CN103435776A - Preparation method of environment-friendly PU plastic for race tracks - Google Patents
Preparation method of environment-friendly PU plastic for race tracks Download PDFInfo
- Publication number
- CN103435776A CN103435776A CN2013103422388A CN201310342238A CN103435776A CN 103435776 A CN103435776 A CN 103435776A CN 2013103422388 A CN2013103422388 A CN 2013103422388A CN 201310342238 A CN201310342238 A CN 201310342238A CN 103435776 A CN103435776 A CN 103435776A
- Authority
- CN
- China
- Prior art keywords
- preparation
- environment
- plastic cement
- friendly type
- plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Landscapes
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a preparation method of environment-friendly PU plastic for race tracks. The preparation method is characterized in that the PU plastic comprises the components of polyether polyol, diphenyl methane diisocyanate, 1,4-butanediol and an organic composite rare-earth catalyst; the preparation method comprises the steps of prepolymerization, removal of air bubbles in vacuum, pouring, curing and finished product forming. The PU plastic prepared by the preparation method has low toxicity and good mechanical property; a plastic race track prepared with the PU plastic is safe, environment-friendly and free from defects such as bubbles and depression.
Description
Technical field
The present invention relates to the plastic cement preparing technical field, particularly relate to the preparation method of a kind of runway with environment-friendly type PU plastic cement.
Background technology
The polyurethane plastic runway overwhelming majority of laying at present is mixed type, its basic recipe is the TDI(tolylene diisocyanate)-MOCA(3,3 ＇-bis-chloro-4,4 ＇-diaminodiphenyl-methane)-heavy metal catalyst system, cause be laid to plastic cement race track to have the problem of poisoning and laying high cost.TDI belongs to II level poisonous substance, it is suspicious human carcinogen's thing, international movement runway technology association (IST) just proposed the suggestion of " not accepting to use the motion runway containing the polyurethane system of TDI composition " as far back as 1994, MOCA belongs to arylamine ester class chemical, toxicity is larger, can cause bladder cancer, take organic mercury/lead or organic mercury/zinc composite catalyst as main heavy metal catalyst system harmful to human, contaminate environment.
Summary of the invention
The technical problem that the present invention mainly solves is to provide the preparation method of a kind of runway with environment-friendly type PU plastic cement, can solve the large problem of conventional P U plastic cement race track toxicity.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: the preparation method of environment-friendly type PU plastic cement for a kind of runway, and component comprises: polyether glycol, diphenylmethanediisocyanate, BDO, organic composite rare earth catalyst; Preparation method's step is: prepolymerization-vacuum outgas bubble-cast-solidify-finished product.
In a preferred embodiment of the present invention, described organic composite rare earth catalyst is isooctoate of rare earth metal and isocaprylic acid zinc, and proportioning is 2:1.
In a preferred embodiment of the present invention, described prepolymerization method is: in reaction vessel, add polyether glycol, stirring is warmed up to certain temperature, and vacuumize stirring dehydration l h, after having dewatered, be cooled to temperature required, add the diphenylmethanediisocyanate that becomes certain proportioning with polyether glycol, BDO, finally add the organic RE composite catalyst.
In a preferred embodiment of the present invention, the technique of described vacuum outgas bubble is: vacuum tightness 0.02～0.05MPa, time 2h.
In a preferred embodiment of the present invention, described curing process is: 140 ℃ of solidification values, set time 4h.
In a preferred embodiment of the present invention, the temperature that described stirring heats up is 110～120 ℃.
In a preferred embodiment of the present invention, described temperature required be 50～60 ℃.
In a preferred embodiment of the present invention, the quality proportioning of described polyether glycol, diphenylmethanediisocyanate, BDO is 100:50:15.
The invention has the beneficial effects as follows: the preparation method of environment-friendly type PU plastic cement for a kind of runway of the present invention, the PU plastic cement toxicity of preparation is low, and mechanical property is good, and the plastic cement race track prepared with it is safety and environmental protection not only, and there is no the defects such as bubble, depression.
The accompanying drawing explanation
Fig. 1 is the schematic flow sheet of a kind of runway of the present invention by the preparation method of environment-friendly type PU plastic cement.
Embodiment
Below in conjunction with accompanying drawing, preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
Refer to Fig. 1, the embodiment of the present invention comprises:
Agitator is being housed, in 3 mouthfuls of flasks of vacuum meter and thermometer, add 100g polyether glycol 3010, stirring is warmed up to 110～120 ℃, and vacuumize and stir dehydration 1h, after having dewatered, be cooled to 50～60 ℃, add diphenylmethanediisocyanate 50g, then add 1, 4-butyleneglycol 15g, the organic RE composite catalyst 5g that isooctoate of rare earth metal and isocaprylic acid zinc proportioning are 2:1, by said mixture de-bubbled 2h under the vacuum tightness of 0.02～0.05MPa, promptly be poured into and scribble estersil and be preheating in the mould of 80 ℃, solidify 4 h under 140 ℃ after, obtain the PU plastic cement.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes specification sheets of the present invention and accompanying drawing content to do; or directly or indirectly be used in other relevant technical fields, all in like manner be included in scope of patent protection of the present invention.
