CN103352374B - High-grade sport footwear fabric of good permeability and preparation method thereof - Google Patents
High-grade sport footwear fabric of good permeability and preparation method thereof Download PDFInfo
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- CN103352374B CN103352374B CN201310276766.8A CN201310276766A CN103352374B CN 103352374 B CN103352374 B CN 103352374B CN 201310276766 A CN201310276766 A CN 201310276766A CN 103352374 B CN103352374 B CN 103352374B
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Abstract
A kind of high-grade sport footwear fabric of good permeability, it is characterized in that being made up of two layers of compound, base material is cloth, upper strata is polyvinyl chloride resin layer, upper strata is made up of the raw material of following weight portion: SG-4 type polyvinyl chloride resin 70-80, diisopropanolamine (DIPA) 1-2, morpholine 1-2, impact resistant polystyrene 4-5, dibutyl tin laurate 2-3, zinc oxide 2-3, magnesia 1-2, aluminium oxide 2-3, barium sulfate 5-7, MTES 2-3, vinyltriethoxysilane 1-2, triglycidyl isocyanurate 5-7, dibasic lead phosphite 1-2, diglycol benzoic ether 2-3, coumarone 1-2, 2-ethylamino 17 alkenyl imidazoline 1-2, protein powder 10-12, polyvinyl alcohol 2-3, modified clay powder 3-4 the present invention is improved by recipe optimization, protein increases the gas permeability of synthetic leather, impact resistant polystyrene adds toughness and the intensity of synthetic leather, there is the naturally comfortable feel being similar to natural leather and having, 3-5 is not easy breakage or tears damage, is suitable for as Fabric Used for Sport Shoes.
Description
Technical field
The invention belongs to a kind of chemical synthesis leather facing material processing technique field, specifically a kind of polyvinyl chloride synthetic leather and preparation method thereof.
Background technology
The hydrolysis that polyvinyl chloride synthetic leather has, wear-resisting, scratch resistance, the advantage such as fire-retardant, be widely used in the aspects such as high-grade sport footwear, case and bag, sofa, but it still has many deficiencies at aspects such as flexibility, gas permeability, feel, resistance to complications, needs to improve its recipe optimization.
Summary of the invention
High-grade sport footwear fabric that the object of the present invention is to provide a kind of good permeability and preparation method thereof, the synthetic leather good product quality of production.
Object of the present invention can be achieved through the following technical solutions:
A high-grade sport footwear fabric for good permeability, it is characterized in that being made up of two layers of compound, base material is cloth, and upper strata is polyvinyl chloride resin layer, and upper strata is made up of the raw material of following weight portion:
SG-4 type polyvinyl chloride resin 70-80, diisopropanolamine (DIPA) 1-2, morpholine 1-2, impact resistant polystyrene 4-5, dibutyl tin laurate 2-3, zinc oxide 2-3, magnesia 1-2, aluminium oxide 2-3, barium sulfate 5-7, MTES 2-3, vinyltriethoxysilane 1-2, triglycidyl isocyanurate 5-7, dibasic lead phosphite 1-2, diglycol benzoic ether 2-3, coumarone 1-2, 2-ethylamino 17 alkenyl imidazoline 1-2, protein powder 10-12, polyvinyl alcohol 2-3, modified clay powder 3-4,
Described modified clay powder obtains by the following method:
Calcine 3-4 hour at clay being put into 460-480 DEG C, take out, cooling, pulverize; Add the aluminium nitride, the sodium phosphate trimer of 3-4%, the Rosa Damascana of 2-3%, the morpholine of 2-3%, the di-n-octyl-4-isothiazoline-3-ketone of 3-4% that are equivalent to clay powders weight 5-8% again, mix and blend 30-40 minute, and then spray into the Silane coupling agent KH550 being equivalent to clay powders weight 3-5%, under 13000-16000 rev/min, stir 60-70 minute, to obtain final product.
