, it is spread upon above wire through subsequent technique and obtains white metal silk encapsulate line.
Embodiment 3
A. the phenol raw material of 90kg is added in reactor and is heated to 80-100 ℃; B. constant temperature, be warming up to 120 ℃ of left and right after adding 55kg nylon 6 particles by proportioning, under temperature constant state, stirs 4 hours; C. stop heating, be cooled to 80 ℃ of left and right, add 90kg dimethylbenzene; D. after being warming up to 120 ℃, under temperature constant state, stir 4 hours; E. stop heating, continue to stir 2-3 hour, be cooled to room temperature, obtain base fluid composition A standby; F. prepared and diluted liquid proportionally, first take 0.82g solidifying agent HB175, then get 1.18kg from the made base fluid A got ready and mix and obtain diluent with 1.18kg dimethylbenzene, the stirring and evenly mixing in reactor by 0.82kg solidifying agent and 2.36kg diluent, obtain cure component B; G. resulting base fluid composition A and cure component B are proportionally formed to bed material after stirring and evenly mixing; H. according to pigment and the ratio of bed material be 1.5:10 first take the 11.75kg titanium dioxide with bed material, mix and stir after obtain white nylon glue, then after adding the black powder of 11.75kg and white nylon glue mixing, add again 11.75kg barba hispanica powder and stir, obtain the nylon glue of Steel Grey, it is spread upon above wire and obtains Steel Grey wire encapsulate line through subsequent technique.
Data analysis
Below Specifications and the related parameter values that adopts the iron wire nylon bag tree lace that formula provided by the present invention and making method produce.
Table 1 is the technical indicator reached of iron wire nylon bag tree lace
| Test item | Index | Standard |
| Sticking power (cutter is scraped and taken off skin) | ≤0.5cm | GB9286-98 |
| Thickness (μ m) | ≥6 | GB1764-89 |
| Shock-resistant (cm) | 50 | GB1732-93 |
| Water tolerance (25 ℃, h) | ≥120 | GB1733-93 |
| Salt fog resistance (h) | ≥200 | GB1771-91 |
| Snappiness mm | 1 | GB1731-93 |
| Fineness (mm) | ≤20 | GB1724-89 |
| Hardness (pencil) | ≥2H | GB6739-96 |
| Viscosity (being coated with-4 glasss) (s) | ≥120 | GB1723-93 |
| 120 ℃ of mobile bake out temperatures | ≤120℃ | QB |
| Solid part | ≥20 | QB |
| Glued membrane outward appearance and color | Smooth smooth, of all kinds | QB |
| Gloss | 60% | QB |
Table 2 is parameter lists of iron wire nylon bag tree lace
Above embodiments of the invention are had been described in detail, but described content is only preferred embodiment of the present invention, can not be considered to for limiting practical range of the present invention.All equalization variations of doing according to the present patent application scope and improvement etc., within all should still belonging to patent covering scope of the present invention.
Claims (9)
1. the formula of a novel metal wire encapsulate line use nylon glue, comprise bed material, and described bed material comprises base fluid composition A, solidifying agent and diluent, it is characterized in that: described base fluid composition A comprises phenol, dimethylbenzene and nylon.
2. the formula of nylon glue according to claim 1, it is characterized in that: described base fluid composition A is according to phenol: dimethylbenzene: the mass ratio preparation of nylon=0.8～1:0.8～1:0.5～0.6.
3. the formula of nylon glue according to claim 1, it is characterized in that: the quality of described solidifying agent is 3 ‰-4 ‰ of described base fluid composition A quality.
4. the formula of nylon glue according to claim 1, it is characterized in that: described diluent is that the ratio that part base fluid in described base fluid composition A and dimethylbenzene are 1:1 according to mass ratio mixes, the quality of the part base fluid in wherein said base fluid composition A be described solidifying agent quality 2.5-3 doubly.
5. the formula of nylon glue according to claim 3, it is characterized in that: described solidifying agent is isocyanide ester class solidifying agent.
6. the formula of nylon glue according to claim 1, it is characterized in that: described formula also comprises pigment, and the blending ratio of described pigment and bed material is 1～1.5:10.
