CN103408170B - Improve the photocatalytic waste water degradation reactor expansion method of catalyst interception again - Google Patents
Improve the photocatalytic waste water degradation reactor expansion method of catalyst interception again Download PDFInfo
- Publication number
- CN103408170B CN103408170B CN201310327191.8A CN201310327191A CN103408170B CN 103408170 B CN103408170 B CN 103408170B CN 201310327191 A CN201310327191 A CN 201310327191A CN 103408170 B CN103408170 B CN 103408170B
- Authority
- CN
- China
- Prior art keywords
- reactor
- catalyst
- microwave
- back flush
- flush type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 142
- 239000003054 catalyst Substances 0.000 title claims abstract description 102
- 239000002351 wastewater Substances 0.000 title claims abstract description 60
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 37
- 230000015556 catabolic process Effects 0.000 title claims abstract description 32
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 172
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 99
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 96
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 77
- 230000008569 process Effects 0.000 claims abstract description 31
- 239000010453 quartz Substances 0.000 claims abstract description 18
- 239000012528 membrane Substances 0.000 claims description 104
- 239000007788 liquid Substances 0.000 claims description 50
- 239000000835 fiber Substances 0.000 claims description 48
- 238000001471 micro-filtration Methods 0.000 claims description 36
- 229910001220 stainless steel Inorganic materials 0.000 claims description 36
- 239000010935 stainless steel Substances 0.000 claims description 32
- 238000005273 aeration Methods 0.000 claims description 31
- 238000000108 ultra-filtration Methods 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 27
- 230000007704 transition Effects 0.000 claims description 26
- 239000010865 sewage Substances 0.000 claims description 22
- 230000010355 oscillation Effects 0.000 claims description 18
- 238000011045 prefiltration Methods 0.000 claims description 16
- 239000000523 sample Substances 0.000 claims description 16
- 230000009471 action Effects 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 9
- 230000008054 signal transmission Effects 0.000 claims description 9
- 230000003139 buffering effect Effects 0.000 claims description 8
- 230000002441 reversible effect Effects 0.000 claims description 8
- 229920002449 FKM Polymers 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 229920002379 silicone rubber Polymers 0.000 claims description 7
- 238000000151 deposition Methods 0.000 claims description 6
- 230000005611 electricity Effects 0.000 claims description 6
- 239000007769 metal material Substances 0.000 claims description 6
- 238000005086 pumping Methods 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- 230000005484 gravity Effects 0.000 claims description 5
- 238000011001 backwashing Methods 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- 230000014759 maintenance of location Effects 0.000 claims description 4
- 230000010412 perfusion Effects 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 4
- 238000004080 punching Methods 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- 238000003466 welding Methods 0.000 claims description 4
- 230000003190 augmentative effect Effects 0.000 claims description 3
- 239000002245 particle Substances 0.000 abstract description 38
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 16
- 229910052760 oxygen Inorganic materials 0.000 abstract description 16
- 239000001301 oxygen Substances 0.000 abstract description 16
- 238000004065 wastewater treatment Methods 0.000 abstract description 11
- 238000005054 agglomeration Methods 0.000 abstract description 10
- 230000002776 aggregation Effects 0.000 abstract description 10
- 238000012545 processing Methods 0.000 abstract description 4
- 238000011065 in-situ storage Methods 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 32
- 238000000926 separation method Methods 0.000 description 27
- 239000011941 photocatalyst Substances 0.000 description 26
- 230000000712 assembly Effects 0.000 description 24
- 238000000429 assembly Methods 0.000 description 24
- 239000007789 gas Substances 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 19
- 238000005516 engineering process Methods 0.000 description 17
- 238000006555 catalytic reaction Methods 0.000 description 16
- 239000004408 titanium dioxide Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 13
- 230000007246 mechanism Effects 0.000 description 12
- 230000000875 corresponding effect Effects 0.000 description 11
- 238000007146 photocatalysis Methods 0.000 description 11
- 238000007254 oxidation reaction Methods 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- 239000012535 impurity Substances 0.000 description 9
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 9
- 238000000746 purification Methods 0.000 description 9
- 239000002033 PVDF binder Substances 0.000 description 8
- 241001282153 Scopelogadus mizolepis Species 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 230000005855 radiation Effects 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- 230000001590 oxidative effect Effects 0.000 description 7
- 230000035515 penetration Effects 0.000 description 7
- 125000004122 cyclic group Chemical group 0.000 description 6
- 239000010419 fine particle Substances 0.000 description 6
- 238000009825 accumulation Methods 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- 230000003628 erosive effect Effects 0.000 description 5
- 239000002923 metal particle Substances 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 239000002957 persistent organic pollutant Substances 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- 235000003140 Panax quinquefolius Nutrition 0.000 description 4
- 240000005373 Panax quinquefolius Species 0.000 description 4
- 230000004087 circulation Effects 0.000 description 4
- 239000011162 core material Substances 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 238000011049 filling Methods 0.000 description 4
- 239000012634 fragment Substances 0.000 description 4
- 238000002513 implantation Methods 0.000 description 4
- 238000003475 lamination Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000010525 oxidative degradation reaction Methods 0.000 description 4
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 4
- 239000013049 sediment Substances 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000012510 hollow fiber Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000009991 scouring Methods 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000009954 braiding Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 2
- 238000001782 photodegradation Methods 0.000 description 2
- 238000004663 powder metallurgy Methods 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000003252 repetitive effect Effects 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 230000001839 systemic circulation Effects 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- 208000019155 Radiation injury Diseases 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000002169 extracardiac Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000009432 framing Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Physical Water Treatments (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The present invention relates to a kind of photocatalytic waste water degradation reactor expansion method improving catalyst interception again, belong to technical field of waste water processing.In existing correlation technique, have that single tank wastewater treatment capacity is less than normal, key area oxygen supply concentration degree not, catalyst runs off, degraded terminal difficulty is distinguished, agglomeration cannot perceive in time, quartz cavity gushing water precautionary measures shortcoming etc. problem, this case is for above-mentioned series of problems.This case key step comprises: cut off microwave exposure spatial domain; Expansion reactor size; Guiding bubble flow makes it discharge to key area high strength; Catalyst particles is tackled step by step with three grades of back flush type strainers of external cascade; By the ultrasonic in situ strong catalyst agglomerate from reactor bottom, incidentally clean silica tube simultaneously; By ozone sensor sensitive and reactive process, and at once close line related when arriving at degraded terminal; Initiatively detect the main inducement parameter of agglomeration, automatically give the alarm when it transfinites; Etc..
Description
Technical field
The present invention relates to a kind of photocatalytic waste water degradation reactor expansion method improving catalyst interception again, belong to C02F technical field of waste water processing.
Background technology
Microwave and photo catalysis degradation treatment technology, as a kind of effectively for the innoxious process for treating containing organic pollutant trade effluent, quite concerned in recent years.
About microwave and photo catalysis degradation technique, as an example, can be the Chinese patent application case of CN102260003A see publication number.
The disclosure number is the Chinese patent application case of CN102260003A, using microwave as excitaton source, electrodeless ultraviolet lamp is excited to launch ultraviolet, the suspension being mixed with photocatalyst titanium dioxide is irradiated in liquid internal, this electrodeless ultraviolet lamp shroud by silica tube and protect, pneumatic pump is had to continue to inject air to this silica tube inner chamber, the air overflowed by quartz cavity is via pipeline and the micro porous aeration head UNICOM being positioned at reactor bottom, the lower zone of this inside reactor is aeration zone, the upper area of this inside reactor is microwave and photo catalysis reaction zone, the program is also with the membrane separation assemblies that reactor is built-in, carry the water after analysing purification, and realize retaining of photocatalyst titanium dioxide fine particles with this membrane separation assemblies and use again, the program also sets up dividing plate between non-polar ultraviolet light source and membrane separation assemblies, for preventing ultraviolet to the radiation injury of the membrane separation assemblies of organic matter, pass into the air of inside reactor, part participates in the photocatalytic degradation reaction relying on photocatalyst titanium dioxide directly, some air, under the direct irradiation of UV-light, generate a certain amount of ozone, the ozone of this generation also plays the direct oxidative degradation for organic pollutant certainly.
The Chinese patent application case that the disclosure number is CN102260003A certainly serves very important pushing effect for the progress of microwave and photo catalysis wastewater degradation technology, and the work that its research staff launches in this field is admirable.
Based on the meaning of sincere admiration, and common striving direction, what will talk below us is problem.
The problem below will spoken of, has 15; These 15 problems are 15 problems arranged side by side; The priority of its sequence is only consider easily for discussion.
One of problem:
The disclosure number is the Chinese patent application case of CN102260003A, it is be placed in reactor inner chamber for tackling the membrane separation assemblies of catalyzer titanium dioxide fine particles, be immersed among handling object liquid, and what rely on ascension contains ozone bubbles to wash away membrane separation assemblies, remove its surface by this adsorbed, the catalyst particles be detained, reach the recovery of catalyst particles, recycling object, simultaneously, membrane separation assemblies is also rely on this mode self-cleaning and keep its separating power, so, based on this structure, business curtain hollow fiber film assembly or plate film assembly can only be selected, and, this membrane separation assemblies needs to be immersed in the context of the strong oxidizing property of ozone bubbles ascension, therefore, requirement must be had to the tolerance against oxidative power of membrane separation assemblies, the organic membrane separation assembly of common material can not tolerate such environment for use, therefore the membrane separation assemblies of PVDF material can only be selected, this point clearly illustrates that in open text the 0009th section of word of this case and claim 3, this kind needs its material cost of filter membrane of special tolerance against oxidative power higher, and its commercially available price is certainly also higher than common organic micro-filtration membrane module of non-oxidation durability requirements, in other words, the frame mode of this case, causes the PVDF material that the material of membrane separation assemblies is limited to costly.Have again, UV-light possible in device is revealed, organic membrane assembly may be touched, this organic membrane assembly material also in claimed apparatus can resist ultraviolet light irradiation, from this point, based on the organization plan of this device, the material of organic membrane separation assembly also can only be limited in PVDF material costly.
Organic membrane assembly, compared to ceramic filter assemblies, has its apparent advantage; About this point, for the personage of filtering technique specialty, be known, here do not launch to repeat.
Can so, under the prerequisite using organic material membrane module, bypass this PVDF filter membrane material limitation? this is a problem needing to solve, and this is one of problem.
Problem two:
In view of the scouring force of described ascension bubble, cleaning capacity is more weak, therefore, with this cleaning mode with the use of its aperture of membrane separation assemblies can only select the filter opening aperture of larger micro-filtration rank, the filter opening aperture of this micro-filtration rank is 0.1-0.2 micron, about this point, have in open text the 0009th section of word of this case and claim 3 equally and clearly limit, this kind of filter opening aperture limits, from the type selecting of the such membrane separation assemblies of this case, built-in and soak use-pattern, the self-cleaning method of ascension bubble, be inevitable, its filter opening aperture can only be limited in micro-filtration rank.In other words, this its scouring force of mode, cleaning force of washing away with ascension bubble is too weak, to such an extent as to cannot tackle the filter membrane of more small-bore at all, thus, in this case device, filter sizes is limited between 0.1 micron-0.2 micron, is the inevitable choice of not discussing leeway.
The filter opening aperture of so-called 0.1-0.2 micron, if change a measure unit, the filter opening aperture of 100-200 nanometer that corresponding is exactly; Does is what concept that? with 100 nanometer filter opening apertures of its lower limit, its size of catalyst particles that it can be tackled must be more than 100 nanometers, and the catalyst particles being less than 100 nanometers cannot be blocked; In other words, the catalyst particles being less than 100 nanometers, by directly penetrating, by the filter opening of membrane module, is mixed among so-called water purification that DeR device exports.
Present needs are had a talk the particle diameter of photocatalyst involved by ultraviolet catalytic DeR and photocatalyst dosage form selection.
