CN103360585A - Fluorine-modified high scratch resistance light resin and preparation method thereof - Google Patents
Fluorine-modified high scratch resistance light resin and preparation method thereof Download PDFInfo
- Publication number
- CN103360585A CN103360585A CN2012100951737A CN201210095173A CN103360585A CN 103360585 A CN103360585 A CN 103360585A CN 2012100951737 A CN2012100951737 A CN 2012100951737A CN 201210095173 A CN201210095173 A CN 201210095173A CN 103360585 A CN103360585 A CN 103360585A
- Authority
- CN
- China
- Prior art keywords
- resin
- fluorine
- scratch resistance
- high scratch
- resistance light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011347 resin Substances 0.000 title claims abstract description 46
- 229920005989 resin Polymers 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 35
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000011737 fluorine Substances 0.000 claims abstract description 34
- 239000002253 acid Substances 0.000 claims abstract description 17
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims abstract description 11
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000007599 discharging Methods 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 21
- 230000004048 modification Effects 0.000 claims description 19
- 238000012986 modification Methods 0.000 claims description 19
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- 238000010792 warming Methods 0.000 claims description 14
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 229940051250 hexylene glycol Drugs 0.000 claims description 5
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 4
- 229920001225 polyester resin Polymers 0.000 abstract description 2
- 239000004645 polyester resin Substances 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 abstract 2
- 238000004321 preservation Methods 0.000 abstract 2
- 238000001914 filtration Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000010186 staining Methods 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 6
- 238000009835 boiling Methods 0.000 description 5
- -1 hydro Phthalic anhydrides Chemical class 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000004922 lacquer Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to fluorine-modified high scratch resistance light resin and a preparation method thereof. The fluorine-modified high scratch resistance light resin comprises the following components in percentage by weight: 26-32% of isocaprylic acid, 10-15% of phthalic anhydride, 1-5% of maleic anhydride, 1-5% of trimethylolpropane, 5-20% of dihydric alcohol, 10-25% of fluoride-containing resin, 10-15% of solvent and 0.01-0.5% of additive. The preparation method of the fluorine-modified high scratch resistance light resin comprises the following steps of: sequentially adding the isocaprylic acid, the phthalic anhydride, the maleic anhydride, the trimethylolpropane, the dihydric alcohol, the fluoride-containing resin, the solvent and the additive to a reaction kettle, meanwhile, stirring and heating to 140-150 DEG C, and carrying out heat preservation for 2 hours; and uniformly heating to 200+/-2 DEG C within four hours, then carrying out heat preservation till the viscosity and the acid value are qualified, reducing the temperature, filtering and discharging. The fluorine-containing low polymer modified polyester resin prepared by the method has the advantages of staining resistance, fingerprint resistance and high scratch resistance and can meet the coating requirements on high-grade furniture.
Description
Technical field
The invention belongs to the technical field of coating, specifically, is the high scratch resistance light of a kind of fluorine modification resin and preparation method thereof.
Background technology
Owing to having the very high C of more bond energy-F chemical bond in the fluoropolymer molecular chain structure; the fluorine atom close-packed arrays has played good provide protection around polymer carbon; therefore, fluoro-resin has high thermostability and unreactiveness (acid and alkali-resistance, solvent resistance etc.).In addition, very poor etc. to its wettability such as very low surface energy, oil and water because the fluorine resin material also has special surface property, therefore fluorine resin material has the good characteristics such as not viscosity, didirtresistance, oilness and wear resistance.But the simple shortcomings such as price is high, poor adhesive force that exist again when fluoro-resin is used for wood lacquer coating.The polyester that isocaprylic acid is produced has very high second-order transition temperature, has good hardness and certain snappiness is arranged simultaneously, and gained water-white resin has good anti-yellowing property, high gloss, good leveling property, damage resistant.Fluoro-resin is carried out modification to vibrin, can overcome the deficiency of fluorine resin material, the fluorine modified polyester resin that obtains has the two excellent performance, can satisfy the application needs of top-grade furniture.
Summary of the invention
The objective of the invention is to overcome the existing shortcoming and defect of fluorine resin material in the prior art, the high scratch resistance light of a kind of fluorine modification resin and preparation method thereof is provided.The present invention can be used as the top-grade furniture wood lacquer.The present invention designs the high scratch resistance light of a kind of fluorine modification resin, and it is characterized in that: described resin is comprised of following constituent and weight percent:
Component proportion %
Isocaprylic acid 26-32;
Tetra hydro Phthalic anhydride 10-15;
MALEIC ANHYDRIDE 1-5;
TriMethylolPropane(TMP) 1-5;
Dibasic alcohol 5-20;
Fluorine resin 10-25;
Solvent 10-15;
Auxiliary agent 0.01-0.5.
