CN103408895A - Preparation method of graphene/epoxy resin composite material - Google Patents
Preparation method of graphene/epoxy resin composite material Download PDFInfo
- Publication number
- CN103408895A CN103408895A CN2013101372030A CN201310137203A CN103408895A CN 103408895 A CN103408895 A CN 103408895A CN 2013101372030 A CN2013101372030 A CN 2013101372030A CN 201310137203 A CN201310137203 A CN 201310137203A CN 103408895 A CN103408895 A CN 103408895A
- Authority
- CN
- China
- Prior art keywords
- graphene
- preparation
- graphite
- epoxy resin
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention provides a preparation method of a graphene/epoxy resin composite material. The method comprises the following steps of firstly, preparing graphite oxide through a hummer method, and ultrasonically treating the graphite oxide to obtain graphene; and then, carrying out ultrasonic dispersion in an acetone solution, adding an epoxy resin matrix, and carrying out further ultrasonic stirring treatment, vacuumizing and adding a curing agent, pouring and heating after the vacuum treatment to obtain the graphene/epoxy resin composite material. When the content of graphene in the material is 0.5%, the tensile strength of the material is up to 78.084 MPa; when the graphite content gradually increases from 0.1% to 3%, the tensile strength firstly increases and then decreases, and reaches to 0.5% best, the tensile strength is increased by 51.7% compared with pure resin, and the material has good mechanical properties.
Description
Technical field
The present invention relates to a kind of Graphene epoxy resin composite material preparation method.
Background technology
Graphene is with its excellent mechanical property, thermal property, chemical properties etc. are the concern of scientific circles extremely, particularly Graphene is owing to having very high mechanical property, if as packing material, add the mechanical property that can greatly promote polymer materials in polymeric matrix to, thereby the mechanical property of change polymkeric substance itself can not meet the situation of actual needs.Epoxy resin is owing to having good chemical property and physicals simultaneously, price is low, good with various material binding performances, and technological flexibility is that other thermosetting material can not be compared, can be used as the different field such as coating, tackiness agent, composite resin matrix, electronic package material and all brought into play huge effect.If carry out Graphene and resin material compound, due to both consistencies, can between bi-material, generation can become ideal interface, the mechanical property of Graphene excellence and thermal property are fully played like this, thereby can be as reinforcement, play the function that strengthens polymer matrix composites, prepare the polymer matrix composites of mechanical property and thermal property excellence.Therefore studying the Graphene epoxy resin composite material has very wide prospect.
In world wide, many scientific workers have successfully prepared Graphene reinforcement matrix material, and have studied the interfacial interaction between matrix and reinforcement Graphene.The people such as Koratkar prepare and study graphene composite material.He has also prepared Single Walled Carbon Nanotube simultaneously, multi-wall carbon nano-tube composite material contrasts, and carries out performance test and comparison with three kinds of matrix materials that content is all 0.1 ± 0.002%.Result shows that the performance of graphene composite material is apparently higher than carbon nano tube compound material.Graphene than carbon nanotube the superiority on mechanical property may with the high-specific surface area of Graphene, simultaneously between obturator and matrix, bonding makes both interlock due to the configuration of surface of fold, these all make the grapheme material mechanical property fine.Graphene also can improve the toughness of matrix material, because when Graphene is subjected to load, has high modulus in flexure, can absorb energy [Koratkar et al, Enhanced mechanical properties of nanocomposites at Low graphene Content, acsnano, 2009:3:3884].The people such as Yu have prepared the epoxy group(ing) heat interfacial material with few sheet layer graphene.They study discovery.They find that by the thermal conductivity testing research graphene film that thickness is less than 2nm is suitable as the heat conductive filler of epoxy resin very much, the Graphene of interpolation 25% can obtain the matrix material that thermal conductivity is 6.44W/ (mk), thermal conductivity has improved 3000%[Yu A et al than virgin resin, Graphite nanoplatelet-epoxy composite thermal interface materials, Phys.Chem.C, 2007:111:7565].But at present prepared polymer matrix composite, the dispersion of Graphene is not very desirable, this is because Graphene is wetting ability, can not in non-aqueous solution, directly peel off dispersion, and abundant not enough to peeling off of Graphene, can not form the seldom even Graphene of monolithic layer of lamella, when the Graphene of preparation reduces in the aqueous solution simultaneously, irreversible cohesion can occur, make in matrix dispersed bad.