The professional person being engaged in photocatalytic degradation research knows, reacts, its catalyzer multiselect titanium dioxide fine particles catalyzer with the photochemical degradation of uv light induction, at present, laboratory level is developed the photodegradation particle catalyst based on optically catalytic TiO 2 characteristic various in style, certainly, the photodegradation catalyzer that these different preparation methods are formed, its particle diameter is also various, its particle diameter of photocatalyst that different preparation method makes is little of 20 nanometers, and greatly to 100000 nanometer is also 100 microns, has, is wherein no lack of the photocatalyst kind of excellent performance, but due to the restriction of the evaluation of performance permanent stability, preparation cost and the market expansion etc. aspect factor, most its deliverabilities of described photocatalyst is only confined to laboratory level, and does not have to be formed production level commercially available on a large scale, at present known can make a big purchase in large quantities commercially available can actual a large amount of photocatalyst for UV-light wave band used be famous gas phase titanium dioxide P25, its concrete art-recognized meanings of gas phase titanium dioxide P25, insider knows, does not here launch to repeat, the median size of gas phase titanium dioxide P25 is 21 nanometers, gas phase titanium dioxide P25 performance is not very optimum, but, its stable performance, key can commercially make a big purchase in large quantities to obtain, and can use in a large number at industrial scale, therefore, also be usually used as with P25 catalyzer reference pointer or the contrast pointer of weighing various self-made photocatalyst catalytic performance in photochemical catalysis specialized laboratory, in fact, in view of the feature of ultraviolet catalytic DeR, the photocatalyst that dispersity is higher, be applicable to the needs of this type reaction, that is, median size is in its catalyst interfacial area that can provide of photocatalyst of 21 ran, anti-settling ability, catalytic performance permanent stability etc. aspect, comprehensive, optimal.Simply, at present, good and cheap, the photocatalyst of the UV-light wave band of the ready-made commercially available commercial grade can actually make a big purchase in large quantities, used is exactly median size is the gas phase titanium dioxide P25 catalyzer of 21 nanometers; At plant-scale application, this median size is the photocatalyst of 21 nanometers is actual first-selections.
Address above, the disclosure number is the Chinese patent application case of CN102260003A, it is for tackling the membrane module of photocatalyst, adsorbed with the stripping film assembly surface that washes away of ascension bubble, the catalyst particles of deposition, but, its scouring force of mode that this kind washes away with ascension bubble, cleaning force is too weak, to such an extent as to the filter membrane of more small-bore cannot be tackled at all, therefore, in this case device, filter sizes is limited at micro-filtration filter opening rank between 0.1 micron-0.2 micron, change a measure unit, in this case device, filter sizes is limited at the micro-filtration filter opening rank between 100 nanometer-200 nanometers, this is the inevitable choice of not discussing leeway, this case cannot tackle without the micro-filtration filter opening between selectable 100 nanometer-200 nanometers the gas phase titanium dioxide P25 particle that median size as above is 21 nanometers certainly, so, if use P25 photocatalyst, this catalyzer will cannot be tackled completely, and flows in so-called water purification, formation secondary pollution, certainly also causes the heavy losses of catalyzer and unrenewable, even if use the titanium dioxide optical catalyst of special Large stone for this reason of other kind, because mutually colliding or colliding with wall in its use procedure, also a large amount of small particle size fragment can must be produced, wherein particle diameter is less than the fragment of 100 nanometers, equally can not tackle by the micro-filtration filter opening between 100 nanometer-200 nanometers, these small shredss also can enter among so-called water purification through its membrane module, form secondary pollution.
Visible, the disclosure number is the Chinese patent application case of CN102260003A, its for the interception structure scheme of photocatalyst particulate and the cleaning solution of related film assembly all undesirable.
Therefore, how under the prerequisite of this case advantage of incorporating things of diverse nature, reach the meticulous interception for photocatalyst particulate and recycling, be an important topic very worth thinking deeply about, this is problem two.
Problem three:
We know, liquid water body itself also can absorb the energy of microwave, and cause itself temperature-rise effect of the liquid water body that is processed, and this temperature-rise effect occurred with wastewater treatment process, but not the situation that we expect, in other words, microwave energy from magnetron is not used to excite electrodeless ultraviolet lamp completely, and have quite a few should only for exciting the microwave energy of electrodeless ultraviolet lamp to be dissipated in described temperature-rise effect, the temperature-rise effect that this kind is not fond of causes unnecessary microwave energy and wastes, in view of the apparatus structure scheme that the above-mentioned publication number Chinese patent application case that is CN102260003A is shown, its rational approach, can only be reduce single tank process capacity in other words by the volume of minimizing microwave and photo catalysis reactor to reach the object weakening the unnecessary dissipation of microwave, about this point, the clear suitable size that have expressed about this apparatus structure entirety in this its embodiment of CN102260003A application case, what the preferred size expressed by it was corresponding is exactly the very little device of a profile, so, thus, the distance of reactor wall and microwave radiation source is little, the wastewater flow rate contacted with microwave is little, the microwave energy that waste water absorbs is relatively also little, correspond ground, the wastewater treatment capacity of single tank is therefore also little, more particularly, the internal capacity corresponding to device suitable size expressed in embodiment is 40 liters, also namely single tank wastewater treatment capacity is 40 liters, namely 0.04 cube, in other words, it is once a complete set of, substantial length of operation solve only the trade effluent of 0.04 cube, so, just need the repetition operated to the complete set of tail by head carried out many times, the cumulative of its treatment capacity just has plant-scale meaning, so to say, just individual analogy roughly, the wastewater treatment capacity that roughly corresponding 0.04 cube, the single tank of its preferred structure size of this case is such, need repetition 1000 times by head to the complete set of tail, substantial length of operation, its accumulation amount, just can reach 40 cubes such one have industrial level wastewater treatment capacity, so excessively loaded down with trivial details repetitive operation will cause manpower, the serious waste of material resources, visible, the wastewater degradation processing efficiency of its reality of scheme that this kind is shown by CN102260003A may not be fully up to expectations.Therefore, how under not causing more microwave energies to waste or reducing the prerequisite of microwave energy waste, increase single tank wastewater treatment capacity, reduce this intermittent type wastewater treatment equipment unnecessary too many by head to the repetitive operation number of times of tail, improve its waste water treatment efficiency, be a significant technical problem merited attention, this is problem three.
Problem four:
The scheme that this kind is shown by CN102260003A, the bubble of the inner dispersed ascension of its retort, for the cyclic motion of the relative big scale of driving a reaction tank internal liquid, contributes slightly inadequate; Certainly, this weak point, in fact corresponding small size, the low capacity device of CN102260003A scheme as expression clear in its embodiment, the impact that almost has nothing observable.From plant-scale application demand, undersized the device of divergence process amount can have great magnetism certainly; So, as a kind of possibility, if there is certain mode can realize the significantly expansion for the treatment of capacity, under this situation, its importance of cyclic motion of the relative big scale of retort internal liquid will highlight naturally; Imagine the possibility that this treatment capacity is significantly expanded, so, how to strengthen the cyclic motion of the relative big scale of retort internal liquid, be exactly a problem certainly, this is problem four.
Problem five:
For the photochemical catalysis oxidizing reaction of UV-light wave band, there is following so several key element can have influence on the efficiency of this kinds of oxidation reaction, first ultraviolet wavelength, intensity, it two is particle diameters of photocatalyst, the usage quantity of photocatalyst in unit volume reaction solution, himself catalytic performance etc. of photocatalyst, it three is organic concentration in oxidized object and water body, oxidation complexity that organic molecule structure determines himself etc., it four is sufficient degree of oxygen atmosphere, when other condition is identical, the sufficient degree of oxygen atmosphere, the key element that of affecting photochemical catalysis oxidative degradation ability is very important will be become.
As CN102260003A the scheme of showing, its numerous micro porous aeration head disperseds being placed in reactor inner chamber bottom are in bottom, and by the water distribution board alleged by it, the effect of this micro porous aeration head dispersed arrangement is made to become more very, certainly, this is for the situation of the oarse-grained micron-sized photocatalyst of the relatively easy sedimentation of use, really there is the one side that it is favourable, but, from another side, the mode that this micro porous aeration head dispersed arranges, the supply of oxygen atmosphere too disperses, and what in fact need most the region of enhanced oxygen blowing is the most effective area of photochemical catalysis oxidation, because the Effective depth penetration of short wave ultraviolet in liquid water body only has 20 cm, therefore, need most enhanced oxygen blowing to promote that in fact the effective area of photochemical catalysis oxidation course is exactly the region within silica tube periphery about 20 cm distance, in other words, region within silica tube periphery about 20 cm distance really needs enriched with oxygen atmosphere to supply the region ensured, this region oxygen atmosphere supply is stronger, oxidizing reaction is also just carried out faster, especially especially, electrodeless ultraviolet emission is produced in microwave excitation mode, its feature can accomplish high-power, high strength exactly, this is the strong point of this lamp-type of electrodeless ultraviolet lamp, but, just because of the superpower of its uv-radiation, high strength, mate with powerful oxygen atmosphere supply capacity with regard to more needing, otherwise, that powerful uv-radiation ability is really just that major part has been wasted.Address above, as CN102260003A the scheme of showing, factors limits its reactor size, limit its actual treatment capacity, what clearly illustrate that in its specific embodiment is such, that can only be the little reactor that a single tank single treatment amount only has about 40 liters, at so little reactor, when little inner chamber, because size is inherently very little, so, it is oxidized the shortcoming in effective area oxygen supply concentration degree in photochemical catalysis, would not be so obvious, even negligible, a not Problems existing can be regarded more even completely as, in the face of such undersized little reactor, shortcoming problem in oxygen supply concentration degree, not mind may be floated, but, imagine, if described many limiting factors can be overcome, if way actual implementation one can be had large-scale, the reactor of high throughput, within so above-mentioned silica tube periphery 20 cm distance, effective area oxygen supply strengthening problem will show especially out, especially for the situation using electrodeless ultraviolet lamp as UV source, within above-mentioned silica tube periphery 20 cm distance, effective area oxygen supply strengthening problem is not allowed to despise more, therefore, how among the structure of possible large-scale photo-catalytical oxidation DeR device, strengthen the oxygen supply concentration degree of described effective area, improve the usefulness of wastewater degradation equipment, the problem that individual exactly needs are kept a close watch on, this is problem five.
Problem six:
This CN102260003A scheme pump air into include electrodeless ultraviolet lamp silica tube within, reach the aeration-cooling of electrodeless ultraviolet lamp, the object of cooling, and those flow over the air of silica tube, because being subject to ultraviolet irradiation, some air can change ozone into, therefore, the air flowed out from silica tube is exactly the air containing some ozone certainly, this is transferred to containing ozone-air and is positioned at micro porous aeration head below reactor by the program, and disengage from micro porous aeration head, at these containing in ozone bubbles ascension process from bottom to top, wherein contained ozone can meet with the organic molecule that runs among distance and redox reaction occurs, this redox reaction can consume a part of ozone certainly, this be do not have doubt, but, address above, as CN102260003A the scheme of showing, the many factors that cannot ignore certainly existed limit its reactor size, limit its actual treatment capacity, what clearly illustrate that in its specific embodiment is such, that can only be the little reactor that a single tank single treatment amount only has about 40 liters, at so little reactor, when little inner chamber, because overall dimension is inherently very little, so, it also can only be a very little size that the longitudinal size of its reactor inner chamber or regard as with reckoning in every item contains the liquid degree of depth, this size as among its embodiment clearly illustrate that, only have about 40 centimetres, the Sheng that the reckons in every item liquid degree of depth also just only has 40 centimetres, in fact contain the liquid degree of depth and be certainly less than this number, just analyze with the Sheng liquid degree of depth of 40 centimetres, so, does is this Sheng liquid degree of depth of 40 centimetres what concept? that is to say, short 40 centimetres are only had by the path of waste water containing ozone-air ascension, this path is too short, pass through at a gallop containing ozone-air bubble and only only have 40 centimetres of dark water bodys, too short for duration of contact with water body, ozone contained in bubble, a very little part can only be had to be used to oxidative degradation organism, and most ozone in fact just passes by liquid simply, from liquid level effusion and emptying through exhaust port, briefly, the oxygenizement potentiality major part of these ozone has been wasted, and, effusion, in fact the ozone be wasted can cause unnecessary atmospheric pollution, this case main inventive people once squeezed into containing ozone-air via micro porous aeration head with normal domestic use ozone machine in one meter of dark tank, when the depth of water degree of depth reaches one meter, still near the water surface, obviously can smell the smell of ozone, visible, that 40 centimetres of dark Sheng liquid degree of depth are obviously be not enough to utilize ozone completely, visible, for the such equipment of electrodeless ultraviolet light chemical catalysis wastewater degradation reactor, ozone utilizes incomplete problem also to need to pay close attention to, obviously, people are more it is contemplated that ozone utilizes more completely, contaminative exhaust emissions is less without extreme ultraviolet wastewater degradation reactor, and this is problem six.
