CN103350499A - Screw for extruding UHMWPE (Ultra High Molecular Weight PolyEthylene) - Google Patents

Screw for extruding UHMWPE (Ultra High Molecular Weight PolyEthylene) Download PDF

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Publication number
CN103350499A
CN103350499A CN2013103155762A CN201310315576A CN103350499A CN 103350499 A CN103350499 A CN 103350499A CN 2013103155762 A CN2013103155762 A CN 2013103155762A CN 201310315576 A CN201310315576 A CN 201310315576A CN 103350499 A CN103350499 A CN 103350499A
Authority
CN
China
Prior art keywords
screw
molecular weight
uhmwpe
weight polyethylene
extruding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013103155762A
Other languages
Chinese (zh)
Inventor
刘卫祥
王泉
黄学祥
倪中华
孙桂芳
刘晓军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU LIANGUAN HIGH-TECH Co Ltd
Original Assignee
JIANGSU LIANGUAN HIGH-TECH Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU LIANGUAN HIGH-TECH Co Ltd filed Critical JIANGSU LIANGUAN HIGH-TECH Co Ltd
Priority to CN2013103155762A priority Critical patent/CN103350499A/en
Publication of CN103350499A publication Critical patent/CN103350499A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses a screw for extruding UHMWPE (Ultra High Molecular Weight PolyEthylene), and aims to solve the problems of high viscosity, poor fluidity, and susceptibility to fracture and degradation during the manufacturing process of the UHMWPE. Pins and protective screens are arranged on the screw; the rotary speed and the shearing rate are relatively low (the rotary speed is 1-10 r/min, the shearing rate is 40-400 r/min); the compression ratio of the screw is optimized. The extruder screw provided by the invention has a good mixing effect, and can prevent melt fracture and UHMWPE degradation to prevent material blockage in the screw groove, so as to increase the extruding efficiency of the extruder and the mass of the UHMWPE.

Description

A kind of screw rod of extruding ultrahigh molecular weight polyethylene
Technical field
The present invention relates to a kind of screw rod of producing ultra-high molecular weight polyethylene.
Background technology
Ultra-high molecular weight polyethylene (Ultra-High Molecular Weight Polyethylene UHMWPE) was at first succeeded in developing with Ziegler catalyst by U.S. Unichem in nineteen fifty-seven.This is a kind of line polymer, molecular weight is usually 1,000,000-5,000,000, degree of crystallinity is 65-85%, density is 0.92-0.96g/cm3, compare with numerous polymeric materials, UHMWPE has the advantages that coefficient of friction is little, abrasion are low, chemical resistance is good, but also has the good characteristics such as shock-resistant, resistance to pressure, frost resistance, heat insulating ability, self lubricity, ant-scaling, stress cracking resistance, wholesomeness.These good characteristics make UHMWPE tubing have important practical value.Be described as " the novel thermoplastic engineering material that is emerging rapidly ", in various fields, have important practical value.
At present, when ultra-high molecular weight polyethylene being produced the plastic products such as various tubing, sheet material, profile shapes as raw material, extrusion by melting and mould forming method have usually been adopted.So-called extrusion by melting refers to: the raw material that enters extruding machine barrel is extruded behind conveying, compacting, the fusion plastification realizing under the effect of screw rod, and the material of extruding enters die for molding again.As everyone knows, the UHMWPE molecular weight is unordered entanglement between the extraordinary strand up to millions of, and its molecule segment shows as melt viscosity up to 108Pa.S to the warm-up movement delay of response.Just because of the molecular weight of UHMWPE is very large, viscosity is high, does not almost have flowability, does not have viscous state, only has rubbery state, so easily cause material to expand in extruder when adopting common screw to extrude, back pressure is very high, can't realize extruding; Critical shear rate is extremely low in addition, and melt fracture easily occurs; Because the coefficient of sliding friction is low, easily skids in the time of charging; Heat release in the extrusion and accumulation of heat are difficult to control, cause macromolecules degradation, so that the molecular weight less than 1,000,000 of goods, cause all premium properties of ultra-high molecular weight polyethylene also to weaken thereupon and disappear, seriously restrict the application of UHMWPE, become the hot subject of material educational circles and industrial circle joint exploration since the eighties.
Summary of the invention
The invention provides a kind of screw rod of extruding ultrahigh molecular weight polyethylene.
For solving the problem that exists in the ultra-high molecular weight polyethylene production process, the technical step that the present invention adopts is: the ultra-high molecular weight polyethylene raw material of molecular weight 〉=2,000,000 is sent in the extruder, pass through successively after conveying, compacting and the heating, realized extruding according to specific technique by extruder.
Pin and barrier head are set on the above-mentioned extruder screw, thereby material is cut apart, converged with mixing, make the material in the screw channel even.
Above-mentioned screw speed is that 1-10 turns/min, and shear rate is that 40-400 turns/min, because both are all lower, the ultra-high molecular weight polyethylene that can avoid melt fracture to cause can not moulding.
Compression ratio to above-mentioned screw rod has adopted optimization process, can prevent that material from stopping up in screw channel and cause machine barrel to burst.
The specific embodiment
The screw rod of a kind of extruding ultrahigh molecular weight polyethylene of the present invention the steps include: the ultra-high molecular weight polyethylene raw material of molecular weight 〉=2,000,000 is sent in the extruder, passes through successively after conveying, compacting and the heating, is extruded by extruder.At screw rod pin and barrier head are set, keeping screw speed in the extrusion is that 1-10 turns/min, and shear rate is that 40-400 turns/min, and has optimized the compression ratio of screw rod.
The present invention arranges pin and barrier head at screw rod, can cut apart material, converge with mixing, makes the material in the screw channel even; Lower screw speed and shear rate can prevent melt fracture, avoid the degraded of ultra-high molecular weight polyethylene, thereby improve its Forming Quality; The screw compression ratio of optimizing can prevent that material from stopping up and cause machine barrel to burst in screw channel.

