CN103333396A - Modified high-gloss PE bottle material - Google Patents
Modified high-gloss PE bottle material Download PDFInfo
- Publication number
- CN103333396A CN103333396A CN2013102966892A CN201310296689A CN103333396A CN 103333396 A CN103333396 A CN 103333396A CN 2013102966892 A CN2013102966892 A CN 2013102966892A CN 201310296689 A CN201310296689 A CN 201310296689A CN 103333396 A CN103333396 A CN 103333396A
- Authority
- CN
- China
- Prior art keywords
- bottle
- high light
- photostabilizer
- dispersion agent
- bottle material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000463 material Substances 0.000 title claims abstract description 19
- 239000004698 Polyethylene Substances 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 17
- 239000001993 wax Substances 0.000 claims description 13
- 238000012986 modification Methods 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 9
- 239000006096 absorbing agent Substances 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 239000004200 microcrystalline wax Substances 0.000 claims description 6
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 6
- 239000002516 radical scavenger Substances 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 abstract description 10
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 10
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract description 10
- 239000008117 stearic acid Substances 0.000 abstract description 10
- 239000000049 pigment Substances 0.000 abstract description 9
- 239000002699 waste material Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000004611 light stabiliser Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000002356 single layer Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 238000005303 weighing Methods 0.000 description 8
- 238000005453 pelletization Methods 0.000 description 7
- 238000007664 blowing Methods 0.000 description 6
- 239000012467 final product Substances 0.000 description 6
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a modified high-gloss PE bottle material which comprises the following components in percentage by weight: PE 60-80%, stearic acid polymer 3-10%, maleic anhydride graft 3-10%, light stabilizer 3-10%, dispersant 1-15%, and pigment 1-20%. The invention solves the problem that the common PE bottle in the market can not achieve the effect of high brightness of the surface; the nozzle material produced during production can be directly recycled, so that the waste and the cost are reduced; the bottles made by the present invention can be produced on a single layer machine, which reduces cost and does not require the limitations of using multiple layer machines.
Description
[technical field]
The present invention relates to a kind of PE bottle material, relate to the high light PE of a kind of modification bottle material particularly.
[background technology]
The highlighted PE bottle of high light on the existing market has following two kinds substantially:
A kind of is the multilayer bottle, and internal layer is the PE material, and the centre adds bonding agent, and skin is PP or functional plastic; This multilayer bottle causes mouth of a river material can not reclaim use, causes waste big; The production of this multilayer bottle requires high to board, the machine more than three layers just can be produced.
Another kind is that the PE bottle surface of producing is carried out secondary processing, makes its effect that reaches Gao Guang, and secondary processing increases cost increase while scrap rate.
[summary of the invention]
The objective of the invention is to overcome the deficiencies in the prior art, provide a kind of PE of making bottle surface to produce the highlighted effect of high light, the mouth of a river material that produces during production can directly reclaim use, cut the waste and cost, break through and to use the multilayer machine to produce the limitation of the high light bottle of PE in the past, use individual layer machine or multilayer machine all can produce the high light PE of the modification bottle material of the high light bottle of PE.
The present invention for achieving the above object, by the following technical solutions:
The high light PE of modification bottle material is characterized in that being made up of following weight percent component:
PE 60%～80%
Stearic acid polymkeric substance 3%～10%
Maleic anhydride graft 3%～10%
Photostabilizer 3%～10%
Dispersion agent 1%～15%
Pigment 1%～20%.
Photostabilizer among the present invention is one or more mixtures in photomask agent, UV light absorber, quencher and the radical scavenger.
Dispersion agent among the present invention is one or more mixtures in polyethylene wax, Microcrystalline Wax and the synthetic wax.
Stearic acid polymkeric substance, maleic anhydride graft, these three kinds of material combinations of photostabilizer make the PE bottle of making have highlighted effect among the present invention.
The present invention has following advantage compared with the prior art:
1, the invention solves on the market common PE bottle and do not accomplish the highlighted effect of surperficial high light;
2, the present invention makes the mouth of a river material that produces when producing directly reclaim use, cuts the waste and cost;
Can produce with the individual layer machine when 3, preparing bottle with the present invention, not only reduce cost but also do not need to use the restriction of multilayer machine.
[embodiment]
The high light PE of modification bottle material, it is made up of following weight percent component: PE60%～80%, stearic acid polymkeric substance 3%～10%, maleic anhydride graft 3%～10%, photostabilizer 3%～10%, dispersion agent 1%～15%, pigment 1%～20%.
Photostabilizer wherein is one or more mixtures in photomask agent, UV light absorber, quencher and the radical scavenger; Dispersion agent is one or more mixtures in polyethylene wax, Microcrystalline Wax and the synthetic wax.
The method that the present invention prepares the finished product bottle comprises following two kinds of methods:
1, take by weighing raw material by proportioning and mixed 5-10 minute, the bottle blowing machine temperature is set the 170-200 degree, with mixed raw materials by the bottle blowing machine bottle blowing;
2, take by weighing raw material by proportioning and mixed 3-5 minute, then with twin screw extruder routinely the processing parameter setting extruding pelletization be master batch, the bottle blowing machine temperature is set the 170-200 degree, by the bottle blowing machine bottle blowing.