Problem seven:
Its running of waste water catalytic degradation reaction device, requires the expenditure of energy, and therefore, operator are bound to wish, when wastewater degradation reaction proceeds to terminal, can impartially, prematurely immediately stop continuing Implantation Energy to inside reactor only lately; If stop the moment of Implantation Energy too early, then wastewater degradation is incomplete; And if reach reaction end already, but still unceasingly to inside reactor Implantation Energy, that is certainly at the valuable energy of waste.Its structure of CN102260003A scheme as this case technical background can not provide any instant information to the wastewater degradation reaction end moment, so, just can only estimate by experience the terminal that wastewater degradation reacts; And estimate by experience the terminal that wastewater degradation reacts, that obviously can not be satisfactory; So, how to make neither also undelayed instant information output in advance for the wastewater degradation reaction end moment, and immediately close the energy input to reactor in the just right moment, a technical threshold that can not despise exactly, this is problem seven.
Problem eight:
Accept the described trade effluent of microwave and photo catalysis degradation treatment, wherein be mingled with the material that some originate from the metal particle and carbon granules and so on of mechanical system abrasion process unavoidably, even if quantity is small, its existence is almost difficult to avoid, the disclosure number is that the described organic membrane separation assemblies in the Chinese patent application case of CN102260003A is installed in microwave and photo catalysis reaction zone, being installed in wherein does not stop microwave certainly for intercepting ultraviolet dividing plate between silica tube and membrane separation assemblies, so, the practical function region of microwave must cover the installation area of organic membrane separation assemblies institute described in the program, based on the working mechanism of membrane separation assemblies, the particulate of metal particle as above and carbon granules and so on its be difficult to avoid in the accumulation process on the organic top layer of membrane separation assemblies, and the particulate of metal particle and carbon granules and so on described in this type of, the good absorption medium of microwave energy exactly, absorb the particulate of the described metal particle and carbon granules and so on of the accumulation state of microwave energy, nature can to the top layer of the organic membrane separation assemblies that it is close to produce based on heat penetration erosion mechanism continue pierce destruction, as mentioned above, because the structures shape of this its device of CN102260003A application case can only select polyvinylidene fluoride film material, this polyvinylidene fluoride film material heatproof about 140 degrees Celsius, really higher than general film material heatproof many, but, the heat penetration erosion effect that its point-like of particulate absorbing the described metal particle and carbon granules and so on of the accumulation state of microwave energy pierces formula very easily breaks through the heatproof temperature limit of this polyvinylidene fluoride film material, for above-mentioned reasons, well imagine, pvdf membrane material in this its device of CN102260003A application case will be significantly less than expected desirable work-ing life its actual service life, the structure of this its device of CN102260003A application case, determine under this structural framing, the heat penetration erosion destruction problem that above-mentioned point-like pierces formula cannot be avoided, therefore, how to get around the heat penetration erosion destruction problem that this point-like pierces formula, also need to consider, this is problem eight.
Problem nine:
The disclosure number is the Chinese patent application case of CN102260003A, open text text the 0008th section of word of its specification sheets and claim Section 2, for the catalyst particle size scope that its device can be suitable for, have a restriction, this particle size range is defined as 20 nanometers to 100 micron.We know, under some pH value regulates not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles is easily reunited, and then affects its effective working interface area, affects its photochemical catalysis usefulness; Especially for the section of the relatively small particle size of those among this particle size range, easily occur especially because of pH value presetting not in place, pH value is incorrect and the agglomeration traits that causes; For the situation that this catalyst particles is reunited, be immediately to adopt an effective measure, the depolymerization carried out for coacervate operates; But we are among this CN102260003A scheme, do not see any structure contributing to immediately dissolving this problem or can immediately dissolve this problem scheme prompting.Can only be the reactor of small scale structures just like that because factors restriction for such as CN102260003A scheme, still manually directly can mention reactor, carry out toppling over and inspect in reactor outside, process above-mentioned reunion situation, so, if likely expand its capacity, just so to say, if be the several cubes of large-scale reactors to dozens of cube or huge reactor, that is not obviously topple over it by hand to operate the problem that can tackle, so, for the situation that this catalyst particles is reunited mutually, how to realize instant original position to dispose, it is exactly a technical problem, this is problem nine.
Problem ten:
In the apparatus structure of the disclosure number expressed by the Chinese patent application case of CN102260003A, for shielding the silica tube protecting electrodeless ultraviolet lamp, its outer wall, refer to the outer wall of silica tube, through for a long time with the contact of processed trade effluent, unavoidably incrustation gradually, the long-pending material of dirt certainly mainly not easily the mineral-type impurity that touches by light-catalyzed reaction, because of the incrustation phenomenon that this mechanism is formed, be easy to be observed after equipment long-play; Be attached to the dirty lamination of described silica tube outer wall, although just very thin one deck, be also enough to cause significant stop to the ultraviolet radiation of electrodeless ultraviolet lamp, this significantly reduces causing the actual treatment effect of this microwave and photo catalysis reaction treating device; The bubble of dispersed ascension in its reactor is because too disperseing, wash away strength more weak, if only rely on this bubble comparing dispersion to maintain the bright and clean of silica tube surface, really undertake to do what is apparently beyond one's ability, in other words, this compares the bubble of dispersion, and what it was more weak washes away the incrustation process that strength is still not enough to stop completely this silica tube surface; In the use procedure of laboratory yardstick, above-mentioned fouling problem is subtle, but on industrial application yardstick, this fouling problem certainly will highlight; Therefore, how under the prerequisite of not tearing machine open, immediately, effectively remove the dirty lamination on this silica tube outer wall, maintain the high-level efficiency continued of this microwave and photo catalysis treatment unit, this problem is also very important, and this is problem ten.
11 of problem:
This problem for address above nine of problem its problem that derives.Speak of above, under some pH value regulates not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles is easily reunited, and then affects its effective working interface area, affects its photochemical catalysis usefulness; The section of those the relatively small particle size among its suitable catalyst particle size range of especially this CN102260003A scheme being touched upon, easily occur especially because of pH value presetting not in place, pH value is incorrect and the agglomeration traits that causes; For the situation that this catalyst particles is reunited, be immediately to adopt an effective measure, the depolymerization carried out for coacervate operates; Based on this its framework of CN102260003A scheme, operator cannot perceive the situation that described reunion occurs inside reactor immediately, thus also cannot make instant disposal, thus, can only should be that its limited usefulness of reactor of small scale structures can reduce further by factors restriction; Therefore, among the application running of reactor, particularly, for example, among the application running of possible large-scale reactor or huge reactor, the how immediately awareness inside reactor catalyst particles main inducing parameter of reuniting, be a key issue, this is 11 of problem.
12 of problem:
Based on this its framework of CN102260003A scheme, due to the restriction of factors addressed, its reactor can only be the smaller reactor of undersized treatment capacity, the useful size of reactor inner chamber is certainly also smaller, can be used among its structure of reactor inner chamber settling the spatial altitude of curtain type film assembly approximately also just at 30 cm, so, even if just adopt the curtain type film assembly of very small breadth, also almost plug can only be headed on inside reactor in two up and down, due to the little treatment capacity of reactor, small size, so, after its DeR completes, under the situation getting rid of liquid from inside to outside, its curtain type film assembly exposes in atmosphere unavoidably, although each time exposed can not length, but, the accumulation result often bought and sold, this curtain type film assembly is made to contact with air too much exactly, its normal service requirements of curtain type film assembly, will use under complete submerged state, that is, must be that hygrometric state uses, if curtain type film assembly contacts with air too much, it can be made more aging than more quickly, Performance comparision is decayed rapidly, and the situation that this curtain type film assembly contacts with air too much, under this its framework of CN102260003A scheme, cannot avoid, therefore, how protecting the membrane module for tackling catalyzer, can use in normal conditions, the too much contact with air can be avoided, to safeguard its normal usage energy, guarantee its normal service life, the problem faced of needs exactly, this is 12 of problem.
13 of problem:
Based on this its framework of CN102260003A scheme, among its running, by the granules of catalyst that curtain type film assembly is tackled, a part is at curtain type film assembly surface deposition, and another part is then trapped among liquid object phase, and in causing liquid object mutually thus, granules of catalyst concentration progressively raises along with the progressively reduction of liquid phase volume, this is for follow-up membrane sepn, its membrane sepn load also can raise thereupon gradually, and the problem that before and after this membrane sepn load, difference is excessive needs to solve, and this is 13 of problem.
14 of problem:
Based on this its framework of CN102260003A scheme, among its running, to the water pump of reactor inner chamber filling waste water, itself cannot differentiate inside reactor water level height, operator can only rely on experience or range estimation to close the pump motor of this filling waste water in time, if experience error or range estimation respond not prompt enough, be easy to the situation occurring overflowing reactor because waste water filling is excessive, cause unnecessary trouble thus; On the other hand, after DeR terminates, need by inside via curtain type film assembly to extracardiac pumping, failing to know under the situation of inside reactor water level, completely rule of thumb or can only estimate and judge the opportunity of closing down water pump, and operate like this, obviously unreliable, very easily because experience error or range estimation respond not in time, cause this to draw water cannot to shut down in time with water pump, and this dry tap, idle running be easy to cause this pump motor that draws water to burn, this problem can not be out in the cold, and this is 14 of problem.
15 of problem:
Based on this its framework of CN102260003A scheme, electrodeless ultraviolet lamp be placed in silica tube tube chamber within, in order to ensure the normal luminous work of this electrodeless ultraviolet lamp, its inwall of this silica tube must keep clean with the transparent performance maintained UV-light, and, based on the requirement of similar light penetrability aspect, himself lamp wall outer side of involved electrodeless ultraviolet lamp also must keep clean; But this its framework of CN102260003A scheme is difficult to avoid this quartz tube cavity region that gushing water problem occurs; Gushing water alleged by this case, refers to water in reactor not by treating that insight protrudes into the lumen area of this silica tube; The reason of this gushing water situation is caused to have following so two haply: first quartz tube cavity regional air expands with heat and contract with cold and causes quartz tube cavity region under-voltage, it two is that quartz tube cavity regional air is escaped and to cause quartz tube cavity region under-voltage, so, under the promotion of the relative positive pressure of water body around, water in reactor progressively charges into the lumen area of this silica tube, forms gushing water situation; In pneumatic pump power-off and silica tube outer side part is submerged by water or large portion is submerged by water, especially easily there is described gushing water situation; Specifically, this gushing water problem the most incidental period, be following two periods, first period annotates when pending waste water and pneumatic pump not yet start in reactor, and second period is when after pneumatic pump cuts out, water purification extraction procedure not yet completes; When described gushing water situation occurs, the water being mingled with many inorganic impurities charging into this quartz tube cavity is easy to pollute himself lamp wall outer side of this quartz tube cavity inwall and electrodeless ultraviolet lamp, its uv transmittance of relevant translucent construction position is caused significantly to reduce, and then the overall wastewater light degradation treatment efficiency of the relevant wastewater degradation reactor of impact, therefore, this gushing water problem should not be avoided, and this is 15 of problem.
Summary of the invention
Technical problem to be solved by this invention is, with CN102260003A scheme for technical background, for one of this technical background scheme addressed problem existing for it, two, three, four, five, six, seven, eight, nine, ten, 11,12,13,14,15, research and develop a kind of novel method that can solve this series of problems above totally.
