CN103382323A - Cold-resistant coating for outdoor facilities and preparation method thereof - Google Patents
Cold-resistant coating for outdoor facilities and preparation method thereof Download PDFInfo
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- CN103382323A CN103382323A CN2013102837942A CN201310283794A CN103382323A CN 103382323 A CN103382323 A CN 103382323A CN 2013102837942 A CN2013102837942 A CN 2013102837942A CN 201310283794 A CN201310283794 A CN 201310283794A CN 103382323 A CN103382323 A CN 103382323A
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Abstract
The invention relates to a cold-resistant coating for outdoor facilities and a preparation method thereof. The cold-resistant coating comprises following ingredients, by weight: 16 to 30 portions of styrene-butadiene latex, 5 to 13 portions of styrene butadiene rubber, 1.2 to 2.8 portions of liquid coumarone resin, 3 to 8 portions of acrylic acid, 0.2 to 0.5 portion of N, N-diethyl thiourea, 25 to 35 portions of silica, 17 to 25 portions of wollastonite, 1 to 2.5 portions of carbon black, 0.03 to 0.05 portion of tributyl phosphate, 0.2 to 0.5 portion of stearic acid, 0.3 to 0.7 portion of polyethylene glycol, 2 to 3.5 portion of acetone and 50 to 65 portions of water. Stone impact resistance of paint films of the cold-resistant coating is 30kg at a low temperature of -30 DEG C; hydrochloric acid corrosion resistant time is 1100h or longer; and aging resistance and wear resistance are excellent, and original luster of the paint films can be kept for a long time.
Description
Technical field
The present invention relates to a kind of outdoor coating and preparation method thereof, relate in particular to a kind of outdoor facilities cold-resistant coating and preparation method thereof.
Background technology
Outdoor facilities is exposed to outdoor, will stand to expose to the weather to drench with rain throughout the year, and surperficial paint film easily is damaged.And the frequency of utilization of outdoor facilities is very high, and surperficial paint film easily is worn, and affects the attractive in appearance of outdoor facilities and uses.In the situation that winter, temperature was low, the easy bursting by freezing of paint film on facility surface, fades, thereby lose original gloss.In case paint film comes off, inner ferrous materials will be exposed in air, the phenomenon such as get rusty, and outdoor facilities just can't normally use, and causes the waste of resource and the loss of economy.
Summary of the invention
The technical problem that solves:, easily aging shortcoming not low temperature resistant with coating for above-mentioned outdoor facilities the invention provides a kind of outdoor facilities with cold-resistant coating and preparation method thereof.
Technical scheme:The cold-resistant coating of outdoor facilities, contain following composition in mass parts:
16～30 parts of styrene-butadiene latexes
5～13 parts, styrene-butadiene rubber(SBR)
1.2～2.8 parts of liquid coumarone indene resins
3～8 parts, vinylformic acid
N, 0.2～0.5 part of N-diethyl thiourea
25～35 parts of silicon-dioxide
17～25 parts of wollastonites
1～2.5 part of carbon black
0.03～0.05 part of tributyl phosphate
0.2～0.5 part of stearic acid
0.3～0.7 part of polyoxyethylene glycol
2～3.5 parts, acetone
50～65 parts, water.
The cold-resistant coating of outdoor facilities described above, contain following composition in mass parts:
20～27 parts of styrene-butadiene latexes
7～12 parts, styrene-butadiene rubber(SBR)
1.5～2.5 parts of liquid coumarone indene resins
5～8 parts, vinylformic acid
N, 0.3～0.45 part of N-diethyl thiourea
27～32 parts of silicon-dioxide
17～22 parts of wollastonites
1.4～2.1 parts of carbon blacks
0.035～0.045 part of tributyl phosphate
0.25～0.4 part of stearic acid
0.45～0.6 part of polyoxyethylene glycol
2.5～3.2 parts, acetone
55～62 parts, water.
Solid content in styrene-butadiene latexes described above is 60%.