Summary of the invention
The present invention is directed to the problems referred to above of prior art, provide a kind of Graphene and epoxy resin compound preparation method.Make in the steps below:
Step 1: take the 2g synthetic graphite, add in the there-necked flask that the 250ml vitriol oil is housed, want mechanical stirring in the process added, then claim the NaNO of 5g
3Be added among the there-necked flask that is mixed with sulfuric acid and graphite.Mechanical stirring reaction 1h in room temperature.Afterwards, in system, add 10gKMnO
4, added in two hours.Continue to stir 72h again, then stop stirring, after cooling, add appropriate deionized water in there-necked flask, approximately about 200ml, about 15min adds.Finally drip 30% hydrogen peroxide, until solution is by reddish brown flavescence.Use respectively afterwards dilute hydrochloric acid and deionized water wash, until sulphate-containing ion not in solution, and be washed till neutrality.And then baking 12h makes artificial graphite oxide under 70 ℃.；
Step 2: get step 1 gained graphite oxide and put into fast the retort furnace thermal treatment 15s that has been preheating to 1050 ℃, and then disperse in solvent, can obtain Graphene.
Step 3: first the Graphene of preparation is added to a certain proportion of acetone soln, ultrasonic agitation under condition of ice bath, then add a certain proportion of epoxy resin, continue ultrasonic agitation, the heating in water bath magnetic agitation is removed acetone solvent wherein again, adds solidifying agent after vacuumizing afterwards processing, after stirring, vacuumizes processing again, pour into a mould heating, obtain the matrix material batten.Finally with hydrazine, matrix material is reduced.
The further preferred version of the present invention is: described graphite is selected from large particle diameter synthetic graphite (200 order), small particle size synthetic graphite (200 order), a kind of in natural graphite.
The further preferred version of the present invention is: the described method for preparing graphite oxide is selected from a kind of in hummer method, Standenmaier method.
The further preferred version of the present invention is: described organic solvent is selected from a kind of in ethanol, acetone, NMP.
The further preferred version of the present invention is: the treatment process of described graphite oxide is selected from a kind of in ultrasonic method, dilatometry.
The present invention utilizes the standby graphite oxide of hummer legal system to carry out ultrasonic method and processes and to have prepared Graphene.The standby oxidized graphite flake layer of Hummer legal system has the fold-type structure, on lamella, oxygen level is large simultaneously, be that on sheet surfaces,, than horn of plenty, there is good dispersity in functional group in pure water, avoided simultaneously destroying more serious with the standby graphite oxide carbon-coating of Standenmaier legal system.To preparing graphite oxide, carry out supersound process, extent of exfoliation is relatively high, in process due to ultrasonic separation, chemical transformation does not occur simultaneously, so the preparation graphene sheet layer on still with oxygen-containing functional group, avoided dilatometry to process the deoxidation of rear oxidation graphite, the decomposition of a large amount of functional groups, thus in compound with the link property variation of epoxy resin-matrix body interface.By controlling the time of compound tense ultrasonic agitation, control the reunion of graphene sheet layer after disperseing in addition.The content of the standby graphite oxide of Hummer legal system preparation after ultrasonic method is processed is that 0.5% matrix material is that the 51.7%. mechanical property is taken on a new look greatly than the tensile strength increase rate of virgin resin.And the characteristics such as the method synthesis route is simple, reaction conditions is gentle, raw material sources are abundant, selectable range is wide, have commercial applications prospect well.
The accompanying drawing explanation
Accompanying drawing 1 is Graphene scanning electron microscope diagram (SEM) figure after the standby graphene oxide ultrasonic method of hummer legal system is processed.
Accompanying drawing 2 is 0.5% Graphene epoxy resin composite material profile scanning electron microscope picture (SEM) figure for content.
Accompanying drawing 3 is for content is respectively 0,0.3%, and the infrared spectrogram (FT-IR) of 0.5% Graphene epoxy resin composite material is schemed.
