CN103408931B - Preparation method of hybrid material compounded from fullerene micro-nano material and conjugated polymer - Google Patents
Preparation method of hybrid material compounded from fullerene micro-nano material and conjugated polymer Download PDFInfo
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- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 title claims abstract description 82
- 229910003472 fullerene Inorganic materials 0.000 title claims abstract description 54
- 239000000463 material Substances 0.000 title claims abstract description 37
- 239000002086 nanomaterial Substances 0.000 title claims abstract description 33
- 229920000547 conjugated polymer Polymers 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 239000000243 solution Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000012047 saturated solution Substances 0.000 claims abstract description 6
- 238000001914 filtration Methods 0.000 claims abstract description 5
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 5
- 239000011521 glass Substances 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000005457 ice water Substances 0.000 claims abstract description 3
- 239000000835 fiber Substances 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 229920000767 polyaniline Polymers 0.000 claims description 8
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 3
- 229920000128 polypyrrole Polymers 0.000 claims description 3
- 229920000123 polythiophene Polymers 0.000 claims description 3
- 238000005411 Van der Waals force Methods 0.000 claims description 2
- 238000011284 combination treatment Methods 0.000 claims description 2
- 239000012046 mixed solvent Substances 0.000 claims description 2
- 230000010355 oscillation Effects 0.000 claims description 2
- ZBOGUDPFEVIZIQ-UHFFFAOYSA-N toluene;dihydrochloride Chemical compound Cl.Cl.CC1=CC=CC=C1 ZBOGUDPFEVIZIQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 15
- 239000007788 liquid Substances 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000000227 grinding Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000012258 culturing Methods 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 238000001132 ultrasonic dispersion Methods 0.000 abstract 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 9
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 8
- 238000011160 research Methods 0.000 description 8
- 239000000843 powder Substances 0.000 description 5
- 239000013078 crystal Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000002071 nanotube Substances 0.000 description 3
- 239000004160 Ammonium persulphate Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 235000019395 ammonium persulphate Nutrition 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 230000021615 conjugation Effects 0.000 description 2
- 238000002848 electrochemical method Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000005693 optoelectronics Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000004032 porphyrins Chemical group 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000012296 anti-solvent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000009396 hybridization Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000005291 magnetic effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- -1 pyridine alkane ketone Chemical class 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
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- Carbon And Carbon Compounds (AREA)
Abstract
The invention belongs to the technical field of material preparation, and relates to a preparation method of a hybrid material compounded from a fullerene micro-nano material and a conjugated polymer. The preparation method comprises the following steps: placing a fullerene substance into a agate mortar for grinding; dissolving the fullerene substance by adopting a good solvent, and then removing into a transparent glass bottle; carrying out ultrasonic dispersion by using ultrasonic waves in an ice-water bath, then filtering at room temperature to obtain a fullerene saturated solution, and then culturing by adding isopropanol to obtain suspending liquid which contains the fullerene micro-nano material; dissolving the conjugated polymer into the good solvent, and filtering to obtain a conjugated polymer solution; adding the conjugated polymer solution to the suspending liquid which has the volume ratio of 1-10 times and contains the fullerene micro-nano material; and carrying out oscillating mixing processing by using the ultrasonic waves, and culturing to obtain the hybrid material compounded from the fullerene micro-nano material and the conjugated polymer. The preparation method disclosed by the invention has the advantages of simple integral process, reliability in principle and short production period; the prepared material has the advantages of good property, wide application range, high reliability and environment friendliness.
Description
Technical field:
The invention belongs to technical field of material, relate to a kind of fullerene micro Nano material composite modification technology technique, particularly relate to the hybrid material preparation method of a kind of fullerene micro Nano material and conjugated polymer compound.
