CN103396082A - Baking-free brick using steel slag as main raw material - Google Patents

Baking-free brick using steel slag as main raw material Download PDF

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Publication number
CN103396082A
CN103396082A CN2013103227506A CN201310322750A CN103396082A CN 103396082 A CN103396082 A CN 103396082A CN 2013103227506 A CN2013103227506 A CN 2013103227506A CN 201310322750 A CN201310322750 A CN 201310322750A CN 103396082 A CN103396082 A CN 103396082A
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CN
China
Prior art keywords
slag
raw material
brick
blast furnace
raw materials
Prior art date
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Pending
Application number
CN2013103227506A
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Chinese (zh)
Inventor
刘海锋
巢启
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Guangxi Qili New Materials Science And Technology Co Ltd
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Guangxi Qili New Materials Science And Technology Co Ltd
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Priority to CN2013103227506A priority Critical patent/CN103396082A/en
Publication of CN103396082A publication Critical patent/CN103396082A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to a baking-free brick using steel slag as a main raw material. The steel slag baking-free brick of the known technology is high in preparation cost and high in energy consumption in the production process. The baking-free brick is mainly prepared from the following raw materials in percentage by weight: 3 to 15 percent of sodium silicate, 45 to 60 percent of steel slag, 18 to 30 percent of blast furnace granulating slag, and 15 to 25 percent of superfine slag powder. The baking-free brick is prepared by adding various raw materials into a brick maker according to the sequence of steel slag, blast furnace granulating slag, superfine slag powder and sodium silicate, adding water into the brick maker in a mass ratio of the raw materials to the water of 1:(0.1-0.3), pressing and curing for 7-10 days under the natural condition. The prepared steel slag brick has the advantages of low cost, good stability, high compressive strength, small production site and high production efficiency; by using a large quantity of industrial solid wastes, comprehensive utilization and environmental protection of resources are realized, and the treatment problem of the steel slag is effectively solved.

