CN103350032A - Strontium ore beneficiation method - Google Patents

Strontium ore beneficiation method Download PDF

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Publication number
CN103350032A
CN103350032A CN2013102350310A CN201310235031A CN103350032A CN 103350032 A CN103350032 A CN 103350032A CN 2013102350310 A CN2013102350310 A CN 2013102350310A CN 201310235031 A CN201310235031 A CN 201310235031A CN 103350032 A CN103350032 A CN 103350032A
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Prior art keywords
strontium
ore
obtains
ore deposit
flotation
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CN2013102350310A
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Inventor
邱为农
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NANJING JINYAN STRONTIUM INDUSTRY Co Ltd
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NANJING JINYAN STRONTIUM INDUSTRY Co Ltd
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Priority to CN2013102350310A priority Critical patent/CN103350032A/en
Publication of CN103350032A publication Critical patent/CN103350032A/en
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Abstract

The invention provides a strontium ore beneficiation method. The strontium ore beneficiation method comprises the following steps: crushing selected raw ore, performing ball milling, grading, performing sulfur ore flotation first and then performing strontium flotation on ore powder which meets requirements. The strontium ore beneficiation method adopts a full flotation process, so that the resource recovery rate of the strontium ore is improved, the recovery rate of strontium sulphate is improved from about 70% in the prior art to above 93%, and the concentrate grade is kept at 72%.

Description

A kind of strontium ore deposit beneficiation method
Technical field
The present invention relates to the technique of preparing field, particularly a kind of strontium ore deposit technique of preparing.
Background technology
Ore dressing claims again " mineral processing ", exactly the useful constituent in the ore is extracted by certain method.With physics or chemical method with the valuable mineral in the raw mineral materials and useless mineral (usually claiming gangue) or toxic mineral separately, or the technical process that multiple valuable mineral is separated.
Strontium ore deposit technique of preparing mainly contains the modes such as gravity separation, flotation.
Gravity separation be utilize be sorted the difference of relative density between mineral grain, granularity, shape and in medium (water, air or the larger liquid of other relative densities) movement rate and direction different, make it beneficiation method separated from one another.Gravity separation process middling particle will be subject to mechanical force that gravity (if in centrifugal force field then mainly be centrifugal force), equipment applies and the active force of medium, the ingenious combination of these power just makes the different ore particle of density produce different movement velocity and movement locus, finally can make them separated from one another.Gravity separation is widely used in processing coal, non-ferrous metal, rare metal, precious metal ore, also is used for the processing to non-metallic ores such as asbestos, diamonds.Floatation is once called as floating separation, is to use more a kind of beneficiating method in the mineral processing production, is to utilize the difference of mineral surfaces physicochemical properties to select a kind of method of minute ore.
Gravity separation is suitable for the higher ore deposit of the grade of ore, and content of strontium is higher in the mine tailing, and the bit comparison of Commercial Ore product is low, and the rate of recovery of strontium is lower.
 
Summary of the invention
The present invention proposes the beneficiation method in a kind of low-grade strontium ore deposit, reduces the environmental protection treatment expense, has improved the grade of Commercial Ore, and has improved the energy-saving and emission-reduction level that strontium is produced.
A kind of strontium of the present invention ore deposit beneficiation method may further comprise the steps:
1) obtains milling ore from crude ore bin.
2) milling ore is carried out fragmentation.
3) breaking ores is carried out ball milling.
4) the ball milling ore that obtains of ball milling carries out classification, and classification obtains satisfactory breeze and coarse fodder.The coarse fodder that classification is obtained carries out ball milling together with water again.
5) the satisfactory breeze of classification is put into agitator, in agitator, add medicament and stir.
6) the stirring material that stirring is obtained carries out flotation and selects sulphur.
7) flotation is selected the breeze that obtains behind the sulphur carry out the strontium flotation.
8) flotation is selected in the strontium step remaining ore deposit, selected strontium ore deposit then to carry out mine tailing to process.
Milling ore can be the lower ore of head grade.
Fragmentation to milling ore comprises coarse crushing, again the coarse crushing ore that obtains is put into reciprocating sieve.The ore that obtains by reciprocating sieve vibrations carries out in small, broken bits again, and the ore in small, broken bits that obtains in small, broken bits is still put into reciprocating sieve, obtains breaking ores.
Flotation is selected sulphur to comprise and is selected sulphur, concentrator is put in the sulphur ore deposit of selecting, and passes through filtering means dehydration again, obtains at last the sulphur concentrate.
The strontium flotation comprises that fast choosing selects strontium, then concentrator is put in the ore deposit of selecting, and passes through filtering means dehydration again, obtain the strontium concentrate, it is selected that a part of selecting strontium to obtain soon selects the strontium ore deposit to carry out soon, and concentrator is still put in the selected selected strontium ore deposit that obtains, refilter dehydration, obtain the strontium concentrate.
The mine tailing processing comprises puts into concentrator to remaining ore deposit, passes through filtering means dehydration again, obtains mine tailing.
The invention provides a kind of strontium ore deposit beneficiation method, milling ore through behind the crushing raw ore, is entered the grind grading stage, satisfactory breeze adds flotation agent, enters flotation device and carries out ore dressing.At first carry out the sulphur flotation, reclaim pyrite, then carry out the strontium flotation, high-grade pyrite and strontium ore deposit through the thickening filtration dehydration, namely can be used as Commercial Ore respectively.
The buoyancy ore dressing can be processed the lower ore deposit of head grade, and the product bit comparison of Commercial Ore is high, and the rate of recovery of strontium is also higher, the Sulfur iron ore of association in the ore can be separated simultaneously, reduces the discharging of sulfur dioxide in the strontium carbonate production.
Process using bulk flotation technological process of the present invention improves the strontium ore resource rate of recovery, and the strontium sulfate rate of recovery rises to more than 93% by original about 70%, and concentrate grade remains on 72%.
 