The present invention is solve the technical problem by following scheme, the program provides a kind of photocatalytic waste water degradation reactor expansion method improving catalyst interception again, the key step of the method is as follows: a, by the microwave constrainer of the caged of metal material, the electrodeless ultraviolet lamp being positioned at silica tube is contained, electrodeless ultraviolet lamp is made to be in the inside of the microwave constrainer of this caged, the locations of structures of its entirety of microwave constrainer of this caged is also in the inside of described silica tube, this silica tube is isolated for gas-liquid thing, play the component of sequestering action, this silica tube is positioned at the inside of reactor, the microwave constrainer of this caged is a cage type hardware, hole or mesh is a mass of in the microwave constrainer self structure of this caged, the microwave constrainer of this caged is exactly a metal cage, the function of the microwave constrainer of this caged is by the constraint of microwave exposure spatial domain therein, the weak irradiation spatial domain of microwave or microwave zero irradiation spatial domain is built by this between the outer wall and the inwall of reactor of the microwave constrainer of caged, b, probes into the waveguide being derived from magnetron in described silica tube, and the inner chamber probeing into that one end of silica tube and the microwave constrainer of described caged of this waveguide is carried out UNICOM, and described UNICOM refers to connection in microwave channel meaning and through, c, the size in three-dimensional extends, the expands weak irradiation spatial domain of microwave or microwave zero irradiation spatial domain described in inside reactor, d, the many micro porous aeration heads interspersing among reactor inner chamber lower region are gathered and sets up into cluster-shaped micro porous aeration head cluster, and this cluster-shaped micro porous aeration head cluster is erected at reactor inner chamber lower region vacantly, the fore-and-aft distance of this its bottom edge of cluster-shaped micro porous aeration head cluster and reactor inner chamber bottom surface controls between 10 centimetres and 50 centimetres, the transverse distance of this cluster-shaped micro porous aeration head cluster edge and reactor intracavity sidewall arround it controls between 20 centimetres and 300 centimetres, and control this cluster-shaped micro porous aeration head Shi Qi center or center of gravity is positioned immediately below described silica tube, e, at the outside of reactor erection topping-up pump, this topping-up pump is mixed with the water after the DeR of catalyzer suspension grain for supercharging pumping, and is connected with the inner chamber of reactor by the feed-water end of this topping-up pump, f, connects the water-in of preposition to the water side of described topping-up pump and back flush type prefilter, and the filter opening aperture of the preposition prefilter of this back flush type is between 5 microns and 300 microns, g, connected via the water-in of first water purifying valve with back flush type tubular fibre membrane microfiltration strainer by the pure water inlet of preposition for described back flush type prefilter, the filter opening aperture of this back flush type tubular fibre membrane microfiltration strainer is between 25 nanometers and 1000 nanometers, h, connected via the water-in of second water purifying valve with back flush type hollow-fibre membrane ultra filtration filter by the pure water inlet of described back flush type tubular fibre membrane microfiltration strainer, the filter opening aperture of this back flush type hollow-fibre membrane ultra filtration filter is between 15 nanometers and 2 nanometers, i, connects the sewage outlet of preposition for described back flush type prefilter via the inner chamber of first sewage valve with catalyst underflow transition tank, j, connects the sewage outlet of described back flush type tubular fibre membrane microfiltration strainer via the inner chamber of second sewage valve with catalyst underflow transition tank, k, connects the sewage outlet of back flush type hollow-fibre membrane ultra filtration filter with the inner chamber of catalyst underflow transition tank via the 3rd sewage valve, l, at reactor tail gas discharge outlet position erection ozone sensor, m, shifts near reactor tail gas discharge outlet or stretches into the inside of reactor tail gas discharge outlet by the stopple coupon of this ozone sensor, n, connects its ozone induced electricity signal output circuit of this ozone sensor with the composite structure of ozone attention device with ozone content indicating meter, ozone attention device or ozone content indicating meter, o, connected with power-supply controller of electric by its ozone induced electricity signal output circuit of this ozone sensor, this power-supply controller of electric is the power-supply controller of electric that the described electric signal that can receive according to it carries out power switch action, p, is connected this power-supply controller of electric with magnetron by cable, q, is connected this power-supply controller of electric with pneumatic pump by another cable, r, mould this reactor inner chamber bottom surface and make it present by the periphery pattern hollow gradually to central zone, described its gradient hollow is between 5 degree and 35 degree, s, ultrasonic transducer is installed in the outer side position of the part reactor diapire corresponding to this its hollow innermost, reactor inner chamber bottom surface or medial surface position, t, is connected this ultrasonic transducer with HF oscillation electric signal producer by HF oscillation electric signal transmission cable, u, stretches into reactor inner chamber by pH probe through the top of reactor, and with the micropore stainless steel sleeve of the cap for brush shape made through powder metallurgical technique, this pH its part extending into reactor inner chamber of popping one's head in is carried out to suit and gone along with sb. to guard him, v, connects this pH probe with pH analyser, w, connects this pH analyser with warning horn, and this warning horn is for giving the alarm to the pH value situation of transfiniting, x, wedges the buffering isolating pad of viton or silicon rubber material in the junction between micropore stainless steel sleeve its opening end and reactor head of this cap for brush shape, y, two pairs of dry-reed type ball float level controllers are extend into the inner chamber of reactor through the top of reactor, a pair dry-reed type ball float level controller is wherein connected with its power cable of water pump to reactor luminal perfusion waste water by a rly., wherein another is connected with its power cable of described topping-up pump by another rly. dry-reed type ball float level controller, z, catalyst underflow refluxing opening is dug in this its intracavity bottom position of catalyst underflow transition tank, also this catalyst underflow refluxing opening is connected with the inner chamber of reactor through catalyst underflow reverse flow valve via pipeline, this catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control, this catalyst underflow transition tank is the tank body of a hollow, this catalyst underflow transition tank is used for temporarily depositing the higher water body of catalyst concentration that its backwashing procedures of described strainer discharges, the mounting height of this catalyst underflow transition tank bottom it is on its overhead height of this reactor, aa, connecting in gas circuit between this pneumatic pump with this quartz tube cavity accesses a Miniature diaphragm pump with bypass mode, its power of this Miniature diaphragm pump is between 5 watts and 50 watts, its air outlet operating pressure of this Miniature diaphragm pump is between 1 meter water column and 5 meter water columns, and its air output of this Miniature diaphragm pump is between per minute 1 liter and per minute 80 liters.
Described catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control; The opening-closing valve of commercially available various fluid lines, can be applicable to the needs of this locations of structures, and its concrete type selecting can determine as required.
Described dry-reed type ball float level controller, the art-recognized meanings of itself is known for the professional of fluid level controller manufacturing; Described dry-reed type ball float level controller is commercially available.
Described rly. is commercially available.
Valve body on all fluid passages of this case, can choice for use magnetic valve, when choice for use magnetic valve, being arranged on a control panel, so, can realizing long-distance centralized control easily by being concentrated by long-range cable.
Involved pH probe is commercially available; Described pH probe is also known as pH sensor; PH probe or to say itself art-recognized meanings of pH sensor be known.
Involved pH analyser is commercially available; Itself art-recognized meanings of pH analyser is known.PH can be utilized to detect, picking up, showing pH value information of any model made a general reference in this case pH analyser one word, and externally can export pH and to be correlated with the instrument of electric signal, market is sold simple and easy or complicated but all meet the pH correlate meter of this basic demand it is various in style, can select as required.
Involved its thickness of buffering isolating pad is not limit; But have a preferable range, the preferable range of this its thickness of buffering isolating pad is between 1 millimeter to 8 millimeters.
Involved viton and their art-recognized meanings of involved silicon rubber own are known; Involved viton and involved silicon rubber, market is all on sale.
Involved its wall thickness of micropore stainless steel sleeve is not limit; But also have the preferable range that associated, the preferable range of this its wall thickness of micropore stainless steel sleeve is between 3 millimeters to 30 millimeters.
An involved powder sintered word, the art-recognized meanings of itself, for the professional of metallurgical technology field, is known.
Involved micropore stainless steel sleeve, can to the customization of relevant powder metallurgy specialized factory.
Sleeve-shaped micropore Stainless Steel Filter conversion powder sintering process can made is the micropore stainless steel sleeve described in this case; The sleeve-shaped micropore Stainless Steel Filter that described powder sintering process is made is commercially available.
The aperture of involved its micropore of micropore stainless steel sleeve is not limit; But the aperture of this micropore is also have a preferable range, the preferable range of this micropore size is between 0.5 micron to 50 microns.
Described warning horn can send the device that audio frequency warns message or optical frequency warning message by the electric signal received by it; Itself art-recognized meanings of described warning horn is known; Described warning horn is commercially available.
Itself art-recognized meanings of ultrasonic transducer one word is known for the professional in ultrasonic technology field.
Itself art-recognized meanings of HF oscillation electric signal transmission cable one word is also known for the professional in ultrasonic technology field.
Ultrasonic transducer and HF oscillation electric signal transmission cable market all on sale; Described ultrasonic transducer and HF oscillation electric signal transmission cable etc. also can to ultrasonic transducer specialized factory and the customizations of cable specialized factory.
Itself art-recognized meanings of HF oscillation electric signal producer one word is also known for the professional in ultrasonic technology field; Various HF oscillation electric signal producer all has commercially available; Described HF oscillation electric signal producer also can customize to ultrasonic wave equipment specialized factory.
Involved ozone sensor is commercially available; Also can customize to ozone sensor specialized factory as required.
Involved ozone content monitor market is on sale; Also can customize to ozone content indicating meter specialized factory as required; Ozone sensor producer also sells matching used ozone content indicating meter usually.
Involved ozone attention device, refers to warn the mechanism for warning had both at the same time both sound or alarm flashing or warning sound combines with alarm flashing; Ozone attention device is commercially available; Also can customize to ozone attention device specialized factory; Matching used ozone attention device also can be sold usually by ozone sensor producer.
This power-supply controller of electric involved is the power-supply controller of electric that the described electric signal that can receive according to it carries out power switch action; The electric signal that can receive according to it carries out the power-supply controller of electric of power switch action only with regard to its circuit engineering itself, is ripe, known technology; Described power-supply controller of electric is commercially available; Also commercially available power-supply controller of electric can be utilized to change a social system as required; Described power-supply controller of electric also can customize to power-supply controller of electric specialised manufacturers; Its specialised manufacturers of the electron device of power-supply controller of electric and so on spreads all over the world.
Described in this case, spatial domain one word refers to space, territory, boundary.
Its material of microwave constrainer of this caged involved can be any selected metal, but, in view of the ozone gas mixture environment formed by strong ultraviolet radiation residing for it, and, for exporting considering of the UV-light of being launched by electrodeless ultraviolet lamp to greatest extent by complicated specular reflection mechanism as much as possible, the preferred metal material being suitable for the microwave constrainer making this caged is through the stainless steel of mirror polish process; And the preferable range of its hole of microwave constrainer of the caged through mirror polish process of this stainless steel or the bore of mesh is between 0.5 centimetre and 3.0 centimetres; But if must select the described bore outside this preferable range, that is also that this case allows; Even so, the described bore of use more than 3.0 centimetres is not advised.
The microwave constrainer of this caged can be made with bright finished Stainless Steel Wire braiding.
Certainly, also described microwave constrainer can be made with bright finished punching stainless steel plate through mold pressing, welding or splicing process.
Can be take distance selected arbitrarily between its outer wall of microwave constrainer of this caged and described silica tube inwall, but, its preferred form is, its outer wall of microwave constrainer of this caged and described silica tube inwall are mutually close to or mutual spacing is less than 5.0 centimetres.
Further preferred form is that its outer wall of microwave constrainer of this caged and described silica tube inwall are close to mutually.
Described topping-up pump is the machinery for supercharging pumping liquid, and certainly, its pumping pressure can come to select arbitrarily as required, and various topping-up pump market is all on sale.
Described water purifying valve, sewage valve are all water valves, and various water valve market is all on sale; About water valve, itself art-recognized meanings of this word is known; This case adopts different titles, just conveniently states, conveniently distinguishes the water valve of each different structure position.
The preposition prefilter of described back flush type also claims back flush type fore filter or back flush type prefilter, and itself art-recognized meanings of the preposition prefilter of described back flush type is known; The preposition prefilter of described back flush type is commercially available.
Described back flush type tubular fibre membrane microfiltration strainer is the strainer being suitable for micro-filtration; Itself art-recognized meanings of described micro-filtration one word is known; Itself art-recognized meanings of described back flush type tubular fibre membrane microfiltration strainer, for the professional of technical field of membrane separation, is known; Described back flush type tubular fibre membrane microfiltration strainer is commercially available.
Described back flush type hollow-fibre membrane ultra filtration filter is the strainer being suitable for ultrafiltration; Itself art-recognized meanings of described ultrafiltration one word is known; Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter, for the professional of technical field of membrane separation, is known; Described back flush type hollow-fibre membrane ultra filtration filter is commercially available.
Described back flush type hollow-fibre membrane ultra filtration filter can be the form only having a back flush type hollow-fibre membrane ultra filtration filter monomer; Certainly, this back flush type hollow-fibre membrane ultra filtration filter also can be made up of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.
Express an involved word in parallel, the art-recognized meanings itself referred to is clearly.
Express involved monomer one word, refer to itself function and structure equipment individuality completely.
Similarly, described back flush type tubular fibre membrane microfiltration strainer can be the form only having a back flush type tubular fibre membrane microfiltration strainer monomer; Certainly, this back flush type tubular fibre membrane microfiltration strainer also can be made up of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.
The method can also comprise the following steps: on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration its pure water inlet of strainer and described back flush type hollow-fibre membrane ultra filtration filter, be connected in series into second topping-up pump, this second topping-up pump is for augmenting hydraulic pressure to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter; This step is optional.
