CN103397324B - A kind of multifunction phosphide liquid and its production and use - Google Patents
A kind of multifunction phosphide liquid and its production and use Download PDFInfo
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- CN103397324B CN103397324B CN201310343078.9A CN201310343078A CN103397324B CN 103397324 B CN103397324 B CN 103397324B CN 201310343078 A CN201310343078 A CN 201310343078A CN 103397324 B CN103397324 B CN 103397324B
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- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims abstract description 18
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- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 9
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- 229910052751 metal Inorganic materials 0.000 claims description 22
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 9
- 239000010452 phosphate Substances 0.000 claims description 9
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- 238000010276 construction Methods 0.000 claims description 6
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- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- GQDHEYWVLBJKBA-UHFFFAOYSA-H copper(ii) phosphate Chemical compound [Cu+2].[Cu+2].[Cu+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GQDHEYWVLBJKBA-UHFFFAOYSA-H 0.000 claims description 2
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- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical group [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 2
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- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Fireproofing Substances (AREA)
Abstract
The present invention relates to a kind of multifunction phosphide liquid and its production and use, be made up of, it is characterized in that: by mass parts A liquid and B liquid, the ratio of ratio in multifunction phosphide liquid of A liquid and B liquid is 1:0.1-1; 1) by mass parts, the material component of described A liquid comprises: Secondary ammonium phosphate 26-48 part; 85% phosphoric acid 0.9-12 part; Metal-powder 0.8-1.8 part; Gelatin 0.6-1.4 part; Gesso 0.4-10 part; Alum 0.3-0.8 part; Surplus is water; 2) by mass parts, the material component of described B liquid comprises: primary zinc phosphate 20-46 part; Zinc nitrate 38-55 part; Sodium Fluoride 2-3.8 part; Zinc oxide 2-4 part; 85% phosphoric acid 2-6 part; Surplus is water.The multifunction phosphide liquid that the present invention relates to is made up of A liquid and B liquid, completes effect of oil removing, rust cleaning simultaneously, and have antirust, heat insulation, high temperature resistant, insulation, fire-retardant, eliminate the noise, shockproof, insulation, scrubbing, fp effect.Have rust cleaning speed fast, film forming thickness is thick, and antirust time is long waits beneficial effect.
Description
Technical field
The present invention relates to a kind of multifunction phosphide liquid and its production and use.Belong to the technical field of surface of the materials such as metal.
Background technology
Phosphatization is conventional pretreatment technology, and metallic surface contacts with dilute phosphoric acid or superphosphate, and chemical reaction occurs; and the process of stable insoluble phosphate protective membrane is generated in metallic surface; the protective membrane formed is phosphatize phosphate coat, and phosphatize phosphate coat can increase film adhesive, improves corrosion resistance coating.Phosphating Solution be mainly used in electroplate, paint or workpiece processing pre-treatment and seal process up for safekeeping; as the bottom of coating; strengthen bonding force between application rete (as paint, coating etc.) and workpiece; the solidity to corrosion of surface coating after raising application; also can be used as metal cold add lubricant film, the metal surface protection layer in man-hour and be used as the insulation processing of dynamo sheet, the release treatment etc. of die casting, be widely used in the industrial production such as automobile, boats and ships, aerospace, machinofacture and household electrical appliances.
Most of phosphide liquid product has following shortcomings in the market: general Phosphating Solution only has the function of single phosphatization, also needs to carry out the operations such as rust cleaning degreasing to workpiece before carrying out phosphatization operation to workpiece.In addition, the process of phosphatization operation is loaded down with trivial details, also needs to rinse with water after Phosphating Solution process, produces sewage backward outer discharge, causes environmental pollution, and after general Non-water washing Phosphating Solution application workpiece to the poor adhesive force of coating and paint.For requiring tighter cathode electro-coating, before application, deionized water is preferably adopted to wash.
Therefore, be necessary to improve prior art.
Summary of the invention
An object of the present invention is to provide a kind of multifunction phosphide liquid.
Object two of the present invention is the preparation methods in order to provide a kind of multifunction phosphide liquid.