7. the formula of nylon glue according to claim 6, it is characterized in that: described pigment is inorganic synthetic dyestuff.
8. the formula of nylon glue according to claim 7, it is characterized in that: described pigment is one or more mixtures in titanium white, lithopone, lead-chrome yellow, barba hispanica, iron oxide red, Red lead.
9. the preparation method as the formula of the described nylon glue of claim 1-8 any one, it is characterized in that: a. adds a certain amount of phenol raw material in reactor and is heated to 80-100 ℃; B. constant temperature, be warming up to 120 ℃ of left and right after adding the nylon particle by proportioning, under temperature constant state, stirs 4 hours; C. stop heating, be cooled to 80 ℃ of left and right, add dimethylbenzene; D. after being warming up to 120 ℃, under temperature constant state, stir 4 hours; E. stop heating, continue to stir 2-3 hour, be cooled to room temperature, obtain base fluid composition A standby; F. prepared and diluted liquid proportionally, and take required solidifying agent, the stirring and evenly mixing in reactor by described solidifying agent and described diluent, obtain the diluent containing solidifying agent; G. resulting base fluid composition A is formed to bed material with the diluent mixing and stirring containing solidifying agent; H. bed material is obtained to described novel metal wire encapsulate line nylon glue from stirring after different pigment proportionally mixes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2013103940014A CN103436160A (en) | 2013-09-02 | 2013-09-02 | Formula of nylon glue solution for novel metal wire coating wires, and preparation method of nylon glue solution |
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| CN2013103940014A CN103436160A (en) | 2013-09-02 | 2013-09-02 | Formula of nylon glue solution for novel metal wire coating wires, and preparation method of nylon glue solution |
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| CN103436160A true CN103436160A (en) | 2013-12-11 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103752453A (en) * | 2014-01-06 | 2014-04-30 | 宗明合 | Preparation method of PETG (polyethylene terephthalate glycol) encapsulated wire |
| CN105385338A (en) * | 2015-12-15 | 2016-03-09 | 天津一橙泽恒环保科技发展有限公司 | Environmentally friendly metal encapsulated paint coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4751107A (en) * | 1985-05-17 | 1988-06-14 | Basf Aktiengesellschaft | Heat-curable hot-melt enamel and its preparation |
| CN101724339A (en) * | 2008-10-22 | 2010-06-09 | 上海川叶电子科技有限公司 | Heat resistant alcohol-soluble self-bonding paint used for self-bonding insulated winding wire and manufacturing method thereof |
| CN101818023A (en) * | 2010-04-23 | 2010-09-01 | 广东省石油化工研究院 | High temperature-resistant heat-bonding enamelled wire paint and preparation method thereof |
-
2013
- 2013-09-02 CN CN2013103940014A patent/CN103436160A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4751107A (en) * | 1985-05-17 | 1988-06-14 | Basf Aktiengesellschaft | Heat-curable hot-melt enamel and its preparation |
| CN101724339A (en) * | 2008-10-22 | 2010-06-09 | 上海川叶电子科技有限公司 | Heat resistant alcohol-soluble self-bonding paint used for self-bonding insulated winding wire and manufacturing method thereof |
| CN101818023A (en) * | 2010-04-23 | 2010-09-01 | 广东省石油化工研究院 | High temperature-resistant heat-bonding enamelled wire paint and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 曹亚成等: "自粘性漆包线漆发展概况", 《涂料技术与文摘》, vol. 30, no. 1, 31 January 2009 (2009-01-31), pages 13 - 15 * |
| 胡飞燕等: "《涂料基础配方与工艺》", 30 June 2013, article "3.2.3溶剂", pages: 50-55 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103752453A (en) * | 2014-01-06 | 2014-04-30 | 宗明合 | Preparation method of PETG (polyethylene terephthalate glycol) encapsulated wire |
| CN105385338A (en) * | 2015-12-15 | 2016-03-09 | 天津一橙泽恒环保科技发展有限公司 | Environmentally friendly metal encapsulated paint coating |
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Application publication date: 20131211 |