CN103421373B - A kind of seawater pipeline antifouling paint - Google Patents

A kind of seawater pipeline antifouling paint Download PDF

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Publication number
CN103421373B
CN103421373B CN201310370926.5A CN201310370926A CN103421373B CN 103421373 B CN103421373 B CN 103421373B CN 201310370926 A CN201310370926 A CN 201310370926A CN 103421373 B CN103421373 B CN 103421373B
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CN
China
Prior art keywords
parts
antifouling paint
resisting
seawater pipeline
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201310370926.5A
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Chinese (zh)
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CN103421373A (en
Inventor
张学平
朱忠海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhuhai Hengqin Pulse Technology Co., Ltd.
Original Assignee
SUZHOU CHANGSHENG ELECTROMECHANICAL Co Ltd
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Priority to CN201310370926.5A priority Critical patent/CN103421373B/en
Publication of CN103421373A publication Critical patent/CN103421373A/en
Application granted granted Critical
Publication of CN103421373B publication Critical patent/CN103421373B/en
Expired - Fee Related legal-status Critical Current
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Abstract

A kind of seawater pipeline antifouling paint, its composition with mass fraction representation is: diphenyl thiourea 10-15 part; TBT20-25 part; Acrylate 20-25 part; 200# solvent oil 15-35 part; Titanium dioxide 5-10 part; 6101 epoxy resin 20-30 parts; Zinc oxide 5-10 part; Paraffin oil 40-50 part; Dioctyl titanic acid ester 1-5 part; Silica colloidal 1-2 part; Polymeric amide 10-20 part; Product is after 24 months dippings run, and biological attachment area is zero; Normal temperature 1-2h surface drying, 15-20h does solid work; Fineness 70-80 micron, wear-resisting, viscosity 80-100s, acid-alkali-corrosive-resisting, lacquer painting flat smooth; Product is heat-resisting, cold-resistant, antifouling, long service life, the widespread production not division of history into periods can replace current material.

