CN103333586A - Water resistance thermal dissipation coating and preparation method thereof - Google Patents
Water resistance thermal dissipation coating and preparation method thereof Download PDFInfo
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- CN103333586A CN103333586A CN2013102080275A CN201310208027A CN103333586A CN 103333586 A CN103333586 A CN 103333586A CN 2013102080275 A CN2013102080275 A CN 2013102080275A CN 201310208027 A CN201310208027 A CN 201310208027A CN 103333586 A CN103333586 A CN 103333586A
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Abstract
The invention discloses a water resistance thermal dissipation coating and a preparation method thereof. The composed raw materials are E-12 epoxy resin, amide curing agent, ethyl acetate, modified nano titanium dioxide, dimethicone, polyethylene wax powder, phthalic anhydride, anti-oxidant DLTP, sodium tripolyphosphate, tert-butyl peroxide, laurinol sodium sulfate, and propylene glycol. The method adopts E-12 epoxy resin as the main material, because the E-12 epoxy resin has the advantages of aging resistance, large adhesivity, good thermal dissipation effect, and can be used under 160 DEG C for a long time. The nano titanium dioxide and the dimethicone are modified, through coupling the silane coupling agent KH 550, complex structures of the nano titanium dioxide and the dimethicone are increases, which is benefit for the dispersion of the titanium dioxide and the hydrophobicity and has an effective waterproof performance. The coating film has the advantages of durability, water resistance, corrosion resistance and good adhesiveness.
Description
Technical field
The present invention relates to technical field of coatings, be specifically related to a kind of waterproof cooling coating and preparation method thereof.
Background technology
Along with the rapid expansion of light fixture use range, prolong light fixture and also become urgent problem work-ing life; Adopt heat-conducting glue to solve the light fixture heat dissipation problem at present, but there is heatproof and ageing-resistant poor in its employed material, the technical problem little to the base material cohesive force, that radiating effect is not good and construction is inconvenient is difficult to satisfy people to the requirement of light fixture heat radiation.
Summary of the invention
The object of the present invention is to provide a kind of waterproof cooling coating and preparation method thereof.
The present invention adopts following technical scheme:
A kind of waterproof cooling coating is characterized in that the weight part of its constitutive material is: E-12 Resins, epoxy 70-75, amine curing agent 1.7-2.3, ethyl acetate 75-85, modified nano-titanium dioxide 2.5-3.5, dimethyl silicone oil 3.0-4.0, polyethylene wax powder 6.0-7.0, Tetra hydro Phthalic anhydride 5.5-6.5, anti-oxidant DLTP 0.8-1.2, tripoly phosphate sodium STPP 2.3-2.8, tert-butyl peroxide 0.8-1.2, sodium laurylsulfate 1.1-1.3 and propylene glycol 25-28, aluminium nitride 30-35.
Described waterproof cooling coating is characterized in that the weight part of its constitutive material is: E-12 Resins, epoxy 72, amine curing agent 2.0, ethyl acetate 80, modified nano-titanium dioxide 3.0, dimethyl silicone oil 3.5, polyethylene wax powder 6.5, Tetra hydro Phthalic anhydride 6.0, anti-oxidant DLTP 1.0, tripoly phosphate sodium STPP 2.5, tert-butyl peroxide 1.0, sodium laurylsulfate 1.2 and propylene glycol 27, aluminium nitride 30.
The preparation method of described waterproof cooling coating is characterized in that may further comprise the steps:
(1) preparation of modified nano-titanium dioxide: 20-25 part nano titanium oxide and equal proportion dimethyl silicone oil are mixed, add 3.0-4.0 part tripoly phosphate sodium STPP, 1.0-2.5 part silane coupling agent KH550 then, high speed dispersion obtains;
(2) weight part by constitutive material takes by weighing ethyl acetate, modified nano-titanium dioxide, dimethyl silicone oil, polyethylene wax powder, Tetra hydro Phthalic anhydride, after the mixing, adds tert-butyl peroxide, stirs 1-2 hour; To wherein adding E-12 Resins, epoxy, amine curing agent and other residue constitutive materials, mix evenly, when being ground to 35-45 μ m then; Stop to grind packing.
Beneficial effect of the present invention:
The present invention adopts E-12 Resins, epoxy to be major ingredient, and ageing-resistant, cohesive force is big, and good heat dissipation effect can be at 150-200 ℃ of following life-time service; The present invention adopts nano titanium oxide and dimethyl silicone oil to carry out modification, by silane coupling agent KH550, has increased the composite structure of the two, is conducive to the dispersion of titanium dioxide, also is conducive to hydrophobicity, effectively plays waterproof action.Persistence of filming of the present invention, water-fast, moisture-proof, good corrosion resistance, adhesion property is good.
During construction, the heat radiation coating spraying application was dried 1 hour down at 60-70 ℃, got final product film forming, made 35-45 μ m heat radiation coating.
Embodiment
Embodiment 1: waterproof cooling coating, the weight part of its constitutive material (kg) is: E-12 Resins, epoxy 72, amine curing agent 2.0, ethyl acetate 80, modified nano-titanium dioxide 3.0, dimethyl silicone oil 3.5, polyethylene wax powder 6.5, Tetra hydro Phthalic anhydride 6.0, anti-oxidant DLTP 1.0, tripoly phosphate sodium STPP 2.5, tert-butyl peroxide 1.0, sodium laurylsulfate 1.2 and propylene glycol 27, aluminium nitride 30.