It is characterized in that: described dibasic alcohol is ethylene glycol, propylene glycol, BDO, glycol ether, 1, any one or its mixture of 6-hexylene glycol, neopentyl glycol.It is characterized in that, described fluorine resin is that hydroxyl value is 25-60 mg KOH/g, and molecular weight is at the oiliness fluorocarbon resin of 2000-30000.It is characterized in that: described solvent comprises any one of toluene, dimethylbenzene.It is characterized in that; Described auxiliary agent comprises any one of Hypophosporous Acid, 50, triphenyl phosphite.The preparation method of the high scratch resistance light of a kind of fluorine modification resin, it is characterized in that: in reactor, add successively isocaprylic acid, Tetra hydro Phthalic anhydride, MALEIC ANHYDRIDE, TriMethylolPropane(TMP), dibasic alcohol, fluorine resin, solvent, auxiliary agent, start simultaneously and stir and heating, be warming up to 140-150oC, be incubated 2 hours; Be incubated to viscosity, the qualified rear cooling of acid number after evenly being warming up to 200 ± 2 ℃ with 4 hours, filter discharging.
The present invention adopts the high scratch resistance light of the fluorine modification resin of above-mentioned composition and engineering preparation, has resistant, anti-impression of the hand, high scratch resistant advantage.Coating surface is smooth, and adhesivity is little, is difficult for contaminated; Has good anti-yellowing property, high gloss, good leveling property; Can satisfy the application needs of top-grade furniture.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Should be understood that following examples are only for explanation the present invention but not for limiting scope of the present invention.
The experimental technique of unreceipted actual conditions in the following example, usually according to normal condition, or the condition that manufacturer provides is carried out.
Embodiment 1
The preparation method of the high scratch resistance light of a kind of fluorine modification resin may further comprise the steps:
(1) in the 2000 mL four-hole boiling flasks that whipping appts, thermometer and logical nitrogen protection be housed, adds 450 g isocaprylic acids, 150 g Tetra hydro Phthalic anhydrides, 40 g MALEIC ANHYDRIDE, 35 g TriMethylolPropane(TMP)s, 150 g 1 successively, 4-butyleneglycol, 90 g neopentyl glycol, (ETERLON 4101 for 289 g fluorine resins, Changxing Chemical Industry Co Ltd), 230 g toluene, 5g Hypophosporous Acid, 50, start simultaneously and stir and heating, be warming up to 140oC, be incubated 2 hours;
(2) be incubated after evenly being warming up to 200 ± 2 ℃ with 4 hours to acid number less than 12 mg KOH/g, viscosity is greater than 20000 mPas(25 ° C) after cooling, filter discharging.
Embodiment 2
The preparation method of the high scratch resistance light of a kind of fluorine modification resin may further comprise the steps:
(1) in the 2000 mL four-hole boiling flasks that whipping appts, thermometer and logical nitrogen protection be housed, add 432 g isocaprylic acids, 172 g Tetra hydro Phthalic anhydrides, 35 g MALEIC ANHYDRIDE, 38 g TriMethylolPropane(TMP)s, 135 g ethylene glycol, 78 g neopentyl glycol successively, (ETERLON 4101 for 320 g fluorine resins, Changxing Chemical Industry Co Ltd), 230 g toluene, 5g Hypophosporous Acid, 50, start simultaneously and stir and heating, be warming up to 145oC, be incubated 2 hours;
(2) be incubated after evenly being warming up to 200 ± 2 ℃ with 4 hours to acid number less than 12 mg KOH/g, viscosity is greater than 20000 mPas(25 ° C) after cooling, filter discharging.