Outdoor facilities described above is as follows with the preparation process of cold-resistant coating:
The first step: with styrene-butadiene latexes, styrene-butadiene rubber(SBR), vinylformic acid, liquid coumarone indene resin, N, N-diethyl thiourea, stearic acid and tributyl phosphate add in agitator, are to react 2.5～3.5h under 70～80 ℃ in temperature;
Second step: adding silicon-dioxide, wollastonite, carbon black, polyoxyethylene glycol, acetone and water again in agitator, is to stir under 900～1000rpm at rotating speed, filters discharging, obtains the cold-resistant coating of outdoor facilities.
Beneficial effect:Outdoor facilities provided by the invention cold-resistant coating and preparation method thereof, the paint film of this coating anti-stone under-30 ℃ of low temperature hits 30kg, salt tolerant acid corrosion time 〉=1100h, and it is ageing-resistant and wear-resisting effective, and paint film can keep original gloss permanency.
Embodiment
Embodiment 1
The present embodiment provides a kind of outdoor facilities cold-resistant coating, contains following composition in mass parts:
16 parts of styrene-butadiene latexes
5 parts, styrene-butadiene rubber(SBR)
1.2 parts of liquid coumarone indene resins
3 parts, vinylformic acid
N, 0.2 part of N-diethyl thiourea
25 parts of silicon-dioxide
17 parts of wollastonites
1 part of carbon black
0.03 part of tributyl phosphate
0.2 part of stearic acid
0.3 part of polyoxyethylene glycol
2 parts, acetone
50 parts, water.
Outdoor facilities is as follows with the preparation process of cold-resistant coating:
The first step: with styrene-butadiene latexes, styrene-butadiene rubber(SBR), vinylformic acid, liquid coumarone indene resin, N, N-diethyl thiourea, stearic acid and tributyl phosphate add in agitator, are to react 2.5～3.5h under 70～80 ℃ in temperature;
Second step: adding silicon-dioxide, wollastonite, carbon black, polyoxyethylene glycol, acetone and water again in agitator, is to stir under 900～1000rpm at rotating speed, filters discharging, obtains the cold-resistant coating of outdoor facilities.
Embodiment 2
The present embodiment provides a kind of outdoor facilities cold-resistant coating, contains following composition in mass parts:
20 parts of styrene-butadiene latexes
7 parts, styrene-butadiene rubber(SBR)
1.5 parts of liquid coumarone indene resins
5 parts, vinylformic acid
N, 0.3 part of N-diethyl thiourea
27 parts of silicon-dioxide
17 parts of wollastonites
1.4 parts of carbon blacks
0.035 part of tributyl phosphate
0.25 part of stearic acid
0.45 part of polyoxyethylene glycol
2.5 parts, acetone
55 parts, water.
Outdoor facilities is as follows with the preparation process of cold-resistant coating:
The first step: with styrene-butadiene latexes, styrene-butadiene rubber(SBR), vinylformic acid, liquid coumarone indene resin, N, N-diethyl thiourea, stearic acid and tributyl phosphate add in agitator, are to react 2.5～3.5h under 70～80 ℃ in temperature;
Second step: adding silicon-dioxide, wollastonite, carbon black, polyoxyethylene glycol, acetone and water again in agitator, is to stir under 900～1000rpm at rotating speed, filters discharging, obtains the cold-resistant coating of outdoor facilities.
Embodiment 3
The present embodiment provides a kind of outdoor facilities cold-resistant coating, contains following composition in mass parts:
27 parts of styrene-butadiene latexes
12 parts, styrene-butadiene rubber(SBR)
2.5 parts of liquid coumarone indene resins
8 parts, vinylformic acid
N, 0.45 part of N-diethyl thiourea
32 parts of silicon-dioxide
22 parts of wollastonites
2.1 parts of carbon blacks
0.045 part of tributyl phosphate
0.4 part of stearic acid
0.6 part of polyoxyethylene glycol
3.2 parts, acetone
62 parts, water.
