CN103416420A - Dicyclanil containing insecticidal composition - Google Patents
Dicyclanil containing insecticidal composition Download PDFInfo
- Publication number
- CN103416420A CN103416420A CN2012101562399A CN201210156239A CN103416420A CN 103416420 A CN103416420 A CN 103416420A CN 2012101562399 A CN2012101562399 A CN 2012101562399A CN 201210156239 A CN201210156239 A CN 201210156239A CN 103416420 A CN103416420 A CN 103416420A
- Authority
- CN
- China
- Prior art keywords
- cga
- active component
- imidacloprid
- acetamiprid
- rice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 230000000749 insecticidal effect Effects 0.000 title abstract description 5
- PKTIFYGCWCQRSX-UHFFFAOYSA-N 4,6-diamino-2-(cyclopropylamino)pyrimidine-5-carbonitrile Chemical compound NC1=C(C#N)C(N)=NC(NC2CC2)=N1 PKTIFYGCWCQRSX-UHFFFAOYSA-N 0.000 title abstract description 4
- 239000005906 Imidacloprid Substances 0.000 claims abstract description 30
- 229940056881 imidacloprid Drugs 0.000 claims abstract description 30
- 239000005875 Acetamiprid Substances 0.000 claims abstract description 29
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims abstract description 29
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims abstract description 28
- 239000000375 suspending agent Substances 0.000 claims description 37
- 241000238631 Hexapoda Species 0.000 claims description 30
- 150000002825 nitriles Chemical class 0.000 claims description 27
- 239000003094 microcapsule Substances 0.000 claims description 14
- 230000000361 pesticidal effect Effects 0.000 claims description 14
- 241001124076 Aphididae Species 0.000 claims description 13
- 241000209094 Oryza Species 0.000 claims description 13
- 235000007164 Oryza sativa Nutrition 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 13
- 235000009566 rice Nutrition 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 12
- 241001182720 Cacopsylla pyrisuga Species 0.000 claims description 11
- 241001414720 Cicadellidae Species 0.000 claims description 11
- 241000018137 Trialeurodes vaporariorum Species 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 9
- 239000000725 suspension Substances 0.000 claims description 9
- 241000254127 Bemisia tabaci Species 0.000 claims description 7
- 241001465828 Cecidomyiidae Species 0.000 claims description 7
- 241000008892 Cnaphalocrocis patnalis Species 0.000 claims description 7
- 241001364569 Cofana spectra Species 0.000 claims description 7
- 229920000742 Cotton Polymers 0.000 claims description 7
- 241001517923 Douglasiidae Species 0.000 claims description 7
- 241000255967 Helicoverpa zea Species 0.000 claims description 7
- 241000500437 Plutella xylostella Species 0.000 claims description 7
- 241000176086 Sogatella furcifera Species 0.000 claims description 7
- 241000256247 Spodoptera exigua Species 0.000 claims description 7
- 241001414989 Thysanoptera Species 0.000 claims description 7
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 244000269722 Thea sinensis Species 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 abstract description 28
- 239000000575 pesticide Substances 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 5
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 244000144972 livestock Species 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 49
- 239000003814 drug Substances 0.000 description 40
- 239000002131 composite material Substances 0.000 description 35
- 230000003449 preventive effect Effects 0.000 description 24
- 230000002195 synergetic effect Effects 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000002270 dispersing agent Substances 0.000 description 16
- 239000012071 phase Substances 0.000 description 15
- 239000008367 deionised water Substances 0.000 description 14
- 229910021641 deionized water Inorganic materials 0.000 description 14
- 239000013530 defoamer Substances 0.000 description 12
- 239000003995 emulsifying agent Substances 0.000 description 12
- 239000000080 wetting agent Substances 0.000 description 12
- 241001122767 Theaceae Species 0.000 description 10
- 239000000470 constituent Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 230000002528 anti-freeze Effects 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- 241001600408 Aphis gossypii Species 0.000 description 7
- 206010067482 No adverse event Diseases 0.000 description 7
- 230000010165 autogamy Effects 0.000 description 7
- 229940079593 drug Drugs 0.000 description 7
- 238000011835 investigation Methods 0.000 description 7
- 239000000945 filler Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 206010011732 Cyst Diseases 0.000 description 5
- 208000031513 cyst Diseases 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000002917 insecticide Substances 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 4
- 241001672694 Citrus reticulata Species 0.000 description 4
- 240000003553 Leptospermum scoparium Species 0.000 description 4
- 235000015459 Lycium barbarum Nutrition 0.000 description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 4
- 240000001987 Pyrus communis Species 0.000 description 4
- 235000014443 Pyrus communis Nutrition 0.000 description 4
- 240000003768 Solanum lycopersicum Species 0.000 description 4
- 241000896283 Thrips fuscipennis Species 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 4
- 238000000498 ball milling Methods 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 231100000820 toxicity test Toxicity 0.000 description 4
- 241000125167 Rhopalosiphum padi Species 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 3
- 231100000636 lethal dose Toxicity 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 108010062745 Chloride Channels Proteins 0.000 description 2
- 102000011045 Chloride Channels Human genes 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 210000003169 central nervous system Anatomy 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000006184 cosolvent Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 235000021374 legumes Nutrition 0.000 description 2
- 231100000225 lethality Toxicity 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- OGNSCSPNOLGXSM-UHFFFAOYSA-N (+/-)-DABA Natural products NCCC(N)C(O)=O OGNSCSPNOLGXSM-UHFFFAOYSA-N 0.000 description 1
- -1 6-chloro-3-pyridyl Chemical group 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 244000141359 Malus pumila Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 241000251539 Vertebrata <Metazoa> Species 0.000 description 1
- 102000015296 acetylcholine-gated cation-selective channel activity proteins Human genes 0.000 description 1
- 108040006409 acetylcholine-gated cation-selective channel activity proteins Proteins 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000019617 pupation Effects 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 210000004994 reproductive system Anatomy 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a dicyclanil containing insecticidal composition which is an insecticidal composition comprising an active component A and an active component B with a weight ratio of 1:70-70:1, wherein the active component A is dicyclanil, and the active component B is selected from any compound of imidacloprid, acetamiprid and ethiprole. The insecticidal composition has synergy effect on multiple pests harmful to agriculture production, helps to reduce pesticide use amount, reduce pesticide residual quantity on crops and mitigate environmental pollution, and is safe to people and livestock, good in environmental compatibility and insusceptible to arousing drug resistance in pests.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of application of Pesticidal combination on crop pests containing CGA 183893.