The preparation method of the high-grade sport footwear fabric of described good permeability, is characterized in that comprising the following steps:
A) by diisopropanolamine (DIPA), morpholine, impact resistant polystyrene, dibutyl tin laurate, zinc oxide, magnesia, aluminium oxide, barium sulfate, MTES, vinyltriethoxysilane, triglycidyl isocyanurate, dibasic lead phosphite, 10-15 minute is stirred at 135-150 DEG C, then, cooling 100-105 DEG C, add other surplus stock, mixed at high speed 5-8 minute, then, under expect mill carry out abundant mixing after fit to adhesive tape machine, upper strata is attached on base material;
B) product is through surface effect process;
C) finished product inspection is qualified, dispatches from the factory.
The present invention is improved by recipe optimization, and protein increases the gas permeability of synthetic leather, and impact resistant polystyrene adds toughness and the intensity of synthetic leather, has the naturally comfortable feel being similar to natural leather and having; 3-5 is not easy breakage or tears damage, is suitable for as Fabric Used for Sport Shoes.
Detailed description of the invention
A high-grade sport footwear fabric for good permeability, be made up of two layers of compound, base material is cloth, and upper strata is polyvinyl chloride resin layer, and upper strata is made up of the raw material of following weight portion (kilogram):
SG-4 type polyvinyl chloride resin 70, diisopropanolamine (DIPA) 2, morpholine 1, impact resistant polystyrene 5, dibutyl tin laurate 2, zinc oxide 2, magnesia 1, aluminium oxide 2, barium sulfate 7, MTES 2, vinyltriethoxysilane 1, triglycidyl isocyanurate 5, dibasic lead phosphite 2, diglycol benzoic ether 3, coumarone 1,2-ethylamino 17 alkenyl imidazoline 1, protein powder 12, polyvinyl alcohol 2, modified clay powder 4;
The preparation method of the high-grade sport footwear fabric of described good permeability, comprises the following steps:
A) by diisopropanolamine (DIPA), morpholine, impact resistant polystyrene, dibutyl tin laurate, zinc oxide, magnesia, aluminium oxide, barium sulfate, MTES, vinyltriethoxysilane, triglycidyl isocyanurate, dibasic lead phosphite, 10-15 minute is stirred at 135-150 DEG C, then, cooling 100-105 DEG C, add other surplus stock, mixed at high speed 5-8 minute, then, under expect mill carry out abundant mixing after fit to adhesive tape machine, upper strata is attached on base material;
B) product is through surface effect process;
C) finished product inspection is qualified, dispatches from the factory.
Described modified clay powder obtains by the following method:
Calcine 4 hours at clay being put into 460-480 DEG C, take out, cooling, pulverize; Add the aluminium nitride, the sodium phosphate trimer of 3%, Rosa Damascana, the morpholine of 3%, the di-n-octyl-4-isothiazoline-3-ketone of 3% of 2% that are equivalent to clay powders weight 5% again, mix and blend 30-40 minute, and then spray into the Silane coupling agent KH550 being equivalent to clay powders weight 3%, under 13000-16000 rev/min, stir 60-70 minute, to obtain final product.
Synthetic leather of the present invention detects: radial stretch breaking strength/broadwise stretch breaking strength > 435N/3CM, footpath/filling-tear resistance > 29N ,-10 DEG C of low temperature flexibility can reach resistance to tortuous 30,000 times, and degradation does not ftracture.Good air permeability.
Claims (2)
1. the high-grade sport footwear fabric of a good permeability, it is characterized in that being made up of two layers of compound, base material is cloth, upper strata is polyvinyl chloride resin layer, upper strata is made up of the raw material of following weight portion: SG-4 type polyvinyl chloride resin 70-80, diisopropanolamine (DIPA) 1-2, morpholine 1-2, impact resistant polystyrene 4-5, dibutyl tin laurate 2-3, zinc oxide 2-3, magnesia 1-2, aluminium oxide 2-3, barium sulfate 5-7, MTES 2-3, vinyltriethoxysilane 1-2, triglycidyl isocyanurate 5-7, dibasic lead phosphite 1-2, diglycol benzoic ether 2-3, coumarone 1-2, 2-ethylamino 17 alkenyl imidazoline 1-2, protein powder 10-12, polyvinyl alcohol 2-3, modified clay powder 3-4, described modified clay powder obtains by the following method: calcine 3-4 hour at clay being put into 460-480 DEG C, takes out, cooling, pulverize, add the aluminium nitride, the sodium phosphate trimer of 3-4%, the Rosa Damascana of 2-3%, the morpholine of 2-3%, the Kathon of 3-4% that are equivalent to clay powders weight 5-8% again, mix and blend 30-40 minute, and then spray into the Silane coupling agent KH550 being equivalent to clay powders weight 3-5%, under 13000-16000 rev/min, stir 60-70 minute, to obtain final product.
