CN103337209B - Can start assemble organic solar batteries teaching aid - Google Patents
Can start assemble organic solar batteries teaching aid Download PDFInfo
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- CN103337209B CN103337209B CN201310221674.XA CN201310221674A CN103337209B CN 103337209 B CN103337209 B CN 103337209B CN 201310221674 A CN201310221674 A CN 201310221674A CN 103337209 B CN103337209 B CN 103337209B
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Abstract
The invention discloses a kind of organic solar batteries teaching aid of starting to assemble.Described teaching aid comprises control circuit, the power supply be located on described control circuit, electrical appliance and organic solar batteries plate; Described organic solar batteries plate is made up of the negative electrode superposed successively, organic photovoltaic active layer and anode; Described anode is made up of transparent conductive material, and described negative electrode is made up of metal material.The teaching aid of organic solar batteries provided by the invention, the advantages such as organic solar batteries is flexible, the low easily a large amount of preparations of cost are given full play to, and what overcome sun power teaching aid in the past can not self assembly, thus improve user especially adolescent student colony, for the structure of organic solar batteries and the learning initiative of principle of work, fully demonstrate the thought of teaching through lively activities.
Description
Technical field
The present invention relates to a kind of organic solar batteries teaching aid of starting to assemble.
Background technology
In order to improve user especially adolescent student colony, for the structure of organic solar batteries device and the learning initiative of principle of work, devise the teaching aid comprising organic solar batteries that this can do it yourself to assemble, fully demonstrate the thought of teaching through lively activities.There is limited evidence currently of adopts organic solar batteries device as teaching aid, the solar cell teaching aid structure be disclosed in patent of invention CN102054385A and patent CN102654950A in the teaching aid of solar-energy photo-voltaic cell is comparatively complicated, is not easy to user oneself and carries out assembling and operating.Visible sun power teaching aid or educational toy etc. on market in addition, adopts traditional inorganic photovoltaic cell more, and organic solar batteries is easily prepared in a large number, relative price is cheap, soft etc., and premium properties does not also play a role in teaching aid field.
Summary of the invention
The object of this invention is to provide a kind of organic solar batteries teaching aid of starting to assemble, teaching aid structure provided by the invention simply, is easily assembled, and can be used as teaching aid and be applied in the extracurricular interest study of classroom instruction or student;
A kind of organic solar batteries teaching aid of starting to assemble provided by the present invention, it comprises control circuit, the power supply be located on described control circuit, electrical appliance and organic solar batteries plate;
Described organic solar batteries plate is made up of the negative electrode superposed successively, organic photovoltaic active layer and anode;
Described anode is made up of transparent conductive material, and described negative electrode is made up of metal material.
In above-mentioned organic solar batteries teaching aid, the thickness of described organic photovoltaic active layer can be 50nm ~ 500 μm.
In above-mentioned organic solar batteries teaching aid, in described anode, described transparent conductive material is located on transparent base, as being located at above unorganic glass, organic glass and transparent membrane etc.
In above-mentioned organic solar batteries teaching aid, in above-mentioned organic solar batteries teaching aid, the organic film, organic glass, unorganic glass etc. of the optional self-induced transparency of described transparent base.
Conductive coating materials can be the zinc paste of the tin oxide of doping, the indium oxide of doping or doping, as the tin indium oxide (ITO) of tin dope;
Described metal material can be aluminium, calcium, magnesium, nickel, silver or the metal such as golden.
In above-mentioned organic solar batteries teaching aid, described organic photovoltaic active layer can be individual layer photovoltaic material layer or heterojunction photovoltaic material layer.
In above-mentioned organic solar batteries teaching aid, described heterojunction photovoltaic material layer can be double layer heterojunction layer or bulk-heterojunction layer.
In above-mentioned organic solar batteries teaching aid, the electron donor material of described heterojunction photovoltaic material layer can be the micromolecular compound or polymkeric substance with conjugated structure, as polystyrene support, polythiophene and narrow band gap polymkeric substance etc.;
The electron acceptor material of described heterojunction photovoltaic material layer can be fullerene etc.
In above-mentioned organic solar batteries teaching aid, described organic photovoltaic active layer and decorative layer (improve photoelectric transformation efficiency, extend battery) can be provided with between described anode and described negative electrode, described decorative layer can by poly-3,4-ethylene dioxythiophene/poly styrene sulfonate, LiF, ZnO and TiO
2make.
In above-mentioned organic solar batteries teaching aid, described organic photovoltaic active layer can be provided with charge transport layer, and described charge transport layer is made up of NiO, can improve the electricity conversion of Thin film conductive rate and solar cell.