Embodiment 3
The preparation method of the high scratch resistance light of a kind of fluorine modification resin may further comprise the steps:
(1) in the 2000 mL four-hole boiling flasks that whipping appts, thermometer and logical nitrogen protection be housed, adds 410 g isocaprylic acids, 190 g Tetra hydro Phthalic anhydrides, 30 g MALEIC ANHYDRIDE, 40 g TriMethylolPropane(TMP)s, 200 g propylene glycol, 85 g 1 successively, the 6-hexylene glycol, (ETERLON 41011 for 236 g fluorine resins, Changxing Chemical Industry Co Ltd), 240 g toluene, 5g triphenyl phosphite, start simultaneously and stir and heating, be warming up to 150oC, be incubated 2 hours;
(2) be incubated after evenly being warming up to 200 ± 2 ℃ with 4 hours to acid number less than 12 mg KOH/g, viscosity is greater than 20000 mPas(25 ° C) after cooling, filter discharging.
Embodiment 4
The preparation method of the high scratch resistance light of a kind of fluorine modification resin may further comprise the steps:
(1) in the 2000 mL four-hole boiling flasks that whipping appts, thermometer and logical nitrogen protection be housed, adds 320 g isocaprylic acids, 150 g Tetra hydro Phthalic anhydrides, 50 g MALEIC ANHYDRIDE, 25 g TriMethylolPropane(TMP)s, 100 g propylene glycol, 50 g 1 successively, the 6-hexylene glycol, (ETERLON 41011 for 150 g fluorine resins, Changxing Chemical Industry Co Ltd), 150 g toluene, 5g triphenyl phosphite, start simultaneously and stir and heating, be warming up to 150oC, be incubated 2 hours;
(2) be incubated after evenly being warming up to 200 ± 2 ℃ with 4 hours to acid number less than 12 mg KOH/g, viscosity is greater than 20000 mPas(25 ° C) after cooling, filter discharging.
Embodiment 5
The preparation method of the high scratch resistance light of a kind of fluorine modification resin may further comprise the steps:
(1) in the 2000 mL four-hole boiling flasks that whipping appts, thermometer and logical nitrogen protection be housed, adds 260g isocaprylic acid, 150 g Tetra hydro Phthalic anhydrides, 50 g MALEIC ANHYDRIDE, 50 g TriMethylolPropane(TMP)s, 100 g propylene glycol, 50 g 1 successively, the 6-hexylene glycol, (ETERLON 41011 for 185 g fluorine resins, Changxing Chemical Industry Co Ltd), 150 g toluene, 5g triphenyl phosphite, start simultaneously and stir and heating, be warming up to 150oC, be incubated 2 hours;
(2) be incubated after evenly being warming up to 200 ± 2 ℃ with 4 hours to acid number less than 12 mg KOH/g, viscosity is greater than 20000 mPas(25 ° C) after cooling, filter discharging.
Above demonstration and described ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in above-described embodiment and the specification sheets just illustrates principle of the present invention; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (6)
1. the high scratch resistance light of fluorine modification resin, it is characterized in that: described resin is comprised of following constituent and weight percent:
Component proportion %
Isocaprylic acid 26-32;
Tetra hydro Phthalic anhydride 10-15;
MALEIC ANHYDRIDE 1-5;
TriMethylolPropane(TMP) 1-5;
Dibasic alcohol 5-20;
Fluorine resin 10-25;
Solvent 10-15;
Auxiliary agent 0.01-0.5.
2. the high scratch resistance light of a kind of fluorine modification according to claim 1 resin, it is characterized in that: described dibasic alcohol is ethylene glycol, propylene glycol, BDO, glycol ether, 1, any one or its mixture of 6-hexylene glycol, neopentyl glycol.
3. the high scratch resistance light of a kind of fluorine modification according to claim 1 resin is characterized in that, described fluorine resin is that hydroxyl value is 25-60 mg KOH/g, and molecular weight is at the oiliness fluorocarbon resin of 2000-30000.
4. the high scratch resistance light of a kind of fluorine modification according to claim 1 resin, it is characterized in that: described solvent comprises any one of toluene, dimethylbenzene.
5. the high scratch resistance light of a kind of fluorine modification according to claim 1 resin is characterized in that; Described auxiliary agent comprises any one of Hypophosporous Acid, 50, triphenyl phosphite.