2. the preparation method of the high-grade sport footwear fabric of good permeability according to claim 1, is characterized in that comprising the following steps:
A) by diisopropanolamine (DIPA), morpholine, impact resistant polystyrene, dibutyl tin laurate, zinc oxide, magnesia, aluminium oxide, barium sulfate, MTES, vinyltriethoxysilane, triglycidyl isocyanurate, dibasic lead phosphite, 10-15 minute is stirred at 135-150 DEG C, then, cooling 100-105 DEG C, add other surplus stock, mixed at high speed 5-8 minute, then, under expect mill carry out abundant mixing after fit to adhesive tape machine, upper strata is attached on base material;
B) product is through surface effect process;
C) finished product inspection is qualified, dispatches from the factory.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310276766.8A CN103352374B (en) | 2013-07-03 | 2013-07-03 | High-grade sport footwear fabric of good permeability and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310276766.8A CN103352374B (en) | 2013-07-03 | 2013-07-03 | High-grade sport footwear fabric of good permeability and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103352374A CN103352374A (en) | 2013-10-16 |
| CN103352374B true CN103352374B (en) | 2015-12-09 |
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| CN201310276766.8A Active CN103352374B (en) | 2013-07-03 | 2013-07-03 | High-grade sport footwear fabric of good permeability and preparation method thereof |
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Families Citing this family (1)
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| CN105542344A (en) * | 2016-01-21 | 2016-05-04 | 苏州市景荣科技有限公司 | Bending-resistant air-permeable polyvinyl chloride vamp material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002864A (en) * | 2010-12-24 | 2011-04-06 | 揭阳市中诚化学工业有限公司 | PVC synthetic leather for vamp of high-grade sneaker and production method thereof |
| CN102219967A (en) * | 2011-06-07 | 2011-10-19 | 刘立文 | Modified polyvinyl chloride composite material and preparation process of modified polyvinyl chloride composite material |
| CN102995454A (en) * | 2012-10-23 | 2013-03-27 | 合肥市安山涂层织物有限公司 | Polyvinyl chloride synthetic leather for sports shoes and manufacturing method of polyvinyl chloride synthetic leather |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04304242A (en) * | 1991-03-29 | 1992-10-27 | Ajinomoto Co Inc | Resin composition and molding made therefrom |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002864A (en) * | 2010-12-24 | 2011-04-06 | 揭阳市中诚化学工业有限公司 | PVC synthetic leather for vamp of high-grade sneaker and production method thereof |
| CN102219967A (en) * | 2011-06-07 | 2011-10-19 | 刘立文 | Modified polyvinyl chloride composite material and preparation process of modified polyvinyl chloride composite material |
| CN102995454A (en) * | 2012-10-23 | 2013-03-27 | 合肥市安山涂层织物有限公司 | Polyvinyl chloride synthetic leather for sports shoes and manufacturing method of polyvinyl chloride synthetic leather |
Non-Patent Citations (1)
| Title |
|---|
| 合成革在体育用品中的应用;徐桂玲;《中国皮革》;20090730;第38卷(第13期);第51-55页 * |
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Effective date of registration: 20200107 Address after: 366300 Changting Tengfei Economic Development Zone, Changting County, Longyan, Fujian Patentee after: Fujian sky textile new material Co., Ltd. Address before: 237161 Qianjin Road, Lu'an economic and Technological Development Zone, Anhui Patentee before: Liuan Sanxi Leather Products Co., Ltd. |