Background technology
CGA 183893 (dicyclanil) chemical name: 4,6-diaminourea-2-cyclopropylamino pyrimidine-5-nitrile, molecular formula: C
8H
10N
6.The decortication of CGA 183893 interference insect, after being absorbed by the insect genital system, stop larvae pupation or become worm.
Imidacloprid (imidacloprid) chemical name: 1-(6-chloro-3-pyridyl ylmethyl)-N-Nitroimidazoline-2-base amine, molecular formula: C
9H
10ClN
5O
2.Imidacloprid belongs to the nitro-methylene-type systemic insecticide, is the acting body of nicotinic acid nAChR ligands, disturbs the pest movements nervous system that chemical signal is transmitted malfunctioning, without the cross resistance problem.For preventing and treating sucking pest and resistant strain thereof.
Acetamiprid (acetamiprid) chemical name: E-N'-[(6-chloro-3-pyridyl base) methyl]-N^ (2)-cyano group-N'-methylacetamide, molecular formula: C
10H
11ClN
4.This product has stronger tagging and osmosis, and the longevity of residure is long, and the aphid of cucumber, apple tree, orange tree is had to control efficiency preferably.Due to the mechanism of action uniqueness, can prevent and treat the aphid that existing medicament is had to resistance.
Inferior sulphur (sulphur) acyl group of second worm nitrile (ethiprole) chemical name: 5-amino-1-(2,6-dichloro-4-fluoromethylphenyl)-4-ethyl pyrazoles-3-itrile group, molecular formula: C
13H
9C
L2F
3N
4OS.Second worm nitrile is the novel pyrazole insecticides, and insecticidal spectrum is wide.Disturb chloride channel by γ-aminobutyric acid (GABA), thereby destroy central nervous system (CNS) normal activity, make insect lethal.This medicine is tightr to the white clothing constraint comparison vertebrate of insect GABA chloride channel.Thereby provide very high selection toxicity.Its mechanism of action is different from the main insecticide families such as pyrethroid, organic phosphor, carbamate, almost with the existing insecticide of majority, does not produce the chance of interactivity.Therefore, it is the desirable standby kind of resistance management, can be with the mixed pesticide of other chemical family, be used alternatingly.
Yet, in the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor research, find after CGA 183893 and Imidacloprid, Acetamiprid, second worm nitrile is composite to produce good synergistic effect, and composite relevant report is not yet open about CGA 183893 and Imidacloprid, Acetamiprid, second worm nitrile.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good Pesticidal combination containing CGA 183893.The Pesticidal combination that the present invention proposes contains active components A and active component B, active components A and active component B weight ratio are 1 ︰ 70 ~ 70 ︰ 1, described active components A is selected from CGA 183893, active component B is selected from a kind of in Imidacloprid, Acetamiprid, second worm nitrile, and active components A and the preferred weight ratio of active component B are 1 ︰ 50 ~ 50 ︰ 1; More preferably the weight ratio of CGA 183893 and Imidacloprid is 1 ︰ 30 ~ 15 ︰ 1, and the weight ratio of CGA 183893 and Acetamiprid is 1 ︰ 30 ~ 30 ︰ 1, and the weight ratio of CGA 183893 and second worm nitrile is 1 ︰ 30 ~ 15 ︰ 1.
The purposes of the described Pesticidal combination containing CGA 183893 for preventing and treating insect on fruit tree, vegetables, cereal crops, fiber crop, legume crop, ornamental plants, lawn, forest.
Described insect comprises: aphid, trialeurodes vaporariorum, leaf miner, pear sucker, rice fulgorid, rice gall midge, tea lesser leafhopper, Bemisia tabaci, thrips, rice leaf roller, cotton bollworm, cotton boll resemble, beet armyworm, rice leafhopper, diamond-back moth.
