CN103408836A - Anti-bacterial plastic alloy compounded of PP and HIPS - Google Patents

Anti-bacterial plastic alloy compounded of PP and HIPS Download PDF

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Publication number
CN103408836A
CN103408836A CN2013103195628A CN201310319562A CN103408836A CN 103408836 A CN103408836 A CN 103408836A CN 2013103195628 A CN2013103195628 A CN 2013103195628A CN 201310319562 A CN201310319562 A CN 201310319562A CN 103408836 A CN103408836 A CN 103408836A
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CN
China
Prior art keywords
hips
plastic alloy
compound
bacterial
antibiotic plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013103195628A
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Chinese (zh)
Inventor
黄丽红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI YINGZHI RUBBER PLASTIC PRODUCT CO Ltd
Original Assignee
SHANGHAI YINGZHI RUBBER PLASTIC PRODUCT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by SHANGHAI YINGZHI RUBBER PLASTIC PRODUCT CO Ltd filed Critical SHANGHAI YINGZHI RUBBER PLASTIC PRODUCT CO Ltd
Priority to CN2013103195628A priority Critical patent/CN103408836A/en
Publication of CN103408836A publication Critical patent/CN103408836A/en
Pending legal-status Critical Current

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Abstract

The invention discloses an anti-bacterial plastic alloy compounded of PP and HIPS. The anti-bacterial plastic alloy comprises the following ingredients by weight: 100 parts of PP, 20 to 40 parts of HIPS, 4 to 6 parts of SBS, and 0.6 to 0.8 part of anti-bacterial agent. The anti-bacterial plastic alloy is excellent in anti-bacterial effect.

Description

The antibiotic plastic alloy that PP and HIPS are compound
Technical field
The present invention relates to a kind of polyblend, relate in particular to the antibiotic plastic alloy that a kind of PP and HIPS are compound.
Background technology
Polypropylene, English name: Polypropylene, be called for short: PP.Polypropylene is lighter a kind of in common plastics, and its electrical property excellence can be used as the application of wet-heat resisting high-frequency insulation material.
Impact resistant polystyrene, HIPS, be a kind of shock proof polystyrene products of producing by the way of adding poly-isoprene-isobutylene rubber particle in polystyrene.
Yet the polyblend anti-microbial property that current PP and HIPS are compound is not good.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of PP and the compound antibiotic plastic alloy of HIPS.
Technical problem to be solved by this invention is achieved by the following technical solution:
The antibiotic plastic alloy that PP and HIPS are compound consists of by weight following component: 100 parts of PP, 20-40 part HIPS, 4-6 part SBS, 0.6-0.8 part antiseptic-germicide.
Described compatilizer SBS is SBS.
Described antiseptic-germicide consists of by weight following component: zirconium phosphate 10-30 part, silver suboxide 20-40 part, chitosan 10-30 part, 2-thiazolyl-4-benzoglyoxaline 20-40 part.
Zirconium phosphate, English name: Phosphoric acid, zirconium (4+) salt (2:1), CAS Number:13772-29-7.
Silver suboxide, CAS Number:20667-12-3.
Chitosan, English name: Chitosan, CAS Number:9012-76-4.
2-thiazolyl-4-benzoglyoxaline, English name: 2-(4-thiazolyl) benzimidazole, CASNumber:148-79-8.
Zirconium phosphate, silver suboxide, chitosan and 2-thiazolyl-4-benzoglyoxaline are uniformly mixed, can make described antiseptic-germicide.
Can adopt industry universal method to be prepared PP of the present invention and the compound antibiotic plastic alloy of HIPS, for example: by proportioning, take each component, after mixing, melting mixing, extruding pelletization, namely obtain the antibiotic plastic alloy that described PP and HIPS are compound.
The antibiotic plastic alloy that PP of the present invention and HIPS are compound, the antibacterial effect excellence.
Embodiment
Embodiment 1
According to corresponding embodiment 1 data in table 1, take each raw material, after mixing, melting mixing, extruding pelletization, namely obtain the antibiotic plastic alloy that described PP and HIPS are compound.
Table 1: composition of raw materials list position: kilogram
? Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
The PP resin 100 100 100 100 100
The HIPS resin 30 30 30 30 30
Compatilizer SBS 5 5 5 5 5
Zirconium phosphate 0.14 / 0.35 0.14 0.14
Silver suboxide 0.21 0.35 / 0.21 0.21
Chitosan 0.14 0.14 0.14 / 0.35
2-thiazolyl-4-benzoglyoxaline 0.21 0.21 0.21 0.35 /
The Co-polypropylene PP K7726H that the PP resin selects Yanshan Petrochemical company to produce.
The HIPS resin of the HIPS resin Zhenjiang trade mark PH-88 of Qi Mei company.
It is the compatilizer SBS of YH-815 that compatilizer SBS selects the Ba Ling petro-chemical corporation trade mark.
Embodiment 2-4
According to corresponding embodiment 2-4 data in table 1, take each raw material respectively.Adopt the described method of embodiment 1 to prepare described PP and the compound antibiotic plastic alloy of HIPS.
Test case 1
The polyblend that each embodiment preparation is obtained carries out the anti-microbial property test.
Antibacterial test standard: QB/T2591-2003A " antibiotic plastic anti-microbial property test method and antibacterial effect ".Detect and use bacterium: intestinal bacteria (Escherichia coli) ATCC25922, streptococcus aureus (Staphy lococcus aureus) ATCC6538.
Table 2: polyblend anti-microbial property test chart
? The intestinal bacteria antibiotic rate, % The streptococcus aureus antibiotic rate, %
Embodiment 1 90.7 89.5
Embodiment 2 89.4 88.2
Embodiment 3 88.7 87.8
Embodiment 4 88.9 87.6
Polyblend of the present invention, after adding antiseptic-germicide, mechanical property is not impact almost.Adopt the antiseptic-germicide of specified raw material and proportioning, play the antibiotic effect of synergy.

Claims (2)

1.PP with the compound antibiotic plastic alloy of HIPS, it is characterized in that, by following component, formed by weight: 100 parts of PP, 20-40 part HIPS, 4-6 part SBS, 0.6-0.8 part antiseptic-germicide.
2. the antibiotic plastic alloy that PP as claimed in claim 1 and HIPS are compound, it is characterized in that, described antiseptic-germicide consists of by weight following component: zirconium phosphate 10-30 part, silver suboxide 20-40 part, chitosan 10-30 part, 2-thiazolyl-4-benzoglyoxaline 20-40 part.
CN2013103195628A 2013-07-26 2013-07-26 Anti-bacterial plastic alloy compounded of PP and HIPS Pending CN103408836A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2013103195628A CN103408836A (en) 2013-07-26 2013-07-26 Anti-bacterial plastic alloy compounded of PP and HIPS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2013103195628A CN103408836A (en) 2013-07-26 2013-07-26 Anti-bacterial plastic alloy compounded of PP and HIPS

Publications (1)

Publication Number Publication Date
CN103408836A true CN103408836A (en) 2013-11-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN2013103195628A Pending CN103408836A (en) 2013-07-26 2013-07-26 Anti-bacterial plastic alloy compounded of PP and HIPS

Country Status (1)

Country Link
CN (1) CN103408836A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107964204A (en) * 2017-12-20 2018-04-27 何志方 The anti-aging HIPs plastics of bacteria mildew-proof and its processing technology

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107964204A (en) * 2017-12-20 2018-04-27 何志方 The anti-aging HIPs plastics of bacteria mildew-proof and its processing technology

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Application publication date: 20131127