CN103342501A - Waterborne artificial stone and preparation method thereof - Google Patents
Waterborne artificial stone and preparation method thereof Download PDFInfo
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- CN103342501A CN103342501A CN2013102744026A CN201310274402A CN103342501A CN 103342501 A CN103342501 A CN 103342501A CN 2013102744026 A CN2013102744026 A CN 2013102744026A CN 201310274402 A CN201310274402 A CN 201310274402A CN 103342501 A CN103342501 A CN 103342501A
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- rostone
- emulsion
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- polyurethane
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
Abstract
The invention provides a formula of an artificial stone and a preparation method thereof. The artificial stone is prepared from a waterborne high polymer material and an inorganic material, wherein the waterborne high polymer material is selected from one or more of an acrylate emulsion, a silicone acrylic emulsion, a styrene-acrylic emulsion, a polyurethane modified acrylate emulsion, a veova 10-acrylate emulsion, a vinyl acetate-acrylate emulsion, a waterborne polyurethane dispersant, an organic silicon modified polyurethane dispersant, a waterborne amino resin, a waterborne epoxy resin and an epoxy modified acrylic emulsion. The preparation method comprises the following steps of: uniformly mixing the waterborne high polymer material, the inorganic material and a pigment, decompressing and setting, standing by, and grinding to obtain the high-quality artificial stone which is high in mechanical performance, flame-retardant, staining-resistant and low in volatile organic compound (VOC).
Description
Technical field
The present invention relates to a kind of prescription for the manufacture of rostone and preparation method, belong to field of new.
Background technology
The rostone formal name used at school is entity plane materiel (Solid Surfacing Material), typically refers to rostone entity plane materiel, rostone quartzite, rostone hilllock stone etc.It is a kind of novel environment-friendly composite material.Compare traditional construction materials such as stainless steel, pottery, rostone is diverse in function not only, and color is abundant, and range of application is also more extensive.Also have nontoxicity, radioactivity, fire-retardant, sticking oil, do not ooze dirt, antibacterial and mouldproof, wear-resisting, shock-resistant, easy maintenance, seamless spliced, numerous advantages such as moulding is changeable.
Rostone type difference, its composition also is not quite similar.Mainly being to be matrix with the organic polymer material, is filler with natural ore powder, particle etc., adds pigment and other auxiliarys, through the polymer composite of vacuum casting or compression molding.
The macromolecular material matrix that the making of rostone is mainly used at present is vibrin or acrylic resin (polymethylmethacrylate).Vibrin since in the manufacturing processed with an organic solvent, the rostone of making can discharge the gas harmful to human body and environment.The acrylic resin then needs hot setting, and energy consumption is bigger, and price is very expensive.And the acrylic resin itself is inflammable substance, and its heat-drawn wire is 96 ℃, and the highest continuous use temperature is 65-95 ℃.So the rostone thermotolerance of making, flame retardant resistance are all not enough.Unsaturated polyester is because cure shrinkage is bigger, and the processing constancy is bad, and heat-drawn wire is at 50-60 ℃, and heatproof combustion resistance is all undesirable.These have influenced being extensive use of of rostone.
Summary of the invention
In order to solve above-mentioned problems of the prior art, the invention provides a kind of prescription and manufacture method of rostone, this kind rostone is that the organic solvent-free system is produced rostone, the problem that its later stage discharges obnoxious flavour can be solved, problems such as poor mechanical property, flame retardant resistance are not high can also be solved simultaneously.
The objective of the invention is to be achieved by following technical solution.The invention provides a kind of rostone, this rostone is prepared from by aqueous high molecular material and inorganic materials, wherein said aqueous high molecular material is acrylic ester emulsion, organosilicon-modified acrylate emulsion (calling organosilicon crylic acid latex in the following text), cinnamic acrylic ester emulsion (calling benzene emulsion in the following text), polyurethane-modified acrylic acid ester emulsion, tertiary ethylene carbonate-acrylic ester emulsion, the vinyl acetate-acrylate emulsion, hydroxyl acrylic emulsion, aqueous polyurethane dispersion, the organic silicon modified polyurethane dispersion, water-compatible amino resin, aqueous epoxy resins, one or more in the epoxy-modified acrylic acid emulsion etc.; Wherein, the viscosity of each emulsion is 50-2500mPas, and solids content (wt%) is 30-70%.