Outdoor facilities is as follows with the preparation process of cold-resistant coating:
The first step: with styrene-butadiene latexes, styrene-butadiene rubber(SBR), vinylformic acid, liquid coumarone indene resin, N, N-diethyl thiourea, stearic acid and tributyl phosphate add in agitator, are to react 2.5～3.5h under 70～80 ℃ in temperature;
Second step: adding silicon-dioxide, wollastonite, carbon black, polyoxyethylene glycol, acetone and water again in agitator, is to stir under 900～1000rpm at rotating speed, filters discharging, obtains the cold-resistant coating of outdoor facilities.
Embodiment 4
The present embodiment provides a kind of outdoor facilities cold-resistant coating, contains following composition in mass parts:
24 parts of styrene-butadiene latexes
10 parts, styrene-butadiene rubber(SBR)
2 parts of liquid coumarone indene resins
6.5 parts, vinylformic acid
N, 0.39 part of N-diethyl thiourea
30 parts of silicon-dioxide
20 parts of wollastonites
1.7 parts of carbon blacks
0.04 part of tributyl phosphate
0.33 part of stearic acid
0.52 part of polyoxyethylene glycol
2.8 parts, acetone
59 parts, water.
Outdoor facilities is as follows with the preparation process of cold-resistant coating:
The first step: with styrene-butadiene latexes, styrene-butadiene rubber(SBR), vinylformic acid, liquid coumarone indene resin, N, N-diethyl thiourea, stearic acid and tributyl phosphate add in agitator, are to react 2.5～3.5h under 70～80 ℃ in temperature;
Second step: adding silicon-dioxide, wollastonite, carbon black, polyoxyethylene glycol, acetone and water again in agitator, is to stir under 900～1000rpm at rotating speed, filters discharging, obtains the cold-resistant coating of outdoor facilities.
The above-mentioned outdoor facilities of stating embodiment 1～embodiment 4 technical performance index of cold-resistant coating, its detected result is as follows:
Detected result
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Anti-10%HCl | 1100h | 1158h | 1210h | 1253h |
| The temper(ing) time | 1078h | 1089h | 1105h | 1198h |
| Low temperature resistant (anti-stone hits 30kg) | -30℃ | -32℃ | -33℃ | -35℃ |
The above outdoor facilities that the embodiment of the present invention is provided is described in detail with cold-resistant coating and preparation method thereof, for one of ordinary skill in the art, thought according to the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (4)
1. outdoor facilities with cold-resistant coating, is characterized in that containing following composition in mass parts:
16～30 parts of styrene-butadiene latexes
5～13 parts, styrene-butadiene rubber(SBR)
1.2～2.8 parts of liquid coumarone indene resins
3～8 parts, vinylformic acid
N, 0.2～0.5 part of N-diethyl thiourea
25～35 parts of silicon-dioxide
17～25 parts of wollastonites
1～2.5 part of carbon black
0.03～0.05 part of tributyl phosphate
0.2～0.5 part of stearic acid
0.3～0.7 part of polyoxyethylene glycol
2～3.5 parts, acetone
50～65 parts, water.
2. outdoor facilities according to claim 1 with cold-resistant coating, is characterized in that containing following composition in mass parts:
20～27 parts of styrene-butadiene latexes
7～12 parts, styrene-butadiene rubber(SBR)
1.5～2.5 parts of liquid coumarone indene resins
5～8 parts, vinylformic acid
N, 0.3～0.45 part of N-diethyl thiourea
27～32 parts of silicon-dioxide
17～22 parts of wollastonites
1.4～2.1 parts of carbon blacks
0.035～0.045 part of tributyl phosphate
0.25～0.4 part of stearic acid
0.45～0.6 part of polyoxyethylene glycol
2.5～3.2 parts, acetone
55～62 parts, water.
3. outdoor facilities according to claim 1 with cold-resistant coating, is characterized in that the solid content in described styrene-butadiene latexes is 60%.
