CN103432884A - Composite organic acid salt solution for absorbing sulfur dioxide - Google Patents
Composite organic acid salt solution for absorbing sulfur dioxide Download PDFInfo
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- CN103432884A CN103432884A CN2013102846104A CN201310284610A CN103432884A CN 103432884 A CN103432884 A CN 103432884A CN 2013102846104 A CN2013102846104 A CN 2013102846104A CN 201310284610 A CN201310284610 A CN 201310284610A CN 103432884 A CN103432884 A CN 103432884A
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- acid salt
- tartrate
- aqueous solution
- organic acid
- sulfur dioxide
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- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 150000007524 organic acids Chemical class 0.000 title claims abstract description 17
- 239000012266 salt solution Substances 0.000 title abstract 3
- 239000007864 aqueous solution Substances 0.000 claims abstract description 30
- 239000007788 liquid Substances 0.000 claims abstract description 23
- 238000010521 absorption reaction Methods 0.000 claims abstract description 22
- -1 organic acid salt Chemical class 0.000 claims abstract description 18
- 239000000243 solution Substances 0.000 claims abstract description 13
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 10
- 229940095064 tartrate Drugs 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 4
- AVTYONGGKAJVTE-OLXYHTOASA-L potassium L-tartrate Chemical compound [K+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O AVTYONGGKAJVTE-OLXYHTOASA-L 0.000 claims description 16
- 229940111695 potassium tartrate Drugs 0.000 claims description 16
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical group [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims description 16
- 239000001433 sodium tartrate Substances 0.000 claims description 16
- 239000001472 potassium tartrate Substances 0.000 claims description 14
- 235000011005 potassium tartrates Nutrition 0.000 claims description 14
- 238000009938 salting Methods 0.000 claims description 14
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical compound CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 claims description 10
- 229960002167 sodium tartrate Drugs 0.000 claims description 10
- 235000011004 sodium tartrates Nutrition 0.000 claims description 10
- KFYGELIIGMESGJ-UHFFFAOYSA-N 3-aminopropanoic acid;sodium Chemical compound [Na].NCCC(O)=O KFYGELIIGMESGJ-UHFFFAOYSA-N 0.000 claims description 8
- 235000013905 glycine and its sodium salt Nutrition 0.000 claims description 8
- 239000004247 glycine and its sodium salt Substances 0.000 claims description 8
- 229940029258 sodium glycinate Drugs 0.000 claims description 8
- 235000011006 sodium potassium tartrate Nutrition 0.000 claims description 8
- DXDTUQXKMVJYAM-UHFFFAOYSA-N 2-aminoacetic acid;potassium Chemical compound [K].NCC(O)=O DXDTUQXKMVJYAM-UHFFFAOYSA-N 0.000 claims description 6
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical class NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 claims description 6
- WUWHFEHKUQVYLF-UHFFFAOYSA-M sodium;2-aminoacetate Chemical compound [Na+].NCC([O-])=O WUWHFEHKUQVYLF-UHFFFAOYSA-M 0.000 claims description 6
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 claims description 4
- OEFVXZYHJJGTNH-UHFFFAOYSA-N [K].NCCC(O)=O Chemical compound [K].NCCC(O)=O OEFVXZYHJJGTNH-UHFFFAOYSA-N 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- 239000001476 sodium potassium tartrate Substances 0.000 claims description 2
- 159000000000 sodium salts Chemical group 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 32
- 238000006477 desulfuration reaction Methods 0.000 abstract description 25
- 239000007789 gas Substances 0.000 abstract description 25
- 230000023556 desulfurization Effects 0.000 abstract description 19
- 239000012528 membrane Substances 0.000 abstract description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 16
- 239000003546 flue gas Substances 0.000 abstract description 16
- 239000002250 absorbent Substances 0.000 abstract description 13
- 230000002745 absorbent Effects 0.000 abstract description 13
- 238000012546 transfer Methods 0.000 abstract description 8
- 238000000926 separation method Methods 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 239000006096 absorbing agent Substances 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 229940074439 potassium sodium tartrate Drugs 0.000 description 6
- 239000008246 gaseous mixture Substances 0.000 description 5
- 230000003009 desulfurizing effect Effects 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 230000036632 reaction speed Effects 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 239000000809 air pollutant Substances 0.000 description 2
- 231100001243 air pollutant Toxicity 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000005272 metallurgy Methods 0.000 description 2
- 238000003908 quality control method Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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Abstract
The invention relates to the field of liquid-gas separation, in particular to the field of flue gas desulfurization, and more particularly relates to a composite organic acid salt solution for absorbing sulfur dioxide. The invention aims to provide a sulfur dioxide absorbent which can be used for absorption of a membrane contactor. The invention discloses an organic acid salt aqueous solution, which consists of tartrate and amino acid salt aqueous solution, wherein the mixing molar ratio of the tartrate to the amino acid salt is 1: (0.5-2.8). The solution of organic acid salt provided by the invention has the advantages of good chemical stability, small foamability, small viscosity, rich raw material source, easy purchase and low price. The desulfurization process using the organic acid salt solution disclosed by the invention has the advantages of high mass transfer coefficient, no disturbance of gas-liquid flow, small mass transfer resistance, high desulfurization rate, convenience in operation, high operation flexibility, no secondary pollution and capability of stably running in a membrane contactor.