Description

A kind of non-burning brick take slag as main raw material
Technical field
What the present invention relates to is that a kind of building energy conservation is non-burning brick, and particularly a kind of non-burning brick take slag as main raw material, belong to building material technical field.
Background technology
Slag is a kind of slag that discharges in steelmaking process, it is the melting slag that contains the oxide compounds such as calcium oxide, magnesium oxide, ferric oxide, silicon oxide, aluminum oxide, manganese oxide of finally discharging in order to adjust molten steel composition in steelmaking process, smelt the slag that steel per ton approximately produces 15%-20%, present stage, China approximately had the slag more than 200,000,000 tons pending.To the treatment process of slag, have multiple at present, such as the remelting of ironmaking slag making raw materials recovery, make steel slag cement, slag micro powder, steel slag wall building blocks etc., but the slag that above method is processed only accounts for the last 20% of slag discharge capacity, also has a large amount of slags without use to need to process.
Preparing steel slag brick is an effective means of slag processing, and the building materials investigator has proposed a lot of just preparation methods of slag brick in recent years, has solved certain Technologies of Steel Slag Treatment problem.China Patent No. is that 200810014015.8 patent discloses a kind of steel scoria unburned brick, this invention take Steel-slag Sand, steel-making slag powder, blast furnace slag, lime as raw material through the compression moulding of brick machine, then through maintenance, pass into CO at a certain temperature 2The process of ageing, the deficiency that this invention exists is high to equipment requirements, be in autoclave the ageing certain hour, therefore cause equipment cost high, complex process, the place that production process needs is large, manpower and materials are many, and the steel slag brick cost of final preparation is high, are difficult for promoting.China Patent No. is the preparation that the patent of CN 102976709 A has been announced a kind of steel slag brick, this patent of invention is take slag, cement, flyash, shale as main raw material, after the brick machine is prepared into base, while being dried to a certain degree, enter in kiln and under 900-1200 ℃ and fired 96 hours, obtain goods, this invention weak point is that preparation cost is high, and the production process energy-output ratio is large.Therefore, preparing a kind of unburned steel quarrel brick with low cost, is the useless quarrel that takes full advantage of after steel-making, the effective way that turns waste into wealth.
Summary of the invention
Purpose of the present invention just is to provide the steel slag brick that a kind of with low cost, product performance are stable, ultimate compression strength is high, production technique is simple, production site is little, utilize in a large number simultaneously Industrial Solid Waste, realize the commercial run environmental protection, overcome simultaneously the existing production cost of brick prepared by present same type of material high, the production process complexity, the deficiency that production process energy consumption and site area are large.
The foregoing invention purpose is achieved through the following technical solutions: a kind of non-burning brick take slag as main raw material, and mainly the raw material by following mass percent (wt%) is prepared from:
Water glass 3-15%, slag 45-60%, blast furnace granulated slag 18-30%, slag micropowder 15-25%;
By following method, prepared by above-mentioned raw materials:
(1) proportionally take various raw materials;
(2) order of various raw materials according to slag-blast furnace granulated slag-slag micropowder-water glass being joined in the brick machine, is the ratio of 1 ︰ 0.1-0.3 with the mass ratio of raw material and water, water is added to preparation together in the brick machine, through compression moulding;
(3) maintenance 7-10 days under field conditions (factors).
Described water glass is the service water glass through modification, and modulus is 1.5-2.5, and solid content is 30% commercial goods;
Described slag is a kind of or two kinds of mixtures that form with arbitrary proportion in converter slag, electric furnace slag, and its stability is qualified slag;
Described blast furnace granulated slag is the water-quenched blast-furnace slag that produces in the blast furnace ironmaking process, and its fineness is 5-100 purpose particulate state slag;
Described slag micropowder is that fineness is at the blast furnace granulated slag of 100-600 purpose through fine grinding.
Take the present invention of above-mentioned measure, the non-burning brick not only cost of preparation is low, good stability, production technique are simple, and can also consume in a large number slag, realizes the comprehensive utilization of resource, and the environmental improvement of steel mill is played to significant role.
Embodiment
Embodiment 1
The present invention fills a prescription one:
Component Formula (wt%)
Water glass (m=1.5) 3
Slag 325 orders 20
Slag 45
Blast furnace granulated slag 32
Add up to 100
The preparation method:
Proportionally take various raw materials, the order of various raw materials according to slag-blast furnace granulated slag-slag micropowder-water glass-water joined in the brick machine, and the ratio that is 1 ︰ 0.1 according to the mass ratio of raw material and water adds water, and through compression moulding, maintenance is 7 days under field conditions (factors).
Embodiment 2
The present invention fills a prescription two:
Component Formula (wt%)
Water glass (m=2.1) 7
Slag micropowder 425 orders 15
Slag 48
Blast furnace granulated slag 30
Add up to 100
Preparation and constructional method:
Proportionally take various raw materials, the order of various raw materials according to slag-blast furnace granulated slag-slag micropowder-water glass-water joined in the brick machine, and the ratio that is 1 ︰ 0.2 according to the mass ratio of raw material and water adds water, and through compression moulding, maintenance is 7 days under field conditions (factors).
Embodiment 3
The present invention fills a prescription three:
Component Formula (wt%)
Water glass (m=1.8) 12
Slag micropowder 100 orders 20
Slag 50
Blast furnace granulated slag 18
Add up to 100
Preparation and constructional method:
Proportionally take various raw materials, the order of various raw materials according to slag-blast furnace granulated slag-slag micropowder-water glass-water joined in the brick machine, and the ratio that is 1 ︰ 0.15 according to the mass ratio of raw material and water adds water, and through compression moulding, maintenance is 7 days under field conditions (factors).
Embodiment 4
The present invention fills a prescription four:
Component Formula (wt%)
Water glass (m=2.5) 7
Slag micropowder 600 orders 15
Slag 60
Blast furnace granulated slag 18
Add up to 100
Preparation and constructional method:
Proportionally take various raw materials, the order of various raw materials according to slag-blast furnace granulated slag-slag micropowder-water glass-water joined in the brick machine, and the ratio that is 1 ︰ 0.3 according to the mass ratio of raw material and water adds water, and through compression moulding, maintenance is 7 days under field conditions (factors).
Embodiment 5
The present invention fills a prescription five:
Component Formula (wt%)
Water glass (m=2.2) 15
Slag micropowder 350 orders 20
Blast furnace granulated slag 20
Slag 45
Add up to 100
Preparation and constructional method:
Proportionally take various raw materials, the order of various raw materials according to slag-blast furnace granulated slag-slag micropowder-water glass-water joined in the brick machine, and the ratio that is 1 ︰ 0.22 according to the mass ratio of raw material and water adds water, and through compression moulding, maintenance is 7 days under field conditions (factors).