Object three of the present invention is the purposes in order to provide a kind of multifunction phosphide liquid.
The present invention is to make up the deficiencies in the prior art, have simultaneously oil removing, rust cleaning, antirust, heat insulation, high temperature resistant, insulation, fire-retardant, eliminate the noise, shockproof, insulation, scrubbing, the function such as fire prevention, make simply, easy for operation.
In order to realize one of foregoing invention object, the technical solution used in the present invention is as follows:
A kind of multifunction phosphide liquid, be made up of A liquid and B liquid, it is characterized in that: by mass parts, the ratio of ratio in multifunction phosphide liquid of A liquid and B liquid is 1:0.1-1;
1) by mass parts, the material component of described A liquid comprises: Secondary ammonium phosphate 26-48 part; 85% phosphoric acid 0.9-12 part; Metal-powder 0.8-1.8 part; Gelatin 0.6-1.4 part; Gesso 0.4-10 part; Alum 0.3-0.8 part; Surplus is water;
2) by mass parts, the material component of described B liquid comprises: primary zinc phosphate 20-46 part; Zinc nitrate 38-55 part; Sodium Fluoride 2-3.8 part; Zinc oxide 2-4 part; 85% phosphoric acid 2-6 part; Surplus is water.
Further, the material component of described A liquid also comprises a small amount of additive and a small amount of promotor.
Further, described metal-powder was silver powder or the aluminium powder of 200 order mesh sieves; Described gelatin is gelatinum.
Further, described additive is one or more in chromic oxide, cupric phosphate and polyhydroxy carboxylic acids or fluorochemicals, and described promotor is molybdate.
In order to realize foregoing invention object two, the technical solution used in the present invention is as follows:
A preparation method for multifunction phosphide liquid, is characterized in that comprising the following steps:
1) take each material composition of described A liquid and B liquid respectively by the weight part of material each in prescription for subsequent use, wherein gelatin hot water melts, and metal-powder crosses mesh sieve;
2) A liquid is prepared, ready for step 1) Secondary ammonium phosphate and phosphoric acid are slowly added to the water stirring and dissolving evenly, form A liquor, again the gelatin melted, the metal-powder sieved, gesso, alum are added above-mentioned A liquor respectively, after stirring, obtain A liquid;
3) prepare B liquid, ready for step 1) primary zinc phosphate, zinc nitrate, Sodium Fluoride, zinc oxide, 85% phosphoric acid are slowly added to the water respectively, after stirring, obtain B liquid;
4) by step 2) the B liquid prepared of the A liquid prepared, step 3) packages for subsequent use respectively, or in proportion by step 2) to form mixed solution for subsequent use for the B liquid mixing prepared of the A liquid prepared, step 3).
Further, step 2) when preparing A liquid, also add additive and promotor in proportion, the method adding additive and promotor is, after the gelatin melted, the metal-powder sieved, gesso, alum are added A liquor respectively, add additive and promotor and stir.
Secondary ammonium phosphate in the present invention's formula and phosphoric acid etc. are all conventional ingredients of Phosphating Solution; Gelatin can play the effect of tensio-active agent, and the structure of the gelatin microencapsulation melted can fill rapidly tiny space; Metal-powder and gesso have fire-retardant effect, and the metal-powder of white can play the effect of enhancing surface.
In order to realize foregoing invention object three, the technical solution used in the present invention is as follows:
A kind of purposes of multifunction phosphide liquid, it is characterized in that: for the rust cleaning of steelwork, comprise and bridge construction, construction work, large-scale pipeline are produced and the rust cleaning of installation work and marine vessel, steel surface is contacted multifunction phosphide liquid 1-5 minute, become rusty thick seriously want etch 10-25 minute, complete steel surface rust cleaning, fill spray again if uneven and drench multifunction phosphide liquid reprocessing.
Further, multifunction phosphide liquid is used for new metallic surface process, and by new metal etch multifunction phosphide liquid, added water by 1:3 or 4 by multifunction phosphide liquid and mix well, thin spray 3 times, reaches etch-proof effect.