Wherein, the quality of described aqueous high molecular material accounts for the 2%-20% of prescription total mass.
Organosilicon crylic acid latex is that organosilane monomer and the acrylic monomer that will contain unsaturated link(age) coat the emulsion that polymerization technique is polymerized by nucleocapsid.It combines organosilicon fire-resistant, weathering resistance, chemical-resistant, low high tint retention, snappiness, the tack that is difficult for contaminative and acrylic resin of hydrophobic, surface energy.It is a kind of high weather-proof, high water-fast, resistant to pollution emulsion.Finished market product is arranged, optimize suitable organosilicon crylic acid latex needs of the present invention through test and satisfy following parameter: viscosity (25 ℃, 3 rotor 60r/min) 50-800mPas; Solids content (wt%) is 40-60%; 50-600mPas more preferably, solid content is 45-50%.
Benzene emulsion is to be got through emulsion copolymerization by vinylbenzene and acrylate monomer.Benzene emulsion is the more system of research in the letex polymerization, also is that the world today has one of ten big non-crosslinked type emulsions of essential industry using value.Benzene emulsion sticking power is good, and glued membrane is transparent, water-fast, oil resistant, heat-resisting, ageing-resistant performance is good.Milky white liquid, the band blue light.Finished market product is arranged, optimize through test and be fit to benzene emulsion needs of the present invention and satisfy following parameter: solids content (wt%) is 40～60%, and viscosity 80～2000mPas, level of residual monomers be less than 1.0%, pH value 8～9; Viscosity 80-1000mPas more preferably, solid content is 50-55%.
The content of urethane is 25%-65% in the polyurethane-modified acrylic acid emulsion.
That the rostone that acrylate resin (PA) makes as base-material has is weather-proof, anti-pollution, acidproof, alkaline-resisting, performance such as the transparency is good, and production cost is lower, therefore is widely used as the base-material of rostone water-based.Yet the polyacrylate(s) rostone also exists shortcomings such as low temperature easily becomes fragile, the high temperature change is glutinous, has influenced its decorative effect and use value.For this reason, adopt the research of other resin modified polyacrylic ester resinoid to be subjected to people's extensive concern.In urethane (PU) molecule because containing a large amount of ammonia ester bonds and urea key etc., easily form hydrogen bond between macromole, produce extensive physical crosslinking, make latex film have excellent solvent resistance, wear resistance, damage resistant, snappiness and elasticity etc., but its production cost is higher, and the urethane that urethane and polyacrylic ester are combined and obtain.Polyacrylic ester (PUA) composite emulsion not only greatly reduce production cost, and latex film is with both advantages.
Preferred water-based macromolecular material is made up of the organosilicon crylic acid latex of 44-64%, the benzene emulsion of 20-40%, the polyurethane-modified acrylic acid emulsion of 8-25%.
The quality of aqueous high molecular material accounts for the 2%-20% of prescription total mass, is preferably 5-15%.
The invention provides a kind of rostone, its prescription is as follows:
Aqueous high molecular material 5-15%
Quartz sand 15-30%
Glass powder 15-25%
Silicate 30-50%.
Pigment 1-3%
Water surplus
Particle diameter 40 orders of quartz sand are preferably 60 orders to 800 orders to 1000 orders;
Glass powder particle diameter 40 orders are preferably 60 orders to 800 orders to 1000 orders;
Silicate is selected from water glass, asbestos, feldspar (K
2OAl
2O
36SiO
2), wilkinite, polynite, attapulgite, cement, at least a in the clay; Particle diameter be 40 orders to 1000 orders, be preferably 60 orders to 800 orders;
Pigment can be a natural colour mineral material, also can be organic Masterbatch, only otherwise with formula system generation destructive reaction and can all can use by mixing.Preferred commercial grade rostone pigment.
Preferred above-mentioned prescription is:
Organosilicon crylic acid latex 7%
Benzene emulsion 4%
Polyurethane-modified acrylic acid emulsion 2%
Quartz sand 20%
Glass powder 20%
Silicate 40%.
Pigment 2%
Water 5%
The invention provides the manufacture method of above-mentioned rostone: by above-mentioned formula ratio, each component is mixed, pour mould then into, being evacuated to vacuum tightness is the 0.06-0.1MPa typing, place more than 7 days, and polishing, rostone gets product.