Background technology:
The micro-nano class carbon materials of low-dimensional is the ideal system of the physical propertiess such as the behavior of research electric transmission, optical characteristics and mechanical property, play an important role in the research field of the integrated circuits such as micro-nano electronics and opto-electronic device and functional element, for realizing its application extension, functional diversities, modification is carried out to low-dimensional nano carbon structured material, becomes the hot issue of current micro Nano material scientific research.Kroto in 1985 etc. find soccerballene C
60, there is the symmetry of height, the π-electron conjugated system of spherical delocalization, there are unique physicochemical property; The sex-limited behavior of the optical physics that soccerballene is unusual, electroconductibility, photoconductivity and light has caused the great interest of scientists, through the research of two more than ten years, there is the subject that organic soccerballene chemistry, soccerballene supramolecular chemistry, TXEndohedral Metallofullerenes, soccerballene pharmaceutical chemistry, soccerballene photoelectricity magnetics etc. are new, and in continuous development; (V.Georgakilas, V.F.Pellarini, the M.Prato such as Prato, D.M.Guldi, M.Melle-Franco and F.Zerbetto, Proc.Natl.Acad.Sci.U.S.A., 2002,99,5075) a kind of Ionized C containing porphyrin unit of reported first
60derivative can form nanotube, and this is presumably because that the π-π of soccerballene and porphyrin interacts, caused by electrostatic interaction self-assembly.Chinese patent CN1195103 and CN1215973 discloses and utilizes electrochemical method to make the aggregate electrophoresis of soccerballene in the nano-void of foraminous die plate, thus forms orderly micro-nano mitron and the method for micro-nano whisker; Chinese patent 1267342C discloses the C obtained by template contral radical polymerization
60the C that covalent intermolecular bond connects
60one dimension aggregate nano pipe, its radical polymerization to be adsorbed with monomer C
60the template of molecule maintains 2-4 hour, 1 kilowatt of ultraviolet lighting 0.5-1 hour in 400-550 DEG C under protection of inert gas.
But there is the problems such as the sample length-to-diameter ratio obtained is little, the bad control of purity, technology of preparing complexity in above-mentioned several method.In recent years, Japanese Laid-Open Patent 2005-254393A and 2006-124266A discloses near room temperature C
60saturated organic solution and the liquid-liquid interface liberation method preparation of Virahol there is the soccerballene C of single crystal structure
60nano whisker and nanotube, the method synthesis nanofiber there is single crystal structure, high length-diameter ratio and high purity (99.9%), but the method Problems existing prepares soccerballene C
60and C
70nanotube there is growth cycle long (more than a week), and reproducibility is poor, is difficult to extensive preparation; For these problems, Chinese patent CN100581998C disclose a kind of simple, reproducible, fullerene micro nanometer fiber of being applicable to preparing in a large number, having single crystal structure, high length-diameter ratio and highly purified solid or hollow without method for preparing template.Meanwhile, the research prepared about soccerballene micro Nano material gets more and more, as (M.G.Yao, B.M.Andersson such as Liu, P.Stenmark, B.Sundqvist, B.B.Liu, T.Wagberg, Carbon, 2009,47:1181) to pass through to use different solvents by simple method of evaporation, different vaporization temperatures prepares the soccerballene nano and micro materials of different dimensions, (the J.Y.Jeong such as Jeong, W.S.Kim, S.I.Park, T.S.Yoon, and B.H.Chung, J.Phys.Chem.C, 2010,114:12976) pass through to C
60add anti-solvent in-toluene solution and make soccerballene crystallization, prepare the fullerene nanomaterial etc. of different-shape.
At present, liquid-liquid interface liberation method has become prepares fullerene micro nanometer fiber and micro-nano wafer is simple, effective means the most, but can not only be confined to prepare on the fullerene micro Nano material (micro-nano whisker/micro-nano mitron/micro-nano wafer) of different structure for the research of soccerballene; Research finds that the nanostructure of soccerballene, fullerene derivate and soccerballene base is the good acceptor of electronics, can as receptor system application on the solar cell, but compared with carbon nanotube, the main shortcoming of fullerene micro nanometer fiber is that specific conductivity is lower, which limits its application, but find the C of alkali-metal-doped
60soccerballene has fabulous supraconductivity, with original C
60powder is compared, and has better electroconductibility; And the structure of fullerene micro nanometer fiber uniqueness, size are controlled, the feature that dissolves in some organic solvent, again can as the carrier of uniqueness and reacting field; Therefore fullerene micro nanometer fiber is modified to the paces in the epoch of having complied with.