Description

A kind of seawater pipeline antifouling paint
Technical field
The application belongs to metallic paint field, particularly relates to a kind of seawater pipeline antifouling paint.
Background technology
Stainless steel produces stress corrosion at the corrosive medium environment of the chlorion containing aerobic.Ratio shared by stress corrosion inefficacy is up to about 45%; Pitting corrosion generally easily occurs in static medium.Pit is usually along gravity direction or horizontal direction development, and pitting, once be formed, is namely accelerated to depths automatically., the oxide film of stainless steel surface just creates dissolving in containing the aqueous solution of chlorion, and it is 20 μm ~ 30 μm little pits that result generates aperture on base metal, and these little pits are pitting core.As long as containing a certain amount of chlorion in medium, erosion core just may be made to develop into pit.Common preventive measures: add the elements such as molybdenum, nitrogen, silicon or improve chromium content while adding these elements in stainless steel.Reduce chlorion content in media as well.Add inhibiter, increase the stability of passive film or be conducive to impaired passive film and be able to passivation again; Along with the development of social city, technicalization, hommization, seawater pipeline obtains vigorous growth, increasing seawater pipeline comes into operation, and the consequent is the increase of seawater pipeline antifouling paint usage quantity and seawater pipeline antifouling paint showing mostly easily by microorganic adhesion and the problem such as time of drying is slow.
Antifouling paint prevents boats and ships when ocean row, marine organisms attachment and cause boats and ships to advance to be obstructed, to cause stained.Antifouling paint can keep immersion, and position is smooth adheres to without dirt.Antifouling paint can be divided into: contact-type, increase formulation, dispersion pattern, from throwing type, be mainly used in the antifouling engineerings such as the boats and ships in seawater, fresh water, marine structure, pipeline.And popularizing along with humanity concept, and the formation of novel harmonious society, design a kind of seawater pipeline antifouling paint and be very important.
Summary of the invention
the technical problem solved:
The technical problems such as the application, for above-mentioned technical problem, provides a kind of seawater pipeline antifouling paint, solves existing seawater pipeline antifouling paint and is subject to microbial attack, the slow and lacquer painting unfairness of rate of drying.
technical scheme:
A kind of seawater pipeline antifouling paint, is made up of following raw materials according, with mass fraction representation is: diphenyl thiourea 10-15 part; TBT20-25 part; Acrylate 20-25 part; 200# solvent oil 15-35 part; Titanium dioxide 5-10 part; 6101 epoxy resin 20-30 parts; Zinc oxide 5-10 part; Paraffin oil 40-50 part; Dioctyl titanic acid ester 1-5 part; Silica colloidal 1-2 part; Polymeric amide 10-20 part.
As a preferred technical solution of the present invention: its composition with mass fraction representation is: diphenyl thiourea 12.5 parts; TBT22.5 part; Acrylate 22.5 parts; 200# solvent oil 25 parts; Titanium dioxide 7.5 parts; 6101 epoxy resin 25 parts; 7.5 parts, zinc oxide; Paraffin oil 45 parts; Dioctyl titanic acid ester 3 parts; Silica colloidal 1.5 parts; Polymeric amide 15 parts.
beneficial effect:
A kind of seawater pipeline antifouling paint of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product is after 24 months dippings run, and biological attachment area is zero; 2, normal temperature 1-2h surface drying, 15-20h does solid work; 3, fineness 70-80 micron, wear-resisting, viscosity 80-100s, acid-alkali-corrosive-resisting, lacquer painting flat smooth; 4, product is heat-resisting, cold-resistant, antifouling, long service life, the widespread production not division of history into periods can replace current material.
Embodiment
embodiment 1:
A kind of seawater pipeline antifouling paint, its composition with mass fraction representation is: diphenyl thiourea 10-15 part; TBT20-25 part; Acrylate 20-25 part; 200# solvent oil 15-35 part; Titanium dioxide 5-10 part; 6101 epoxy resin 20-30 parts; Zinc oxide 5-10 part; Paraffin oil 40-50 part; Dioctyl titanic acid ester 1-5 part; Silica colloidal 1-2 part; Polymeric amide 10-20 part.
Product is after 24 months dippings run, and biological attachment area is zero; Normal temperature 2h surface drying, 20h does solid work; Fineness 70 microns, wear-resisting, viscosity 80s.
embodiment 2:
A kind of seawater pipeline antifouling paint, its composition with mass fraction representation is: diphenyl thiourea 10-15 part; TBT20-25 part; Acrylate 20-25 part; 200# solvent oil 15-35 part; Titanium dioxide 5-10 part; 6101 epoxy resin 20-30 parts; Zinc oxide 5-10 part; Paraffin oil 40-50 part; Dioctyl titanic acid ester 1-5 part; Silica colloidal 1-2 part; Polymeric amide 10-20 part.
Product is after 24 months dippings run, and biological attachment area is zero; Normal temperature 1.5h surface drying, 17h does solid work; Fineness 75 microns, wear-resisting, viscosity 90s.
embodiment 3:
A kind of seawater pipeline antifouling paint, is characterized in that: its composition with mass fraction representation is: diphenyl thiourea 12.5 parts; TBT22.5 part; Acrylate 22.5 parts; 200# solvent oil 25 parts; Titanium dioxide 7.5 parts; 6101 epoxy resin 25 parts; 7.5 parts, zinc oxide; Paraffin oil 45 parts; Dioctyl titanic acid ester 3 parts; Silica colloidal 1.5 parts; Polymeric amide 15 parts.
Product is after 24 months dippings run, and biological attachment area is zero; Normal temperature 1h surface drying, 15h does solid work; Fineness 70 microns, wear-resisting, viscosity 100s.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for setting forth content of the present invention, instead of restriction, and any change therefore in the implication suitable with claims of the present invention and scope, all should think to be included in the scope of claims.