Claims (8)
1. the preparation method of a runway use environment-friendly type PU plastic cement, is characterized in that, component comprises: polyether glycol, diphenylmethanediisocyanate, BDO, organic composite rare earth catalyst; Preparation method's step is: prepolymerization-vacuum outgas bubble-cast-solidify-finished product.
2. the preparation method of environment-friendly type PU plastic cement for runway according to claim 1, is characterized in that, described organic composite rare earth catalyst is isooctoate of rare earth metal and isocaprylic acid zinc, and proportioning is 2:1.
3. the preparation method of environment-friendly type PU plastic cement for runway according to claim 1, it is characterized in that, described prepolymerization method is: add polyether glycol in reaction vessel, stir and be warmed up to certain temperature, and vacuumize stirring dehydration l h, after having dewatered, be cooled to temperature requiredly, add the diphenylmethanediisocyanate that becomes certain proportioning with polyether glycol, 1, the 4-butyleneglycol, finally add the organic RE composite catalyst.
4. the preparation method of environment-friendly type PU plastic cement for runway according to claim 1, is characterized in that, the technique of described vacuum outgas bubble is: vacuum tightness 0.02～0.05MPa, time 2h.
5. the preparation method of environment-friendly type PU plastic cement for runway according to claim 1, is characterized in that, described curing process is: 140 ℃ of solidification values, set time 4h.
6. the preparation method of environment-friendly type PU plastic cement for runway according to claim 3, is characterized in that, the temperature that described stirring heats up is 110～120 ℃.
7. the preparation method of environment-friendly type PU plastic cement for runway according to claim 3, is characterized in that, described temperature required be 50～60 ℃.
8. the preparation method of environment-friendly type PU plastic cement for runway according to claim 3, is characterized in that, the quality proportioning of described polyether glycol, diphenylmethanediisocyanate, BDO is 100:50:15.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013103422388A CN103435776A (en) | 2013-08-08 | 2013-08-08 | Preparation method of environment-friendly PU plastic for race tracks |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013103422388A CN103435776A (en) | 2013-08-08 | 2013-08-08 | Preparation method of environment-friendly PU plastic for race tracks |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103435776A true CN103435776A (en) | 2013-12-11 |
Family
ID=49689503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013103422388A Pending CN103435776A (en) | 2013-08-08 | 2013-08-08 | Preparation method of environment-friendly PU plastic for race tracks |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103435776A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709923A (en) * | 2013-12-18 | 2014-04-09 | 黎明化工研究设计院有限责任公司 | Wear-resistant spraying polyurethane resin composition, and preparation method and construction method thereof |
| CN104725659A (en) * | 2015-03-13 | 2015-06-24 | 华南理工大学 | Polyurethane using rare earth as foaming aid and preparation method thereof |
| CN105949751A (en) * | 2016-07-06 | 2016-09-21 | 苏州亚科塑胶有限公司 | Preparation method of anti-skid, abrasion-resistant and high-elasticity composite plastic runway surface layer |
| CN106977679A (en) * | 2017-03-28 | 2017-07-25 | 江苏耐斯坦铺装材料有限公司 | A kind of composite catalyst and plastic cement race track adhesive based on based on organic RE material |
| CN107216800A (en) * | 2017-06-28 | 2017-09-29 | 吕超 | A kind of hydrophobically modified nano barium sulfate fills the preparation method of aqueous polyurethane coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1580163A (en) * | 2004-05-19 | 2005-02-16 | 深圳市奥顺达实业有限公司 | Environmentally friendly track rubber, and its production method and track construction method using same |
| CN101245184A (en) * | 2007-02-15 | 2008-08-20 | 天津市景鸿体育设施技术有限公司 | Nano-environment protection type polyurethane paving material for athletic ground and manufacture method thereof |
| CN102424721A (en) * | 2011-11-25 | 2012-04-25 | 广州杰锐体育设施有限公司 | Environment friendly plastic slurry for sports field and preparation method thereof |
-
2013
- 2013-08-08 CN CN2013103422388A patent/CN103435776A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1580163A (en) * | 2004-05-19 | 2005-02-16 | 深圳市奥顺达实业有限公司 | Environmentally friendly track rubber, and its production method and track construction method using same |