Accompanying drawing 4 is for content is respectively 0,0.1%, the tensile strength curve figure of 0.2%, 0.5%, 1%, 2%, 3% Graphene epoxy resin composite material.
Embodiment
The present invention is described in detail below in conjunction with drawings and Examples:
Embodiment 1
Take the 2g synthetic graphite, add in the there-necked flask that the 250ml vitriol oil is housed, want mechanical stirring in the process added, then claim the NaNO of 5g
3Be added among the there-necked flask that is mixed with sulfuric acid and graphite.Mechanical stirring reaction 1h in room temperature.Afterwards, in system, add 10gKMnO
4, added in two hours.Continue to stir 72h again, then stop stirring, after cooling, add appropriate deionized water in there-necked flask, approximately about 200ml, about 15min adds.Finally drip 30% hydrogen peroxide, until solution is by reddish brown flavescence.Use respectively afterwards dilute hydrochloric acid and deionized water wash, until sulphate-containing ion not in solution, and be washed till neutrality.And then baking 12h makes artificial graphite oxide under 70 ℃.Graphite oxide is put into fast and has been preheating to 1050 ℃ and processes 15s, obtain Graphene.By weight 5:1000, take 0.05g Graphene and 10g epoxy resin, the 0.5g Graphene is dissolved in acetone, under condition of ice bath with 6 cycles of the ultrasonic dispersion of cell pulverization machine (being 2376s), then add 10g epoxy resin, continuation is by cell pulverization and carry out 20 cycles of ultrasonic agitation (7920s), and then magnetic agitation is removed acetone in the water-bath of 70 ℃.After in the vacuum drying oven of 70 ℃, vacuumizing 2h, add the 2-ethyl 4-methylimidazole of 0.6g in resin, hand operated mixing 5min, in vacuum drying oven, vacuumize again and process 20min, then carry out casting, finally at 80 ℃ of 1h, 120 ℃ of 3h heat treated obtain matrix material.
As accompanying drawing 1 scanning electron microscope diagram (SEM), the analysis showed that the Graphene extent of exfoliation obtained is higher, lamella is thinner; The analysis showed that as accompanying drawing 2 scanning electron microscope diagrams (SEM) in the product section obtained that Graphene disperses better, the pleated structure of Graphene makes the Graphene can be fine with the hinge ability of resin group simultaneously; As accompanying drawing 3 infrared spectrograms (FT-IR) analytical results, show, in the place that wave number is 1108.28, formed the vibration peak of ester bond, mean to have formed the crosslinked of new key between Graphene and epoxy resin, interface junction credit union is tightr.As the accompanying drawing 4 tensile strength curve figure matrix material tensile strength that to show at content be 0.5%, be 78.084MPa.
Embodiment 2
Working method is with embodiment 1, and difference is to take 0.02g Graphene and 10g epoxy resin by weight 2:1000, and all the other conditions are constant, finally obtains content and be 0.2% Graphene epoxy resin composite material.Through infrared spectrogram (FT-IR) analytical results and surface sweeping electron micrograph, confirm, between Graphene and epoxy resin, formed the chemical bond of ester bond, interface is in conjunction with tight.Graphene disperses to teach in matrix.Content is that the tensile strength of 0.2% Graphene epoxy resin composite material is 56.345MPa.
Embodiment 3
Working method is with embodiment 1, and difference is to take 0.2g Graphene and 10g epoxy resin by weight 2:100, and all the other conditions are constant, finally obtains content and be 2% Graphene epoxy resin composite material.Through infrared spectrogram (FT-IR) analytical results and surface sweeping electron micrograph, confirm, between Graphene and epoxy resin, formed the chemical bond of ester bond, interface is in conjunction with tight.Graphene disperses in matrix be not very desirable, and more reunion is arranged.Content is that the tensile strength of 2% Graphene epoxy resin composite material is 54.574MPa.
Embodiment 4
Working method is with embodiment 1, and difference is, with 10 cycles of the ultrasonic dispersion of cell pulverization machine (being 3960s), all the other conditions are constant under condition of ice bath, finally obtains content and be 0.5% Graphene epoxy resin composite material.Through scanning electronic microscope (SEM) photo, confirm, the Graphene in more ultrasonic 10 cycles of the Graphene in ultrasonic 6 cycles is scattered, the graphene sheet layer in ultrasonic 6 cycles is approximately 2.9 microns wide, and the graphene sheet layer in ultrasonic 10 cycles is approximately 3.96 microns wide.