6. the preparation method of the high scratch resistance light of an a kind of fluorine modification as claimed in claim 1 resin, it is characterized in that: in reactor, add successively isocaprylic acid, Tetra hydro Phthalic anhydride, MALEIC ANHYDRIDE, TriMethylolPropane(TMP), dibasic alcohol, fluorine resin, solvent, auxiliary agent, start simultaneously and stir and heating, be warming up to 140-150oC, be incubated 2 hours; Be incubated to viscosity, the qualified rear cooling of acid number after evenly being warming up to 200 ± 2 ℃ with 4 hours, filter discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210095173.7A CN103360585B (en) | 2012-03-31 | 2012-03-31 | A kind of fluorine richness high scratch resistance light resin and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210095173.7A CN103360585B (en) | 2012-03-31 | 2012-03-31 | A kind of fluorine richness high scratch resistance light resin and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103360585A true CN103360585A (en) | 2013-10-23 |
| CN103360585B CN103360585B (en) | 2016-06-08 |
Family
ID=49362903
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210095173.7A Active CN103360585B (en) | 2012-03-31 | 2012-03-31 | A kind of fluorine richness high scratch resistance light resin and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103360585B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106103541A (en) * | 2014-02-19 | 2016-11-09 | 关西涂料株式会社 | Copolymer resin and coating composition |
| CN111087841A (en) * | 2019-12-23 | 2020-05-01 | 中昊北方涂料工业研究设计院有限公司 | Anticorrosive coating for surface of magnesium alloy substrate |
| CN111592817A (en) * | 2020-04-14 | 2020-08-28 | 四川轻化工大学 | Fluorocarbon modified water-based alkyd resin coating and preparation method and application thereof |
| CN116891676A (en) * | 2023-07-13 | 2023-10-17 | 珠海优泰科技有限公司 | Preparation method of powder control scraping plate |
| CN116891676B (en) * | 2023-07-13 | 2024-10-25 | 珠海优泰科技有限公司 | Preparation method of powder control scraping plate |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3255131A (en) * | 1961-05-10 | 1966-06-07 | Minnesota Mining & Mfg | Fluorochemical-containing varnishes |
| JP2004503690A (en) * | 2000-06-12 | 2004-02-05 | スリーエム イノベイティブ プロパティズ カンパニー | Water / oil repellent composition |
| CN101139434A (en) * | 2007-09-30 | 2008-03-12 | 大连理工大学 | Fluorinated polyesters with low surface energy and preparation method thereof |
| CN101265324A (en) * | 2008-05-07 | 2008-09-17 | 大连理工大学 | Fluoroalkyl group end sealing super-branching polyhydroxypolyester and preparation method thereof |
| CN102199280A (en) * | 2011-04-08 | 2011-09-28 | 浙江大学 | Fluoro-polyester resin and preparation method and application thereof |
-
2012
- 2012-03-31 CN CN201210095173.7A patent/CN103360585B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3255131A (en) * | 1961-05-10 | 1966-06-07 | Minnesota Mining & Mfg | Fluorochemical-containing varnishes |
| JP2004503690A (en) * | 2000-06-12 | 2004-02-05 | スリーエム イノベイティブ プロパティズ カンパニー | Water / oil repellent composition |
| CN101139434A (en) * | 2007-09-30 | 2008-03-12 | 大连理工大学 | Fluorinated polyesters with low surface energy and preparation method thereof |
| CN101265324A (en) * | 2008-05-07 | 2008-09-17 | 大连理工大学 | Fluoroalkyl group end sealing super-branching polyhydroxypolyester and preparation method thereof |
| CN102199280A (en) * | 2011-04-08 | 2011-09-28 | 浙江大学 | Fluoro-polyester resin and preparation method and application thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106103541A (en) * | 2014-02-19 | 2016-11-09 | 关西涂料株式会社 | Copolymer resin and coating composition |
| US9683074B2 (en) | 2014-02-19 | 2017-06-20 | Kansai Paint Co., Ltd. | Copolymer resin and coating composition |
| CN106103541B (en) * | 2014-02-19 | 2018-03-30 | 关西涂料株式会社 | Copolymer resin and coating composition |
| CN111087841A (en) * | 2019-12-23 | 2020-05-01 | 中昊北方涂料工业研究设计院有限公司 | Anticorrosive coating for surface of magnesium alloy substrate |
| CN111087841B (en) * | 2019-12-23 | 2023-01-03 | 中昊北方涂料工业研究设计院有限公司 | Anticorrosive coating for surface of magnesium alloy substrate |
| CN111592817A (en) * | 2020-04-14 | 2020-08-28 | 四川轻化工大学 | Fluorocarbon modified water-based alkyd resin coating and preparation method and application thereof |
| CN111592817B (en) * | 2020-04-14 | 2022-03-11 | 四川轻化工大学 | Fluorocarbon modified water-based alkyd resin coating and preparation method and application thereof |
| CN116891676A (en) * | 2023-07-13 | 2023-10-17 | 珠海优泰科技有限公司 | Preparation method of powder control scraping plate |
| CN116891676B (en) * | 2023-07-13 | 2024-10-25 | 珠海优泰科技有限公司 | Preparation method of powder control scraping plate |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103360585B (en) | 2016-06-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112566990B (en) | Polyester resin composition, powder coating and workpiece | |