Further, multifunction phosphide liquid, for electroplating front metal treatment, adds water by 1:2 and mixes well use by multifunction phosphide liquid.
Further, the purposes of multifunction phosphide liquid includes high, medium and low and normal temperature phosphating processing mode,
1) iron and steel Phosphating Solution of the present invention, takes middle high temperature phosphorization, forms hard phosphatize phosphate coat, and metal iron and steel hardness can be made to improve 80%, and anti-impact force is strong, becomes shellproof metal;
2) metallic surface is with after Phosphating Solution bonderizing of the present invention, then sprayed coating, can realize heat insulation, high temperature resistant, insulation, be mainly used in automobile bodies, outdoor steel structure is heat insulation; Or spray this Phosphating Solution dry after, spray-applied primer and finish paint, automobile plays sunshade thermal insulation, high temperature resistant, saves the use of hot summer air-conditioning, reduces automobile energy consumption, save gasoline;
3) steel surface is with after Phosphating Solution process of the present invention, and spraying 54-11 vinylformic acid vibration-absorbing and silencing damping paint, has good shock resistance, water tolerance, resistance to gasoline, salt fog resistance, acid resistance, damping property.Be used in the vehicles and comprise aircraft, steamer, automobile and train, play and reduce vibration, noise elimination, heat insulation, antihunt action.
Main beneficial effect of the present invention is:
1, complete function.The multifunction phosphide liquid that the present invention relates to is made up of A liquid and B liquid, when applying Phosphating Solution provided by the invention, A liquid and B liquid can be mixed in proportion rear use, also first B liquid can be used with after A liquid, reach the effect simultaneously completing oil removing, rust cleaning, and have antirust, heat insulation, high temperature resistant, insulation, fire-retardant, eliminate the noise, shockproof, insulation, scrubbing, fp effect.Have rust cleaning speed fast, film forming thickness is thick, and antirust time is long waits beneficial effect.
2, the preparation method that the present invention relates to, simple to operate, save labour, enhance productivity.
3, Application Areas of the present invention is wide.Both can be applicable to metal iron and steel, stainless steel, aluminum and its alloy parts that hull etc. is large-scale, also can be used for the decontamination oil removing of plastics, rubber, ceramic tile, woodwork etc., except long-pending renovation and fire prevention process.
4, working conditions of the present invention is simple.Do not need harsh high temperature phosphorization environment, also do not need the equipment such as special deionized water, Phosphating Slot, the Phosphating Solution prepared by tap water is at normal temperatures painted on workpiece and just can uses, and finishes using without the need to washing natural air drying.
5, adopt the present invention that coating can be made bright and clean attractive in appearance.
Embodiment
Below by specific embodiment, the present invention is further detailed.
Specific embodiment 1:
To calculate the Phosphating Solution by following formula preparation by mass parts, wherein,
A liquid: Secondary ammonium phosphate 26 parts; 85% phosphoric acid 0.9 part; 0.8 part, aluminium powder/silver powder; Gelatin 0.6 part; Gesso 0.4 part; 0.3 part, alum; Water is surplus.
B liquid: primary zinc phosphate 20 parts; Zinc nitrate 38 parts; Sodium Fluoride 2 parts; 2 parts, zinc oxide; 85% phosphoric acid 2 parts; Surplus is water.
Wherein gelatin can select industrial gelatinum, muscle glue etc. to melt with hot water; Metal-powder crosses mesh sieve; Secondary ammonium phosphate and phosphoric acid are added in Phosphating Solution Preparation tank, then adds other composition successively, and additive and promotor.The General Acidity in Phosphating Solution of above-mentioned formulated is less, the surface treatment that applicable corrosion is not quite serious, and the phosphatize phosphate coat formed in metallic surface is comparatively frivolous.The methods such as immersion, brushing can be adopted, be taken up in order of priority and A liquid and B liquid are acted on pending metallic substance; Be disposed natural air drying.