Description of drawings
Fig. 1 is the schematic flow sheet of strontium ore deposit beneficiation method according to an embodiment of the invention.
Fig. 2 is the schematic flow sheet of the crushing raw ore step in the beneficiation method of strontium ore deposit according to an embodiment of the invention.
Fig. 3 is the schematic flow sheet that the sulphur step is selected in the according to an embodiment of the invention flotation in the beneficiation method of strontium ore deposit.
Fig. 4 is the schematic flow sheet of the strontium flotation step in the beneficiation method of strontium ore deposit according to an embodiment of the invention.
Fig. 5 is the schematic flow sheet of the mine tailing treatment step in the beneficiation method of strontium ore deposit according to an embodiment of the invention.
 
The specific embodiment
For above-mentioned purpose of the present invention, feature and advantage can be become apparent more, below in conjunction with accompanying drawing the specific embodiment of the present invention is described in detail, it will be more clear making above-mentioned and other purpose of the present invention, Characteristics and advantages.Reference numeral identical in whole accompanying drawings is indicated identical part.Deliberately do not draw in proportion accompanying drawing, focus on illustrating purport of the present invention.
Strontium of the present invention ore deposit beneficiation method through behind the crushing raw ore, enters the grind grading stage with milling ore, and satisfactory breeze adds flotation agent, enters flotation device and carries out ore dressing.At first select the sulphur flotation, reclaim pyrite, then carry out the strontium flotation, high-grade pyrite and strontium ore deposit through the thickening filtration dehydration, namely can be used as Commercial Ore respectively.
Process using bulk flotation technological process of the present invention improves the strontium ore resource rate of recovery, and the strontium sulfate rate of recovery rises to more than 93% by original about 70%, and concentrate grade remains on 72%.
According to one embodiment of present invention, strontium of the present invention ore deposit beneficiation method specifically may further comprise the steps.
Step 101 is obtained milling ore from crude ore bin.Milling ore can be the lower ore of head grade.
Step 102 is carried out fragmentation with milling ore.In conjunction with Fig. 2, the fragmentation of milling ore is comprised step 201 coarse crushing, in step 202 the coarse crushing ore that obtains is put into reciprocating sieve again.The ore that obtains by reciprocating sieve vibrations enters step 203 again and carries out in small, broken bitsly, and the ore in small, broken bits that obtains in small, broken bits is still put into reciprocating sieve, obtains breaking ores.
Step 103, the breaking ores that reciprocating sieve is obtained carries out ball milling.
The ball milling ore that step 104, ball milling obtain carries out classification, and classification obtains satisfactory breeze and coarse fodder.The coarse fodder that classification is obtained enters step 103 again, and water carries out ball milling together.。
Step 105 is put into agitator with the satisfactory breeze of classification, adds medicament and stir in agitator.
Step 106, the stirring material that stirring is obtained carries out flotation and selects sulphur.In conjunction with Fig. 3, flotation selects sulphur to comprise that step 301 selects sulphur, then enters step 302, and concentrator is put in the sulphur ore deposit of selecting, and passes through step 303 again, carries out filtering means dehydration, obtains at last the sulphur concentrate.
Step 107 selects the breeze that obtains behind the sulphur to carry out the strontium flotation flotation.Referring to Fig. 4, the strontium flotation comprises the fast strontium that selects of step 401, then enter step 402, concentrator is put in the ore deposit of selecting, pass through again step 403 filtering means dehydration, obtain the strontium concentrate, the part that step 401 soon selects strontium to obtain is selected the strontium ore deposit to enter step 404 to carry out selectedly, the selected selected strontium ore deposit that obtains is still entered step 402, put into concentrator soon, pass through again step 403 filtering means dehydration, obtain the strontium concentrate.
Step 108, the mine tailing processing is then carried out in remaining ore deposit, selected strontium ore deposit in the strontium flotation step.In conjunction with Fig. 5, mine tailing is processed and is comprised step 501, and concentrator is put in remaining ore deposit, passes through step 502 filtering means dehydration again, obtains mine tailing.
The buoyancy ore dressing can be processed the lower ore deposit of head grade, and the product bit comparison of Commercial Ore is high, and the rate of recovery of strontium is also higher, the Sulfur iron ore of association in the ore can be separated simultaneously, reduces the discharging of sulfur dioxide in the strontium carbonate production.
The invention solves the ore dressing problem in low-grade strontium ore deposit, the pyrite of association can be separated simultaneously, reduce the environmental protection treatment expense, improved the grade of Commercial Ore, improve the energy-saving and emission-reduction level that strontium carbonate is produced.
In above description, a lot of details have been set forth so that fully understand the present invention.But above description only is preferred embodiment of the present invention, and the present invention can implement much to be different from alternate manner described here, so the present invention is not subjected to the restriction of top disclosed implementation.Any skilled personnel are not breaking away from the technical solution of the present invention scope situation simultaneously, all can utilize method and the technology contents of above-mentioned announcement that technical solution of the present invention is made many possible changes and modification, or be revised as the equivalent embodiment of equivalent variations.Every content that does not break away from technical solution of the present invention according to any simple modification, equivalent variations and the modification that technical spirit of the present invention is done above embodiment, all still belongs in the scope of technical solution of the present invention protection.