The weight ratio of active components A, active component B is 1 ︰ 70 ~ 70 ︰ 1.Usually in composition, the weight percentage of active component is gross weight 0.5%～90%, is preferably 5%～80%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1%～70% active substance by weight, is preferably 5%～50%; Solid pharmaceutical preparation contains 5%～80% active substance by weight, is preferably 10%～80%.
At least contain a kind of surfactant in Pesticidal combination of the present invention, the dispersion of active component in water while being beneficial to use.Surface-active contents is 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, binding agent or defoamer.According to different dosage form, in preparation, can also contain disintegrant known in those skilled in the art, antifreeze etc.
Pesticidal combination of the present invention can be by the user before use through dilution or directly use.Its preparation can be by common processing method preparation known in those skilled in the art, be about to active substance and after liquid flux or solid carrier mix, then add surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, defoamer etc.
Pesticidal combination of the present invention, can be processed on demand acceptable formulation on any agricultural chemicals, wherein more preferably formulation is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent, soluble liquid, soluble powder.
When making wetting powder, composition comprises following constituent content: active components A 1% ~ 70%, active component B1% ~ 70%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, filler surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 1% ~ 70%, active component B1% ~ 70%, dispersant 3% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
Comprise following constituent content when composition is made suspending agent: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Comprise following constituent content when composition is made suspension emulsion: active components A 1% ~ 50%, active component B1% ~ 50%, dispersant 2% ~ 10%, defoamer 0.01% ~ 2%, solvent 1% ~ 15%, thickener 0 ~ 2%, emulsifier 2% ~ 12%, antifreeze 0 ~ 8%, deionized water add to 100%.
Comprise following constituent content when composition is made aqueous emulsion: active components A 1% ~ 50%, active component B1% ~ 50%, solvent 1% ~ 30%, emulsifier 1% ~ 15%, antifreeze 0 ~ 8%, thickener 0 ~ 2%, defoamer 0.01% ~ 2%, deionized water are supplied surplus.
Comprise following constituent content when composition is made microemulsion: active components A 1% ~ 50%, active component B1% ~ 50%, solvent 1% ~ 30%, emulsifier 3% ~ 25%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, stabilizing agent 0 ~ 4%, deionized water is supplied surplus.
Comprise following constituent content when composition is made microcapsule suspending agent: active components A 1% ~ 50%, active component B1% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 10%, organic solvent 1% ~ 10%, emulsifier 1% ~ 7%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
Composition comprises following constituent content while making microcapsule suspension-suspending agent: active components A 1% ~ 50%, active component B1% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, organic solvent 1% ~ 15%, emulsifier 1% ~ 6%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%;
Comprise following constituent content when composition is made soluble liquid: active components A 1% ~ 70%, active component B 1% ~ 70%, emulsifier 1% ~ 10%, cosolvent 2% ~ 6%, solvent add to 100%.
When making soluble powder, composition comprises following constituent content: active components A 1% ~ 70%, active component B 1% ~ 70%, dispersant 2% ~ 10%, wetting agent 1%-8%, stabilizing agent 0 ~ 4%, filler surplus.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension of the present invention-suspending agent the key technical indexes:
Soluble liquid the key technical indexes of the present invention:
Soluble powder the key technical indexes of the present invention:
The invention has the advantages that:
(1) CGA 183893 and Imidacloprid, Acetamiprid, second worm nitrile composite after, there is obvious synergy and lasting effect; (2) to the aphid on fruit tree, vegetables, cereal crops, fiber crop, legume crop, ornamental plants, lawn, forest, trialeurodes vaporariorum, leaf miner, pear sucker, rice fulgorid, rice gall midge, tea lesser leafhopper, Bemisia tabaci, thrips, rice leaf roller, cotton bollworm, cotton boll resemble, beet armyworm, rice leafhopper, diamond-back moth etc. all have greater activity; (3) reduce the agricultural chemicals dosage, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), to the person poultry safety, Environmental compatibility is good; And the preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment all is weight percentage, but the present invention is not limited thereto.
Application Example one
Example 1 ~ 10 wetting powder
CGA 183893, active component B, dispersant, wetting agent, filler are mixed in mixed cylinder, mix again after airslide disintegrating mill is pulverized, can make wetting powder product of the present invention, specifically in Table 1.
Table 1 embodiment 1 ~ 10 each component and weight portion
Example 11 ~ 23 water dispersible granules
CGA 183893, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needed through air-flow crushing together, then add other auxiliary agent such as binding agent (can add and can not add), obtain the materials of granulating.By item quantitatively send in the fluidized bed granulation dryer through granulation and drying after, can make water dispersible granules product of the present invention, specifically in Table 2.
Table 2 embodiment 11 ~ 23 each component and weight portions
Example 24 ~ 36 suspending agents
By dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), through high speed shear, mix, add CGA 183893, active component B, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, surplus is supplied by deionized water, can make suspending agent product of the present invention, specifically in Table 3.
Table 3 embodiment 24 ~ 36 each component and weight portions
Example 37 ~ 46 suspension emulsions
Dispersant, defoamer, thickener (can add and can not add), antifreeze (can add and can not add) are mixed through high speed shear, add CGA 183893, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make the CGA 183893 suspending agent, then by active component B, solvent, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, surplus is supplied by deionized water, make suspension emulsion product of the present invention, specifically in Table 4,5.