In above-mentioned organic solar batteries teaching aid, described electrical appliance can be luminescent device, heater members, electric device or display device, and described solar panel produces electric energy under visible light to drive described electrical appliance work.
The teaching aid of organic solar batteries provided by the invention, the advantages such as organic solar batteries is flexible, the low easily a large amount of preparations of cost are given full play to, and what overcome sun power teaching aid in the past can not self assembly, thus improve user especially adolescent student colony, for the structure of organic solar batteries and the learning initiative of principle of work, fully demonstrate the thought of teaching through lively activities.In addition, the distinguishing feature of teaching aid provided by the invention sun power teaching aid different from the past is that user can according to instructions direct, assemble voluntarily fast, convenient and safely, assembling process user can be more deep understand the principle of work of solar cell device and structure.
Accompanying drawing explanation
Fig. 1 is the structural representation of the solar panel of organic solar batteries teaching aid of the present invention;
Fig. 2 is the structural representation of organic solar batteries teaching aid of the present invention; In Fig. 3 embodiment 2, organic solar batteries drives the photo of the teaching aid of bulb luminescence;
In Fig. 4 embodiment 3, organic solar batteries drives the photo of the teaching aid of small fan;
In Fig. 5 embodiment 4, organic solar batteries drives the photo of the teaching aid of electrochromic variable color.
In figure, each mark is as follows: 1 transparent base, 2 anodes, 3 organic photovoltaic active layers, 4 negative electrodes, 1 transparent base, 5 packing washers, 6 organic solar batteries plates, 7 power supplys, 8 electrical appliances.
Embodiment
The experimental technique used in following embodiment if no special instructions, is conventional method.
Material used in following embodiment, reagent etc., if no special instructions, all can obtain from commercial channels.
Embodiment 1, organic solar batteries teaching aid
As shown in Figure 2, provided by the invention can the organic solar batteries teaching aid of assembled by hand comprise control circuit, the power supply 7 be located on this control circuit, electrical appliance 8 and organic solar batteries plate 6; Wherein, organic solar batteries plate 6 is made up of the negative electrode 4 superposed successively, organic photovoltaic active layer 3 and anode 2, and anode 2 is made up of transparent conductive material, and negative electrode 4 is by metal material system; The thickness of organic photovoltaic active layer 3 is 50nm ~ 500 μm.As shown in Figure 1, anode 2 and negative electrode 4 are located on transparent base 1.In use, the superficial layer of transparent base 1 all attaches one deck gasket seal 5.
In organic solar batteries teaching aid provided by the invention, transparent conductive material can select the tin oxide, the indium oxide of doping or the zinc paste of doping that adulterate, as the tin indium oxide (ITO) of tin dope; Metal material can select aluminium, calcium, magnesium, silver or the metal such as golden.Transparent base wherein can be unorganic glass, organic glass and transparent membrane etc.
Organic photovoltaic active layer in organic solar batteries teaching aid provided by the invention can be individual layer photovoltaic material layer or heterojunction photovoltaic material layer, wherein heterojunction photovoltaic material layer can be double layer heterojunction layer or bulk-heterojunction layer, as heterojunction photovoltaic material layer, the electron donor material of heterojunction photovoltaic material layer can be the micromolecular compound or polymkeric substance with conjugated structure, as polystyrene support, polythiophene and narrow band gap polymkeric substance etc., and the electron acceptor material of heterojunction photovoltaic material layer can be fullerene etc.
In organic solar batteries teaching aid provided by the invention, can be provided with decorative layer at organic photovoltaic active layer 4 and between anode 2 and negative electrode 3, it can by poly-3,4-ethylene dioxythiophene/poly styrene sulfonate, LiF, ZnO and TiO
2make.And can be provided with charge transport layer on organic photovoltaic active layer 5, it specifically can be made up of NiO.
Embodiment 2, organic solar batteries teaching aid of the present invention is utilized to drive bulb luminous
According to Fig. 1 and embodiment 1 assembling solar cell panel, the solar panel formed after each assembling parts is of a size of 10cm × 10cm.Specifically be made up of following material under upper: transparent base, anode, organic photovoltaic active layer, negative electrode, transparent base, packing washer, wherein transparent base selects organic glass, negative electrode selects aluminium, tin indium oxide (ITO) film of anode selection tin dope, organic photovoltaic active layer selects polystyrene support and fullerene, and its thickness is 500 μm.