Compare with traditional technology, technical scheme of the present invention has following excellent characteristics:
1) employed aqueous high molecular material all has the excellent water tolerance energy, has ensured that the water-based rostone of made has the excellent water tolerance energy.
2) owing to adopted the aqueous high molecular material to replace traditional vibrin, no longer contain the composition of solvent in the system, avoided rostone in use to discharge obnoxious flavour.The tradition rostone is its VOC(volatile organic compounds after tested) can reach 300-400ppm, and the test of water-based rostone can't check VOC.
3) the aqueous high molecular material contracts rate of Cai Yonging is very little, and the deformation in the course of processing of the rostone of making is very little, is easy to the processing typing, also is of value to and makes seamless spliced panel.
4) the aqueous high molecular material of Cai Yonging itself has higher heat-drawn wire, and because the cohesive force of material itself is very high, less consumption can reach requirement, can improve the ratio of other inorganic materials, thereby make the water-based rostone have higher resistant, thermotolerance, flame retardant resistance and higher mechanical property.
5) because used aqueous high molecular material has higher weathering resistance, can ensure that the water-based rostone has higher weathering resistance in using out of doors.
Embodiment
Following content be in conjunction with concrete preferred implementation to further describing that the present invention does, can not assert that concrete enforcement of the present invention is confined to these explanations.For the general technical staff of the technical field of the invention; without departing from the inventive concept of the premise; can also make some simple deduction or replace; all should be considered as belonging to protection scope of the present invention; the present invention uses but the technology and the indexing section that do not describe, is prior art.
Stain resistance test, resistance to chemical attack test, the test of anti-heating property, water resistance test all adopt JC908-2002; Mensuration about VOC adopts the method for standard GB18582-2008 to carry out, VOC referred to herein as under the 101.3kPa standard pressure, any initial boiling point is equal to or less than 250 ℃ organic compound, for the content of the volatile organic compounds of product deduction moisture, to restrain every kilogram (g/kg) expression.Bending strength, bending elastic modulus are measured and are all adopted GB/T2570-1995, and shock strength is measured and adopted GB/T2571-1995, Barcol hardness to measure employing GB/T3854-2005.Wherein, adopt flexural strength and the bending elastic modulus of CMT4254 type electronic universal experimental test rostone; Adopt XJJ-50 type shock-testing machine to test its impelling strength; The employing model is that the Bareol hardness meter of HBA-1 is measured its Barcol hardness.
Pasteur (Ba Keer) hardness is according to GB/T 3854 regulation tests.
Ball falling impact: four jiaos with 660mm * 810mm sample steadily are stuck on the test fixture, use diameter 38.1mm, the 0.225kg steel ball with 610mm drop freely falling body in distance sample mid point 48mm scope.Used steel ball is answered non-notch, indenture, distortion or other surface imperfection.Impelling strength: undertaken by the GB/T2571-1995 regulation.Flexural strength and bending elastic modulus are undertaken by the GB/T2550-1995 regulation.
Ageing-resistant performance is undertaken by GB/T164422-1999 regulation, and the hernia arc lamp exposes 200h to the open air, be (63 ± 5) ℃ according to plate temperature, and radiant flux density is controlled under 340mm in the 0.35w/ ㎡.Outer optical filtering is combined as high silicon borate glass.Do not need controlling moisture.Flame retardant properties: oxygen index carries out according to GB/T 2406-1993 regulation.Press EN13501-1 building products and member the fire prevention classification (A1, A2, B, C, D, E F) carries out classification.
Mensuration about VOC adopts the method for standard GB18582-2008 to carry out, VOC(volatile organic compounds wherein) refers under the 101.3kPa standard pressure, any initial boiling point is equal to or less than 250 ℃ organic compound, for the content of the volatile organic compounds of product deduction moisture, to restrain every kilogram (g/kg) expression.
?