Above preferred embodiment of the present invention is illustrated, but the present invention is not limited to described embodiment, those of ordinary skill in the art also can make all modification be equal to or replacement under the prerequisite without prejudice to spirit of the present invention, the modification that these are equal to or replacement all are included in the application's claim limited range.
Claims (6)
1. the preparation method of a conducting polymer-based nanometer carbon fibers is characterized in that making by following method:
Step 1: take the 2g synthetic graphite, add in the there-necked flask that the 250ml vitriol oil is housed, want mechanical stirring in the process added, then claim the NaNO of 5g
3Be added among the there-necked flask that is mixed with sulfuric acid and graphite.Mechanical stirring reaction 1h in room temperature.Afterwards, in system, add 10gKMnO
4, added in two hours.Continue to stir 72h again, then stop stirring, after cooling, add appropriate deionized water in there-necked flask, approximately about 200ml, about 15min adds.Finally drip 30% hydrogen peroxide, until solution is by reddish brown flavescence.Use respectively afterwards dilute hydrochloric acid and deionized water wash, until sulphate-containing ion not in solution, and be washed till neutrality.And then baking 12h makes artificial graphite oxide under 70 ℃;
Step 2: get step 1 gained graphite oxide and put into fast the retort furnace thermal treatment 15s that has been preheating to 1050 ℃, and then disperse in solvent, can obtain Graphene;
Step 3: first the Graphene of preparation is added to a certain proportion of acetone soln, ultrasonic agitation under condition of ice bath, then add a certain proportion of epoxy resin, continue ultrasonic agitation, the heating in water bath magnetic agitation is removed acetone solvent wherein again, adds solidifying agent after vacuumizing afterwards processing, after stirring, vacuumizes processing again, pour into a mould heating, obtain the matrix material batten.Finally with hydrazine, matrix material is reduced.
2. the preparation method of conducting polymer-based nanometer carbon fibers as claimed in claim 1, it is characterized in that: described graphite is selected from large particle diameter synthetic graphite (200 order), small particle size synthetic graphite (200 order), a kind of in natural graphite.
3. the preparation method of conducting polymer-based nanometer carbon fibers as claimed in claim 1 is characterized in that: the described method for preparing graphite oxide is selected from a kind of in hummer method, Standenmaier method.
4. the preparation method of conducting polymer-based nanometer carbon fibers as claimed in claim 1 is characterized in that: described organic solvent is selected from a kind of in ethanol, acetone, NMP.
5. the preparation method of conducting polymer-based nanometer carbon fibers as claimed in claim 1 is characterized in that: the treatment process of described graphite oxide is selected from a kind of in ultrasonic method, dilatometry.
6. one kind by the described method gained of claim 1 to 5 Graphene epoxy resin composite material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101372030A CN103408895A (en) | 2013-04-18 | 2013-04-18 | Preparation method of graphene/epoxy resin composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101372030A CN103408895A (en) | 2013-04-18 | 2013-04-18 | Preparation method of graphene/epoxy resin composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103408895A true CN103408895A (en) | 2013-11-27 |
Family
ID=49601943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013101372030A Pending CN103408895A (en) | 2013-04-18 | 2013-04-18 | Preparation method of graphene/epoxy resin composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103408895A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140639A (en) * | 2014-08-01 | 2014-11-12 | 黑龙江大学 | Method for preparing graphene/epoxy resin composite |
| CN104530653A (en) * | 2014-12-26 | 2015-04-22 | 黑龙江大学 | Preparation method of epoxy resin/graphene/nano copper composite material |