Description
Technical field
The present invention relates to liquid gas separation field, particularly relate to the desulfuration field of flue gas, more specifically relate to the composite organic acid salting liquid for sulfur dioxide absorption.
Background technology
SO in the flue gas such as coal-burning power plant, metallurgy industry
2being one of Air Pollutant Discharge, is the formation source of acid rain.The raising day by day Air Pollutant Emission required along with environmental protection, in flue gas desulfurization purifies, reasonable selection sulfur removal technology how, reach SO after flue gas desulfurization with low investment and operating cost
2discharge capacity meets the regulation of discharging standards, is the key issue that the flue gas desulfurizations such as coal-burning power plant, metallurgy industry develop in a healthy way.Therefore, various high-performance SO
2the exploitation of absorbent is one of theme of this area research, and in recent years, composite absorber was because its unique performance has become the heat subject of acid gas absorbent research and development.
In flue gas desulfurization (Flue gas desulfurization is called for short FGD) technology, the method common by the kind of desulfurizing agent has: with CaCO
3(lime stone) is basic calcium method, take MgO as basic magnesium method, with Na
2sO
3for basic sodium method, with NH
3for basic ammonia process, take organic base as basic organic alkaline process.Commercialization flue gas desulfurization more than 90% adopts calcium method desulfur technology in the world, and the calcium method is divided into wet method, dry method and half-dried (half is wet) method.Wet technique is to adopt solution or the slurries contain absorbent to process sulfur-containing smoke gas, and this method has that desulphurization reaction speed is fast, equipment simple, the desulfuration efficiency advantages of higher, but the ubiquity seriously corroded, operation and maintenance cost is high and cause secondary pollution problems.Dry technique is that the processing of absorption process and product is all carried out under anhydrous state, this method have without spent acid sewage discharge, equipment corrosion is lighter, the problems such as flue-gas temperature is without the advantage such as obviously reducing, secondary pollution is few, but exists desulfuration efficiency low, and reaction speed is slow, equipment is huge.Semi-dry process refers to desulfurizing agent desulfurization under drying regime, regeneration under wet condition (as washing regenerating active carbon flow process), or desulfurization under wet condition, processes the flue gas desulfurization technique of desulfurization product (as spray drying process) under dry state.Particularly desulfurization under wet condition, process the semidry method of desulfurization product under dry state, with its advantage that existing wet desulphurization reaction speed is fast, desulfuration efficiency is high, have again dry method without the sewage spent acid discharge, the easy-to-handle advantage of desulfurization afterproduct and be subject to people and pay close attention to widely.In chemical absorbing flue gas desulfurization, the performance of absorbent has fundamentally determined SO
2the efficiency of absorption operation, thereby the performance of absorbent is had to very high requirement.Carry out chemical absorbing SO for flue gas
2process, in order to strengthen mass transport process, improve desulfuration efficiency, reduce investment and the operating cost of equipment, also must possess certain requirement to desulfurizer and operation.
The composite absorber compatibility premium properties of single absorbent, higher mass transfer force, higher absorptive capacity, higher absorption rate and regeneration rate can be provided in absorption process.Therefore composite absorber has higher premium properties, in the flue gas desulfurization field, has obtained paying close attention to widely and applying.