(1) preparation of modified nano-titanium dioxide: 20 parts of nano titanium oxides and equal proportion dimethyl silicone oil are mixed, add 3.0 parts of tripoly phosphate sodium STPPs, 2.5 parts of silane coupling agent KH550 then, high speed dispersion obtains;
(2) weight part by constitutive material takes by weighing ethyl acetate, modified nano-titanium dioxide, dimethyl silicone oil, polyethylene wax powder, Tetra hydro Phthalic anhydride, after the mixing, adds tert-butyl peroxide, stirs 2 hours; To wherein adding E-12 Resins, epoxy, amine curing agent and other residue constitutive materials, mix evenly, when being ground to 35-45 μ m then; Stop to grind packing.The heat radiation coating that above-described embodiment 1 makes directly is sprayed at through on the glass light fixture that cleans up, heatproof test: behind the 220 ℃/3h of baking oven baking, the baking oven baking after 135 ℃/15 days the glass light fixture coat color and luster and do not have considerable change; Uviolizing 3.5h, not shedding of coating is non-yellowing, artificial accelerated aging test under 130 ℃ and 260W ultraviolet light irradiation condition, 5320 hours ageing-resistant time, 260 ℃ of heatproof high temperature, bonding shearing force 20.2MPa, thermal conductivity 298W/(mK).
Claims (3)
1. a waterproof cooling coating is characterized in that the weight part of its constitutive material is: E-12 Resins, epoxy 70-75, amine curing agent 1.7-2.3, ethyl acetate 75-85, modified nano-titanium dioxide 2.5-3.5, dimethyl silicone oil 3.0-4.0, polyethylene wax powder 6.0-7.0, Tetra hydro Phthalic anhydride 5.5-6.5, anti-oxidant DLTP 0.8-1.2, tripoly phosphate sodium STPP 2.3-2.8, tert-butyl peroxide 0.8-1.2, sodium laurylsulfate 1.1-1.3 and propylene glycol 25-28, aluminium nitride 30-35.
2. waterproof cooling coating according to claim 1 is characterized in that the weight part of its constitutive material is: E-12 Resins, epoxy 72, amine curing agent 2.0, ethyl acetate 80, modified nano-titanium dioxide 3.0, dimethyl silicone oil 3.5, polyethylene wax powder 6.5, Tetra hydro Phthalic anhydride 6.0, anti-oxidant DLTP 1.0, tripoly phosphate sodium STPP 2.5, tert-butyl peroxide 1.0, sodium laurylsulfate 1.2 and propylene glycol 27, aluminium nitride 30.
3. the preparation method of a waterproof cooling coating as claimed in claim 1 is characterized in that may further comprise the steps:
(1) preparation of modified nano-titanium dioxide: 20-25 part nano titanium oxide and equal proportion dimethyl silicone oil are mixed, add 3.0-4.0 part tripoly phosphate sodium STPP, 1.0-2.5 part silane coupling agent KH550 then, high speed dispersion obtains;
(2) weight part by constitutive material takes by weighing ethyl acetate, modified nano-titanium dioxide, dimethyl silicone oil, polyethylene wax powder, Tetra hydro Phthalic anhydride, after the mixing, adds tert-butyl peroxide, stirs 1-2 hour; To wherein adding E-12 Resins, epoxy, amine curing agent and other residue constitutive materials, mix evenly, when being ground to 35-45 μ m then; Stop to grind packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2013102080275A CN103333586A (en) | 2013-05-30 | 2013-05-30 | Water resistance thermal dissipation coating and preparation method thereof |
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| CN2013102080275A CN103333586A (en) | 2013-05-30 | 2013-05-30 | Water resistance thermal dissipation coating and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046203A (en) * | 2014-05-14 | 2014-09-17 | 阜阳市美叶家具有限公司 | Composite heat dissipation coating combination |
| CN104497745A (en) * | 2014-12-15 | 2015-04-08 | 深圳市优宝惠新材料科技有限公司 | Waterproof coating material composition |
| CN105295419A (en) * | 2015-12-08 | 2016-02-03 | 苏州鑫德杰电子有限公司 | Thermally conductive waterproof insulating material and preparation method thereof |
| CN105754473A (en) * | 2016-03-28 | 2016-07-13 | 山东天竞电子科技有限公司 | LED electronic display screen repairing agent, preparation method and repairing method |
| CN108410330A (en) * | 2018-04-16 | 2018-08-17 | 合肥仁德电子科技有限公司 | A kind of heat radiation coating of cell phone mainboard and preparation method thereof |
| CN114015295A (en) * | 2021-11-18 | 2022-02-08 | 哈尔滨工业大学无锡新材料研究院 | Preparation method of high-oxygen-barrier acrylate coating |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046203A (en) * | 2014-05-14 | 2014-09-17 | 阜阳市美叶家具有限公司 | Composite heat dissipation coating combination |
| CN104497745A (en) * | 2014-12-15 | 2015-04-08 | 深圳市优宝惠新材料科技有限公司 | Waterproof coating material composition |
| CN105295419A (en) * | 2015-12-08 | 2016-02-03 | 苏州鑫德杰电子有限公司 | Thermally conductive waterproof insulating material and preparation method thereof |
| CN105754473A (en) * | 2016-03-28 | 2016-07-13 | 山东天竞电子科技有限公司 | LED electronic display screen repairing agent, preparation method and repairing method |
| CN108410330A (en) * | 2018-04-16 | 2018-08-17 | 合肥仁德电子科技有限公司 | A kind of heat radiation coating of cell phone mainboard and preparation method thereof |
| CN114015295A (en) * | 2021-11-18 | 2022-02-08 | 哈尔滨工业大学无锡新材料研究院 | Preparation method of high-oxygen-barrier acrylate coating |
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Application publication date: 20131002 |