Specific embodiment 2:
The Phosphating Solution by following formula preparation is calculated by mass parts, wherein:
A liquid: Secondary ammonium phosphate 35 parts; 85% phosphoric acid 6 parts; 1.0 parts, aluminium powder/silver powder; Gelatin 1.0 parts; Gesso 5 parts; 0.5 part, alum; Water is surplus.
B liquid: primary zinc phosphate 32 parts; Zinc nitrate 45 parts; Sodium Fluoride 3 parts; 3 parts, zinc oxide; 85% phosphatase 24 part; Surplus is water.
Above-mentioned formulated Phosphating Solution process and using method are with embodiment 1, and the General Acidity in Phosphating Solution of preparation is moderate, are applicable to the surface treatment that corrosion degree is medium.
Specific embodiment 3:
The Phosphating Solution by following formula preparation is calculated by mass parts, wherein:
A liquid: Secondary ammonium phosphate 48 parts; 85% phosphatase 11 2 parts; 1.8 parts, aluminium powder/silver powder; Gelatin 1.4 parts; Gesso 10 parts; 0.8 part, alum; Water is surplus.
B liquid: primary zinc phosphate 46 parts; Zinc nitrate 55 parts; Sodium Fluoride 3.8 parts; 4 parts, zinc oxide; 85% phosphoric acid 6 parts; Surplus is water.
Above-mentioned formulated Phosphating Solution process is with embodiment 1, the General Acidity in Phosphating Solution of preparation can reach 68, this kind of the most applicable brushing of Phosphating Solution uses the surface treatment that early corrosion degree is serious and higher to specification of quality, and before phosphatize phosphate coat is formed, corrosion thing that is abundant and metallic surface reacts.The content of higher gelatin, metal-powder and the plaster of Paris makes phosphatize phosphate coat appearance more bright fine and close.
Other specific embodiments:
The feature of other specific embodiments of the present invention is: multifunction phosphide liquid, be made up of A liquid and B liquid, it is characterized in that: by mass parts, the ratio of ratio in multifunction phosphide liquid of A liquid and B liquid is 1:0.1-1, and namely 1 part of A liquid mixes rear use with 0.1,0.15,0.2,0.25,0.3,0.35,0.4,0.45,0.5,0.55,0.6,0.65,0.7,0.75,0.8,0.9 or 1 part of B liquid.
1) by mass parts, the material component of described A liquid comprises: Secondary ammonium phosphate 26-48 part; 85% phosphoric acid 0.9-12 part; Metal-powder 0.8-1.8 part; Gelatin 0.6-1.4 part; Gesso 0.4-10 part; Alum 0.3-0.8 part; Surplus is water;
2) by mass parts, the material component of described B liquid comprises: primary zinc phosphate 20-46 part; Zinc nitrate 38-55 part; Sodium Fluoride 2-3.8 part; Zinc oxide 2-4 part; 85% phosphoric acid 2-6 part; Surplus is water.
The operation instruction of multifunction phosphide liquid prepared by the present invention:
(1) rust cleaning of the most applicable band large-scale metal steelwork, as bridge construction, construction work, large-scale pipeline are produced and installation work and marine vessel etc., derusts after spraying automatically, without the need to polishing, saves artificial, waits direct spray base after doing.Metallic steel iron surface is allowed to contact rust removing solution 1-5 minute, to become rusty thick wanting etch 10-25 minute (the rust cleaning film of thicker rust is thicker seriously, film forming makes priming paint, adsorb with rust-proofing primer and equal double-deck priming paint, rust-proof effect is better), be combined with the rust film that produces of eliminating rust and be used as priming paint, and then spary rust-proofing primer and finish paint.Metallic surface blackening is blue, and black and blue color anti-rust film evenly just can rust prevention by applying liquid material paint and finish paint (fill spray if uneven and drench multifunction phosphide liquid reprocessing)
(2) new metal etch multifunction phosphide liquid (adds water by 1:3 or 4 and mixes well, thin spray 3 times) reach etch-proof effect: as rustless iron and steel, during etch, bubble is few, remove because of rustless, metallic surface bubble-free is emerged, but equally have conjunctiva antirust when liquid is done, generally speaking the thicker antirust time of etch conjunctiva is longer, and the thin antirust time of conjunctiva is short.Because multifunction phosphide liquid contacts with metal iron and steel, solution is naturally quick deeply to be adsorbed to steel surface, and go deep into endosome rust cleaning, also can be sealed going deep into integrated membrane in pore as rustless, equally play rust inhibition, the more integrated membranes of etch number of times are thicker, antirust more of a specified duration.