Conducting polymer is the hot research problem of Material Field in recent years always, but during this type of conducting polymer eigenstate, Conductivity Ratio is lower, just has good specific conductivity after having to pass through doping, fullerene is good electron acceptor(EA), and containing the atom with lone-pair electron in conjugated polymer, is electron donor(ED), so available fullerene molecular dopant conjugated polymer, to increase its specific conductivity, report about the original fullerene powder of preparation and conjugation polymer hybridisation material emerges in an endless stream, as (Wang Q, Wang S, Li J, et al.J.Polym.Sci., Part B:Polym.Phys, 2012,50 (20): 1426-1432) such as Wang use C
60powder and aniline have prepared C as starting material by interfacial polymerization
60/ polyaniline composite material, at C
60with under the certain proportion of polyaniline, the electroconductibility of matrix material is good, I.Sapurina etc. (I.Sapurina, M.Mokeev, V.Lavrentev, V.Zgonnik, et al.Eur.Polym.J, 36,2000:2321-2326) pass through C
60be doped in polyaniline, add the thermostability of polyaniline and specific conductivity increases, but these methods all just make use of the character of soccerballene electron acceptor(EA), its electroconductibility is increased with its conjugated polymer that adulterates, this doping makes costly, if the fullerene micro Nano material prepared by original fullerene powder and conjugated polymer can be carried out hydridization, both can make the pattern of fullerene micro nanometer fiber/wafer that huge change occurs, meanwhile conjugated polymer is doped specific conductivity and is improved, such recombination energy obtains having brand-new photoelectromagnetism and the nano-hybrid material of mechanical property.
Summary of the invention:
The object of the invention is to the shortcoming overcoming prior art existence, seek to design a kind of method preparing the hybrid material of fullerene micro Nano material and conjugated polymer compound, fullerene micro Nano material is carried out compound with conjugated polymer by direct ultrasonic mixing, both pattern modification was carried out to fullerene micro Nano material, again conjugated polymer is adulterated, form novel hybrid material, its material has new photoelectromagnetism and mechanical property.
To achieve these goals, the processing method that the present invention relates to comprises the following steps:
(1) fullerene micro Nano material is prepared: be placed in agate mortar by fullerene material, be ground to metalluster, get the toluene of fullerene, pyridine, dimethylbenzene, benzene, dithiocarbonic anhydride, tetracol phenixin, the mixed solvent of toluene dichloride or methylene dichloride good solvent or its any ratio adds in mortar and dissolves fullerene material, move into clear-glass bottle again, disperse 10 minutes with the ultrasonic echography of 50-500W in ice-water bath after, filtered at room temperature obtains fullerene saturated solution, then Virahol is added by the volume ratio of 1:1, put into 4 DEG C of constant incubators and carry out the suspension that cultivation obtains containing fullerene micro Nano material for 24 hours,
(2) polyaniline, aniline, polypyrrole or Polythiophene conjugated polymer are dissolved in its good solvent, obtain the solution of conjugated polymer after filtration;
(3) conjugated polymer solution prepared by step (2) being added volume ratio is in the suspension prepared of the step (1) of 1-10 times, after ultrasonic oscillation combination treatment, put into the hybrid material that 4 DEG C of refrigerators cultivate obtained fullerene micro Nano material and conjugated polymer compound, complete the preparation of hybrid material.