Claims (7)

1. a strontium ore deposit beneficiation method is characterized in that, may further comprise the steps:
1) obtains milling ore from crude ore bin;
2) milling ore is carried out fragmentation;
3) breaking ores is carried out ball milling;
4) the ball milling ore that obtains of ball milling carries out classification, and classification obtains satisfactory breeze and coarse fodder, and the coarse fodder that classification is obtained carries out ball milling together with water again;
5) the satisfactory breeze of classification is put into agitator, in agitator, add medicament and stir;
6) the stirring material that stirring is obtained carries out flotation and selects sulphur;
7) flotation is selected the breeze that obtains behind the sulphur carry out the strontium flotation;
8) the mine tailing processing is then carried out in remaining ore deposit, selected strontium ore deposit in the strontium flotation step.
2. strontium according to claim 1 ore deposit beneficiation method is characterized in that milling ore can be the lower ore of head grade in the step 1).
3. strontium according to claim 1 ore deposit beneficiation method is characterized in that the step 6) flotation is selected sulphur to comprise and selected sulphur, concentrator is put in the sulphur ore deposit of selecting, and passes through filtering means dehydration again, obtains at last the sulphur concentrate.
4. strontium according to claim 1 ore deposit beneficiation method, it is characterized in that, the flotation of step 7) strontium comprises that fast choosing selects strontium, then concentrator is put in the ore deposit of selecting, passed through again filtering means dehydration, obtain the strontium concentrate, it is selected that a fast part of selecting strontium to obtain selects the strontium ore deposit to carry out soon, concentrator is still put in the selected selected strontium ore deposit that obtains, refiltered dehydration, obtain the strontium concentrate.
5. strontium according to claim 1 ore deposit beneficiation method, it is characterized in that, step 2) fragmentation of milling ore comprised coarse crushing, again the coarse crushing ore that obtains is put into reciprocating sieve, the ore that obtains by the reciprocating sieve vibrations carries out in small, broken bits again, the ore in small, broken bits that obtains in small, broken bits is still put into reciprocating sieve, obtains breaking ores.
6. strontium according to claim 1 ore deposit beneficiation method is characterized in that, the step 8) mine tailing is processed and comprised concentrator is put in remaining ore deposit, passes through filtering means dehydration again, obtains mine tailing.
7. a strontium ore deposit beneficiation method is characterized in that, milling ore through after the fragmentation, is carried out ball milling and classification, and satisfactory breeze at first carries out the sulphur flotation, then carries out the strontium flotation.
CN2013102350310A 2013-06-14 2013-06-14 Strontium ore beneficiation method Pending CN103350032A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109047039A (en) * 2018-09-19 2018-12-21 南京金焰锶业有限公司 A kind of low-grade strontium mine green optional equipment and technique again
CN109806966A (en) * 2019-02-21 2019-05-28 中国地质科学院矿产综合利用研究所 Beneficiation method for comprehensively recovering strontium minerals from rare earth tailings

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4043902A (en) * 1975-06-06 1977-08-23 American Cyanamid Company Tri-carboxylated and tetra-carboxylated fatty acid aspartates as flotation collectors
CN102716807A (en) * 2012-06-20 2012-10-10 南京金焰锶业有限公司 Ore dressing method for strontium ore deposit

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4043902A (en) * 1975-06-06 1977-08-23 American Cyanamid Company Tri-carboxylated and tetra-carboxylated fatty acid aspartates as flotation collectors
CN102716807A (en) * 2012-06-20 2012-10-10 南京金焰锶业有限公司 Ore dressing method for strontium ore deposit

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
唐德坤等: "天青石矿石的选矿工艺", 《化工矿山技术》 *
陈滨: "青海省天青石矿的选矿工艺设计", 《工程设计与建筑》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109047039A (en) * 2018-09-19 2018-12-21 南京金焰锶业有限公司 A kind of low-grade strontium mine green optional equipment and technique again
CN109806966A (en) * 2019-02-21 2019-05-28 中国地质科学院矿产综合利用研究所 Beneficiation method for comprehensively recovering strontium minerals from rare earth tailings

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Application publication date: 20131016