| CN104845009A (en) * | 2015-05-19 | 2015-08-19 | 中国科学院化学研究所 | Fluorine resin/graphene composite material with isolation structure and preparation method and application thereof |
| CN105837790A (en) * | 2016-06-20 | 2016-08-10 | 山东欧铂新材料有限公司 | Preparation method of graphene modified epoxy resin |
| CN106449952A (en) * | 2016-10-09 | 2017-02-22 | 常州市鼎日环保科技有限公司 | Preparation method for LED packaging material |
| WO2018205336A1 (en) * | 2017-05-12 | 2018-11-15 | 深圳市华星光电技术有限公司 | Led packaging material and preparation method |
| CN109852002A (en) * | 2019-01-02 | 2019-06-07 | 浙江华正新材料股份有限公司 | A kind of preparation method of high-strength light laminated composite board material |
| CN110615970A (en) * | 2019-09-16 | 2019-12-27 | 海安南京大学高新技术研究院 | High-quality graphene, heat-conducting epoxy resin composite material thereof and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101812194A (en) * | 2010-03-17 | 2010-08-25 | 湖北大学 | Graphene-based barrier composite material and preparation method thereof |
| CN101864098A (en) * | 2010-06-03 | 2010-10-20 | 四川大学 | Preparation method of polymer/graphene composite material through in situ reduction |
| CN102161785A (en) * | 2011-03-10 | 2011-08-24 | 四川大学 | Preparation method of graphene/polymer nano composite material |
| CN102286189A (en) * | 2011-06-24 | 2011-12-21 | 中国科学院理化技术研究所 | Preparation method of graphene oxide/epoxy resin nanocomposite |
| CN102557021A (en) * | 2012-02-06 | 2012-07-11 | 上海交通大学 | Nanocomposite material preparation method based on graphene oxide autocatalysis |
-
2013
- 2013-04-18 CN CN2013101372030A patent/CN103408895A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101812194A (en) * | 2010-03-17 | 2010-08-25 | 湖北大学 | Graphene-based barrier composite material and preparation method thereof |
| CN101864098A (en) * | 2010-06-03 | 2010-10-20 | 四川大学 | Preparation method of polymer/graphene composite material through in situ reduction |
| CN102161785A (en) * | 2011-03-10 | 2011-08-24 | 四川大学 | Preparation method of graphene/polymer nano composite material |
| CN102286189A (en) * | 2011-06-24 | 2011-12-21 | 中国科学院理化技术研究所 | Preparation method of graphene oxide/epoxy resin nanocomposite |
| CN102557021A (en) * | 2012-02-06 | 2012-07-11 | 上海交通大学 | Nanocomposite material preparation method based on graphene oxide autocatalysis |
Non-Patent Citations (1)
| Title |
|---|
| 韩韬: "石墨烯环氧树脂复合材料的制备及性能研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》, no. 10, 15 October 2012 (2012-10-15) * |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140639A (en) * | 2014-08-01 | 2014-11-12 | 黑龙江大学 | Method for preparing graphene/epoxy resin composite |
| CN104140639B (en) * | 2014-08-01 | 2016-08-24 | 黑龙江大学 | A kind of preparation method of Graphene/epoxy resin composite material |
| CN104530653A (en) * | 2014-12-26 | 2015-04-22 | 黑龙江大学 | Preparation method of epoxy resin/graphene/nano copper composite material |
| CN104845009B (en) * | 2015-05-19 | 2018-03-23 | 中国科学院化学研究所 | Fluororesin/graphene composite material with isolation structure and preparation method and application |
| CN104845009A (en) * | 2015-05-19 | 2015-08-19 | 中国科学院化学研究所 | Fluorine resin/graphene composite material with isolation structure and preparation method and application thereof |
| CN105837790A (en) * | 2016-06-20 | 2016-08-10 | 山东欧铂新材料有限公司 | Preparation method of graphene modified epoxy resin |
| CN106449952A (en) * | 2016-10-09 | 2017-02-22 | 常州市鼎日环保科技有限公司 | Preparation method for LED packaging material |
| WO2018205336A1 (en) * | 2017-05-12 | 2018-11-15 | 深圳市华星光电技术有限公司 | Led packaging material and preparation method |
| US20180366624A1 (en) * | 2017-05-12 | 2018-12-20 | Shenzhen China Star Optoelectronics Technology Co., Ltd. | Led packaging material and manufacturing method of the same |
| US10418531B2 (en) | 2017-05-12 | 2019-09-17 | Shenzhen China Star Optoelectronics Technology Co., Ltd. | LED packaging material and manufacturing method of the same |
| US10461228B2 (en) | 2017-05-12 | 2019-10-29 | Shenzhen China Star Optoelectronics Technology Co., Ltd | LED packaging material and manufacturing method of the same |