This case method can further include some other steps, other step described such as: the anchor being used for fixing electrodeless ultraviolet lamp in the erection of the inside of microwave constrainer; Other step described also such as, installs the anchor being used for fixing microwave constrainer in silica tube; Other step described more such as, progressively regulates microwave exposure power, makes its power reach a desired value, work in optimum regime to enable electrodeless ultraviolet lamp; Other step described more such as, progressively regulates the air flux flowing through silica tube inner chamber, is in a suitable warm area constantly to enable its working temperature of the electrodeless ultraviolet lamp under working order; Other step described is more such as: the strainer being used for impurity screening in reactor waste water input terminus serial connection, in order to avoid impurity particle enters reactor inner chamber; Other step described is more such as: at reactor waste water input front end serial connection settling tank, for the impurity that sediment fraction is precipitable; Other step described is more such as: at reactor waste water input front end serial connection waste water pH value equalizing tank, reaching equipment to make the waste water pH value of input reactor needs level; Other step described is more such as: remove the lift pump for connecting with built-in membrane separation assemblies that reactor is external, this step is for background technology scheme; Etc..
Advantage of the present invention is, by the microwave constrainer of the caged of metal material, electrodeless ultraviolet lamp is wrapped among its inner chamber, and by its inner chamber of microwave constrainer of this caged and the waveguide UNICOM being derived from magnetron, the locations of structures of its entirety of microwave constrainer of this caged is also in the inside of described silica tube, this silica tube is isolated for gas-liquid thing, play the component of sequestering action, this silica tube is positioned at the inside of reactor, by this step, the microwave come via waveguide transmissions is constrained within its effective workspace, contain the unhelpful dissipation of microwave to periphery waste water water body, and between microwave constrainer outer wall and reactor wall, build the weak irradiation spatial domain of microwave or microwave zero irradiation spatial domain, the step of this case method also comprises: the size in extend on three-dimensional, the expand weak irradiation spatial domain of microwave or microwave zero irradiation spatial domain described in inside reactor, by this step, significantly can expand the design volume of reactor, allow reactor list tank wastewater treatment capacity significantly to promote, and need not worry that microwave energy dissipates too much in unhelpful waste water water body temperature-rise effect again.
When adopting bright finished Stainless Steel Wire cylinder mould as microwave constrainer, and, when adopting punching stainless steel plate to make microwave constrainer through mold pressing, welding or splicing process, via the specular reflection mechanism of complexity, to greatest extent the UV-light from electrodeless ultraviolet lamp can be transferred out, and make up himself entity of described metal cage to greatest extent and light is blocked, absorbs caused loss.
Rely on this case method, design volume and single tank wastewater treatment capacity of this wastewater degradation reactor can be expanded to several cubes to dozens of cube; The volume that even single tank is hundreds of cubes is also allow; Based on this case the method, the frequency of a complete set, the operation of omnidistance wastewater degradation can be reduced significantly, be conducive to the saving of human and material resources.
On the other hand, among this case method, its high-density ascension bubble flow discharged of described cluster-shaped micro porous aeration head cluster, while upwards ascension, and wrapped folder, carry, guided liquid-flow, form a kind of motion being similar to fountain form, in this kind of motion, the high-density bubble flow wrapped folder being derived from described cluster-shaped micro porous aeration head cluster liquid to silica tube region gush and on, and then more intensively impact, by the effective area of the described photochemical catalysis oxidizing reaction of silica tube periphery, by described high-density bubble flow wrapped folder, the liquid stream carried is in impact, after described effective area by silica tube periphery, spread to surrounding by the liquid layer of top area, sink via neighboring area, arrive reactor intracavity bottom region, again through the wrapped folder of its high-density ascension bubble flow discharged of described cluster-shaped micro porous aeration head cluster, carry, continue the motion that it is similar to fountain form, circulation like this endlessly, the liquid circulation campaign of this relative big scale guided, contributes to the homogenizing guaranteeing inside reactor liquid degradation reaction process, and this, for large-scale electrodeless ultraviolet light catalysis DeR device, is necessary.
Its UV source of this case method relies on microwave excited electrodeless ultraviolet lamp, the uv-radiation feature of this lamp-type can accomplish high-power, high strength exactly, but the Effective depth penetration of ultraviolet in liquid water body only has 20 cm, therefore, region within silica tube periphery about 20 cm distance is effective area, and this region is exactly the efficient region of photochemical catalysis oxidative degradation; This case method is to be positioned at the described cluster-shaped micro porous aeration head cluster immediately below silica tube, intensively discharge highdensity ascension bubble flow, make it as fountain intensively towards silica tube periphery photochemical catalysis oxidation effective area release, this method contributes to the oxygen atmosphere supply intensity improving effective area described in silica tube periphery, contributes to accelerating ultraviolet catalyzing oxidizing degrading reaction process.
Based on this case method, the capacity of reactor or treatment capacity can significantly be expanded, describedly significantly to expand, that design volume by significantly expanding microwave zero irradiation zone or the weak irradiation zone of microwave realizes, so, the lateral dimension of reactor, longitudinal size is all significantly to expand certainly, therefore, inside reactor is contained the liquid degree of depth and can be deepened significantly similarly, such as, can deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc., when containing the liquid degree of depth and being enough dark, containing ozone-air bubble ascension path sufficiently long, the time sufficiently long contacted with water body is steeped containing ozone-air, just can with abundant reducing substances fortune in its ascension process, and thoroughly or be close to and exhaust ozone contained in bubble up hill and dale, thus, incomplete problem is utilized to be solved containing ozone composition oxidation potential in ozone-air bubble, and, because long ascension path causes ozone depletion, the ozone that can cause environmental pollution would not be entrained with again in reactor tail gas.
This case method is with external multistage filter, reach the interception step by step counting the collision fragment of the small scale of nanometers from coacervate macrobead to ten to catalyst particles, be close to reclaim up hill and dale, reuse photocatalyst, be close to and take precautions against catalyst loss and the secondary pollution that causes up hill and dale; This is hold-up interception method secondary filter can be protected to make its filtration passage from the rigid obstruction of large particulate matter step by step; Wherein the pre-filtering aperture of the first step is between 5 microns and 300 microns, and its aperture of the micro-filtration of the second stage is between 25 nanometers and 1000 nanometers, and its aperture of the ultrafiltration of the third stage is between 15 nanometers and 2 nanometers; Such hold-up interception method, can fully tackle nano level photocatalyst, and it can be close to certainly tackles the catalyzer that this median size of gas phase titanium dioxide P25 is 21 nanometers up hill and dale; Address above, the gas phase titanium deoxide catalyst of nano level P25 and so on, it is the commercially available catalyzer that can buy in a large number, also be weather resistance, stability, the known excellent photocatalyst of UV-light wave band photocatalysis performance, certainly, it is also in fact pay the utmost attention to the photocatalyst selected in industrial scale applications; This case catalyzer hold-up interception method matches with the virtual rating of catalyzer market supply, actual kind, merges mutually.
And, in this case method, catalyzer interception mechanism is external mechanism, and based on the method, its filter core need not be soaked in the liquid of the Strong oxdiative of inside reactor, strong uv irradiation, therefore, can need not consider the tolerance to uv irradiation, Strong oxdiative condition completely, like this, select just without the restriction in extraordinary tolerance in filter core material, can select in more vast optional material kind, and the material of PVDF costly and so on need not be confined to completely again.
Involved strainer at different levels all has commercially available, commercially available strainers at different levels, the discharge outlet of draining-off sewage when its sewage draining exit is exactly back flushing, this case uses this kind of back flush type to equip, be used to tackle catalyst particles step by step, originally the sewage draining exit of commercially available relevant device, is used delivery port again by recycling delivery port or backflow that conversion is used as by retaining catalyst particles in this case method.
Address above, based on this case method, the capacity of reactor or treatment capacity can significantly be expanded, describedly significantly to expand, that design volume by significantly expanding microwave zero irradiation zone or the weak irradiation zone of microwave realizes, so, from the appearance, the lateral dimension of reactor, longitudinal size is all significantly to expand certainly, therefore, inside reactor is contained the liquid degree of depth and can be deepened significantly similarly, such as, can deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc., when containing the liquid degree of depth and being enough dark, containing ozone-air bubble ascension path sufficiently long, the time sufficiently long contacted with water body is steeped containing ozone-air, just can with abundant reducing substances fortune in its ascension process, and thoroughly or be close to and exhaust ozone contained in bubble up hill and dale, thus, incomplete problem is utilized to be solved containing ozone composition oxidation potential in ozone-air bubble, and, because long ascension path causes ozone depletion, the ozone that can cause environmental pollution would not be entrained with again in reactor tail gas, only when being subject to processing when in water body, reducing substances and organic pollutant are degraded totally, again without can for the organic pollutant of ozone oxidation reaction in water body, those unnecessary ozone just likely no longer consume and to overflow liquid level through long ascension path, speak of above, one among the some problem that this case solves simultaneously, it is the circulation of the relative big scale of enhanced reactor internal liquid, systemic circulation that this enhances mechanism facilitates the uniformity of inside reactor liquid organic pollutants DeR process contained by it, thus, several cubes that allow at its corresponding framework of this case method under the process capacity framework of dozens of cube even hundreds of cube volume, when inside reactor ullage has ozone to overflow, namely show that the DeR of inside reactor reaches terminal, and be the overall uniformity of internal liquid reach the terminal of DeR, this terminal point determining factor is the matching criteria that can provide with this case scheme, this case is at its exhaust port position of reactor installing ozone sensor, ozone is detected in this locations of structures, just mean that inside reactor DeR is reached home, ozone sensor and connecting with the composite structure of ozone content indicating meter with ozone attention device or ozone content indicating meter or ozone attention device, for providing indication information accurately to operator, this case and by ozone sensor export electric signal send power-supply controller of electric to by cable, this power-supply controller of electric is also connected with magnetron and pneumatic pump respectively by cable, the described electric signal of power-supply controller of electric received by it carries out power switch action, certainly, its function mode is, receive the signal of the ozone effusion that ozone sensor sends at power-supply controller of electric when, the power supply of magnetron and pneumatic pump is led in automatic closedown, this case Using such method, can know the terminal of inside reactor DeR process in time, and Using such method, when reaction reaches terminal, automatically close the power supply of magnetron and pneumatic pump, stop to inside reactor Implantation Energy in time, so can avoid unnecessary energy dissipation, and, this case Using such method, when DeR is reached home, the power supply of described magnetron and pneumatic pump can be closed in time, this power-off action is synchronous, the same generation process terminating in a flash ozone also, because ozone generation process is stopped in time, a large amount of ozone exceeding needs would not be had to disengage from described exhaust port, thus avoid unnecessary secondary pollution or say secondary pollution, this case method determines the ozone that the framework corresponding to it does not have more than needed can for discharge.
Rely on this case method, the microwave exposure spatial domain of inside reactor is subject to forcing to cut off, limit, this case and adopt external cascading multiple stages backwash filter to carry out the meticulous interception for catalyst particles, among this method, back flush type hollow fiber microfiltration membrane assembly and back flush type polysulfone hollow fiber ultrafiltration membrane system are all by external and away from reactor core, microwave can not be irradiated to described membrane module completely, based on this case the method, got around the heat penetration erosion destruction problem that described point-like pierces formula completely, this problem is settled properly thus.
This case method moulds reactor inner chamber bottom surface makes it hollow gradually to central zone by periphery, and described its gradient hollow is between 5 degree and 35 degree, this case method also installs ultrasonic transducer on the outer side position or medial surface position of the part reactor diapire corresponding to described its innermost hollow, address above, this case method and be beneficial to the cyclic motion that driving a reaction device internal liquid makes relative big scale, the mode of this liquid circulation campaign is that peripheral liquid sinks, and middle liquid rises, and so constantly moves in circles, address above, under some pH value regulates not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles is easily reunited, and then affects its effective working interface area, affects its photochemical catalysis usefulness, especially for the section of the relatively small particle size of those among this particle size range, easily occur especially because of pH value presetting not in place, pH value is incorrect and the agglomeration traits that causes, for the situation that this catalyst particles is reunited, be immediately to adopt an effective measure, the depolymerization carried out for coacervate operates, when catalyst particles generation serious agglomeration, some heavier macro aggregates are wherein due to action of gravity, tend to gradually to the sedimentation of reactor intracavity bottom, this case method moulds reactor inner chamber bottom surface makes it be hollow pattern, and, its enforcement of this case method can make the cyclic motion of described relative big scale by driving a reaction device internal liquid, the effect of this systemic circulation campaign is together with the effect of ubiquitous natural gravity, the macro aggregate of sedimentation can be pushed away along the slope, bottom surface of described hollow pattern and sweep to hollow innermost and make them be gathered in there, the ultrasonic transducer that this case method is installed is positioned at this hollow innermost position just, this hollow innermost region, it is the region that described macro aggregate is finally assembled, also be that ultrasonic wave can be damply minimum simultaneously, closest range ground, the most consumingly, depolymerization operating area is carried out most effectively for macro aggregate, this case the method can allow with minimum ultrasonic energy loss, realizes maximized ultrasonic depolymerization effect, this case Using such method, can converge coacervate sediment, and in the most concentrated region of coacervate sediment, implements depolymerization running, based on the method, the ultrasonic wave being derived from reactor bottom also can be radiated other region in inside reactor liquid of course simultaneously, and the coacervate that be still in suspended state smaller to those plays unzipping, its running of this case associated ultrasonic Splitting by radiation is the running that can start as required or close, the instant original position that this case method achieves for catalyst particles aggregate is disposed.