The invention will be described further below in conjunction with specific embodiment:
Embodiment 1:
PE60%, stearic acid polymkeric substance 10%, maleic anhydride graft 10%, photostabilizer 10%, dispersion agent 1%, pigment 9%.Take by weighing raw material and mix by above proportioning, then with twin screw extruder routinely the processing parameter extruding pelletization get final product;
Photostabilizer wherein is photomask agent; Dispersion agent is polyethylene wax.
Embodiment 2:
PE70%, stearic acid polymkeric substance 6%, maleic anhydride graft 6%, photostabilizer 6%, dispersion agent 7%, pigment 5%.Take by weighing raw material and mix by above proportioning, then with twin screw extruder routinely the processing parameter extruding pelletization get final product;
Photostabilizer wherein is UV light absorber; The dispersion agent Microcrystalline Wax.
Embodiment 3:
PE80%, stearic acid polymkeric substance 3%, maleic anhydride graft 3%, photostabilizer 3%, dispersion agent 1%, pigment 10%.Take by weighing raw material and mix by above proportioning, then with twin screw extruder routinely the processing parameter extruding pelletization get final product;
Photostabilizer quencher wherein and the mixture of radical scavenger; The dispersion agent synthetic wax.
Embodiment 4:
PE60%, stearic acid polymkeric substance 3%, maleic anhydride graft 3%, photostabilizer 3%, dispersion agent 15%, pigment 16%.Take by weighing raw material and mix by above proportioning, then with twin screw extruder routinely the processing parameter extruding pelletization get final product;
Photostabilizer wherein is the mixture of photomask agent and UV light absorber; Dispersion agent is the mixture of polyethylene wax and Microcrystalline Wax.
Embodiment 5:
PE60%, stearic acid polymkeric substance 6%, maleic anhydride graft 7%, photostabilizer 6%, dispersion agent 1%, pigment 20%.Take by weighing raw material and mix by above proportioning, then with twin screw extruder routinely the processing parameter extruding pelletization get final product;
Photostabilizer wherein is the mixture of photomask agent, UV light absorber and radical scavenger; Dispersion agent is the mixture of polyethylene wax and synthetic wax.
Embodiment 6:
PE65%, stearic acid polymkeric substance 10%, maleic anhydride graft 7%, photostabilizer 8%, dispersion agent 9%, pigment 1%.Take by weighing raw material and mix by above proportioning, then with twin screw extruder routinely the processing parameter extruding pelletization get final product;
Photostabilizer wherein is the mixture of photomask agent, UV light absorber and quencher; Dispersion agent is the mixture of polyethylene wax, Microcrystalline Wax and synthetic wax.
Beat transparent sample board and high light PP with the master batch of embodiment of the invention 1-6, the transparent sample board that common PE is beaten carries out the haze detection contrast by the GB-T2410-2008 detection method, and its mist degree test result under same light source is as shown in table 1:
Table 1:
| The sample board | Haze value H(%) |
| Embodiment 1 | 5.8 |
| Embodiment 2 | 6.2 |
| Embodiment 3 | 6.1 |
| Embodiment 4 | 5.5 |
| Embodiment 5 | 6.0 |
| Embodiment 6 | 5.9 |
| High light PP | 1.4 |
| Common PE | 26 |
Transparent material refers to its haze value between 0-30%, when the haze value of material greater than 30% the time, be opaque material then, haze value is more little, transparency is more good, the highlighted better effects if of high light.
Data from table 1 can see, the high light PE of modification of the present invention is substantially near high light PP, than little many of common PE mist degree; Thereby reach the highlighted effect of high light.
Claims (3)
1. the high light PE of modification bottle material is characterized in that being made up of following weight percent component:
2. the high light PE of modification according to claim 1 bottle material is characterized in that described photostabilizer is one or more mixtures in photomask agent, UV light absorber, quencher and the radical scavenger.
3. the high light PE of modification according to claim 1 bottle material is characterized in that described dispersion agent is one or more mixtures in polyethylene wax, Microcrystalline Wax and the synthetic wax.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102966892A CN103333396A (en) | 2013-07-15 | 2013-07-15 | Modified high-gloss PE bottle material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102966892A CN103333396A (en) | 2013-07-15 | 2013-07-15 | Modified high-gloss PE bottle material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103333396A true CN103333396A (en) | 2013-10-02 |
Family
ID=49241609
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102966892A Pending CN103333396A (en) | 2013-07-15 | 2013-07-15 | Modified high-gloss PE bottle material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103333396A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04119170A (en) * | 1990-09-08 | 1992-04-20 | Nissan Maruzen Poriechiren Kk | High-density polyethylene resin composition for monofilament |
| CN102627827A (en) * | 2012-03-19 | 2012-08-08 | 上海锦湖日丽塑料有限公司 | Aesthetic resin composition having metal appearance and preparation method thereof |
-
2013
- 2013-07-15 CN CN2013102966892A patent/CN103333396A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04119170A (en) * | 1990-09-08 | 1992-04-20 | Nissan Maruzen Poriechiren Kk | High-density polyethylene resin composition for monofilament |
| CN102627827A (en) * | 2012-03-19 | 2012-08-08 | 上海锦湖日丽塑料有限公司 | Aesthetic resin composition having metal appearance and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20131002 |