Claims (2)

1. a seawater pipeline antifouling paint, is characterized in that: its composition with mass fraction representation is: diphenyl thiourea 10-15 part; TBT20-25 part; Acrylate 20-25 part; 200# solvent oil 15-35 part; Titanium dioxide 5-10 part; 6101 epoxy resin 20-30 parts; Zinc oxide 5-10 part; Paraffin oil 40-50 part; Dioctyl titanic acid ester 1-5 part; Silica colloidal 1-2 part; Polymeric amide 10-20 part.
2. a kind of seawater pipeline antifouling paint according to claim 1, is characterized in that: its composition with mass fraction representation is: diphenyl thiourea 12.5 parts; TBT22.5 part; Acrylate 22.5 parts; 200# solvent oil 25 parts; Titanium dioxide 7.5 parts; 6101 epoxy resin 25 parts; 7.5 parts, zinc oxide; Paraffin oil 45 parts; Dioctyl titanic acid ester 3 parts; Silica colloidal 1.5 parts; Polymeric amide 15 parts.
CN201310370926.5A 2013-08-23 2013-08-23 A kind of seawater pipeline antifouling paint Expired - Fee Related CN103421373B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310370926.5A CN103421373B (en) 2013-08-23 2013-08-23 A kind of seawater pipeline antifouling paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310370926.5A CN103421373B (en) 2013-08-23 2013-08-23 A kind of seawater pipeline antifouling paint

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CN103421373A CN103421373A (en) 2013-12-04
CN103421373B true CN103421373B (en) 2016-01-06

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819986A (en) * 2014-02-08 2014-05-28 荣成市泓远化工有限公司 Gray marine antifouling paint without copper compound and preparation method of gray marine antifouling paint
CN106752173A (en) * 2016-05-31 2017-05-31 陈斌 A kind of seawater pipeline antifouling paint and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6248806B1 (en) * 1996-05-22 2001-06-19 J.C. Hempel's Skibsfarve-Fabrik A/S Antifouling paint
CN101287805A (en) * 2005-09-06 2008-10-15 诺华丝国际股份有限公司 Marine antifouling coating compositions
CN101842453A (en) * 2007-10-31 2010-09-22 中国涂料株式会社 Anti-stain coating composition containing copper compound and having improved slime resistance and storage stability

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6248806B1 (en) * 1996-05-22 2001-06-19 J.C. Hempel's Skibsfarve-Fabrik A/S Antifouling paint
CN101287805A (en) * 2005-09-06 2008-10-15 诺华丝国际股份有限公司 Marine antifouling coating compositions
CN101842453A (en) * 2007-10-31 2010-09-22 中国涂料株式会社 Anti-stain coating composition containing copper compound and having improved slime resistance and storage stability

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
国外船舶防污涂料的研究及其发展趋势;虞子森等;《造船技术》;20111231(第4期);第46-49页,下转第56页 *
有机锡高分子防污涂料";韩哲文;《石油化工》;19871231;第16卷(第4期);第313页左栏第2段至右栏第2段 *

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Effective date of registration: 20160817

Address after: 211111 Jiangsu Province, Nanjing Zijin (Jiangning) technology start-ups in particular communities (Jiangning District Mo Zhou Road No. 12)

Patentee after: Nanjing Valley Intellectual Property Service Co., Ltd.

Address before: 215000 Jiangsu city of Suzhou province high tech Zone No. 121 Hua Feng Lu

Patentee before: Suzhou Changsheng Electromechanical Co., Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20170706

Address after: 519031, 69, Xiangyang Village, Hengqin, Guangdong, Zhuhai 201-1

Patentee after: Zhuhai Hengqin Pulse Technology Co., Ltd.

Address before: 211111 Jiangsu Province, Nanjing Zijin (Jiangning) technology start-ups in particular communities (Jiangning District Mo Zhou Road No. 12)

Patentee before: Nanjing Valley Intellectual Property Service Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160106

Termination date: 20200823