For shielding the silica tube protecting electrodeless ultraviolet lamp in photocatalytic degradation reactor, its outer wall, refer to the outer wall of silica tube, through the long contact with processed trade effluent, unavoidable incrustation gradually, the long-pending material of dirt certainly mainly not easily the mineral-type impurity that touches by light-catalyzed reaction, because of the incrustation phenomenon of this mechanism formation, be easy to be observed after equipment long-play; Be attached to the dirty lamination of described silica tube outer wall, although just very thin one deck, be also enough to cause significant stop to the ultraviolet radiation of electrodeless ultraviolet lamp, this significantly reduces causing the actual treatment effect of this microwave and photo catalysis reaction treating device; Its step of this case method is included in the step that reactor bottom installs ultrasonic transducer, this ultrasonic transducer is among the irregular depolymerization running carried out for accidental catalyst particles serious agglomeration situation, the ultrasonic wave of its radiation, certainly also silica tube position can be arrived, this ultrasonic wave, while carrying out original position depolymerization running, also to carry out the ultrasonic clean scale removal work for the long-pending thing of silica tube surface dirt in the lump; And, this ultrasonic transducer is away from silica tube position, ultrasonic radiation decays when arriving silica tube position to some extent, therefore, ultrasonic impact suffered by silica tube surface is low intensive ultrasonic impact, this low intensive ultrasonic impact can leniently scale removal, can avoid again or significantly weaken its silica tube surface smoothness that may cause of ultrasonic cavitation and lose; Based on this case method, under the prerequisite of not tearing machine open, can immediately, effectively remove the dirty lamination on this silica tube outer wall, this case method contributes to the high-level efficiency continued safeguarding this photocatalytic degradation reactor.
The pH value of wastewater degradation inside reactor water body is the key factor affecting catalyst dispersion stabilization; The pH value display instrument that this case method introduces pH probe and association thereof and the warning horn etc. be associated, based on this, can when pH value exceeds catalyst stably dispersing scope, initiatively give the alarm, based on this case the method, relating operation personnel can the inside reactor of awareness immediately agglomeration be inclined to, and make instant disposal.Micropore stainless steel sleeve involved by this case method is the indispensable important component matched with this case principle and this case method.
In this case method, membrane module is among the operating mode of the use of complete submergence, membrane module is wherein had no chance ingress of air, keep the state of hygrometric state and complete submergence always, therefore, the membrane module easily occurred in that background technology is there will be no often to expose aerial situation, its applying working condition of membrane module in this case method meets itself intrinsic working conditions requirement of membrane module more, be more conducive to safeguard its normal usage energy of membrane module, be more conducive to guarantee its normal service life of membrane module.
This case method is recharged on passage in catalyst underflow and is added a catalyst underflow transition tank link, this catalyst underflow transition tank is used for temporarily depositing the liquid higher containing catalyst concentration washed away from each its backwashing procedures of back flush type strainer, thus avoid liquid higher for this catalyst concentration directly to fill with back reactor, so, avoid the problem that in inside reactor liquid, catalyst concentration progressively raises along with the extraction process of water purification, this extracts to its follow-up water purification and reduce the heavy burdens, there is so catalyst underflow transition tank link, just can after water purification extraction procedure completes, again catalyst underflow is filled with back within reactor.
In this case method, utilize the dry-reed type ball float level controller connected with its power cable of water pump pouring into waste water to reactor through rly. for a pair, avoid excessive filling waste water to reactor inner chamber, avoid waste water to overflow reactor thus; The method utilizes another to the dry-reed type ball float level controller connected with its power cable of described topping-up pump through another rly.; after avoiding the degraded of inside reactor, liquid is excessively extracted and causes this topping-up pump to dally, dryly to turn, and so the described booster motor of protection is in order to avoid it burns.
Any valve body on all fluid channels involved by the method, can choice for use magnetic valve, and these cables can be concentrated and be routed on a panel, the method allows the valve body switch action corresponding to each program of long-distance centralized control.
The method connecting in gas circuit between this pneumatic pump with this quartz tube cavity accesses a Miniature diaphragm pump with bypass mode, its power of this Miniature diaphragm pump is between 5 watts and 50 watts, its air outlet operating pressure of this Miniature diaphragm pump is between 1 meter water column and 5 meter water columns, and its air output of this Miniature diaphragm pump is between per minute 1 liter and per minute 80 liters; Its object, when relatively powerful described pneumatic pump quits work, this Miniature diaphragm pump can start in good time, with relatively much lower power loss, relatively much lower air flow quantity and relatively much lower air outlet operating pressure, resist the quartz tube cavity atmospheric pressure decay because air in quartz tube cavity expands with heat and contract with cold and the reason such as air escape may cause, prevent, check the generation of quartz tube cavity gushing water situation by this; This Miniature diaphragm pump of bypass access, based on the power consumption that it is relatively much lower, in fact it also can be the state being in normal open shop all the time, and this method can stop described quartz tube cavity gushing water.
In brief, the method for this case method by utilizing metal cage to retrain microwave more closely, has reached the target allowing reactor design capacity significantly to expand; Meanwhile, its method also enhances the cyclic motion of the relative big scale of inside reactor liquid; The method also to be set up in its highdensity bubble flow discharged of described cluster-shaped micro porous aeration head cluster immediately below silica tube, realizes the significantly lifting of the oxygen supply concentration degree for emphasis reaction zone; The method and reached for nm-class catalyst particulate from its coacervate macrobead to the collision fragment of ten number nanometers widely, meticulous interception; Based on the method, the selection face of its filter core material also thus expanded; Its DeR endpoint information can be known in time; Automatically the energy input to reactor can be closed when its DeR terminal; When its DeR terminal, also automatically stop the generation process of ozone in time, avoid unnecessary secondary pollution; The method also immediately original position can dispose accidental catalyst particles serious agglomeration situation, also simultaneously incidentally with silica tube surface described in the supersonic cleaning of the low intensive gentleness after the reduction of teletransmission appropriateness, the UV-light transparent performance keeping it excellent; The method also initiatively can detect agglomeration tendency, and gives the alarm when correlation parameter exceeds standard; The method is also conducive to membrane module and uses among complete submergence operating mode; The method and being deposited by the appropriate transition that catalyst underflow transition tank link realizes catalyst underflow, overcomes the problem that before and after membrane sepn load, difference is excessive; The method and can achieve waste water perfusion water level automatic control; The method also when water purification is extracted into restricted water supply position, can close the power supply of described topping-up pump automatically, in time, is beneficial to the protection of booster motor; The method and described quartz tube cavity gushing water can be checked.
This case method solves described series of problems totally.
Embodiment
The enforcement of this case method, key step is as follows:
A, by the microwave constrainer of the caged of metal material, the electrodeless ultraviolet lamp being positioned at silica tube is contained, electrodeless ultraviolet lamp is made to be in the inside of the microwave constrainer of this caged, the locations of structures of its entirety of microwave constrainer of this caged is also in the inside of described silica tube, this silica tube is isolated for gas-liquid thing, play the component of sequestering action, this silica tube is positioned at the inside of reactor, the microwave constrainer of this caged is a cage type hardware, hole or mesh is a mass of in the microwave constrainer self structure of this caged, the microwave constrainer of this caged is exactly a metal cage, the function of the microwave constrainer of this caged is by the constraint of microwave exposure spatial domain therein, the weak irradiation spatial domain of microwave or microwave zero irradiation spatial domain is built by this between the outer wall and the inwall of reactor of the microwave constrainer of caged,
B, probes into the waveguide being derived from magnetron in described silica tube, and the inner chamber probeing into that one end of silica tube and the microwave constrainer of described caged of this waveguide is carried out UNICOM, and described UNICOM refers to connection in microwave channel meaning and through;
C, the size in three-dimensional extends, the expands weak irradiation spatial domain of microwave or microwave zero irradiation spatial domain described in inside reactor;
D, the many micro porous aeration heads interspersing among reactor inner chamber lower region are gathered and sets up into cluster-shaped micro porous aeration head cluster, and this cluster-shaped micro porous aeration head cluster is erected at reactor inner chamber lower region vacantly, the fore-and-aft distance of this its bottom edge of cluster-shaped micro porous aeration head cluster and reactor inner chamber bottom surface controls between 10 centimetres and 50 centimetres, the transverse distance of this cluster-shaped micro porous aeration head cluster edge and reactor intracavity sidewall arround it controls between 20 centimetres and 300 centimetres, and control this cluster-shaped micro porous aeration head Shi Qi center or center of gravity is positioned immediately below described silica tube,
E, at the outside of reactor erection topping-up pump, this topping-up pump is mixed with the water after the DeR of catalyzer suspension grain for supercharging pumping, and is connected with the inner chamber of reactor by the feed-water end of this topping-up pump;
F, connects the water-in of preposition to the water side of described topping-up pump and back flush type prefilter, and the filter opening aperture of the preposition prefilter of this back flush type is between 5 microns and 300 microns;
G, connected via the water-in of first water purifying valve with back flush type tubular fibre membrane microfiltration strainer by the pure water inlet of preposition for described back flush type prefilter, the filter opening aperture of this back flush type tubular fibre membrane microfiltration strainer is between 25 nanometers and 1000 nanometers;
H, connected via the water-in of second water purifying valve with back flush type hollow-fibre membrane ultra filtration filter by the pure water inlet of described back flush type tubular fibre membrane microfiltration strainer, the filter opening aperture of this back flush type hollow-fibre membrane ultra filtration filter is between 15 nanometers and 2 nanometers;
I, connects the sewage outlet of preposition for described back flush type prefilter via the inner chamber of first sewage valve with catalyst underflow transition tank;
J, connects the sewage outlet of described back flush type tubular fibre membrane microfiltration strainer via the inner chamber of second sewage valve with catalyst underflow transition tank;
K, connects the sewage outlet of back flush type hollow-fibre membrane ultra filtration filter with the inner chamber of catalyst underflow transition tank via the 3rd sewage valve;
L, at reactor tail gas discharge outlet position erection ozone sensor;
M, shifts near reactor tail gas discharge outlet or stretches into the inside of reactor tail gas discharge outlet by the stopple coupon of this ozone sensor;
N, connects its ozone induced electricity signal output circuit of this ozone sensor with the composite structure of ozone attention device with ozone content indicating meter, ozone attention device or ozone content indicating meter;
O, connected with power-supply controller of electric by its ozone induced electricity signal output circuit of this ozone sensor, this power-supply controller of electric is the power-supply controller of electric that the described electric signal that can receive according to it carries out power switch action;
P, is connected this power-supply controller of electric with magnetron by cable;
Q, is connected this power-supply controller of electric with pneumatic pump by another cable;
R, mould this reactor inner chamber bottom surface and make it present by the periphery pattern hollow gradually to central zone, described its gradient hollow is between 5 degree and 35 degree;
S, ultrasonic transducer is installed in the outer side position of the part reactor diapire corresponding to this its hollow innermost, reactor inner chamber bottom surface or medial surface position;
T, is connected this ultrasonic transducer with HF oscillation electric signal producer by HF oscillation electric signal transmission cable;
U, stretches into reactor inner chamber by pH probe through the top of reactor, and with the micropore stainless steel sleeve of the cap for brush shape made through powder metallurgical technique, this pH its part extending into reactor inner chamber of popping one's head in is carried out to suit and gone along with sb. to guard him;
V, connects this pH probe with pH analyser;
W, connects this pH analyser with warning horn, and this warning horn is for giving the alarm to the pH value situation of transfiniting;
X, wedges the buffering isolating pad of viton or silicon rubber material in the junction between micropore stainless steel sleeve its opening end and reactor head of this cap for brush shape;
Y, two pairs of dry-reed type ball float level controllers are extend into the inner chamber of reactor through the top of reactor, a pair dry-reed type ball float level controller is wherein connected with its power cable of water pump to reactor luminal perfusion waste water by a rly., wherein another is connected with its power cable of described topping-up pump by another rly. dry-reed type ball float level controller;
Z, catalyst underflow refluxing opening is dug in this its intracavity bottom position of catalyst underflow transition tank, also this catalyst underflow refluxing opening is connected with the inner chamber of reactor through catalyst underflow reverse flow valve via pipeline, this catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control, this catalyst underflow transition tank is the tank body of a hollow, this catalyst underflow transition tank is used for temporarily depositing the higher water body of catalyst concentration that its backwashing procedures of described strainer discharges, the mounting height of this catalyst underflow transition tank bottom it is on its overhead height of this reactor,
Aa, connecting in gas circuit between this pneumatic pump with this quartz tube cavity accesses a Miniature diaphragm pump with bypass mode, its power of this Miniature diaphragm pump is between 5 watts and 50 watts, its air outlet operating pressure of this Miniature diaphragm pump is between 1 meter water column and 5 meter water columns, and its air output of this Miniature diaphragm pump is between per minute 1 liter and per minute 80 liters.