| CN101445593B (en) | Aquosity short oil alkyd resin and preparation method thereof | |
| CN103555120B (en) | A kind of polyacrylate grafting modified poly ester water-borne coatings and its preparation method | |
| CN105694651A (en) | A preparing method of water-based self-crosslinking acrylic acid modified polyurethane matte resin | |
| Wei et al. | Facile synthesis of a castor oil‐based hyperbranched acrylate oligomer and its application in UV‐curable coatings | |
| CN109575255B (en) | Preparation method of odorless quick-drying alkyd resin | |
| JP2013521357A5 (en) | ||
| CN103319971A (en) | Metalized aqueous fluorocarbon coating for exterior wall and preparation method thereof | |
| CN103360585A (en) | Fluorine-modified high scratch resistance light resin and preparation method thereof | |
| TW201041986A (en) | Powder coating composition comprising a polyester and a crosslinker with oxirane groups providing improved corrosion resistance to a substrate coated therewith | |
| CN105199053A (en) | Recoat-able polishing-free unsaturated polyester resin for piano lacquer and preparation method of unsaturated polyester resin | |
| CN1090659C (en) | Universal primer for non-stick finish | |
| CN113004776A (en) | Water-based self-repairing coating and application thereof | |
| CN110527370A (en) | A kind of polyurea modified fluorine carbon reflective heat-insulation paint and preparation method thereof | |
| CN114957616B (en) | Fluorine-containing hydroxyl resin and preparation method and application thereof | |
| CN102942839A (en) | Nanofiller modified solvent-free insulating paint and preparation method thereof | |
| CN112646156A (en) | Polyphenylene sulfide ether ketone modified waterborne alkyd resin and preparation method thereof | |
| CN117467315B (en) | Fluorocarbon weather-resistant resin powder coating and preparation method thereof | |
| CN108383989A (en) | A kind of epoxy acrylic resin and its preparation method and application of two degrees of functionality | |
| CN110092895B (en) | Air-drying waterborne alkyd resin and preparation method thereof | |
| CN104152048B (en) | A kind of new rosin resin for painting | |
| CN112029030A (en) | Water-based acrylic resin for organic silicon modified glass paint and preparation method and application thereof | |
| CN112521591A (en) | Polyester resin with lasting high temperature resistance and excellent hardness for powder coating and preparation method thereof | |
| CN115558403A (en) | Ultraviolet photocureable coating for stainless steel condenser tube | |
| CN107523197A (en) | A kind of novel aqueous polyester resin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Applicant after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Applicant after: ZHANCHEN PAINT GROUP Co.,Ltd. Applicant after: Beijing Zhanchen Chemical Co.,Ltd. Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant before: Shanghai Vision Chemical Co.,Ltd. Applicant before: ZHANCHEN PAINT GROUP Co.,Ltd. Applicant before: Beijing Zhanchen Chemical Co.,Ltd. |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: SHANGHAI FUCHEN CHEMICAL CO. LTD. TO: SHANGHAI ZHANCHEN PAINT CO., LTD. |
|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Applicant after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Applicant after: China Zhanchen New Materials Group Co.,Ltd. Applicant after: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. Address before: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Applicant before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Applicant before: ZHANCHEN PAINT GROUP Co.,Ltd. Applicant before: Beijing Zhanchen Chemical Co.,Ltd. |
|
| COR | Change of bibliographic data | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Co-patentee after: China Zhanchen New Materials Group Co.,Ltd. Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee after: Beijing zhanchen Intelligent Property Management Co.,Ltd. Address before: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Co-patentee before: China Zhanchen New Materials Group Co.,Ltd. Patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200702 Address after: 201799 8555 Songze Avenue, Qingpu District, Shanghai Co-patentee after: Zhuhai zhanchen New Material Co.,Ltd. Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Address before: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Co-patentee before: China Zhanchen New Materials Group Co.,Ltd. Patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: Beijing zhanchen Intelligent Property Management Co.,Ltd. |
|
| TR01 | Transfer of patent right |