Table 4 embodiment 37 ~ 40 each component and weight portions
Table 5 embodiment 41 ~ 46 each component and weight portions
Example 47 ~ 56 aqueous emulsions
CGA 183893, active component B, solvent, emulsifier are added together, make to be dissolved into even oil phase; Deionized water, antifreeze (can add and can not add), thickener (can add and can not add), defoamer are mixed, become the homogeneous water.Under high-speed stirred, water is added to oil phase, surplus is supplied by deionized water; Can make aqueous emulsion product of the present invention, specifically in Table 6,7.
Table 6 embodiment 47 ~ 50 each component and weight portions
Table 7 embodiment 51 ~ 56 each component and weight portions
Example 57 ~ 59 microemulsions
CGA 183893, active component B, solvent, emulsifier, antifreeze (can add and can not add), thickener, stabilizing agent (can add and can not add), defoamer fully are mixed into to the oil phase of homogeneous transparent, under agitation slowly add deionized water, form WO emulsion, again through agitating heating, make it rapid phase inversion and become oil-in-water type, be chilled to room temperature and make it to reach balance, after filtration, surplus is supplied by deionized water; Can make microemulsion product of the present invention, specifically in Table 8.
Table 8 embodiment 57 ~ 59 each component and weight portions
Imidacloprid, Acetamiprid, second worm nitrile in table 1 ~ 8 are exchanged, can make novel formulation.
Example 60,61 microcapsule suspending agents
By CGA 183893, active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, under shearing condition, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent, dispersant, surplus is supplied by deionized water, bi-material reacts at oil-water interfaces, forms the macromolecule cyst wall, makes the finely disseminated microcapsule suspending agent product of the present composition.Specifically in Table 9.
Table 9 embodiment 60,61 each component and weight portions
Example 62,63 microcapsule suspensions-suspending agent
By active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent under shearing condition, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener (can add and can not add) are mixed through high speed shear, add CGA 183893, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make suspending agent, then suspending agent is joined in the aqueous phase solution of micro-capsule suspension, deionized water is supplied surplus, make the finely disseminated microcapsule suspension of the present composition-suspending agent product, specifically in Table 10.
Table 10 embodiment 62,63 each component and weight portions
Example 64 ~ 68 soluble liquids
Emulsifier, cosolvent are mixed through high speed shear, add CGA 183893, active component B, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, surplus is supplied with solvent, can make soluble liquid product of the present invention, specifically in Table 11.
Table 11 embodiment 64 ~ 68 each component and weight portions
Example 69 ~ 73 soluble powders
CGA 183893, active component B, dispersant, wetting agent, stabilizing agent (can add and can not add), filler are mixed in mixed cylinder, mix again after airslide disintegrating mill is pulverized, can make soluble powder product of the present invention, specifically in Table 12.
Table 12 embodiment 69 ~ 73 each component and weight portions
Imidacloprid, Acetamiprid, second worm nitrile in table 11 ~ 12 are exchanged, can make novel formulation.
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC<80 are antagonism, and 80≤CTC≤120 are summation action, and CTC>120 are synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, is placed in respectively beaker standby.Adopt and first to soak after leaf the method that connects worm, take out, naturally dry after the blade of the same size that does not contact any medicament is soaked to 5s in the liquid configured, put into insect box, then connect for the examination larva, raise under 25 ℃ of conditions, every processing repeats for 3 times, every to repeat examination borer population used be 50, establishes blank simultaneously, in 72h, checks dead borer population, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality is greater than 10%, be considered as invalid test.Computing formula is as follows:
The insect corrected mortality is converted into to probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, with method of least squares, draws virulence regression equation, and calculates thus the value of every kind of medicament, according to the abundant equation of Sun Yun, calculates co-toxicity coefficient CTC.Computing formula following (take CGA 183893 as the standard medicament, its toxicity index is 100):
TI * the P of the theoretical toxicity index (TTI) of M=CGA 183893
CGA 183893+TI * P of effective active composition B
Effective active composition B
In formula: the mixture that M is different proportionings
P
Effective active composition BFor effective active composition B shared ratio in composition
P
CGA 183893For CGA 183893 shared ratio in composition
B is selected from a kind of in Imidacloprid, Acetamiprid, second worm nitrile.
Application Example two:
For trying insect: cotton aphid
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining the former medicine of CGA 183893 and Imidacloprid and the two different proportioning mixture through preliminary experiment.
