CN103398875B - A kind of device measuring the distribution of ocean suspension oil spilling Petroleum Hydrocarbon concentration vertical - Google Patents
A kind of device measuring the distribution of ocean suspension oil spilling Petroleum Hydrocarbon concentration vertical Download PDFInfo
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- CN103398875B CN103398875B CN201310364103.1A CN201310364103A CN103398875B CN 103398875 B CN103398875 B CN 103398875B CN 201310364103 A CN201310364103 A CN 201310364103A CN 103398875 B CN103398875 B CN 103398875B
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Abstract
Description
技术领域 technical field
本发明涉及一种测定海洋悬浮溢油中石油烃浓度垂直分布的装置,属于海洋环境监测技术领域。 The invention relates to a device for measuring the vertical distribution of petroleum hydrocarbon concentration in marine suspended oil spill, belonging to the technical field of marine environment monitoring.
背景技术 Background technique
近年来,随着海洋石油资源的开采与利用,在石油加工产品的生产和运输过程中,海上溢油事故频发。例如,2010年4月墨西哥湾“深水地平线”钻井平台爆炸溢油事故、2010年7月大连大孤山新港码头输油管线溢油事故、2011年6月蓬莱19-3油田溢油事故。石油组成以相对分子质量较大的烷烃为主,在自然条件下降解需要较长时间。石油漂浮在海面上,迅速扩散形成油膜,影响海洋浮游生物生长,破坏海洋生态平衡。海洋溢油不仅对环境危害巨大,而且也会影响人类的生产生活,危害人类健康。海面油污染的处理大致分为物理法、化学法和生物法三种。物理处理法主要通过物理的手段对溢油进行回收,化学处理方法是喷洒各种化学药剂,如消油分散剂、吸附剂等其他界面活性剂等,能把海面的浮油分散成极小的颗粒,使其在海水中乳化、分散、溶解或沉降到海底。生物处理方法是根据某些天然存在于海洋或土壤中的微生物有较强的氧化和分解石油的能力,利用生物的这一特性清除流入海水中的石油。可是,到目前为止人们并不十分清楚海洋悬浮溢油石油烃在海洋中垂直分布的规律,因此也就无法有效的指导物理、化学、生物方法进行溢油处理。 In recent years, with the exploitation and utilization of offshore oil resources, marine oil spill accidents have occurred frequently during the production and transportation of petroleum processed products. For example, in April 2010, the "Deepwater Horizon" drilling platform explosion in the Gulf of Mexico oil spill accident, in July 2010, the Dalian Dagushan Xingang wharf oil pipeline oil spill accident, in June 2011, the Penglai 19-3 oil field oil spill accident. Petroleum is mainly composed of alkanes with relatively large molecular weights, and it takes a long time to degrade under natural conditions. Oil floats on the sea surface and spreads rapidly to form an oil film, which affects the growth of marine plankton and destroys the ecological balance of the ocean. Marine oil spills are not only harmful to the environment, but also affect human production and life and endanger human health. The treatment of sea surface oil pollution can be roughly divided into three types: physical method, chemical method and biological method. The physical treatment method mainly uses physical means to recover the spilled oil. The chemical treatment method is to spray various chemical agents, such as oil dispersants, adsorbents and other surfactants, which can disperse the oil slick on the sea surface into extremely small particles. , making it emulsify, disperse, dissolve or settle to the seabed in seawater. The biological treatment method is based on the fact that some microorganisms naturally existing in the ocean or soil have a strong ability to oxidize and decompose oil, and use this characteristic of organisms to remove oil flowing into seawater. However, so far, people do not know the law of the vertical distribution of petroleum hydrocarbons suspended in the ocean, so they cannot effectively guide physical, chemical, and biological methods for oil spill treatment.
发明内容 Contents of the invention
针对上述问题,本发明的目的在于提供一种简便、快速的室内测定海洋悬浮溢油中石油烃浓度垂直分布的装置。 In view of the above problems, the object of the present invention is to provide a simple and rapid indoor device for measuring the vertical distribution of petroleum hydrocarbon concentration in marine suspended oil spills.
本发明包括一有底圆柱形容器和安装于容器顶部的取样器,所述取样器包括多根长度不同的取样管,以及用于固定所述取样管的固定装置;所述取样管为管状结构,其上端开口,下端为弯曲的尖口结构,尖口方向与取样管垂直,尖口设计可以最大限度避免扰动水中的石油烃,并且各取样管底部的尖口都朝向圆柱形容器的中心,保证所取水样在同一条垂直线上。 The present invention comprises a cylindrical container with a bottom and a sampler installed on the top of the container, the sampler includes a plurality of sampling tubes with different lengths, and a fixing device for fixing the sampling tubes; the sampling tube is a tubular structure , the upper end is open, the lower end is a curved tip structure, the direction of the tip is perpendicular to the sampling tube, the tip design can avoid disturbing the petroleum hydrocarbons in the water to the greatest extent, and the tips at the bottom of each sampling tube are all facing the center of the cylindrical container, Ensure that the water samples taken are on the same vertical line.