(3) metal treatment (by 1:2: add water and mix well use) before plating: electroplating technology requirement is quite high, use water quality requirement high to plating, as not fine and close in used tap water and well water usually to cause piece surface to bubble, easy rust corrosion, serious basic plating is not gone up.Requiring with water of electroplating technology is tight, use pure distilled water and ionized water.When metal spare and accessory parts have removed rust, use multifunction phosphide liquid provided by the invention, there has been one deck blue-black film on spare and accessory parts top layer, gets final product electroplating activity after air-dry, electroplating quality can with plate out effect with the most high-grade pure water and compare favourably.
Multifunction phosphide liquid parco-lubrizing provided by the invention, has high, medium and low and normal temperature phosphating processing mode, through in after high temperature phosphorization process, the hardness (making shellproof, protecting against shock) of metal iron and steel can be improved, wear-resisting (bearing), lubricate.After normal temperature bonderizing, metal iron and steel heat insulation (making automobile top layer sunshade thermal insulation), insulation can be done; The functions such as fire-retardant, fire prevention, insulation, anti-electrostatic, scrubbing are had through the parkerized plastics of normal temperature, rubber.After Phosphating Solution bonderizing of the present invention, improve metal iron and steel, plastics, rubber to the sticking power of all kinds of paint and coating, adsorb; Use together with priming paint and other coating, water tolerance, resistance to gasoline, oil resistant, salt fog resistance, acid resistance can be improved, reach antirust, heat insulation, high temperature resistant, insulation, fire-retardant, eliminate the noise, shockproof effect.
Iron and steel Phosphating Solution of the present invention, takes middle high temperature phosphorization, forms hard phosphatize phosphate coat, and metal iron and steel hardness can be made to improve 80%, and anti-impact force is strong, becomes shellproof metal.If this technology is used on automobile can increase steel plate hardness, improve automobile collision preventing function.
Metallic surface is with after Phosphating Solution bonderizing of the present invention, then sprayed coating, can realize heat insulation, high temperature resistant, insulation, be mainly used in automobile bodies, outdoor steel structure is heat insulation.Spray this Phosphating Solution dry after, spray-applied primer and finish paint, automobile plays sunshade thermal insulation, high temperature resistant, saves the use of hot summer air-conditioning, reduces automobile energy consumption, save gasoline.
Steel surface is with after Phosphating Solution process of the present invention, and spraying 54-11 vinylformic acid vibration-absorbing and silencing damping paint, has good shock resistance, water tolerance, resistance to gasoline, salt fog resistance, acid resistance, damping property.Be used in the vehicles (aircraft, steamer, automobile, train) and play minimizing vibration, noise elimination, heat insulation, antihunt action.
The present embodiment object is to make professional and technical personnel in the field understand technical scheme of the present invention according to it and to be implemented; can not limit the scope of the invention with it; protection scope of the present invention is as the criterion with claims; allly disclose according to the present invention any equivalent formulas or equivalent method and distortion and retouching that technology does; or be directly or indirectly used in other relevant technical field, all fall into protection scope of the present invention.
Claims (8)
1. a multifunction phosphide liquid, is made up of A liquid and B liquid, it is characterized in that: by mass parts, and the ratio of ratio in multifunction phosphide liquid of A liquid and B liquid is 1:0.1-1;
1) by mass parts, the material component of described A liquid comprises: Secondary ammonium phosphate 26-48 part; 85% phosphoric acid 0.9-12 part; Metal-powder 0.8-1.8 part; Gelatin 0.6-1.4 part; Gesso 0.4-10 part; Alum 0.3-0.8 part; Surplus is water;
2) by mass parts, the material component of described B liquid comprises: primary zinc phosphate 20-46 part; Zinc nitrate 38-55 part; Sodium Fluoride 2-3.8 part; Zinc oxide 2-4 part; 85% phosphoric acid 2-6 part; Surplus is water.