Claims (3)

1. the screw rod of claim 1 extruding ultrahigh molecular weight polyethylene is characterized in that: pin and barrier head are set on the described screw rod.
2. the screw rod of claim 2 a kind of extruding ultrahigh molecular weight polyethylene according to claim 1, it is characterized in that: described screw speed is that 1-10 turns/min, shear rate is that 40-400 turns/min.
3. claim 3 is characterized in that according to the screw rod of claims 1 described a kind of extruding ultrahigh molecular weight polyethylene: described screw compression ratio is optimized processing.
CN2013103155762A 2013-07-25 2013-07-25 Screw for extruding UHMWPE (Ultra High Molecular Weight PolyEthylene) Pending CN103350499A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2013103155762A CN103350499A (en) 2013-07-25 2013-07-25 Screw for extruding UHMWPE (Ultra High Molecular Weight PolyEthylene)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2013103155762A CN103350499A (en) 2013-07-25 2013-07-25 Screw for extruding UHMWPE (Ultra High Molecular Weight PolyEthylene)

Publications (1)

Publication Number Publication Date
CN103350499A true CN103350499A (en) 2013-10-16

Family

ID=49306958

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2013103155762A Pending CN103350499A (en) 2013-07-25 2013-07-25 Screw for extruding UHMWPE (Ultra High Molecular Weight PolyEthylene)

Country Status (1)

Country Link
CN (1) CN103350499A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105061806A (en) * 2015-07-22 2015-11-18 浦江县金鑫废旧物资回收有限公司 Recovery process of ultra-high molecular weight polyethylene waste

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105061806A (en) * 2015-07-22 2015-11-18 浦江县金鑫废旧物资回收有限公司 Recovery process of ultra-high molecular weight polyethylene waste
CN105061806B (en) * 2015-07-22 2017-12-22 浦江县金鑫废旧物资回收有限公司 A kind of recovery process of ultra-high molecular weight polyethylene discarded object

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Legal Events

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C06 Publication
PB01 Publication
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20131016