The toxicity test result
The composite analysis of results table of the toxicity test to cotton aphid of table 13 CGA 183893 and Imidacloprid
| Reagent agent | Proportioning | LC 50(ug/mL) | Co-toxicity coefficient (CTC) |
| CGA 183893 | — | 1.85 | — |
| Imidacloprid | — | 3.78 | — |
| Huan Chong Jing ︰ Imidacloprid | 70:1 | 1.06 | 175.79? |
| Huan Chong Jing ︰ Imidacloprid | 50:1 | 0.98? | 190.69? |
| Huan Chong Jing ︰ Imidacloprid | 30:1 | 0.94? | 200.11? |
| Huan Chong Jing ︰ Imidacloprid | 15:1 | 0.86? | 222.21? |
| Huan Chong Jing ︰ Imidacloprid | 10:1 | 0.80? | 242.52? |
| Huan Chong Jing ︰ Imidacloprid | 5:1 | 0.79? | 255.98? |
| Huan Chong Jing ︰ Imidacloprid | 1:2 | 0.99? | 283.42? |
| Huan Chong Jing ︰ Imidacloprid | 1:8 | 1.34? | 252.96? |
| Huan Chong Jing ︰ Imidacloprid | 1:15 | 1.48? | 239.95? |
| Huan Chong Jing ︰ Imidacloprid | 1:30 | 1.63? | 224.53? |
| Huan Chong Jing ︰ Imidacloprid | 1:40 | 1.76? | 209.61? |
| Huan Chong Jing ︰ Imidacloprid | 1:50 | 1.94? | 191.10? |
| Huan Chong Jing ︰ Imidacloprid | 1:70 | 2.05? | 181.87? |
As shown in Table 13, CGA 183893 and Imidacloprid to the cotton aphid proportioning when 1 ︰ 70 ~ 70 ︰ 1, co-toxicity coefficient all is greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 70 ~ 70 ︰ 1 scopes, when the proportioning of CGA 183893 and Imidacloprid during at 1 ︰ 30 ~ 15 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient all is greater than 220.Co-toxicity coefficient maximum when CGA 183893 and Imidacloprid weight ratio are 1:2 wherein, synergistic effect is the most obvious.Test and find that CGA 183893 and Imidacloprid proportioning are 15:1 through the applicant, 12:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:12, 1:14, 1:15, 1:20, during 1:30 to the aphid on various crop, trialeurodes vaporariorum, leaf miner, pear sucker, rice fulgorid, rice gall midge, tea lesser leafhopper, Bemisia tabaci, thrips, rice leaf roller, cotton bollworm, cotton boll resembles, beet armyworm, rice leafhopper, the control of diamond-back moth has obvious synergistic effect synergistic effect obvious, co-toxicity coefficient all is greater than 120.
Application Example three
For trying insect: wheat aphid
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining the former medicine of CGA 183893 and Acetamiprid and the two different proportioning mixture through preliminary experiment.
The composite analysis of results table of the toxicity test to wheat aphid of table 14 CGA 183893 and Acetamiprid
| Reagent agent | Proportioning | LC 50(ug/mL) | Co-toxicity coefficient (CTC) |
| CGA 183893 | — | 1.96 | — |
| Acetamiprid | — | 2.03 | — |
| Huan Chong Jing ︰ Acetamiprid | 70:1 | 1.11 | 176.66? |
| Huan Chong Jing ︰ Acetamiprid | 50:1 | 1.06? | 185.03? |
| Huan Chong Jing ︰ Acetamiprid | 40:1 | 1.02? | 192.32? |
| Huan Chong Jing ︰ Acetamiprid | 30:1 | 0.91? | 215.62? |
| Huan Chong Jing ︰ Acetamiprid | 15:1 | 0.86? | 228.40? |
| Huan Chong Jing ︰ Acetamiprid | 5:1 | 0.82? | 240.41? |
| Huan Chong Jing ︰ Acetamiprid | 1:1 | 0.73? | 273.21? |
| Huan Chong Jing ︰ Acetamiprid | 1:5 | 0.81? | 249.14? |
| Huan Chong Jing ︰ Acetamiprid | 1:15 | 0.89? | 227.59? |
| Huan Chong Jing ︰ Acetamiprid | 1:30 | 0.93? | 218.03? |
| Huan Chong Jing ︰ Acetamiprid | 1:40 | 1.05? | 193.17? |
| Huan Chong Jing ︰ Acetamiprid | 1:50 | 1.11? | 182.76? |
| Huan Chong Jing ︰ Acetamiprid | 1:70 | 1.16? | 174.92? |
As shown in Table 14, CGA 183893 and Acetamiprid to the wheat aphid proportioning when 1 ︰ 70 ~ 70 ︰ 1, co-toxicity coefficient all is greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 70 ~ 70 ︰ 1 scopes, when the proportioning of CGA 183893 and Acetamiprid during at 1 ︰ 30 ~ 30 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient all is greater than 215.Co-toxicity coefficient maximum when CGA 183893 and Acetamiprid weight ratio are 1:1 wherein, synergistic effect is the most obvious.Test and find that CGA 183893 and Acetamiprid proportioning are 30:1 through the applicant, 20:1, 15:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:12, 1:14, 1:15, 1:20, during 1:30 to the aphid on various crop, trialeurodes vaporariorum, leaf miner, pear sucker, rice fulgorid, rice gall midge, tea lesser leafhopper, Bemisia tabaci, thrips, rice leaf roller, cotton bollworm, cotton boll resembles, beet armyworm, rice leafhopper, the control of diamond-back moth has obvious synergistic effect synergistic effect obvious, co-toxicity coefficient all is greater than 120.
Application Example four
For trying insect: rice hoppers
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining CGA 183893 and the former medicine of second worm nitrile and the two different proportioning mixture through preliminary experiment.