Embodiment 1
By following prescription, make rostone:
(viscosity is 600mPas to ACRYLIC EMULSION; Solids content (wt%) is 60%) 8%
Quartz sand (particle diameter is the 40-800 order) 30%
Glass powder (particle diameter is the 40-800 order) 15%
Polynite (particle diameter is the 40-800 order) 30%
Rostone black pigment (commodity) 1%
Water surplus
By above-mentioned formula ratio, each component is mixed, pour mould then into, vacuumize (vacuum tightness is 0.08MPa) typing, place maintenance 7 days, polishing, rostone gets product.The finished product rostone is detected by above-mentioned relevant criterion, and the result is as follows:
The Mechanics Performance Testing result sees Table 1-1, shows the equal conformance with standard regulation of every mechanical property of this rostone.
Table 1-1 Mechanics Performance Testing result
Weathering resistance test (burn-in test of anti-UV): 200 hours, outward appearance crack-free, bubble, slight crack and surperficial texture changed, aberration 1.16 before and after the burn-in test.
The stain resistance test sees Table 1-2:
The resistant value result of table 1-2 all ingredients
Annotate: I represents to be exposed to airborne drop; II represents the drop that covers with watch-glass: the numeral resistant value in the form; The pollution level minimum of 1 expression, the pollution level maximum of 5 expressions when the resistant value reaches 5, then needs to measure the greatest contamination degree of depth.
Resistant value summation is 64, and the greatest contamination mark degree of depth is that 0.11mm(is recorded by the blue aqueous ink of not adding a cover).Examination criteria JC 908-2002 requirement, resistant value summation must not surpass 64, and the greatest contamination mark degree of depth is not more than 0.12mm, so sample test conformance with standard as a result.
Resistance to chemical attack test, the test of anti-heating property, water resistance test all meet the requirement of JC 908-2002.Oxygen index is 40, and flame retardant rating is the A1 level, all meets national standard.
VOC content does not detect, and is lower than standard value.
Embodiment 2
By following prescription, make rostone:
(viscosity is 100mPas to aqueous epoxy resins; Solids content (wt%) is 45%) 15%
Quartz sand (particle diameter is the 40-800 order) 30%
Glass powder (particle diameter is the 60-600 order) 15%
Water glass (particle diameter is the 40-800 order) 30%
Rostone black pigment (commodity) 1%
Water surplus
By above-mentioned formula ratio, each component is mixed, pour mould then into, vacuumize (vacuum tightness is 0.07MPa) typing, maintenance 10 days, polishing, rostone gets product.The finished product rostone is detected by above-mentioned relevant criterion, and the result is as follows:
The Mechanics Performance Testing result sees Table 2-1, shows the equal conformance with standard regulation of every mechanical property of this rostone.
Table 2-1 Mechanics Performance Testing result
Weathering resistance test (burn-in test of anti-UV): 200 hours, outward appearance crack-free, bubble, slight crack and surperficial texture changed, aberration 1.17 before and after the burn-in test.
The stain resistance test sees Table 2-2:
The resistant value result of table 2-2 all ingredients
Resistant value summation is 64, and the greatest contamination mark degree of depth is that 0.10mm(is recorded by the blue aqueous ink of not adding a cover), sample test is conformance with standard as a result.
Resistance to chemical attack test, the test of anti-heating property, water resistance test all meet the requirement of JC 908-2002.Oxygen index is 40, and flame retardant rating is the A1 level, all meets national standard.
VOC content does not detect, and is lower than standard value.
Embodiment 3
By following prescription, make rostone:
Organosilicon crylic acid latex (viscosity 300mPas; Solids content (wt%) is 46%) 7%
Benzene emulsion (viscosity is 400mPas, and solids content (wt%) is 40%, level of residual monomers 0.5%, pH value 8.5) 4%
Polyurethane-modified acrylic acid emulsion (content of urethane is 35%) 2%
Quartz sand (particle diameter is the 60-600 order) 20%
Glass powder (particle diameter is the 60-600 order) 20%
Feldspar (particle diameter is the 60-600 order) 40%
Rostone black pigment (commodity) 2%
Water surplus
By above-mentioned formula ratio, each component is mixed, pour mould then into, vacuumize (vacuum tightness is 0.08MPa) typing, maintenance 15 days, polishing, rostone gets product.The finished product rostone is detected by above-mentioned relevant criterion, and the result is as follows:
Mechanics Performance Testing result (seeing Table 3-1) shows the equal conformance with standard regulation of every mechanical property of this rostone.