4. outdoor facilities as claimed in claim 1 with the preparation method of cold-resistant coating, is characterized in that the preparation process of the method is as follows:
The first step: with styrene-butadiene latexes, styrene-butadiene rubber(SBR), vinylformic acid, liquid coumarone indene resin, N, N-diethyl thiourea, stearic acid and tributyl phosphate add in agitator, are to react 2.5～3.5h under 70～80 ℃ in temperature;
Second step: adding silicon-dioxide, wollastonite, carbon black, polyoxyethylene glycol, acetone and water again in agitator, is to stir under 900～1000rpm at rotating speed, filters discharging, obtains the cold-resistant coating of outdoor facilities.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310283794.2A CN103382323B (en) | 2013-07-08 | 2013-07-08 | Outdoor facilities Cold resistant paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310283794.2A CN103382323B (en) | 2013-07-08 | 2013-07-08 | Outdoor facilities Cold resistant paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103382323A true CN103382323A (en) | 2013-11-06 |
| CN103382323B CN103382323B (en) | 2016-02-24 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310283794.2A Expired - Fee Related CN103382323B (en) | 2013-07-08 | 2013-07-08 | Outdoor facilities Cold resistant paint and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694856A (en) * | 2013-12-20 | 2014-04-02 | 海安县吉程机械有限公司 | Cold-resistant anticorrosive coating |
| CN107629557A (en) * | 2017-09-30 | 2018-01-26 | 浙江瀚镪自动化设备股份有限公司 | A kind of belt conveyor belt surface coating paste |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2128753A1 (en) * | 1994-01-24 | 1995-07-25 | John M. Chacko | Water-based coating composition |
| CN1167796A (en) * | 1997-06-10 | 1997-12-17 | 中国科学院广州化学研究所 | Non-asphalt emulsion type waterproof coating and preparation method thereof |
| CN102140281A (en) * | 2011-02-21 | 2011-08-03 | 广东新粤建材有限公司 | Coating for protecting back face of stone |
| CN102443322A (en) * | 2010-10-12 | 2012-05-09 | 3M创新有限公司 | Paint composition and coating product prepared from same |
-
2013
- 2013-07-08 CN CN201310283794.2A patent/CN103382323B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2128753A1 (en) * | 1994-01-24 | 1995-07-25 | John M. Chacko | Water-based coating composition |
| CN1167796A (en) * | 1997-06-10 | 1997-12-17 | 中国科学院广州化学研究所 | Non-asphalt emulsion type waterproof coating and preparation method thereof |
| CN102443322A (en) * | 2010-10-12 | 2012-05-09 | 3M创新有限公司 | Paint composition and coating product prepared from same |
| CN102140281A (en) * | 2011-02-21 | 2011-08-03 | 广东新粤建材有限公司 | Coating for protecting back face of stone |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694856A (en) * | 2013-12-20 | 2014-04-02 | 海安县吉程机械有限公司 | Cold-resistant anticorrosive coating |
| CN107629557A (en) * | 2017-09-30 | 2018-01-26 | 浙江瀚镪自动化设备股份有限公司 | A kind of belt conveyor belt surface coating paste |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103382323B (en) | 2016-02-24 |
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| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: SUZHOU XINQIXUN NETWORK CO., LTD. Free format text: FORMER OWNER: WUJIANG WUHUA HARDWARE CO., LTD. Effective date: 20150703 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Tan Xing Inventor before: Zhuang Yadong |
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| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: ZHUANG YADONG TO: TAN XING |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20150703 Address after: Song Ling Zhen Wujiang District of Suzhou City, Jiangsu province 215200 High Road No. 249 Applicant after: The novel fast Networks Co., Ltd in Suzhou Address before: Wujiang City, Suzhou City, Jiangsu province 215200 Li Zhendong Village Bridge Bridge Applicant before: Wujiang Wuhua Hardware Products Co., Ltd. |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
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| CB03 | Change of inventor or designer information |
Inventor after: Zhuang Yadong Inventor before: Tan Xing |
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| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160324 Address after: Wujiang District of Suzhou City, Jiangsu province 215200 Li Zhendong Village Bridge Bridge Patentee after: Wujiang Wuhua Hardware Products Co., Ltd. Address before: Song Ling Zhen Wujiang District of Suzhou City, Jiangsu province 215200 High Road No. 249 Patentee before: The novel fast Networks Co., Ltd in Suzhou |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160224 Termination date: 20160708 |