It is 98-99.9% soccerballene C that fullerene material of the present invention comprises purity
60, C
70, C
60with C
70mixture and derivative (as C
60[C (OOC
2h
5)
2]) and high carbon number soccerballene (as C
82, C
84, C
100, C
110c
540); Described fullerene micro Nano material comprises micro nanometer fiber and micro-nano wafer, is the micro nanometer fiber that is interconnected to by covalent linkage or ionic linkage or Van der Waals force between fullerene material and micro-nano wafer.
The preparation of the present invention's compared with prior art novelty has the fullerene micro Nano material of unique morphology and the hybrid material of conjugated polymer compound, carries out finishing to fullerene micro Nano material, increases the specific conductivity of conjugated polymer; With clear, colorless Glass Containers, constant incubator without method for preparing template, by the direct ultrasonic hybrid material being mixed with fullerene micro Nano material and conjugated polymer compound; Adopt and there is the fullerene micro-nano mitron of conjugated pi electron structure and micro-nano whisker and the micro-nano wafer new aggregated structure as fullerene, keep the structures and characteristics of fullerene molecule, there is the feature of quasi-one dimensional nanostructure, by making the pattern of fullerene micro nanometer fiber and wafer change with the high molecular hydridization of conjugation, it is made to have wide practical use in fields such as micro-nano device, Flied emission equipment, fuel cell electrode, limited chemical reaction field, high frequency filter and opto-electronic active polymers; Its integrated artistic is simple, and principle is reliable, and with short production cycle, the material property of preparation is good, is widely used, and reliability is strong, environmental friendliness.
Embodiment:
Particular content of the present invention is further illustrated below by embodiment.
Embodiment 1:
The step of preparation process of the present embodiment comprises:
(1) 14mg C is taken
60powder, is dissolved in 5ml toluene after grinding, ultrasonic 10min under condition of ice bath; Add 5ml Virahol wherein with the volume ratio of 1:1 after filtering above-mentioned solution, put in constant incubator 4 DEG C of constant temperature and cultivate 24h, preparation length is 10-20 μm of soccerballene micro nanometer fiber (FM/NFs);
(2) measuring the 100ml concentration that 1.8ml aniline (An) joins is mix and blend in the HCl of 1mol/L; In above-mentioned solution, add 1.14g ammonium persulphate (APS) again, stir after 1min, put into refrigerator temperature control and refrigerate 12h under-12 DEG C of conditions, adding 45ml concentration after suction filtration is that 1.74mol/L ammoniacal liquor soaks 5min, and dry PANI-EB powder, grinds stand-by;
(3) get PANI-EB powder and be dissolved in METHYLPYRROLIDONE (N-methyl-2-pyrrolidone, NMP) in, ultrasonic 5min, filter to obtain PANI-EB/NMP colloid, get PANI-EB/NMP colloid with different volumes than in the mother liquid multi-cavity bottle joined containing FM/NFs, ultrasonic 30min under ice bath, puts into 4 DEG C, refrigerator refrigeration 48h and obtains FM/NFs/PANI hybrid material;
(4) characterize: characterized by the appearance structure of scanning electronic microscope (SEM) to the FM/NFs/PANI hybrid material of preparation.
Embodiment 2:
The present embodiment is identical with embodiment 1 step, adopt liquid-liquid interface legal system for soccerballene micro Nano material, difference is that good solvent selects pyridine, pyridine alkane ketone, benzene, dithiocarbonic anhydride, aniline and ethanol respectively, and the material of preparation is different product shape, comprises sheet and particulate state.
Embodiment 3:
The present embodiment and embodiment 1 step difference, in the preparation of soccerballene micro Nano material, adopt evaporation C
60-toluene saturated solution, C
60-benzene saturated solution and C
60the method of-dichlorobenzene saturated solution, i.e. method of evaporation, be prepared.
Embodiment 4:
The present embodiment and embodiment 1 step difference, in the preparation of soccerballene micro Nano material, adopt electrochemical method in Chinese patent CN1195103 and CN1215973 to be prepared; Or adopt template in Chinese patent 1267342C to be prepared.