Table 3-1 Mechanics Performance Testing result
Weathering resistance test (burn-in test of anti-UV): 200 hours, outward appearance crack-free, bubble, slight crack and surperficial texture changed, aberration 1.10 before and after the burn-in test.
The stain resistance test sees Table 3-2:
The resistant value result of table 3-2 all ingredients
Resistant value summation is 48, and sample test is conformance with standard as a result.
Resistance to chemical attack test, the test of anti-heating property, water resistance test all meet the requirement of JC 908-2002.Oxygen index is 40, and flame retardant rating is the A1 level, all meets national standard.
VOC content does not detect, and is lower than standard value.
Embodiment 4
By following prescription, make rostone:
Organosilicon crylic acid latex (viscosity 600mPas; Solids content (wt%) is 46%) 8%
Benzene emulsion (solids content (wt%) is 50%, viscosity 600mPas, level of residual monomers 0.5%, pH value 8.5) 5%
Polyurethane-modified acrylic acid emulsion (content of urethane is 35%-65%) 2.5%
Quartz sand (particle diameter is the 80-800 order) 30%
Glass powder (particle diameter is the 80-800 order) 25%
Clay (particle diameter is the 80-800 order) 50%
Rostone red pigment (commodity) 3%
Water surplus
By above-mentioned formula ratio, each component is mixed, pour mould then into, vacuumize (vacuum tightness is 0.08MPa) typing, maintenance 20 days, polishing, rostone gets product.The finished product rostone is detected by above-mentioned relevant criterion, and the result is as follows:
Mechanics Performance Testing result (seeing Table 4-1) shows the equal conformance with standard regulation of every mechanical property of this rostone.
Table 4-1 Mechanics Performance Testing result
Weathering resistance test (burn-in test of anti-UV): 200 hours, outward appearance crack-free, bubble, slight crack and surperficial texture changed, aberration 1.17 before and after the burn-in test.
The stain resistance test sees Table 4-2:
The resistant value result of table 4-2 all ingredients
Resistant value summation is 48, and sample test is conformance with standard as a result.
Resistance to chemical attack test, the test of anti-heating property, water resistance test all meet the requirement of JC 908-2002.Oxygen index is 40, and flame retardant rating is the A1 level, all meets national standard.
VOC content does not detect, and is lower than standard value.
Embodiment 5
By following prescription, make rostone:
(viscosity is 50mPas to organosilicon crylic acid latex; Solids content (wt%) is 40%) 6%
Benzene emulsion (solids content (wt%) is 40%, and viscosity is 400mPas, level of residual monomers 0.5%, pH value 9.0) 5%
Polyurethane-modified acrylic acid emulsion (content of urethane is 25%) 1.5%
Quartz sand (particle diameter is the 40-1000 order) 30%
Glass powder (particle diameter is the 40-1000 order) 15%
Water glass (particle diameter is the 40-1000 order) 30%
Rostone black pigment (commodity) 1%
Water surplus
By above-mentioned formula ratio, each component is mixed, pour mould then into, vacuumize (vacuum tightness is 0.07MPa) typing, maintenance 30 days, polishing, rostone gets product.The finished product rostone is detected by above-mentioned relevant criterion, and the result is as follows:
The Mechanics Performance Testing result sees Table 5-1, shows the equal conformance with standard regulation of every mechanical property of this rostone.
Table 5-1 Mechanics Performance Testing result
Weathering resistance test (burn-in test of anti-UV): 200 hours, outward appearance crack-free, bubble, slight crack and surperficial texture changed, aberration 1.16 before and after the burn-in test.
The stain resistance test sees Table 5-2:
The resistant value result of table 5-2 all ingredients
Resistant value summation is 58, and the greatest contamination mark degree of depth is that 0.1mm(is recorded by the blue aqueous ink of not adding a cover), sample test is conformance with standard as a result.
Resistance to chemical attack test, the test of anti-heating property, water resistance test all meet the requirement of JC 908-2002.Oxygen index is 40, and flame retardant rating is the A1 level, all meets national standard.
VOC content does not detect, and is lower than standard value.
