Summary of the invention
The invention reside in solve adopts converter cannot produce thickness and be greater than 114 millimeters, though adopt forging mode to produce, cost is high, and inefficient deficiency, provide a kind of by adopting electric furnace
withthe mode that esr combines, produce not only yield strength and be at least 650MPa, thickness is greater than 114 millimeters, and the ocean platform rack steel of cost 500 ~ 700 yuan/ton steel lower than forging mode and production method thereof.
Realize the measure of above-mentioned purpose:
The ocean platform rack steel of a kind of thickness >=114mm, its component and weight percent content are: C:0.14 ~ 0.192, Si:0.15 ~ 0.35, Mn:0.98 ~ 1.3, P :≤0.014, S :≤0.008, Cr:0.15 ~ 0.35, Ni:1.2 ~ 1.5, Mo:0.40 ~ 0.58, Cu:0.15 ~ 0.26, V:0.032 ~ 0.068, [O]≤0.0003, [N]≤0.007, Sn :≤0.003, As :≤0.003, Sb :≤0.002, and all the other are Fe and relict element; And weld metal embrittlement-sensitive property coefficient should be met: X=(10P+5Sb+4Sn+As) × 1000≤16.
Produce the method for the ocean platform rack steel of a kind of thickness >=114mm, the steps include:
1) carry out electrosmelting, control tapping temperature at 1640-1660 DEG C;
2) at LF refining furnace, quickened lime is added according to 7.1 ~ 10 kgs/tonne of steel;
3) vacuum metling in VD stove, controls argon flow amount at 80-90NL/min;
4) vacuumize in VD stove and carry out pressurize, the control pumpdown time is no less than 30 minutes; When vacuum tightness near not higher than 67Pa time, start pressurize, control the dwell time be not less than 20 minutes;
5) in VD stove, carry out soft blow, soft argon blowing time is not less than 10 minutes;
6) continuous casting, controls starting pulling rate at 1.6 ~ 1.8 ms/min;
7) electric slag refusion and smelting is carried out: add pre-melted slag according to 5.7 ~ 8.6 kgs/tonne of steel; Toast at the temperature of 1600 ~ 1700 DEG C, baking time is 2.5 ~ 4.5 hours; Carrying out slag after oven dry; First 8 minutes of change slag blowing out, in melt cinder, add aluminum shot according to 1.0 ~ 2.0 kgs/tonne of steel carry out pre-deoxidation; Before slagging tap, add Mn powder according to a 0.5kg ~ 1.5 kg/tonne steel, before going out slag hearth, molten steel temperature control is at 1650-1750 DEG C; Adopt aluminum shot to carry out deoxidation, add aluminum shot according to the speed of 30 ~ 40 gram/minute; Enter the remelting phase, stripping speed control is in 8.0 ~ 8.5 mm/min, and burn-off rate controls in 36-38.5 kg/minute; Carry out hole cold, the time is not less than 48 hours;
8) heat electroslag base, Heating temperature is 1200 DEG C ~ 1240 DEG C, and heating rate is 10 ~ 13min/cm, controls tapping temperature at 1180 DEG C ~ 1230 DEG C;
9) segmentation is rolled: control roughing start rolling temperature at 1100 DEG C ~ 1200 DEG C, and control draught per pass 6.25 ~ 10.12%, the steel plate thickness after roughing terminates controls at 190mm ~ 240mm; Control finish rolling start rolling temperature at 840 DEG C ~ 880 DEG C, finishing temperature, at 820 DEG C ~ 840 DEG C, controls the last three passage total reductions of finish rolling and is not less than 40%;
10) carry out air cooling, control final cooling temperature between 650 DEG C ~ 700 DEG C;
11) heat-treat: adopt quenching+tempering processing mode, control normalizing Heating temperature at 920 DEG C ~ 950 DEG C, heat-up time was at 165 ~ 210 minutes; Control tempering Heating temperature at 630 DEG C ~ 670 DEG C, heat-up time was at 195 ~ 240 minutes.
12) stand-by.
The function and mechanism of each element and main technique in the present invention:
C:C is one of element of the indispensable raising steel strength of steel grade, and carbon content often increases by 0.10% tensile strength and approximately improves 60MPa, and yield strength approximately improves 20 ~ 30MPa.Along with the increase of carbon content, in steel, Fe3C increases, and hardenability also increases, and the tensile strength of steel and yield strength can improve, and plasticity and toughness index can decline, and welding property is deteriorated.This steel grade is applicable to high strength and low-temperature flexibility, wherein with C element to ensure high strength, need to ensure certain toughness and welding property, so regulation C content is tending towards medium, lower limit is 0.14%, and the upper limit is 0.192% simultaneously.
Si:Si mainly improves steel strength with solution strengthening form, is also the deoxidant element of steel grade.If but Si content is higher in steel, then reduction of area can be caused to decline, and particularly impact toughness decreased is obvious, simultaneously also unfavorable to the weldability of steel, and the intensity rank of rack steel is higher, need certain Si content proof strength to be main, therefore Si content is selected 0.15% ~ 0.35%.
Mn: in the intensity guaranteeing steel and toughness, Mn are indispensable elements.And the intensity rank of rack steel is higher, need certain Mn content proof strength to be main, therefore the content of Mn is selected 0.98 ~ 1.30%.
P, S: control P≤0.014%, S≤.008%, this is owing to only having smelting Clean Steel, the over-all properties of guarantee steel of the present invention.
Cr: select the content of Cr 0.15 ~ 0.35%, is because Cr can improve steel plate hardening capacity, ferritic phase apparition is moved to right, and the cooling rate of widening bainitic transformation is interval, promotes the formation of middle temperature transformation tissue, improves steel plate yield strength.