2. a kind of multifunction phosphide liquid according to claim 1, is characterized in that: the material component of described A liquid also comprises a small amount of additive and a small amount of promotor; Described additive is one or more in chromic oxide, cupric phosphate, polyhydroxy carboxylic acids or fluorochemicals, and described promotor is molybdate.
3. a kind of multifunction phosphide liquid according to claim 1 and 2, is characterized in that: described metal-powder was silver powder or the aluminium powder of 200 order mesh sieves; Described gelatin is gelatinum.
4. the preparation method of a kind of multifunction phosphide liquid according to claim 1, is characterized in that comprising the following steps:
1) take each material composition of described A liquid and B liquid respectively by the weight part of material each in prescription for subsequent use, wherein gelatin hot water melts, and metal-powder crosses mesh sieve;
2) A liquid is prepared, ready for step 1) Secondary ammonium phosphate and phosphoric acid are slowly added to the water stirring and dissolving evenly, form A liquor, again the gelatin melted, the metal-powder sieved, gesso, alum are added above-mentioned A liquor respectively, after stirring, obtain A liquid;
3) prepare B liquid, ready for step 1) primary zinc phosphate, zinc nitrate, Sodium Fluoride, zinc oxide, 85% phosphoric acid are slowly added to the water respectively, after stirring, obtain B liquid;
4) by step 2) the B liquid prepared of the A liquid prepared, step 3) packages for subsequent use respectively, or in proportion by step 2) to form mixed solution for subsequent use for the B liquid mixing prepared of the A liquid prepared, step 3).
5. the purposes of a kind of multifunction phosphide liquid according to claim 1, it is characterized in that: for the rust cleaning of steelwork, comprise and bridge construction, construction work, large-scale pipeline are produced and the rust cleaning of installation work and marine vessel, steel surface is contacted multifunction phosphide liquid 1-5 minute, complete steel surface rust cleaning.
6. the purposes of a kind of multifunction phosphide liquid according to claim 1, is characterized in that: for new metallic surface process, and by new metal etch multifunction phosphide liquid, added water by 1:3 or 4 by multifunction phosphide liquid and mix well, thin spray 3 times, reaches etch-proof effect.
7. the purposes of a kind of multifunction phosphide liquid according to claim 1, is characterized in that: for electroplating front metal treatment, is added water by multifunction phosphide liquid mix well use by 1:2.
8. the purposes of a kind of multifunction phosphide liquid according to the arbitrary claim of claim 5 to 7, is characterized in that: include high, medium and low and normal temperature phosphating processing mode,
1) iron and steel Phosphating Solution, takes middle high temperature phosphorization, forms hard phosphatize phosphate coat, and metal iron and steel hardness can be made to improve 80%, and anti-impact force is strong, becomes shellproof metal;
2) metallic surface is with after Phosphating Solution bonderizing, then sprayed coating, can realize heat insulation, high temperature resistant, insulation, be mainly used in automobile bodies, outdoor steel structure is heat insulation; Or spray this Phosphating Solution dry after, spray-applied primer and finish paint, automobile plays sunshade thermal insulation, high temperature resistant, saves the use of hot summer air-conditioning, reduces automobile energy consumption, save gasoline;
3) steel surface is with after Phosphating Solution process, and spraying 54-11 vinylformic acid vibration-absorbing and silencing damping paint, has good shock resistance, water tolerance, resistance to gasoline, salt fog resistance, acid resistance, damping property; Be used in the vehicles and comprise aircraft, steamer, automobile and train, play and reduce vibration, noise elimination, heat insulation, antihunt action.