Claims (10)
1. rostone, be prepared from by aqueous high molecular material and inorganic materials, it is characterized in that described aqueous high molecular material is selected from one or more in acrylic ester emulsion, organosilicon crylic acid latex, benzene emulsion, polyurethane-modified acrylic acid ester emulsion, tertiary ethylene carbonate-acrylic ester emulsion, vinyl acetate-acrylate emulsion, hydroxyl acrylic emulsion, aqueous polyurethane dispersion, organic silicon modified polyurethane dispersion, water-compatible amino resin, aqueous epoxy resins, the epoxy-modified acrylic acid emulsion; Wherein, the viscosity of each emulsion is 50-2500mPas, and solids content (wt%) is 30-70%.
2. a kind of rostone as claimed in claim 1 is characterized in that, the quality of described aqueous high molecular material accounts for the 2%-20% of prescription total mass.
3. a kind of rostone as claimed in claim 1 is characterized in that, the viscosity 50-800mPas of organosilicon crylic acid latex, and solids content (wt%) is 40-60%; Viscosity 80～the 2000mPas of benzene emulsion, solids content 45-60%, level of residual monomers are less than 1.0%, and pH value is 8～9; The content of urethane is 25%-65% in the polyurethane-modified acrylic acid emulsion.
4. a kind of rostone as claimed in claim 3 is characterized in that, the viscosity of organosilicon crylic acid latex is 100-600mPas, and solid content is 45-50%.
5. a kind of rostone as claimed in claim 3 is characterized in that, the viscosity of benzene emulsion is 300-1000mPas, and solid content is 50-55%.
6. a kind of rostone as claimed in claim 1 is characterized in that, its prescription is as follows:
Aqueous high molecular material 5-15%
Quartz sand 15-30%
Glass powder 15-25%
Silicate 30-50%
Pigment 1-3%
Water surplus
Wherein, the particle diameter of quartz sand is that 40 orders are to 1000 orders; The glass powder particle diameter is that 40 orders are to 1000 orders; Silicate is selected from water glass, asbestos, feldspar (K
2OAl
2O
36SiO
2), wilkinite, polynite, attapulgite, cement, at least a in the clay, particle diameter is that 40 orders are to 1000 orders.
7. a kind of rostone as claimed in claim 6 is characterized in that, the aqueous high molecular material is made up of the organosilicon crylic acid latex of 40-50%, the benzene emulsion of 20-40%, the polyurethane-modified acrylic acid emulsion of 8-25%.
8. a kind of rostone as claimed in claim 6 is characterized in that, its prescription is as follows:
Organosilicon crylic acid latex 7%
Benzene emulsion 4%
Polyurethane-modified acrylic acid emulsion 2%
Quartz sand 20%
Glass powder 20%
Silicate 40%
Pigment 2%
Water 5%.
9. a kind of rostone as claimed in claim 6 is characterized in that, the particle diameter of quartz sand is that 40 orders are to 800 orders; The glass powder particle diameter is that 40 orders are to 800 orders.
10. the manufacture method as the described a kind of rostone of the power arbitrary claim of 1-9 is characterized in that step is as follows: press formula ratio, each component is mixed, pour mould then into, vacuumize typing, place maintenance more than 7 days, polishing, rostone gets product.