Claims (5)

1. non-burning brick take slag as main raw material, mainly the raw material by following mass percent (wt%) is prepared from:
Water glass 3-15%, slag 45-60%, blast furnace granulated slag 18-30%, slag micropowder 15-25%;
By following method, prepared by above-mentioned raw materials:
(1) proportionally take various raw materials;
(2) order of various raw materials according to slag-blast furnace granulated slag-slag micropowder-water glass being joined in the brick machine, is the ratio of 1 ︰ 0.1-0.3 with raw material and water in mass ratio, water is added to preparation together in the brick machine, through compression moulding;
(3) maintenance 7-10 days under field conditions (factors).
2. non-burning brick take slag as main raw material as claimed in claim 1, is characterized in that, described water glass is the service water glass after modification, and modulus is at 1.5-2.5, and solid content is 30%.
3. non-burning brick take slag as main raw material as claimed in claim 1, is characterized in that, described slag is a kind of or two kinds of mixtures that form with arbitrary proportion in converter slag, electric furnace slag, and its stability is qualified slag.
4. non-burning brick take slag as main raw material as claimed in claim 1, is characterized in that, described blast furnace granulated slag is the water-quenched blast-furnace slag that produces in the blast furnace ironmaking process, and its fineness is 5-100 purpose particulate state slag.
5. non-burning brick take slag as main raw material as claimed in claim 1, is characterized in that, described slag micropowder is that fineness through fine grinding is at 100-600 purpose blast furnace granulated slag.
CN2013103227506A 2013-07-30 2013-07-30 Baking-free brick using steel slag as main raw material Pending CN103396082A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
CN103396082A true CN103396082A (en) 2013-11-20

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103803939A (en) * 2013-12-30 2014-05-21 广西启利新材料科技股份有限公司 Geopolymer based fibreboard
CN105503152A (en) * 2015-12-25 2016-04-20 青岛佰众化工技术有限公司 High-hardness electric furnace steel slag composite floor tile
CN105503217A (en) * 2015-12-25 2016-04-20 青岛佰众化工技术有限公司 Water-permeable brick made from high-hardness electric furnace steel slag
CN105541295A (en) * 2015-12-25 2016-05-04 青岛佰众化工技术有限公司 Heat reserving thin-type electric furnace steel slag decorative brick
CN105541262A (en) * 2015-12-25 2016-05-04 青岛佰众化工技术有限公司 Electric furnace steel slag composite floor tile
CN106145883A (en) * 2016-08-10 2016-11-23 卓达新材料科技集团威海股份有限公司 A kind of slag building waste is non-burning brick and preparation method thereof
CN107651924A (en) * 2017-10-26 2018-02-02 西南科技大学 A kind of alkali-activated carbonatite high-titanium slag small-sized hollow building block and preparation method thereof
CN115286332A (en) * 2022-08-17 2022-11-04 承德建龙特殊钢有限公司 Waste residue baking-free brick and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1955141A (en) * 2005-10-28 2007-05-02 尹小林 Manufacturing high-strength water-proof fire braking-free brick by industrial subgypsum
CN101250050A (en) * 2008-01-21 2008-08-27 济南鲍德炉料有限公司 Steel slag baking-free brick

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1955141A (en) * 2005-10-28 2007-05-02 尹小林 Manufacturing high-strength water-proof fire braking-free brick by industrial subgypsum
CN101250050A (en) * 2008-01-21 2008-08-27 济南鲍德炉料有限公司 Steel slag baking-free brick

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103803939A (en) * 2013-12-30 2014-05-21 广西启利新材料科技股份有限公司 Geopolymer based fibreboard
CN105503152A (en) * 2015-12-25 2016-04-20 青岛佰众化工技术有限公司 High-hardness electric furnace steel slag composite floor tile
CN105503217A (en) * 2015-12-25 2016-04-20 青岛佰众化工技术有限公司 Water-permeable brick made from high-hardness electric furnace steel slag
CN105541295A (en) * 2015-12-25 2016-05-04 青岛佰众化工技术有限公司 Heat reserving thin-type electric furnace steel slag decorative brick
CN105541262A (en) * 2015-12-25 2016-05-04 青岛佰众化工技术有限公司 Electric furnace steel slag composite floor tile
CN106145883A (en) * 2016-08-10 2016-11-23 卓达新材料科技集团威海股份有限公司 A kind of slag building waste is non-burning brick and preparation method thereof
CN107651924A (en) * 2017-10-26 2018-02-02 西南科技大学 A kind of alkali-activated carbonatite high-titanium slag small-sized hollow building block and preparation method thereof
CN115286332A (en) * 2022-08-17 2022-11-04 承德建龙特殊钢有限公司 Waste residue baking-free brick and preparation method and application thereof
CN115286332B (en) * 2022-08-17 2023-09-15 承德建龙特殊钢有限公司 Waste residue baking-free brick and preparation method and application thereof

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Application publication date: 20131120