As shown in Figure 3, the solar panel of above-mentioned assembling being accessed one has in the simple straight circuit of miniature bulb and capacitor, under being placed in sunlight.After connecting circuit, miniature bulb can normal luminous.After taking indoor a period of time, after connecting circuit, luminescent device still can be luminous.
Embodiment 3, organic solar batteries teaching aid drive fan of the present invention is utilized to rotate
According to Fig. 1 and embodiment 1 assembling solar cell panel, the solar panel formed after each assembling parts is of a size of 15cm × 15cm.Specifically be made up of following material under upper: packing washer, transparent base, anode, organic photovoltaic active layer, negative electrode and packing washer, wherein transparent base selects organic film, negative electrode selects magnesium, tin indium oxide (ITO) film of anode selection tin dope, organic photovoltaic active layer selects polythiophene and fullerene, and its thickness is 50nm.
As shown in Figure 4, the solar panel of above-mentioned assembling being accessed one has in the simple straight circuit of small fan and capacitor, under being placed in sunlight.After connecting circuit, small fan can normal rotation.After taking indoor a period of time, after connecting circuit, small fan still can rotate.
Embodiment 4, organic solar batteries teaching aid of the present invention is utilized to drive controllable color variable color
According to Fig. 1 and embodiment 1 assembling solar cell panel, the solar panel formed after each assembling parts is of a size of 15cm × 15cm.Specifically be made up of following material under upper: packing washer, transparent base, anode, organic photovoltaic active layer, negative electrode and packing washer, wherein transparent base selects organic glass, negative electrode selects calcium, tin indium oxide (ITO) film of anode selection tin dope, organic photovoltaic active layer selects polystyrene support and fullerene, and its thickness is 500nm.
As shown in Figure 5, the solar panel of above-mentioned assembling being accessed one has in the simple straight circuit of electrochromic and capacitor, under being placed in sunlight.Electrochromic can change the change showing as color or transmittance by response voltage.After connecting circuit, electrochromic can present the change of obvious color or transmittance change.After taking indoor a period of time, after connecting circuit, electrochromic still response voltage change can present color or transmittance change.
Above embodiment just understands method of the present invention, principle of work and design philosophy for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can do some improvement and modification to the present invention, these improve and modify also in the protection domain of this patent requirement.
Claims (9)
1. can start assemble an organic solar batteries teaching aid, it is characterized in that: described teaching aid comprises control circuit, the power supply be located on described control circuit, electrical appliance and organic solar batteries plate;
Described organic solar batteries plate is made up of the negative electrode superposed successively, organic photovoltaic active layer and anode;
Described anode is made up of transparent conductive material, and described negative electrode is made up of metal material;
Described transparent conductive material is the tin oxide, the indium oxide of doping or the zinc paste of doping that adulterate;
Described metal material is aluminium, calcium, magnesium, nickel, silver or golden.
2. organic solar batteries teaching aid according to claim 1, is characterized in that: the thickness of described organic photovoltaic active layer is 50nm ~ 500 μm.
3. organic solar batteries teaching aid according to claim 1 and 2, is characterized in that: described organic solar batteries plate also comprises transparent base, and described transparent conductive material is located on transparent base.
4. organic solar batteries teaching aid according to claim 1 and 2, is characterized in that: described organic photovoltaic active layer is individual layer photovoltaic material layer or heterojunction photovoltaic material layer.
5. organic solar batteries teaching aid according to claim 4, is characterized in that: described heterojunction photovoltaic material layer is double layer heterojunction layer or bulk-heterojunction layer.
6. organic solar batteries teaching aid according to claim 5, is characterized in that: the electron donor material of described heterojunction photovoltaic material layer is micromolecular compound or the polymkeric substance with conjugated structure;
The electron acceptor material of described heterojunction photovoltaic material layer is fullerene or imido derivant.
7. organic solar batteries teaching aid according to claim 1 and 2, it is characterized in that: described organic photovoltaic active layer and be provided with decorative layer between described anode and described negative electrode, described decorative layer is by gathering 3,4-ethylene dioxythiophene/poly styrene sulfonate, LiF, ZnO and TiO
2make.
8. organic solar batteries teaching aid according to claim 1 and 2, is characterized in that: described organic photovoltaic active layer is provided with charge transport layer, and described charge transport layer is made up of NiO.
9. organic solar batteries teaching aid according to claim 1 and 2, is characterized in that: described electrical appliance is luminescent device, heater members, electric device or display device.