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| CN201310274402.6A CN103342501B (en) | 2013-07-02 | 2013-07-02 | Waterborne artificial stone and preparation method thereof |
| PCT/CN2014/000336 WO2015000283A1 (en) | 2013-07-02 | 2014-03-28 | Aqueous artificial stone and preparation method therefor |
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| CN201310274402.6A CN103342501B (en) | 2013-07-02 | 2013-07-02 | Waterborne artificial stone and preparation method thereof |
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| WO2015000283A1 (en) * | 2013-07-02 | 2015-01-08 | Yi Chengzhi | Aqueous artificial stone and preparation method therefor |
| CN105271944A (en) * | 2015-11-16 | 2016-01-27 | 武宣县宝信石材有限公司 | Board or artware produced through marble leftover materials |
| CN106007531A (en) * | 2016-05-20 | 2016-10-12 | 江多忠 | Engineering stone terrazzo |
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| CN106145810A (en) * | 2016-06-24 | 2016-11-23 | 安徽弗仕通实业有限公司 | A kind of artificial stone of resistance to water logging and preparation method thereof |
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| CN111919857A (en) * | 2020-08-12 | 2020-11-13 | 高时(厦门)石业有限公司 | Preparation method of sterilization powder, sterilization powder and antibacterial inorganic artificial stone using sterilization powder |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101734942A (en) * | 2008-11-19 | 2010-06-16 | 石汇玉 | Method for preparing article stones with holes |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084806A (en) * | 1992-09-29 | 1994-04-06 | 湖南省建筑材料研究设计院 | Artificial stone mirror plate and manufacture method thereof |
| CA2318122C (en) * | 1998-01-16 | 2007-10-23 | Doppel Co., Ltd. | Non-slip artificial stone |
| CN101357836B (en) * | 2007-07-30 | 2013-03-20 | 比亚迪股份有限公司 | Artificial stone composition, manufacturing method thereof, artificial stone and method for preparing molding |
| CN103342501B (en) * | 2013-07-02 | 2014-04-23 | 广东海顺新材料科技有限公司 | Waterborne artificial stone and preparation method thereof |
| CN103360561B (en) * | 2013-07-02 | 2014-06-25 | 广东海顺新材料科技有限公司 | Polyurethane modified acrylic emulsion, preparation method of acrylic emulsion and prepared artificial stone |
| CN103342782B (en) * | 2013-07-02 | 2014-06-25 | 广东海顺新材料科技有限公司 | Organosilicone modified acrylate emulsion, preparation method thereof and water-based artificial stone prepared from organosilicone modified acrylate emulsion |
| CN103342770B (en) * | 2013-07-02 | 2014-10-08 | 广东海顺新材料科技有限公司 | Styrene-acrylic emulsion for manufacturing artificial stone, preparation method, and artificial stone prepared from styrene-acrylic emulsion |
-
2013
- 2013-07-02 CN CN201310274402.6A patent/CN103342501B/en active Active
-
2014
- 2014-03-28 WO PCT/CN2014/000336 patent/WO2015000283A1/en active Application Filing
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101734942A (en) * | 2008-11-19 | 2010-06-16 | 石汇玉 | Method for preparing article stones with holes |
Non-Patent Citations (1)
| Title |
|---|
| 赵慧春: "环氧树脂水性化技术与研究进展", 《黑龙江科技信息》, no. 21, 31 December 2009 (2009-12-31) * |
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| WO2015000283A1 (en) * | 2013-07-02 | 2015-01-08 | Yi Chengzhi | Aqueous artificial stone and preparation method therefor |
| CN104072048A (en) * | 2014-07-11 | 2014-10-01 | 赵玲强 | Formula for preparing building material and product thereof by utilizing caustic sludge |
| CN106365547A (en) * | 2015-07-24 | 2017-02-01 | 上海凯迈建筑科技股份有限公司 | Cement-based artificial molding stone |
| CN105271944A (en) * | 2015-11-16 | 2016-01-27 | 武宣县宝信石材有限公司 | Board or artware produced through marble leftover materials |
| CN106007531A (en) * | 2016-05-20 | 2016-10-12 | 江多忠 | Engineering stone terrazzo |
| CN106045387A (en) * | 2016-05-20 | 2016-10-26 | 江多忠 | Sand-stone terrazzo |
| CN106145810A (en) * | 2016-06-24 | 2016-11-23 | 安徽弗仕通实业有限公司 | A kind of artificial stone of resistance to water logging and preparation method thereof |
| CN109485303A (en) * | 2018-12-13 | 2019-03-19 | 珠海色萨利健康石材有限公司 | A kind of two-color artificial quartz and preparation method thereof |
| CN109485303B (en) * | 2018-12-13 | 2021-04-27 | 珠海色萨利健康石材有限公司 | Double-color artificial quartz stone and preparation method thereof |
| CN111892352A (en) * | 2020-07-20 | 2020-11-06 | 广西利升石业有限公司 | Multicolor series inorganic artificial stone and preparation method thereof |
| CN111919857A (en) * | 2020-08-12 | 2020-11-13 | 高时(厦门)石业有限公司 | Preparation method of sterilization powder, sterilization powder and antibacterial inorganic artificial stone using sterilization powder |
| WO2023235907A1 (en) * | 2022-06-10 | 2023-12-14 | STRASSER Steine GmbH | Plastic-bonded work top |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015000283A1 (en) | 2015-01-08 |
| CN103342501B (en) | 2014-04-23 |
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