| CN101245184A (en) * | 2007-02-15 | 2008-08-20 | 天津市景鸿体育设施技术有限公司 | Nano-environment protection type polyurethane paving material for athletic ground and manufacture method thereof |
| CN102424721A (en) * | 2011-11-25 | 2012-04-25 | 广州杰锐体育设施有限公司 | Environment friendly plastic slurry for sports field and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 孙青峰 等: ""MDI型双组分聚氨酯塑胶跑道浆料的研制"", 《聚氨酯工业》, vol. 18, no. 3, 15 September 2003 (2003-09-15), pages 22 - 24 * |
| 苏政权 等: ""稀土催化剂在MDI型聚氨酯塑胶跑道材料中的应用研究"", 《新型建筑材料》, 25 May 2006 (2006-05-25), pages 29 - 31 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709923A (en) * | 2013-12-18 | 2014-04-09 | 黎明化工研究设计院有限责任公司 | Wear-resistant spraying polyurethane resin composition, and preparation method and construction method thereof |
| CN103709923B (en) * | 2013-12-18 | 2016-08-17 | 黎明化工研究设计院有限责任公司 | A kind of wear-resisting spraying polyurethane resin combination and preparation method thereof and construction method |
| CN104725659A (en) * | 2015-03-13 | 2015-06-24 | 华南理工大学 | Polyurethane using rare earth as foaming aid and preparation method thereof |
| CN104725659B (en) * | 2015-03-13 | 2018-02-23 | 华南理工大学 | A kind of polyurethane by the use of rare earth as blowing promotor and preparation method thereof |
| CN105949751A (en) * | 2016-07-06 | 2016-09-21 | 苏州亚科塑胶有限公司 | Preparation method of anti-skid, abrasion-resistant and high-elasticity composite plastic runway surface layer |
| CN106977679A (en) * | 2017-03-28 | 2017-07-25 | 江苏耐斯坦铺装材料有限公司 | A kind of composite catalyst and plastic cement race track adhesive based on based on organic RE material |
| CN106977679B (en) * | 2017-03-28 | 2021-03-19 | 江苏耐斯坦建设有限公司 | Composite catalyst based on organic rare earth material and adhesive for plastic track |
| CN107216800A (en) * | 2017-06-28 | 2017-09-29 | 吕超 | A kind of hydrophobically modified nano barium sulfate fills the preparation method of aqueous polyurethane coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103435776A (en) | Preparation method of environment-friendly PU plastic for race tracks | |
| CN104559138B (en) | A kind of hydrophilic two-component grouting leak-stopping material | |
| CN104558514A (en) | High-strength polyurethane modified silicate grouting reinforcement material as well as preparation method and application thereof | |
| CN102070874B (en) | High-permeability and high-strength epoxy grouting material, preparation method thereof and application thereof | |
| CN102504522B (en) | Polyurethane elastomer composition for producing polishing wheel | |
| CN101456963B (en) | Method for preparing microsphere composite foam material | |
| CN105315878A (en) | Solvent-free one-component polyurethane waterproof coating | |
| CN104263307A (en) | Room temperature curing polyurethane encapsulating material and preparation method thereof | |
| CN103214822A (en) | Polyurethane composite for grouting and preparation method thereof | |
| CN103923557A (en) | Special prime coat for spraying polyurea elastomer and preparation method of special prime coat | |
| CN104448713B (en) | A kind of open cell type heat conductivity epoxy radicals composite porous material and preparation method thereof and application | |
| CN110684165B (en) | Polyurethane composition, polyurethane composite material and preparation method thereof | |
| CN103351459B (en) | The tackiness agent of a kind of ester class plasticising and preparation method | |
| CN104559137B (en) | High resiliency no-solvent polyurethane loss circulation material and preparation method and application | |
| CN107216609A (en) | Fast blockage epoxide resin grouting material | |
| CN103224600A (en) | Polyurethane foamed material for soil heavy mental ion adsorption | |
| CN103724985B (en) | A kind of hollow ceramic microspheres fills the preparation method of epoxy modified polyurethane | |
| CN104497946B (en) | A kind of resistance to water resistance to deformation binding agent | |
| CN104031240B (en) | A kind of polyurethane adhesive and preparation method thereof | |
| CN104178016B (en) | The preparation method of environment-friendly type FJS water-repellent paint | |
| CN109535382A (en) | A kind of non yellowing polyurethane sponge and preparation method thereof | |
| CN101914205B (en) | Resin with low surface energy and preparation method thereof | |
| CN105399918B (en) | Rubber roller silicane-modified polyurethane elastic material and preparation method thereof | |
| CN102181224A (en) | Reactive polymer cement waterproof coating | |
| CN104530379B (en) | Make marine glue mono-component polyurethane material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20131211 |