The composite analysis of results table of the toxicity test to rice hoppers of table 15 CGA 183893 and second worm nitrile
| Reagent agent | Proportioning | LC 50(ug/mL) | Co-toxicity coefficient (CTC) |
| CGA 183893 | — | 2.01 | — |
| Second worm nitrile | — | 4.16 | — |
| Huan Chong Jing ︰ second worm nitrile | 70:1 | 1.16 | 174.55? |
| Huan Chong Jing ︰ second worm nitrile | 50:1 | 1.12? | 181.30? |
| Huan Chong Jing ︰ second worm nitrile | 30:1 | 1.05? | 194.67? |
| Huan Chong Jing ︰ second worm nitrile | 15:1 | 0.95? | 218.64? |
| Huan Chong Jing ︰ second worm nitrile | 10:1 | 0.95? | 222.01? |
| Huan Chong Jing ︰ second worm nitrile | 5:1 | 0.85? | 258.76? |
| Huan Chong Jing ︰ second worm nitrile | 1:2 | 1.12? | 273.80? |
| Huan Chong Jing ︰ second worm nitrile | 1:8 | 1.46? | 254.65? |
| Huan Chong Jing ︰ second worm nitrile | 1:15 | 1.67? | 233.48? |
| Huan Chong Jing ︰ second worm nitrile | 1:30 | 1.86? | 216.18? |
| Huan Chong Jing ︰ second worm nitrile | 1:40 | 2.04? | 198.73? |
| Huan Chong Jing ︰ second worm nitrile | 1:50 | 2.23? | 182.71? |
| Huan Chong Jing ︰ second worm nitrile | 1:70 | 2.38? | 172.19? |
As shown in Table 15, CGA 183893 and second worm nitrile to the rice hoppers proportioning when 1 ︰ 70 ~ 70 ︰ 1, co-toxicity coefficient all is greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 70 ~ 70 ︰ 1 scopes, when the proportioning of CGA 183893 and second worm nitrile during at 1 ︰ 30 ~ 15 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient all is greater than 215.Co-toxicity coefficient maximum when CGA 183893 and second worm nitrile weight ratio are 1:2 wherein, synergistic effect is the most obvious.Test and find that CGA 183893 and second worm nitrile proportioning are 15:1 through the applicant, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:15, 1:20, 1:25, during 1:30, to the aphid on various crop, trialeurodes vaporariorum, leaf miner, pear sucker, rice fulgorid, rice gall midge, tea lesser leafhopper, Bemisia tabaci, thrips, rice leaf roller, cotton bollworm, cotton boll resembles, beet armyworm, rice leafhopper, the control of diamond-back moth has obvious synergistic effect synergistic effect obvious, co-toxicity coefficient all is greater than 120.
Application Example five CGA 183893 and active component B and composite control mandarin tree Control of Aphids thereof
This test arrangement is at Shaanxi Province's Hanzhong City, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 20% CGA 183893 suspending agent (autogamy), 10% Imidacloprid missible oil (commercial), 5% acetamiprid EC (commercial), 10% second worm nitrile suspending agent (commercial).
Before medicine, investigation mandarin tree aphid insect pest index, in the dispenser of insect pest initial stage of origination, investigate the insect pest indexes and calculate preventive effect in after dispenser 1 day, 3 days, 7 days.Result of the test is as follows:
Table 16 CGA 183893 and active component B and composite control mandarin tree Control of Aphids thereof
As can be seen from Table 16, after CGA 183893 and active component B are composite, can effectively prevent and treat the mandarin tree aphid, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example six CGA 183893 and active component B and the composite control pear tree pear sucker test of pesticide effectiveness thereof
This test arrangement is at Shaanxi Province's Weinan City Baishui County, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 20% CGA 183893 suspending agent (autogamy), 10% Imidacloprid missible oil (commercial), 5% acetamiprid EC (commercial), 10% second worm nitrile suspending agent (commercial).
Before medicine, investigation pear tree pear sucker insect pest index, in the dispenser of insect pest initial stage of origination, investigate the insect pest indexes and calculate preventive effect in after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 17 CGA 183893 and active component B and the composite control pear tree pear sucker test of pesticide effectiveness thereof
As can be seen from Table 17, after CGA 183893 and active component B are composite, can effectively prevent and treat the pear tree pear sucker, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example seven CGA 183893 and active component B and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
This test arrangement is in Hanzhong City suburb, Shaanxi Province, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 20% CGA 183893 suspending agent (autogamy), 10% Imidacloprid missible oil (commercial), 5% acetamiprid EC (commercial), 10% second worm nitrile suspending agent (commercial).
Investigation rice hoppers insect pest index before medicine, in the dispenser of insect pest initial stage of origination, investigate the insect pest indexes and calculate preventive effect in after dispenser 1 day, 3 days, 7 days.Result of the test is as follows:
Table 18 CGA 183893 and active component B and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 18, CGA 183893 and active component B and the composite rice hoppers of preventing and treating thereof, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example eight CGA 183893 and active component B and the composite control cotton aphid test of pesticide effectiveness thereof
This test arrangement is in Weinan City Dali County, Shaanxi Province, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 20% CGA 183893 suspending agent (autogamy), 10% Imidacloprid missible oil (commercial), 5% acetamiprid EC (commercial), 10% second worm nitrile suspending agent (commercial).