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| CN201310221674.XA CN103337209B (en) | 2013-06-05 | 2013-06-05 | Can start assemble organic solar batteries teaching aid |
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| CN201310221674.XA CN103337209B (en) | 2013-06-05 | 2013-06-05 | Can start assemble organic solar batteries teaching aid |
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| CN103337209A CN103337209A (en) | 2013-10-02 |
| CN103337209B true CN103337209B (en) | 2016-04-13 |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103531062A (en) * | 2013-10-16 | 2014-01-22 | 北京博如德工程技术研究有限公司 | PLED (polymer light emitting diode) teaching aid capable of being manually assembled |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201207239Y (en) * | 2008-05-09 | 2009-03-11 | 北京双威富能科技有限公司 | Battery demonstration pack oriented to teaching aid market |
| CN201251878Y (en) * | 2008-06-06 | 2009-06-03 | 上海寰晟新能源科技有限公司 | Teaching experimental facility of solar photovoltaic system |
| CN101694755A (en) * | 2009-09-07 | 2010-04-14 | 无锡市新区梅村镇同春太阳能光伏农业种植园 | Noctilucent device on solar photovoltaic windmill |
| CN201532711U (en) * | 2009-09-14 | 2010-07-21 | 无锡市新区梅村镇同春太阳能光伏农业种植园 | Organic light-emitting display device on solar photovoltaic windmill |
| CN201673616U (en) * | 2010-04-16 | 2010-12-15 | 北京市太阳能研究所有限公司 | Solar PV system principle demonstration board |
| CN102654950A (en) * | 2011-03-03 | 2012-09-05 | 深圳市神达实业有限公司 | Portable solar teaching aid |
| CN202434106U (en) * | 2011-12-14 | 2012-09-12 | 盐城师范学院 | Solar battery demonstration experimental instrument |
| CN102931354A (en) * | 2012-11-16 | 2013-02-13 | 中国科学技术大学 | Compound transparent electrode, polymer solar cell and preparation methods of compound transparent electrode and polymer solar cell |
| CN202838804U (en) * | 2012-10-25 | 2013-03-27 | 马锦凤 | Demonstration device of solar battery vehicle |
| CN103050627A (en) * | 2012-11-29 | 2013-04-17 | 中国乐凯胶片集团公司 | Organic solar battery and preparation method of organic solar battery |
| CN203562123U (en) * | 2013-06-05 | 2014-04-23 | 北京博如德工程技术研究有限公司 | Organic solar cell teaching aid capable of being assembled by hand |
-
2013
- 2013-06-05 CN CN201310221674.XA patent/CN103337209B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201207239Y (en) * | 2008-05-09 | 2009-03-11 | 北京双威富能科技有限公司 | Battery demonstration pack oriented to teaching aid market |
| CN201251878Y (en) * | 2008-06-06 | 2009-06-03 | 上海寰晟新能源科技有限公司 | Teaching experimental facility of solar photovoltaic system |
| CN101694755A (en) * | 2009-09-07 | 2010-04-14 | 无锡市新区梅村镇同春太阳能光伏农业种植园 | Noctilucent device on solar photovoltaic windmill |
| CN201532711U (en) * | 2009-09-14 | 2010-07-21 | 无锡市新区梅村镇同春太阳能光伏农业种植园 | Organic light-emitting display device on solar photovoltaic windmill |
| CN201673616U (en) * | 2010-04-16 | 2010-12-15 | 北京市太阳能研究所有限公司 | Solar PV system principle demonstration board |
| CN102654950A (en) * | 2011-03-03 | 2012-09-05 | 深圳市神达实业有限公司 | Portable solar teaching aid |
| CN202434106U (en) * | 2011-12-14 | 2012-09-12 | 盐城师范学院 | Solar battery demonstration experimental instrument |
| CN202838804U (en) * | 2012-10-25 | 2013-03-27 | 马锦凤 | Demonstration device of solar battery vehicle |
| CN102931354A (en) * | 2012-11-16 | 2013-02-13 | 中国科学技术大学 | Compound transparent electrode, polymer solar cell and preparation methods of compound transparent electrode and polymer solar cell |
| CN103050627A (en) * | 2012-11-29 | 2013-04-17 | 中国乐凯胶片集团公司 | Organic solar battery and preparation method of organic solar battery |
| CN203562123U (en) * | 2013-06-05 | 2014-04-23 | 北京博如德工程技术研究有限公司 | Organic solar cell teaching aid capable of being assembled by hand |
Non-Patent Citations (1)
| Title |
|---|
| 有机太阳能电池用聚合物给体材料的研究进展;叶怀英 等;《有机化学》;20121231;第32卷(第2期);第266-283页 * |
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