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| CN104109862B (en) * | 2014-08-01 | 2016-04-13 | 武钢集团昆明钢铁股份有限公司 | A kind of water-based antirust and its preparation method and application |
| CN104894549A (en) * | 2015-06-18 | 2015-09-09 | 广西柳州市龙发金属表面处理技术有限公司 | Preparation technology of trivalent chromium black zinc passivating solution |
| CN105296984A (en) * | 2015-11-12 | 2016-02-03 | 镇江市隆盛工具有限公司 | Screw tap handle shrinkage technology |
| CN107620057B (en) * | 2015-12-10 | 2019-01-25 | 吴联凯 | A kind of application method of the phosphating solution for metal processing |
| CN105483681B (en) * | 2015-12-10 | 2018-02-09 | 广东志远环保设备有限公司 | A kind of preparation method of zinc system metal treatment fluid |
| CN105925186A (en) * | 2016-05-12 | 2016-09-07 | 黄健 | Multifunctional anti-rusting agent |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU639964A1 (en) * | 1977-03-16 | 1978-12-30 | Институт Физико-Химических Основ Переработки Минерального Сырья Со Ан Ссср | Zing parkerizing solution |
| JPS5554576A (en) * | 1978-10-13 | 1980-04-21 | Nippon Parkerizing Co Ltd | Forming method for phosphate film of steel |
| NL176281C (en) * | 1973-08-23 | 1985-03-18 | Metallgesellschaft Ag | METHOD FOR PHOSPHATING METALS, IN PARTICULAR IRON AND STEEL. |
| CN88100060A (en) * | 1988-01-19 | 1988-08-03 | 廖运秀 | High efficient rust-removing passivator |
| US4774145A (en) * | 1985-11-07 | 1988-09-27 | Nippondenso Co., Ltd. | Zinc phosphate chemical conversion film and method for forming the same |
| CN1057681A (en) * | 1991-06-29 | 1992-01-08 | 中科院近代物理研究所新技术实验工厂 | Phosphating solution at room temperature and compound method thereof |
| CN1283710A (en) * | 2000-08-02 | 2001-02-14 | 暨南大学 | Phosphonating liquid for cold deformation of iron and steel and its phosphonation process |
| CN1306100A (en) * | 2000-11-16 | 2001-08-01 | 华萱 | Phosphonation process for heteropoly acid system |
| CN1358883A (en) * | 2000-12-14 | 2002-07-17 | 华萱 | Heteropolyacid system phosphorization technology |
| CN1361309A (en) * | 2000-12-28 | 2002-07-31 | 张军 | Medium-temperature phosphorizing liquid for automobile painting |
-
2013
- 2013-08-07 CN CN201310343078.9A patent/CN103397324B/en not_active Expired - Fee Related
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL176281C (en) * | 1973-08-23 | 1985-03-18 | Metallgesellschaft Ag | METHOD FOR PHOSPHATING METALS, IN PARTICULAR IRON AND STEEL. |
| SU639964A1 (en) * | 1977-03-16 | 1978-12-30 | Институт Физико-Химических Основ Переработки Минерального Сырья Со Ан Ссср | Zing parkerizing solution |
| JPS5554576A (en) * | 1978-10-13 | 1980-04-21 | Nippon Parkerizing Co Ltd | Forming method for phosphate film of steel |
| US4774145A (en) * | 1985-11-07 | 1988-09-27 | Nippondenso Co., Ltd. | Zinc phosphate chemical conversion film and method for forming the same |
| CN88100060A (en) * | 1988-01-19 | 1988-08-03 | 廖运秀 | High efficient rust-removing passivator |
| CN1057681A (en) * | 1991-06-29 | 1992-01-08 | 中科院近代物理研究所新技术实验工厂 | Phosphating solution at room temperature and compound method thereof |
| CN1283710A (en) * | 2000-08-02 | 2001-02-14 | 暨南大学 | Phosphonating liquid for cold deformation of iron and steel and its phosphonation process |
| CN1306100A (en) * | 2000-11-16 | 2001-08-01 | 华萱 | Phosphonation process for heteropoly acid system |
| CN1358883A (en) * | 2000-12-14 | 2002-07-17 | 华萱 | Heteropolyacid system phosphorization technology |
| CN1361309A (en) * | 2000-12-28 | 2002-07-31 | 张军 | Medium-temperature phosphorizing liquid for automobile painting |
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