Membrane gas absorption technology (being called for short film absorbs) is separated the new gas separation process combined with the solvent absorption gas technology as film, adopt membrane contactor as desulfurizer, it has stable mass transfer interface, high-specific surface area, high mass transfer efficiency, energy consumption is low, the advantages such as device volume is little, and stable operation and elasticity are large; Microporous barrier in membrane contactor is only the barrier between gas-liquid two-phase, and to the separation non-selectivity of gas, absorbent provides high selectivity and high drive in separation process.Therefore exploitation and membrane material mutually the high-performance absorbent of compatibility there is the meaning of particular importance.At present, absorb SO for membrane contactor
2composite absorber is less, and absorbent properties also need to improve.We absorb SO at film
2lot of experiments work has been done in the composite absorber aspect, has proposed the composite absorber of novel and high-efficiency, at present at gas cleaning SO
2field has no uses and reports.
Summary of the invention
The object of the present invention is to provide a kind of sulfur dioxide absorbent that can absorb for membrane contactor.
Concrete scheme is as follows:
1, a kind of salting liquid of the composite organic acid for sulfur dioxide absorption, be comprised of the aqueous solution of tartrate and amino-acid salt, and described tartrate is 1:(0.5 ~ 2.8 with the mol ratio of mixing of amino-acid salt).
2, the mixture that described amino-acid salt is any one or two kinds in Beta-alanine salt or glycinate.
3, described amino-acid salt is sodium salt or sylvite.
4, described tartrate is sodium tartrate or potassium tartrate.
5, the aqueous solution that the described acylate aqueous solution is sodium tartrate and Beta-alanine sodium, be perhaps the aqueous solution of sodium tartrate and Beta-alanine potassium, be perhaps the aqueous solution of potassium tartrate and Beta-alanine sodium, be perhaps the aqueous solution of potassium tartrate and Beta-alanine sodium, be perhaps the aqueous solution of sodium tartrate and Sodium Glycinate, be perhaps the aqueous solution of sodium tartrate and glycine potassium, or be the aqueous solution of potassium tartrate and Sodium Glycinate, or be the aqueous solution of potassium tartrate and glycine potassium.
6, the total concentration of described acylate aqueous solution mesotartrate and amino-acid salt is 0.1 ~ 3.0mol/L.
7, the total concentration of described acylate aqueous solution mesotartrate and amino-acid salt is 0.5～2.0mol/L.
8, described tartrate and amino-acid salt mol ratio are 1:(1～1.8).
It is good that the acylate that the present invention proposes holds two grandfather's chemical stabilities, and foaminess is little, and viscosity is little, nontoxic, and raw material sources are abundant, easily buys low price.Apply acylate solution disclosed by the invention and there is high mass tranfer coefficient as trapping agent in sulfur removal technology, the Liquid Flow undisturbed, resistance to mass tranfer is little, and desulfurization degree is high, easy to operate, and operating flexibility is large, can stable operation in membrane contactor.The desulfuration solution non-scaling, do not stop up simultaneously, corrosion-free.The acylate solution that the present invention proposes can be used as laminated desulfurizer in membrane contactor, can certainly in tower class reactor (as bubble tower, packed tower, plate column etc.), use.
The accompanying drawing explanation
Fig. 1 is that film absorbs SO
2middle trapping agent absorbent properties evaluating apparatus.
Wherein:
1-1-N
2gas bomb, 1-2-SO
2gas bomb, 2-gas Quality Control instrument, 3-mixing steady-flow tank, 4-membrane contactor, 5-peristaltic meatering pump, 6-the first solution storage trough, 7-the second solution storage trough, 8-infrared gas analyser, P-pressure gauge, A-sample point.
The specific embodiment
Below in conjunction with accompanying drawing, the present invention is described in further detail.
Embodiment 1
The trapping absorbent properties evaluation method that is used for the composite organic acid salting liquid of sulfur dioxide absorption.
Operating condition: room temperature (19-22 ℃), mixture pressure 0.11MPa, membrane mass transfer area 1.5 m
2, gas flow rate 0.5-2 L/min, flow rate of liquid 200-500mL/min.