Embodiment 5:
The present embodiment is identical with embodiment 1 step, and difference is that the conjugated polymer selected is respectively polypyrrole and Polythiophene.
Embodiment 6:
The present embodiment is identical with embodiment 1 step, and difference is that the ultrasonic time selected by ultrasonic hybrid system is different different with the digestion time of hybrid material after ultrasonic mixing.
Claims (2)
1. a hybrid material preparation method for fullerene micro Nano material and conjugated polymer compound, is characterized in that concrete steps comprise:
(1) fullerene material is placed in agate mortar, be ground to metalluster, get the toluene of fullerene, pyridine, dimethylbenzene, benzene, dithiocarbonic anhydride, tetracol phenixin, the mixed solvent of toluene dichloride or methylene dichloride good solvent or its any ratio adds in mortar and dissolves fullerene material, move into clear-glass bottle again, disperse 10 minutes with the ultrasonic echography of 50-500W in ice-water bath after, filtered at room temperature obtains fullerene saturated solution, then Virahol is added by the volume ratio of 1:1, put into 4 DEG C of constant incubators and carry out the suspension that cultivation obtains containing fullerene micro Nano material for 24 hours,
(2) polyaniline, polypyrrole or Polythiophene conjugated polymer are dissolved in its good solvent, obtain the solution of conjugated polymer after filtration;
(3) conjugated polymer solution prepared by step (2) being added volume ratio is in the suspension prepared of the step (1) of 1-10 times, after ultrasonic oscillation combination treatment, put into the hybrid material that 4 DEG C of refrigerators cultivate obtained fullerene micro Nano material and conjugated polymer compound, complete the preparation of hybrid material.
2. the hybrid material preparation method of fullerene micro Nano material according to claim 1 and conjugated polymer compound, it is characterized in that described fullerene material comprises purity is 98-99.9% soccerballene C
60, C
70, C
60with C
70mixture and derivative C
60[C (OOC
2h
5)
2] and high carbon number soccerballene, its medium high carbon number soccerballene comprises C
82, C
84, C
100, C
110and C
540; Described fullerene micro Nano material comprises micro nanometer fiber and micro-nano wafer, is the micro nanometer fiber that is interconnected to by covalent linkage or ionic linkage or Van der Waals force between fullerene material and micro-nano wafer.
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| CN105679553A (en) * | 2016-04-22 | 2016-06-15 | 青岛科技大学 | Super capacitor based on fullerene nano fiber/polyaniline composite |
| CN106219485B (en) * | 2016-08-10 | 2018-08-31 | 哈尔滨工业大学深圳研究生院 | A kind of self-assembling method of one-dimensional micro-nanometer material |
| CN106633733A (en) * | 2017-01-04 | 2017-05-10 | 青岛科技大学 | Preparation method of fullerene square lamellar crystal/polymer composite material |
| CN108559111A (en) * | 2018-01-16 | 2018-09-21 | 四川龙华光电薄膜股份有限公司 | The preparation method of strong adhesive force fullerene micro/nano-fibre antistatic film |
| CN113045894A (en) * | 2019-12-26 | 2021-06-29 | 有研工程技术研究院有限公司 | Preparation method of polyaniline-fullerene of ammonia-sensitive organic composite material |
| CN112126217B (en) * | 2020-10-12 | 2022-09-16 | 广东工业大学 | Fullerene/carbon nanotube/thermoplastic resin composite film, and preparation method and application thereof |
| CN113828356B (en) * | 2021-07-13 | 2023-01-24 | 中国科学院化学研究所 | Application of fullerene donor-acceptor composite material in photocatalysis |
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| CN102953150A (en) * | 2012-11-14 | 2013-03-06 | 青岛科技大学 | Preparation of fullerene micro-nano fiber in volatilization and diffusion ways |
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