Investigation cotton aphid insect pest index before medicine, in the dispenser of insect pest initial stage of origination, investigate the insect pest indexes and calculate preventive effect in after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 19 CGA 183893 and active component B and the composite control cotton aphid test of pesticide effectiveness thereof
As can be seen from Table 19, after CGA 183893 and active component B are composite, can effectively prevent and treat cotton aphid, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example nine CGA 183893 and active component B and the composite control tomato trialeurodes vaporariorum test of pesticide effectiveness thereof
This test arrangement is at the Xian District, Shanxi Province suburban area, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 20% CGA 183893 suspending agent (autogamy), 10% Imidacloprid missible oil (commercial), 5% acetamiprid EC (commercial), 10% second worm nitrile suspending agent (commercial).
Before medicine, investigation tomato trialeurodes vaporariorum insect pest index, in the dispenser of insect pest initial stage of origination, investigate the insect pest indexes and calculate preventive effect in after dispenser 1 day, 3 days, 7 days.Result of the test is as follows:
Table 20 CGA 183893 and active component B and the composite control tomato trialeurodes vaporariorum test of pesticide effectiveness thereof
As can be seen from Table 20, after CGA 183893 and active component B are composite, can effectively prevent and treat the tomato trialeurodes vaporariorum, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example ten CGA 183893 and active component B and the composite control tea tree tea lesser leafhopper test of pesticide effectiveness thereof
This test arrangement is in the Ya'an, Sichuan Province, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 20% CGA 183893 suspending agent (autogamy), 10% Imidacloprid missible oil (commercial), 5% acetamiprid EC (commercial), 10% second worm nitrile suspending agent (commercial).
Before medicine, investigation tea tree tea lesser leafhopper insect pest index, in the dispenser of insect pest initial stage of origination, investigate the insect pest indexes and calculate preventive effect in after dispenser 3 days, 10 days, 20 days.Result of the test is as follows:
Table 21 CGA 183893 and active component B and the composite control tea tree tea lesser leafhopper test of pesticide effectiveness thereof
As can be seen from Table 21, CGA 183893 and active component B and composite control tea tree tea lesser leafhopper thereof, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example 11 CGA 183893 and active component B and the composite control rose thrips test of pesticide effectiveness thereof
This test arrangement is in the nursery, Xi'an City, Shanxi Province, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 20% CGA 183893 suspending agent (autogamy), 10% Imidacloprid missible oil (commercial), 5% acetamiprid EC (commercial), 10% second worm nitrile suspending agent (commercial).
Before medicine, investigation rose thrips insect pest index, in the dispenser of insect pest initial stage of origination, investigate the insect pest indexes and calculate preventive effect in after dispenser 1 day, 3 days, 7 days.Result of the test is as follows:
Table 22 CGA 183893 and active component B and the composite control rose thrips test of pesticide effectiveness thereof
As can be seen from Table 22, CGA 183893 and active component B and composite control rose thrips thereof, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
After through different local throughout the country tests, draw, CGA 183893 and Imidacloprid, Acetamiprid, second worm nitrile composite rear to the aphid on various crop, trialeurodes vaporariorum, leaf miner, pear sucker, rice fulgorid, rice gall midge, tea lesser leafhopper, Bemisia tabaci, thrips, rice leaf roller, cotton bollworm, cotton boll resemble, the preventive effect of the common insect such as beet armyworm, rice leafhopper, diamond-back moth is all more than 95%, be better than the single dose preventive effect, synergistic effect is obvious.
Claims (6)
1. the Pesticidal combination containing CGA 183893, contain active components A and active component B, it is characterized in that: active components A and active component B weight ratio are 1 ︰ 70 ~ 70 ︰ 1, and described active components A is selected from CGA 183893, and active component B is selected from a kind of in Imidacloprid, Acetamiprid, second worm nitrile.
2. the Pesticidal combination containing CGA 183893 according to claim 1, it is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 50 ~ 50 ︰ 1.
3. the Pesticidal combination containing CGA 183893 according to claim 2 is characterized in that:
The weight ratio of CGA 183893 and Imidacloprid is 1 ︰ 30 ~ 15 ︰ 1;
The weight ratio of CGA 183893 and Acetamiprid is 1 ︰ 30 ~ 30 ︰ 1;
The weight ratio of CGA 183893 and second worm nitrile is 1 ︰ 30 ~ 15 ︰ 1.
4. according to the described Pesticidal combination containing CGA 183893 of any one in claims 1 to 3, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent, soluble liquid, soluble powder.
5. the Pesticidal combination containing CGA 183893 according to claim 4 is used for the purposes of preventing and treating insect on crops.