As shown in Figure 1, respectively from N
2gas bomb 1-1 and SO
2the gas of gas bomb 1-2, after gas Quality Control instrument 2 metering, enters and mixes steady-flow tank 3 and form containing the 0.1%-0.6%(percentage by volume) SO
2gaseous mixture, the gaseous mixture after the air-flow current stabilization enters in membrane contactor 4, SO in gaseous mixture
2diffuse to the film opposite side by fenestra, absorbed by compound trapping agent, enter liquid phase, the gas phase after absorption is emitted from membrane contactor other end gas vent, and the compound trapping agent in membrane contactor is from the first solution storage trough 6.Compound trapping agent is extracted out by peristaltic meatering pump 5, and the compound trapping agent in the first solution storage trough 6 is sent in membrane contactor 4, thus the SO that the trapping diffusion is come
2.Compound trapping agent after use is discharged from membrane contactor 4, and is stored by the second solution storage trough 7.
Gas phase is imported and exported to be comprised of infrared gas analyser 8 and is measured.Solution component through the sampling after, by hplc determination, liquid phase SO
2content adopts spectrophotometry.
Above-mentioned compound trapping agent refers to acylate solution disclosed in this invention.
Evaluation criterion:
The cumulative volume mass tranfer coefficient
k g a:
SO
2removal efficiency
η:
In formula
g,
awith
lbe respectively gaseous phase volume flow velocity, film cross-sectional area and film length,
c g, inwith
c g, outbe respectively gas phase and import and export SO
2concentration.
The aqueous solution that is potassium tartrate/sodium tartrate and glycinate for the composite organic acid salting liquid of sulfur dioxide absorption at the present embodiment, potassium tartrate/sodium tartrate and the glycine total concentration in the aqueous solution is 0.1 ~ 3.0mol/L, and the mol ratio of potassium tartrate/sodium tartrate and glycinate is 1:(0.5 ~ 2.8).
Glycinate can be the mixture of Sodium Glycinate, glycine potassium or Sodium Glycinate and glycine potassium in the present embodiment.
Adopt the method for evaluating performance in embodiment 1 to be detected.
Process condition: room temperature, gaseous pressure 0.11MPa, gaseous mixture SO
2content 0.1%-0.6%(percentage by volume), membrane mass transfer area 1.5m
2, gas speed: 0.5-2L/min, liquid speed: 200-500mL/min.
Various desulfurizing agents Evaluation results under various conditions is shown in Table 1.
Table 1 laminated desulfurizer Evaluation results
Result shows: compound trapping agent adaptability disclosed by the invention is high, not only adapts to low-concentration flue gas, also adapts to high-concentration fume, the concentration of absorbing wide ranges of use, and gas-liquid speed operating flexibility is large, SO
2removal efficiency is high, is greater than 99%, and the film device mass tranfer coefficient is large, between 0.20 ~ 0.31.
In the present embodiment, the aqueous solution that the composite organic acid salting liquid that is used for sulfur dioxide absorption is potassium tartrate/sodium tartrate and Beta-alanine salt, potassium tartrate/sodium tartrate and the total concentration of Beta-alanine salt in the aqueous solution are 0.1 ~ 3.0mol/L, and the mol ratio of potassium tartrate/sodium tartrate and Beta-alanine salt is 1:(0.5 ~ 2.8).
Beta-alanine salt can be the mixture of Beta-alanine sodium, Beta-alanine potassium or Beta-alanine sodium and Beta-alanine potassium in the present embodiment.
Adopt the method for evaluating performance in embodiment 1 to be detected.
Process condition: room temperature, gaseous pressure 0.11MPa, gaseous mixture SO
2content 0.1%-0.6%(percentage by volume), membrane mass transfer area 1.5m
2, gas speed: 0.5-2L/min, liquid speed: 200-500mL/min.
Various desulfurizing agents Evaluation results under various conditions is shown in Table 2.
Table 2 laminated desulfurizer Evaluation results
Result shows: compound trapping agent adaptability is high, not only adapts to low-concentration flue gas, also adapts to high-concentration fume, the concentration of absorbing wide ranges of use, and gas-liquid speed operating flexibility is large, SO
2removal efficiency is high, is greater than 99%, and the film device mass tranfer coefficient is large, at 0.20-0.30.