Implement involved Miniature diaphragm pump commercially available.
Described catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control; The opening-closing valve of commercially available various fluid lines, can be applicable to the needs of this locations of structures, and its concrete type selecting can determine as required.
Described dry-reed type ball float level controller, the art-recognized meanings of itself is known for the professional of fluid level controller manufacturing; Described dry-reed type ball float level controller is commercially available.
Described rly. is commercially available.
Valve body on all fluid passages of this case, can choice for use magnetic valve, when choice for use magnetic valve, being arranged on a control panel, so, can realizing long-distance centralized control easily by being concentrated by long-range cable.
Involved pH probe is commercially available; Described pH probe is also known as pH sensor; PH probe or to say itself art-recognized meanings of pH sensor be known.
Involved pH analyser is commercially available; Itself art-recognized meanings of pH analyser is known.PH can be utilized to detect, picking up, showing pH value information of any model made a general reference in this case pH analyser one word, and externally can export pH and to be correlated with the instrument of electric signal, market is sold simple and easy or complicated but all meet the pH correlate meter of this basic demand it is various in style, can select as required.
Involved its thickness of buffering isolating pad is not limit; But have a preferable range, the preferable range of this its thickness of buffering isolating pad is between 1 millimeter to 8 millimeters.
Involved viton and their art-recognized meanings of involved silicon rubber own are known; Involved viton and involved silicon rubber, market is all on sale.
Involved its wall thickness of micropore stainless steel sleeve is not limit; But also have the preferable range that associated, the preferable range of this its wall thickness of micropore stainless steel sleeve is between 3 millimeters to 30 millimeters.
An involved powder sintered word, the art-recognized meanings of itself, for the professional of metallurgical technology field, is known.
Involved micropore stainless steel sleeve, can to the customization of relevant powder metallurgy specialized factory.
Sleeve-shaped micropore Stainless Steel Filter conversion powder sintering process can made is the micropore stainless steel sleeve described in this case; The sleeve-shaped micropore Stainless Steel Filter that described powder sintering process is made is commercially available.
The aperture of involved its micropore of micropore stainless steel sleeve is not limit; But the aperture of this micropore is also have a preferable range, the preferable range of this micropore size is between 0.5 micron to 50 microns.
Described warning horn can send the device that audio frequency warns message or optical frequency warning message by the electric signal received by it; Itself art-recognized meanings of described warning horn is known; Described warning horn is commercially available.
Described its gradient enforcement value hollow is between 5 degree and 35 degree, and any set point value within this gradient scope is all the operable enforcement value that this case allows; This its gradient enforcement value hollow can be such as 5 degree, 8 degree, 10 degree, 15 degree, 20 degree, 25 degree, 30 degree, 35 degree, etc.
Itself art-recognized meanings of ultrasonic transducer one word is known for the professional in ultrasonic technology field.
Itself art-recognized meanings of HF oscillation electric signal transmission cable one word is also known for the professional in ultrasonic technology field.
Ultrasonic transducer and HF oscillation electric signal transmission cable market all on sale; Described ultrasonic transducer and HF oscillation electric signal transmission cable etc. also can to ultrasonic transducer specialized factory and the customizations of cable specialized factory.
Itself art-recognized meanings of HF oscillation electric signal producer one word is also known for the professional in ultrasonic technology field; Various HF oscillation electric signal producer all has commercially available; Described HF oscillation electric signal producer also can customize to ultrasonic wave equipment specialized factory.
Implement involved ozone sensor commercially available; Also can customize to ozone sensor specialized factory as required.
Implement involved ozone content monitor market on sale; Also can customize to ozone content indicating meter specialized factory as required; Ozone sensor producer also sells matching used ozone content indicating meter usually.
Implementing involved ozone attention device, referring to warn the mechanism for warning had both at the same time both sound or alarm flashing or warning sound combines with alarm flashing; Ozone attention device is commercially available; Also can customize to ozone attention device specialized factory; Matching used ozone attention device also can be sold usually by ozone sensor producer.
Implementing this power-supply controller of electric involved is the power-supply controller of electric that the described electric signal that can receive according to it carries out power switch action; The electric signal that can receive according to it carries out the power-supply controller of electric of power switch action only with regard to its circuit engineering itself, is ripe, known technology; Described power-supply controller of electric is commercially available; Also commercially available power-supply controller of electric can be utilized to change a social system as required; Described power-supply controller of electric also can customize to power-supply controller of electric specialised manufacturers; Its specialised manufacturers of the electron device of power-supply controller of electric and so on spreads all over the world.
This case the method with CN102260003A scheme for technical background launch describe; The net result that its series of steps of this case method is formed then has nothing to do with this CN102260003A scheme.
Among its enforcement of this case method, its material of microwave constrainer of this caged involved can be any selected metal, but, in view of the ozone gas mixture environment formed by strong ultraviolet radiation residing for it, and, for exporting considering of the UV-light of being launched by electrodeless ultraviolet lamp to greatest extent by complicated specular reflection mechanism as much as possible, the preferred metal material being suitable for the microwave constrainer making this caged is through the stainless steel of mirror polish process, and, the preferable range of its hole of microwave constrainer of the caged through mirror polish process of this stainless steel or the bore of mesh is between 0.5 centimetre and 3.0 centimetres, any set point value within this scope is all preferred, available enforcement value, can be such as 0.5 centimetre, 0.9 centimetre, 1.75 centimetre, 2.2 centimetre, 3.0 centimetre, etc., but if must select the described bore outside this preferable range, that is also that this case allows, even so, the described bore of use more than 3.0 centimetres is not advised.
Among its enforcement of this case method, the microwave constrainer of this caged can be made with bright finished Stainless Steel Wire braiding.
Certainly, among its enforcement of this case method, also described microwave constrainer can be made with bright finished punching stainless steel plate through mold pressing, welding or splicing process.
Among its enforcement of this case method, can be take distance selected arbitrarily between its outer wall of microwave constrainer of this caged and described silica tube inwall, but its preferred form is, its outer wall of microwave constrainer of this caged and described silica tube inwall are mutually close to or mutual spacing is less than 5.0 centimetres; In other words, any distance value being less than 5.0 centimetres from the state be mutually close to phase mutual edge distance is all the preferred enforcement value that can allow; Further preferred example is that its outer wall of microwave constrainer of this caged and described silica tube inwall are close to mutually.
Its enforcement of the method can also allow to comprise the following steps: on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration its pure water inlet of strainer and described back flush type hollow-fibre membrane ultra filtration filter, be connected in series into second topping-up pump, this second topping-up pump is for augmenting hydraulic pressure to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter; This step is optional.
This case method can further include some other steps, other step described such as: the anchor being used for fixing electrodeless ultraviolet lamp in the erection of the inside of microwave constrainer; Other step described also such as, installs the anchor being used for fixing microwave constrainer in silica tube; Other step described more such as, progressively regulates microwave exposure power, makes its power reach a desired value, work in optimum regime to enable electrodeless ultraviolet lamp; Other step described more such as, progressively regulates the air flux flowing through silica tube inner chamber, is in a suitable warm area constantly to enable its working temperature of the electrodeless ultraviolet lamp under working order; Other step described is more such as: the strainer being used for impurity screening in reactor waste water input terminus serial connection, in order to avoid impurity particle enters reactor inner chamber; Other step described is more such as: at reactor waste water input front end serial connection settling tank, for the impurity that sediment fraction is precipitable; Other step described is more such as: at reactor waste water input front end serial connection waste water pH value equalizing tank, reaching equipment to make the waste water pH value of input reactor needs level; Other step described is more such as: remove the lift pump for connecting with built-in membrane separation assemblies that reactor is external, this step is for background technology scheme; Etc..
Its enforcement of this case method, is not limited to the above step.
From this case visual angle, as the CN102260003A scheme of this case background technology, the water distribution board of its appellation related in this case structure, ripple dividing plate, the component such as built-in membrane separation assemblies and the external lift pump associated with membrane separation assemblies, be all unnecessary component, all need to give removal; Certainly, the housing of its reactor also needs to be torn down, and rebuilds according to this case intention; In other words, if with this CN102260003A scheme for starting point builds, then this case method can also comprise the removal step for described unnecessary component, and, to the step that its reactor shell tears down, and, carry out according to this case intention the details step that reactor shell rebuilds.