6. purposes according to claim 5, it is characterized in that, described insect comprises: aphid, trialeurodes vaporariorum, leaf miner, pear sucker, rice fulgorid, rice gall midge, tea lesser leafhopper, Bemisia tabaci, thrips, rice leaf roller, cotton bollworm, cotton boll resemble, beet armyworm, rice leafhopper, diamond-back moth.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510393596.0A CN104996453B (en) | 2012-05-18 | 2012-05-18 | A kind of Pesticidal combination containing CGA 183893 |
| CN201210156239.9A CN103416420B (en) | 2012-05-18 | 2012-05-18 | A kind of Pesticidal combination containing CGA 183893 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210156239.9A CN103416420B (en) | 2012-05-18 | 2012-05-18 | A kind of Pesticidal combination containing CGA 183893 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510393596.0A Division CN104996453B (en) | 2012-05-18 | 2012-05-18 | A kind of Pesticidal combination containing CGA 183893 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103416420A true CN103416420A (en) | 2013-12-04 |
| CN103416420B CN103416420B (en) | 2015-10-14 |
Family
ID=49642227
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510393596.0A Active CN104996453B (en) | 2012-05-18 | 2012-05-18 | A kind of Pesticidal combination containing CGA 183893 |
| CN201210156239.9A Active CN103416420B (en) | 2012-05-18 | 2012-05-18 | A kind of Pesticidal combination containing CGA 183893 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510393596.0A Active CN104996453B (en) | 2012-05-18 | 2012-05-18 | A kind of Pesticidal combination containing CGA 183893 |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN104996453B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87103168A (en) * | 1986-04-30 | 1987-12-16 | 希巴-盖格公司 | The pyrimidines that replaces |
| CN1268125A (en) * | 1997-08-27 | 2000-09-27 | 诺瓦提斯公司 | Dicyclanil Polymorphs and hydrates and their preparation |
| IE20080400A1 (en) * | 2007-06-01 | 2009-06-10 | Jurox Pty Ltd | Pesticide composition |
| AU2010201828A1 (en) * | 2009-05-08 | 2010-11-25 | Jurox Pty Ltd | Veterinary composition |
| CN102283238A (en) * | 2010-06-19 | 2011-12-21 | 海利尔药业集团股份有限公司 | Insecticidal composition containing imidacloprid and cyromazine |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2262368A1 (en) * | 2008-03-28 | 2010-12-22 | Novartis AG | Dicyclanil formulation |
-
2012
- 2012-05-18 CN CN201510393596.0A patent/CN104996453B/en active Active
- 2012-05-18 CN CN201210156239.9A patent/CN103416420B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87103168A (en) * | 1986-04-30 | 1987-12-16 | 希巴-盖格公司 | The pyrimidines that replaces |
| CN1268125A (en) * | 1997-08-27 | 2000-09-27 | 诺瓦提斯公司 | Dicyclanil Polymorphs and hydrates and their preparation |
| IE20080400A1 (en) * | 2007-06-01 | 2009-06-10 | Jurox Pty Ltd | Pesticide composition |
| AU2010201828A1 (en) * | 2009-05-08 | 2010-11-25 | Jurox Pty Ltd | Veterinary composition |
| CN102283238A (en) * | 2010-06-19 | 2011-12-21 | 海利尔药业集团股份有限公司 | Insecticidal composition containing imidacloprid and cyromazine |
Non-Patent Citations (1)
| Title |
|---|
| 徐英 等: ""具有杀虫活性的嘧啶类化合物的研究进展"", 《农药》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104996453A (en) | 2015-10-28 |
| CN103416420B (en) | 2015-10-14 |
| CN104996453B (en) | 2018-06-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103563901B (en) | A kind of Efficient insecticidal composition containing propylene glycol alginate | |
| CN104115845A (en) | Efficient pesticide composition containing flubendiamide | |
| CN103563962B (en) | A kind of Pesticidal combination containing propylene glycol alginate and anabasine | |
| CN103563963B (en) | Insecticidal composition containing propylene glycol alginate | |
| CN103931630A (en) | Insecticide composition containing SYP9080 | |
| CN103960280A (en) | High-efficiency insecticidal composition containing tetrachlorantraniliprole | |
| CN103918673A (en) | Insecticidal composition containing compound improved from chlorantraniliprole and biological-source insecticide | |
| CN103651503A (en) | Pesticidal composition containing fluorine furan pyrazole ketone | |
| CN103651403B (en) | A kind of Efficient insecticidal composition containing Spiromesifen | |
| CN103931641A (en) | Insecticidal composition containing silvchongxian'an and carbamate | |
| CN103651498A (en) | Insecticidal composition containing spiromesifen | |
| CN103651367A (en) | Efficient insecticidal composition containing spiromesifen | |
| CN103651548B (en) | A kind of Pesticidal combination containing Spiromesifen | |
| CN103461369A (en) | Insect disinfestation composition containing bromoantraniliprole and neonicotine | |
| CN104115830A (en) | Insecticidal composition containing flubendiamide and nereistoxin | |
| CN103416420B (en) | A kind of Pesticidal combination containing CGA 183893 | |
| CN103931620A (en) | Insecticidal composition containing silvchongxian'an and nereistoxin insecticide | |
| CN102715166A (en) | Pesticide composition containing chlorfenapyr benzamide | |
| CN103621548B (en) | A kind of Pesticidal combination containing Spiromesifen and pyrethroid | |
| CN103960290A (en) | Insecticidal composition containing conidiobous thromboides | |
| CN103563977B (en) | Pesticide pest-killing composition containing propylene glycol alginate | |
| CN104430484A (en) | Insecticidal composition containing trifluoro-phenylpyridine and pyrethroids | |
| CN103416406B (en) | A kind of Pesticidal combination containing CGA 183893 and neires toxin | |
| CN103461366A (en) | Insecticidal composition containing dicyclanil and carbamate compound | |
| CN103416430A (en) | Pesticide composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| OL01 | Intention to license declared | ||
| OL01 | Intention to license declared |