所述取样管顶部通过橡胶连接管连接用于取样的注射器,并用止水夹止水。 The top of the sampling tube is connected to the syringe used for sampling through a rubber connecting tube, and the water is stopped with a water stop clamp.
所述圆柱形容器底部安装有排水开关。 A drain switch is installed at the bottom of the cylindrical container.
所述圆柱形容器可固定于底座上。 The cylindrical container can be fixed on the base.
本发明在使用时,先将取样器固定于圆柱形容器的顶部,并可将所述圆柱形容器固定于底座上,然后往容器中注水至0刻度,顶部倒入少量石油模拟溢油;最后通过不同深度的取样管进行取样,即可测定石油烃在的垂直分布规律。先固定取样器的好处是,可以随时取样,并且取样时不会扰动水面的溢油,也不会扰动水中的石油烃。取样结束后,将取样管中的水慢慢吹出,再用止水夹止水,这样可以确保下次取样时,所取的水样不是上次残存在取样管中的水。 When the present invention is in use, the sampler is first fixed on the top of the cylindrical container, and the cylindrical container can be fixed on the base, then water is poured into the container to 0 scale, and a small amount of oil is poured into the top to simulate an oil spill; finally By sampling through sampling pipes of different depths, the vertical distribution law of petroleum hydrocarbons can be determined. The advantage of fixing the sampler first is that samples can be taken at any time without disturbing the oil spill on the water surface or the petroleum hydrocarbons in the water. After sampling, slowly blow out the water in the sampling tube, and then stop the water with a water stop clamp, so as to ensure that the water sample taken is not the water remaining in the sampling tube last time when sampling next time.
本发明的优点是结构简单,可以方便快速测定悬浮溢油中石油烃浓度的垂直分布,为不同方法进行溢油处理提供科学的依据。 The invention has the advantages of simple structure, can conveniently and quickly measure the vertical distribution of petroleum hydrocarbon concentration in suspended oil spill, and provide scientific basis for oil spill treatment by different methods.
附图说明 Description of drawings
图1是本发明的整体结构示意图。 Fig. 1 is a schematic diagram of the overall structure of the present invention.
图2是本发明圆柱形容器的结构示意图。 Fig. 2 is a structural schematic diagram of a cylindrical container of the present invention.
图3是本发明取样器的结构示意图。 Fig. 3 is a schematic structural view of the sampler of the present invention.
图4是本发明底座的结构示意图。 Fig. 4 is a structural schematic diagram of the base of the present invention.
图5是利用本发明测定石油烃浓度垂直分布随时间变化图。 Fig. 5 is a graph showing the vertical distribution of petroleum hydrocarbon concentration as a function of time measured by the present invention.
其中,1.圆柱形容器;2.排水开关;3.取样管固定装置;4.橡胶连接管;5.止水夹;6.注射器;7.取样器;8.取样管一;9.取样管二;10.取样管三;11.取样管四;12.底座。 Among them, 1. Cylindrical container; 2. Drainage switch; 3. Sampling tube fixing device; 4. Rubber connecting tube; 5. Water stop clamp; 6. Syringe; 7. Sampler; 8. Sampling tube one; Tube two; 10. Sampling tube three; 11. Sampling tube four; 12. Base.
具体实施方式 detailed description
下面结合附图并通过具体实施例来详细说明本发明。 The present invention will be described in detail below in conjunction with the accompanying drawings and through specific embodiments.