Claims (10)
1. improve the photocatalytic waste water degradation reactor expansion method of catalyst interception again, the key step of the method is as follows: a, by the microwave constrainer of the caged of metal material, the electrodeless ultraviolet lamp being positioned at silica tube is contained, electrodeless ultraviolet lamp is made to be in the inside of the microwave constrainer of this caged, the locations of structures of its entirety of microwave constrainer of this caged is also in the inside of described silica tube, this silica tube is isolated for gas-liquid thing, play the component of sequestering action, this silica tube is positioned at the inside of reactor, the microwave constrainer of this caged is a cage type hardware, hole or mesh is a mass of in the microwave constrainer self structure of this caged, the microwave constrainer of this caged is exactly a metal cage, the function of the microwave constrainer of this caged is by the constraint of microwave exposure spatial domain therein, the weak irradiation spatial domain of microwave or microwave zero irradiation spatial domain is built by this between the outer wall and the inwall of reactor of the microwave constrainer of caged, b, probes into the waveguide being derived from magnetron in described silica tube, and the inner chamber probeing into that one end of silica tube and the microwave constrainer of described caged of this waveguide is carried out UNICOM, and described UNICOM refers to connection in microwave channel meaning and through, c, the size in three-dimensional extends, the expands weak irradiation spatial domain of microwave or microwave zero irradiation spatial domain described in inside reactor, d, the many micro porous aeration heads interspersing among reactor inner chamber lower region are gathered and sets up into cluster-shaped micro porous aeration head cluster, and this cluster-shaped micro porous aeration head cluster is erected at reactor inner chamber lower region vacantly, the fore-and-aft distance of this its bottom edge of cluster-shaped micro porous aeration head cluster and reactor inner chamber bottom surface controls between 10 centimetres and 50 centimetres, the transverse distance of this cluster-shaped micro porous aeration head cluster edge and reactor intracavity sidewall arround it controls between 20 centimetres and 300 centimetres, and control this cluster-shaped micro porous aeration head Shi Qi center or center of gravity is positioned immediately below described silica tube, e, at the outside of reactor erection topping-up pump, this topping-up pump is mixed with the water after the DeR of catalyzer suspension grain for supercharging pumping, and is connected with the inner chamber of reactor by the feed-water end of this topping-up pump, f, connects the water-in of preposition to the water side of described topping-up pump and back flush type prefilter, and the filter opening aperture of the preposition prefilter of this back flush type is between 5 microns and 300 microns, g, connected via the water-in of first water purifying valve with back flush type tubular fibre membrane microfiltration strainer by the pure water inlet of preposition for described back flush type prefilter, the filter opening aperture of this back flush type tubular fibre membrane microfiltration strainer is between 25 nanometers and 1000 nanometers, h, connected via the water-in of second water purifying valve with back flush type hollow-fibre membrane ultra filtration filter by the pure water inlet of described back flush type tubular fibre membrane microfiltration strainer, the filter opening aperture of this back flush type hollow-fibre membrane ultra filtration filter is between 15 nanometers and 2 nanometers, i, connects the sewage outlet of preposition for described back flush type prefilter via the inner chamber of first sewage valve with catalyst underflow transition tank, j, connects the sewage outlet of described back flush type tubular fibre membrane microfiltration strainer via the inner chamber of second sewage valve with catalyst underflow transition tank, k, connects the sewage outlet of back flush type hollow-fibre membrane ultra filtration filter with the inner chamber of catalyst underflow transition tank via the 3rd sewage valve, l, at reactor tail gas discharge outlet position erection ozone sensor, m, shifts near reactor tail gas discharge outlet or stretches into the inside of reactor tail gas discharge outlet by the stopple coupon of this ozone sensor, n, connects its ozone induced electricity signal output circuit of this ozone sensor with the composite structure of ozone attention device with ozone content indicating meter, ozone attention device or ozone content indicating meter, o, connected with power-supply controller of electric by its ozone induced electricity signal output circuit of this ozone sensor, this power-supply controller of electric is the power-supply controller of electric that the described electric signal that can receive according to it carries out power switch action, p, is connected this power-supply controller of electric with magnetron by cable, q, is connected this power-supply controller of electric with pneumatic pump by another cable, r, mould this reactor inner chamber bottom surface and make it present by the periphery pattern hollow gradually to central zone, described its gradient hollow is between 5 degree and 35 degree, s, ultrasonic transducer is installed in the outer side position of the part reactor diapire corresponding to this its hollow innermost, reactor inner chamber bottom surface or medial surface position, t, is connected this ultrasonic transducer with HF oscillation electric signal producer by HF oscillation electric signal transmission cable, u, stretches into reactor inner chamber by pH probe through the top of reactor, and with the micropore stainless steel sleeve of the cap for brush shape made through powder metallurgical technique, this pH its part extending into reactor inner chamber of popping one's head in is carried out to suit and gone along with sb. to guard him, v, connects this pH probe with pH analyser, w, connects this pH analyser with warning horn, and this warning horn is for giving the alarm to the pH value situation of transfiniting, x, wedges the buffering isolating pad of viton or silicon rubber material in the junction between micropore stainless steel sleeve its opening end and reactor head of this cap for brush shape, y, two pairs of dry-reed type ball float level controllers are extend into the inner chamber of reactor through the top of reactor, a pair dry-reed type ball float level controller is wherein connected with its power cable of water pump to reactor luminal perfusion waste water by a rly., wherein another is connected with its power cable of described topping-up pump by another rly. dry-reed type ball float level controller, z, catalyst underflow refluxing opening is dug in this its intracavity bottom position of catalyst underflow transition tank, also this catalyst underflow refluxing opening is connected with the inner chamber of reactor through catalyst underflow reverse flow valve via pipeline, this catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control, this catalyst underflow transition tank is the tank body of a hollow, this catalyst underflow transition tank is used for temporarily depositing the higher water body of catalyst concentration that each its backwashing procedures of described strainer discharges, the mounting height of this catalyst underflow transition tank bottom it is on its overhead height of this reactor, aa, connecting in gas circuit between this pneumatic pump with this quartz tube cavity accesses a Miniature diaphragm pump with bypass mode, its power of this Miniature diaphragm pump is between 5 watts and 50 watts, its air outlet operating pressure of this Miniature diaphragm pump is between 1 meter water column and 5 meter water columns, and its air output of this Miniature diaphragm pump is between per minute 1 liter and per minute 80 liters.
2. the photocatalytic waste water degradation reactor expansion method improving catalyst interception more according to claim 1, it is characterized in that, its material of microwave constrainer of this caged is through the stainless steel of mirror polish process, and its hole of microwave constrainer of this caged or the size of mesh are between 0.5 centimetre and 3.0 centimetres.
3. the photocatalytic waste water degradation reactor expansion method improving catalyst interception more according to claim 2, is characterized in that, the microwave constrainer of this caged is woven by mirror polish Stainless Steel Wire to make.
4. the photocatalytic waste water degradation reactor expansion method improving catalyst interception more according to claim 2, it is characterized in that, the microwave constrainer of this caged is made up through mold pressing, welding or splicing process of mirror polish punching stainless steel plate.
5. the photocatalytic waste water degradation reactor expansion method improving catalyst interception more according to claim 1, it is characterized in that, its outer wall of microwave constrainer of this caged and described silica tube inwall are mutually close to or mutual spacing is less than 5.0 centimetres.
6. the photocatalytic waste water degradation reactor expansion method improving catalyst interception more according to claim 5, it is characterized in that, its outer wall of microwave constrainer and the described silica tube inwall of this caged are close to mutually.
7. the photocatalytic waste water degradation reactor expansion method improving catalyst interception more according to claim 1, it is characterized in that, this back flush type hollow-fibre membrane ultra filtration filter is made up of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.
8. the photocatalytic waste water degradation reactor expansion method improving catalyst interception more according to claim 1, it is characterized in that, this back flush type tubular fibre membrane microfiltration strainer is made up of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.
9. the photocatalytic waste water degradation reactor expansion method improving catalyst interception more according to claim 1, it is characterized in that, the method is further comprising the steps of: on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration its pure water inlet of strainer and described back flush type hollow-fibre membrane ultra filtration filter, be connected in series into second topping-up pump, this second topping-up pump is for augmenting hydraulic pressure to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter.
10. the photocatalytic waste water degradation reactor expansion method improving catalyst interception more according to claim 1, it is characterized in that, this its wall thickness of micropore stainless steel sleeve is between 3 millimeters to 30 millimeters, this its micropore size of micropore stainless steel sleeve is between 0.5 micron to 50 microns, and this its thickness of buffering isolating pad is between 1 millimeter to 8 millimeters.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310327191.8A CN103408170B (en) | 2013-07-24 | 2013-07-24 | Improve the photocatalytic waste water degradation reactor expansion method of catalyst interception again |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310327191.8A CN103408170B (en) | 2013-07-24 | 2013-07-24 | Improve the photocatalytic waste water degradation reactor expansion method of catalyst interception again |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103408170A CN103408170A (en) | 2013-11-27 |
CN103408170B true CN103408170B (en) | 2016-04-06 |
Family
ID=49601230
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310327191.8A Active CN103408170B (en) | 2013-07-24 | 2013-07-24 | Improve the photocatalytic waste water degradation reactor expansion method of catalyst interception again |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103408170B (en) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0696259B1 (en) * | 1993-04-28 | 1999-12-29 | Wastech International Inc. | Apparatus for the treatment of waste water |
CN201080438Y (en) * | 2007-07-11 | 2008-07-02 | 四川睿赛柯环境科技有限公司 | Microwave sewage disposal and microwave ultraviolet ray disinfection integral device |
CN102616950A (en) * | 2012-04-20 | 2012-08-01 | 西安建筑科技大学 | Device for improving water quality of laminated mixed oxygenated water |
CN103159360A (en) * | 2013-03-18 | 2013-06-19 | 宁波大学 | Secondary-ozone-depletion-allowable microwave photocatalytic wastewater degradation reactor capacity-expansion method |
CN103193349A (en) * | 2013-03-18 | 2013-07-10 | 宁波大学 | Expansion method without ozone pollution for non-polar ultraviolet catalytic waste water degradation reactor |
CN103204564A (en) * | 2013-03-23 | 2013-07-17 | 宁波大学 | Method for expanding photochemical catalysis wastewater degradation reactor with automatic endpoint shutdown function |
CN103204565A (en) * | 2013-03-23 | 2013-07-17 | 宁波大学 | Microwave synergistic photocatalysis wastewater degradation reactor capable of avoiding secondary pollution of surplus ozone |
-
2013
- 2013-07-24 CN CN201310327191.8A patent/CN103408170B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0696259B1 (en) * | 1993-04-28 | 1999-12-29 | Wastech International Inc. | Apparatus for the treatment of waste water |
CN201080438Y (en) * | 2007-07-11 | 2008-07-02 | 四川睿赛柯环境科技有限公司 | Microwave sewage disposal and microwave ultraviolet ray disinfection integral device |
CN102616950A (en) * | 2012-04-20 | 2012-08-01 | 西安建筑科技大学 | Device for improving water quality of laminated mixed oxygenated water |
CN103159360A (en) * | 2013-03-18 | 2013-06-19 | 宁波大学 | Secondary-ozone-depletion-allowable microwave photocatalytic wastewater degradation reactor capacity-expansion method |
CN103193349A (en) * | 2013-03-18 | 2013-07-10 | 宁波大学 | Expansion method without ozone pollution for non-polar ultraviolet catalytic waste water degradation reactor |
CN103204564A (en) * | 2013-03-23 | 2013-07-17 | 宁波大学 | Method for expanding photochemical catalysis wastewater degradation reactor with automatic endpoint shutdown function |
CN103204565A (en) * | 2013-03-23 | 2013-07-17 | 宁波大学 | Microwave synergistic photocatalysis wastewater degradation reactor capable of avoiding secondary pollution of surplus ozone |
Also Published As
Publication number | Publication date |
---|---|
CN103408170A (en) | 2013-11-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103232129B (en) | The Microwave photochemical catalytic wastewater degradation reactor expansion method of anti-agglomeration | |
CN103241872B (en) | Improve the photocatalytic waste water degradation reactor expansion method of catalyst interception again | |
CN103265136B (en) | The photocatalytic waste water degradation reactor expansion method of careful recovery catalyst particles | |
CN103435200B (en) | The photocatalytic waste water degradation reactor expansion method that UV radiator state is checked oneself | |
CN103319034B (en) | Incidentally prevent the photocatalytic waste water degradation reactor expansion method of lamp district gushing water | |
CN103288265B (en) | By the photocatalytic waste water degradation reactor expansion method of high frequency ultrasound anti-attachment | |
CN103408170B (en) | Improve the photocatalytic waste water degradation reactor expansion method of catalyst interception again | |
CN103253806B (en) | Coulombic repulsion effect incorporates photocatalytic waste water degradation reactor expansion method therebetween | |
CN103288272B (en) | In conjunction with the photocatalytic waste water degradation reactor expansion method of high frequency ultrasound anti-attachment | |
CN103253809B (en) | Integrate the photocatalytic waste water degradation reactor expansion method of catalyst charging characteristic | |
CN103253810B (en) | In conjunction with the wastewater light degradation reactor expansion method utilizing catalyst particles charging characteristic | |
CN103253805B (en) | Take into account the photocatalytic waste water degradation reactor expansion method of coulombic repulsion effect | |
CN103241874B (en) | The Microwave photocatalytic wastewater degradation device expansion method that catalyst interception link is perfect again | |
CN103288269B (en) | Physics assists the photocatalytic waste water degradation reactor expansion method of gentle anti-attachment | |
CN103466855A (en) | Photocatalysis waste water degradation reactor capacity expanding method with improved catalyst for interception | |
CN103253807B (en) | Make use of the Microwave photocatalytic wastewater degradation device expansion method of electrostatic repulsion effect | |
CN103265135B (en) | The microwave and photo catalysis wastewater degradation reactor expansion method of tight interception catalyst particles | |
CN103241881B (en) | The photocatalytic waste water degradation reactor expansion method initiatively can detected reunion inducement | |
CN103288268A (en) | Capacity expansion method of photocatalysis waste water degrading reactor for maintaining membrane component by soft ultrasound | |
CN103253814B (en) | The microwave and photo catalysis wastewater degradation reactor expansion method of integration coulombic repulsion effect | |
CN103288259B (en) | The reactor expansion method of its main inducement parameter self-inspection of reuniting of wastewater light degradation catalyst | |
CN103435199B (en) | Incidentally supervise the photocatalytic waste water degradation reactor expansion method of lamp source state | |
CN103241797B (en) | Original position clears up the ultraviolet catalytic wastewater degradation reactor expansion method of agglomeration | |
CN103387304A (en) | Capacity expanding method of photocatalysis waste water degrading reactor with lamp zone anti-water bursting maintenance | |
CN103408169A (en) | Capacity expansion method of photocatalytic wastewater degradation reactor for improving medium recovery |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20181022 Address after: 401120 Yubei District, Chongqing Shuangfeng bridge airport development zone, Xiangyu Road, No. 15, 2. Patentee after: Chongqing Yao Qun Environmental Protection Technology Co., Ltd. Address before: 315010 room 604, Lane 169, Lane 169, Haishu Road, Haishu, Ningbo. Patentee before: Li Rongsheng |
|
TR01 | Transfer of patent right |