| US10522724B2 (en) | 2017-05-12 | 2019-12-31 | Shenzhen China Star Optoelectronics Technology Co., Ltd | LED packaging material and manufacturing method of the same |
| CN109852002A (en) * | 2019-01-02 | 2019-06-07 | 浙江华正新材料股份有限公司 | A kind of preparation method of high-strength light laminated composite board material |
| CN110615970A (en) * | 2019-09-16 | 2019-12-27 | 海安南京大学高新技术研究院 | High-quality graphene, heat-conducting epoxy resin composite material thereof and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103408895A (en) | Preparation method of graphene/epoxy resin composite material | |
| Liu et al. | Ultrastrong and highly conductive MXene‐based films for high‐performance electromagnetic interference shielding | |
| Wu et al. | Preparation of a thermally conductive biodegradable cellulose nanofiber/hydroxylated boron nitride nanosheet film: the critical role of edge-hydroxylation | |
| Tang et al. | Fracture toughness and electrical conductivity of epoxy composites filled with carbon nanotubes and spherical particles | |
| Zhang et al. | Exfoliation and defect control of graphene oxide for waterborne electromagnetic interference shielding coatings | |
| CN104672502B (en) | Cyanoethyl cellulose based high-dielectric flexible nano-composite film and preparation method thereof | |
| Wang et al. | Functionalization of MWCNTs with silver nanoparticles decorated polypyrrole and their application in antistatic and thermal conductive epoxy matrix nanocomposite | |
| CN105968717A (en) | Preparation of carbon fiber/graphene/carbon nanotube/epoxy resin prepreg and carbon fiber composite material | |
| CN106117400B (en) | CNT graphene oxide strengthens the preparation method of polymer matrix composite | |
| Xu et al. | Polyamide composites with improved thermal conductivity for effective thermal management: The three-dimensional vertically aligned carbon network | |
| Li et al. | Effect of acid and TETA modification on mechanical properties of MWCNTs/epoxy composites | |
| He et al. | Self-assembled three-dimensional structure with optimal ratio of GO and SiC particles effectively improving the thermal conductivity and reliability of epoxy composites | |
| CN104387671B (en) | A kind of preparation method of PA6/PP/ CNT High performance nanometer composite material | |
| WO2017186127A1 (en) | Method for preparing graphene-modified polymethyl methacrylate composite material having ultra-high conductivity | |
| CN102912626B (en) | Preparation method of fiber surface sizing agent based on carbon nanotube/graphene oxide/POSS (Polysilsesquioxane) monomer | |
| CN105968777B (en) | A kind of antistatic composite nano materials film and preparation method thereof | |
| Li et al. | Toughing epoxy nanocomposites with graphene-encapsulated liquid metal framework | |
| Liu et al. | High-yield, high-conductive graphene/nanocellulose hybrids prepared by Co-exfoliation of low-oxidized expanded graphite and microfibrillated cellulose | |
| CN106633373A (en) | Composite carbon nanotube/polypropylene powder material for SLS (selective laser sintering) and preparation method thereof | |
| Yazdani-Pedram et al. | Mechanical and thermal properties of multiwalled carbon nanotube/polypropylene composites using itaconic acid as compatibilizer and coupling agent | |
| CN103554909B (en) | Carbon nano tube compound material, its preparation method, prepreg and copper-clad base plate that polymer-silica is coated | |
| Jiang et al. | Enhancing the dielectric properties of polymethyl methacrylate by using low loading graphene encapsulated styrene-butyl acrylate copolymer microspheres | |
| Sato et al. | A reinforced, high-κ ternary polymer nanocomposite dielectrics of PVDF, barium titanate nanoparticles, and TEMPO-oxidized cellulose nanofibers | |
| Chen et al. | The influence of functionalized MWCNT reinforcement on the thermomechanical properties and morphology of epoxy nanocomposites | |
| Li et al. | PGMA-grafted MWCNTs: correlation between molecular weight of grafted PGMA and dispersion state of MWCNTs–PGMA in an epoxy matrix |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20131127 |