Claims (8)
1. the salting liquid of the composite organic acid for sulfur dioxide absorption, is characterized in that described solution is comprised of the aqueous solution of tartrate and amino-acid salt, and described tartrate is 1:(0.5 ~ 2.8 with the mol ratio of mixing of amino-acid salt).
2. the salting liquid of the composite organic acid for sulfur dioxide absorption according to claim 1 is characterized in that: the mixture that described amino-acid salt is any one or two kinds in Beta-alanine salt or glycinate.
3. the salting liquid of the composite organic acid for sulfur dioxide absorption according to claim 2, it is characterized in that: described amino-acid salt is sodium salt or sylvite.
4. the salting liquid of the composite organic acid for sulfur dioxide absorption according to claim 1, it is characterized in that: described tartrate is sodium tartrate or potassium tartrate.
5. the salting liquid of the composite organic acid for sulfur dioxide absorption according to claim 2, it is characterized in that: the aqueous solution that the described acylate aqueous solution is sodium tartrate and Beta-alanine sodium, be perhaps the aqueous solution of sodium tartrate and Beta-alanine potassium, be perhaps the aqueous solution of potassium tartrate and Beta-alanine sodium, be perhaps the aqueous solution of potassium tartrate and Beta-alanine sodium, be perhaps the aqueous solution of sodium tartrate and Sodium Glycinate, be perhaps the aqueous solution of sodium tartrate and glycine potassium, be perhaps the aqueous solution of potassium tartrate and Sodium Glycinate, be perhaps the aqueous solution of potassium tartrate and glycine potassium.
6. according to the described salting liquid of the composite organic acid for sulfur dioxide absorption of any one in claim 1 to 5, it is characterized in that: the total concentration of described acylate aqueous solution mesotartrate and amino-acid salt is 0.1 ~ 3.0mol/L.
7. the salting liquid of the composite organic acid for sulfur dioxide absorption according to claim 6, it is characterized in that: the total concentration of described acylate aqueous solution mesotartrate and amino-acid salt is 0.5～2.0mol/L.
8. the salting liquid of the composite organic acid for sulfur dioxide absorption according to claim 1, it is characterized in that: described tartrate and amino-acid salt mol ratio are 1:(1～1.8).
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111189970A (en) * | 2018-11-14 | 2020-05-22 | 中国石油化工股份有限公司 | Method for detecting absorption and elimination performance of hydrogen sulfide |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0851871A (en) * | 1994-08-10 | 1996-02-27 | Toyo Polymer Kk | Embossed fluororesin film for green house |
| CN1298754A (en) * | 2000-10-16 | 2001-06-13 | 中国石油化工集团公司 | Wet process for removing SO2 from fume |
| US20060117954A1 (en) * | 2002-05-08 | 2006-06-08 | Nederlandse Organisatie Voortoegepastnatenschappel Ijk Onderzoek Tno | Method for absorption of acid gases |
| CN1895738A (en) * | 2005-07-12 | 2007-01-17 | 南京理工大学 | Composite solution for membrane contactor to absorb acid gas |
| US20100186590A1 (en) * | 2009-01-29 | 2010-07-29 | Basf Se | Absorption medium for removing acid gases which comprises amino acid and acid promoter |
-
2013
- 2013-07-09 CN CN201310284610.4A patent/CN103432884B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0851871A (en) * | 1994-08-10 | 1996-02-27 | Toyo Polymer Kk | Embossed fluororesin film for green house |
| CN1298754A (en) * | 2000-10-16 | 2001-06-13 | 中国石油化工集团公司 | Wet process for removing SO2 from fume |
| US20060117954A1 (en) * | 2002-05-08 | 2006-06-08 | Nederlandse Organisatie Voortoegepastnatenschappel Ijk Onderzoek Tno | Method for absorption of acid gases |
| CN1895738A (en) * | 2005-07-12 | 2007-01-17 | 南京理工大学 | Composite solution for membrane contactor to absorb acid gas |
| US20100186590A1 (en) * | 2009-01-29 | 2010-07-29 | Basf Se | Absorption medium for removing acid gases which comprises amino acid and acid promoter |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111189970A (en) * | 2018-11-14 | 2020-05-22 | 中国石油化工股份有限公司 | Method for detecting absorption and elimination performance of hydrogen sulfide |
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