如图1所示,本发明的装置包括一有底圆柱形容器1和安装于圆柱形容器1顶部的取样器7;其中,所述圆柱形容器1由5mm厚玻璃制成,高100cm,直径20cm,柱体自上而下标有从0-80cm不同深度的刻度,所述圆柱形容器1底部还安装有排水开关2(如图2);所述取样器7上包括四根长度不同的取样管,以及用于固定所述取样管7的固定装置3;所述取样管分别为取样管一8、取样管二9、取样管三10、取样管四11,其长度不同,分别可取10cm,30cm,50cm,70cm等不同深度处的水样,上述取样管的尖口都朝向圆柱形容器的中心,并在同一条垂直线上。 As shown in Figure 1, the device of the present invention comprises a bottomed cylindrical container 1 and a sampler 7 installed on the top of the cylindrical container 1; wherein, the cylindrical container 1 is made of 5mm thick glass, high 100cm, diameter 20cm, the cylinder is marked with scales of different depths from 0-80cm from top to bottom, and the bottom of the cylindrical container 1 is also equipped with a drain switch 2 (as shown in Figure 2); the sampler 7 includes four different lengths Sampling tube, and the fixture 3 that is used to fix described sampling tube 7; Described sampling tube is sampling tube one 8, sampling tube two 9, sampling tube three 10, sampling tube four 11 respectively, and its length is different, can get 10cm respectively , 30cm, 50cm, 70cm and other water samples at different depths, the points of the above-mentioned sampling tubes all face the center of the cylindrical container and are on the same vertical line.
如图3所示,所述取样管固定装置3是一个可固定所述取样管的硬泡沫,可固定于圆柱形容器1的顶部。 As shown in FIG. 3 , the sampling tube fixing device 3 is a hard foam capable of fixing the sampling tube, and can be fixed on the top of the cylindrical container 1 .
下面以取样管一8为例说明其结构,所述取样管一8以细玻璃管制成,其上端开口,下端为弯曲的尖口结构,尖口方向与取样管8垂直,尖口设计可以最大限度避免扰动水中的石油烃,并且取样管8底部的尖口朝向圆柱形容器的中心;所述取样管8顶部通过橡胶连接管4连接用于取样的注射器6,并使用止水夹5止水。 Take sampling tube one 8 as an example below to illustrate its structure. The sampling tube one 8 is made of a thin glass tube with an open upper end and a curved tip structure at the lower end. The limit avoids disturbing the petroleum hydrocarbons in the water, and the point at the bottom of the sampling pipe 8 faces the center of the cylindrical container; the top of the sampling pipe 8 is connected to the syringe 6 for sampling through a rubber connecting pipe 4, and uses a water stop clip 5 to stop the water .
所述圆柱形容器1可固定于如图4所示的底座12上。 The cylindrical container 1 can be fixed on a base 12 as shown in FIG. 4 .
本发明在使用时,先将图3中四根取样管固定在泡沫取样管固定装置3上,通过橡胶连接管4与玻璃注射器6相连,使用止水夹5止水;再将取样器7固定于图2中的圆柱形容器1的顶部,即组成如图1所示的装置;然后将其放到图4的底座上。测定时,先注水至0刻度,在水面处倒入适量石油,模拟溢油;经过一段时间的沉降后,通过玻璃注射器6抽取不同深度的水样,测定水中石油烃的垂直分布浓度,结果如图5所示。由图5可以看出石油烃浓度是随着水深的增加而减小的,并且随着时间的增加水中不同深度的石油烃浓度都呈现上升趋势,到达一定时间后,浓度趋于稳定。 When the present invention is in use, first fix the four sampling tubes in Fig. 3 on the foam sampling tube fixing device 3, link to each other with the glass syringe 6 through the rubber connecting tube 4, and use the water stop clip 5 to stop the water; then fix the sampler 7 On the top of the cylindrical container 1 in Fig. 2, the device as shown in Fig. 1 is formed; then it is put on the base of Fig. 4 . During the measurement, first inject water to the 0 scale, pour an appropriate amount of oil on the water surface to simulate an oil spill; after a period of settlement, take water samples of different depths through the glass syringe 6, and measure the vertical distribution concentration of petroleum hydrocarbons in the water. The results are as follows: Figure 5 shows. It can be seen from Figure 5 that the concentration of petroleum hydrocarbons decreases with the increase of water depth, and the concentration of petroleum hydrocarbons at different depths in the water shows an upward trend with the increase of time, and the concentration tends to be stable after a certain period of time.
本领域的普通技术人员都会理解,在本发明的保护范围内,对于上述实施例进行修改、添加和替换都是可能的,其都没有超出本发明的保护范围。 Those skilled in the art will understand that within the protection scope of the present invention, it is possible to modify, add and replace the above-mentioned embodiments, and none of them exceed the protection scope of the present invention.
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| CN110940783A (en) * | 2019-10-28 | 2020-03-31 | 陕西众策网络科技发展有限公司 | Portable water quality detection device |
| CN111207954B (en) * | 2020-03-18 | 2023-07-04 | 北华航天工业学院 | A combined in-situ soil liquid and gas phase material collector |
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| GB1178108A (en) * | 1966-10-18 | 1970-01-21 | Whessoe Ltd | Taking of Liquid Samples from a Storage Tank |
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