Ni:Ni has strengthening effect, and the Ni adding 1% can improve steel strength 20MPa.Ni can also improve the toughness, particularly low-temperature flexibility of steel significantly.Steel grade adds Ni, is that base material or simulated welding heat affected zone all significantly enhance low-temperature flexibility. and therefore steel grade of the present invention devises higher Ni content, and select lower limit to be 1.20%, the upper limit is 1.50%.
The content of Mo:Mo is selected 0.40 ~ 0.58%, is because Mo can improve steel plate hardening capacity, ferritic phase apparition is moved to right, and the cooling rate of widening bainitic transformation is interval, promotes the formation of middle temperature transformation tissue, improves steel plate yield strength.And invention steel grade needs to carry out the heat treatment process of quenching, therefore the Mo of this scope is conducive to the hardening capacity improving steel plate.
Cu:Cu is austenite former, while expansion austenite phase field, also in drawing process, facilitate austenitic formation and stabilization.The low-temperature flexibility that Ni improves steel simultaneously also improves the intensity of steel, but the hardening capacity of steel plate and hardenability can be made to increase when Ni too high levels, steel plate HAZ toughness is reduced, the welding property of deterioration steel plate.The existence of a small amount of Cu can significantly improve the corrosion potential of steel, thus improves the corrosion resistance nature of steel.Simultaneously when the content of Cu acquires a certain degree, but the precipitate of ε-Cu can improve the intensity of steel plate. the content of Cu higher than 0.18% time, the hot-short phenomenon of steel can be caused, worsen plate surface quality.Therefore, select lower limit to be 1.20%, the upper limit is 1.50%.
The effect of V:V element crystal grain thinning is comparatively strong, can improve intensity and the toughness of steel, reduce superheated susceptivity, improve thermostability, improve the temper resistance of M body.Reduce the alloy degree of sosoloid because V and C is combined to VC, so hardness reduces, when quenching temperature is increased to a lot more than AC3 point (and having longer soaking time), then VC turns into sosoloid, so hardness can improve.V has adverse influence to hardening capacity in general, but toughness is better, has added V not easily hardening crack.Medium carbon steel of the present invention adds V can improve intensity, simultaneously toughness not step-down.Therefore select lower limit to be 0.032%, the upper limit is 0.068%.
Rare elements: Sn, As and Sb element is harmful element for this invention, these three kinds of elements are very large for the temper brittleness impact of steel grade of the present invention, therefore carried out ceiling restriction for these three kinds of elements.
N :≤0.007%, steel grade N element is comparatively large for the Toughness of steel plate, has therefore done the restriction of the upper limit.
The present invention compared with prior art, utilize the pattern of traditional converter smelting-rolling cannot produce the thick ocean platform rack steel of spy of more than 114mm, and not only cost is high but also efficiency is extremely low to adopt the mode forged to produce the special thick ocean platform rack steel of more than 114mm, the mode that the present invention combines with esr by adopting electric furnace, produce not only yield strength and be at least 650MPa, thickness is at 114 ~ 152 millimeters, and cost 500 ~ 700 yuan/ton steel lower than forging mode, can manufacture, very favourable to improving product competitive power.
Embodiment
Below the present invention is described in detail:
Table 1 is the value list of various embodiments of the present invention and comparative example;
Table 2 is the main technologic parameters list of various embodiments of the present invention and comparative example;
Table 3 is various embodiments of the present invention and the list of comparative example performance monitoring situation;
Various embodiments of the present invention are produced according to following steps:
Its step:
1) carry out electrosmelting, control tapping temperature at 1640-1660 DEG C;
2) at LF refining furnace, quickened lime is added according to 7.1 ~ 10 kgs/tonne of steel;
3) vacuum metling in VD stove, controls argon flow amount at 80-90NL/min;
4) vacuumize in VD stove and carry out pressurize, the control pumpdown time is no less than 30 minutes; When vacuum tightness near not higher than 67Pa time, start pressurize, control the dwell time be not less than 20 minutes;
5) in VD stove, carry out soft blow, soft argon blowing time is not less than 10 minutes;
6) continuous casting, controls starting pulling rate at 1.6 ~ 1.8 ms/min;
7) electric slag refusion and smelting is carried out: add pre-melted slag according to 5.7 ~ 8.6 kgs/tonne of steel; Toast at the temperature of 1600 ~ 1700 DEG C, baking time is 2.5 ~ 4.5 hours; Carrying out slag after oven dry; First 8 minutes of change slag blowing out, in melt cinder, add aluminum shot according to 1.0 ~ 2.0 kgs/tonne of steel carry out pre-deoxidation; Before slagging tap, add Mn powder according to a 0.5kg ~ 1.5 kg/tonne steel, before going out slag hearth, molten steel temperature control is at 1650-1750 DEG C; Adopt aluminum shot to carry out deoxidation, add aluminum shot according to the speed of 30 ~ 40 gram/minute; Enter the remelting phase, stripping speed control is in 8.0 ~ 8.5 mm/min, and burn-off rate controls in 36-38.5 kg/minute; Carry out hole cold, the time is not less than 48 hours;
8) heat electroslag base, Heating temperature is 1200 DEG C ~ 1240 DEG C, and heating rate is 10 ~ 13min/cm, controls tapping temperature at 1180 DEG C ~ 1230 DEG C;
9) segmentation is rolled: control roughing start rolling temperature at 1100 DEG C ~ 1200 DEG C, and control draught per pass 6.25 ~ 10.12%, the steel plate thickness after roughing terminates controls at 190mm ~ 240mm; Control finish rolling start rolling temperature at 840 DEG C ~ 880 DEG C, finishing temperature, at 820 DEG C ~ 840 DEG C, controls the last three passage total reductions of finish rolling and is not less than 40%;
10) carry out air cooling, control final cooling temperature between 650 DEG C ~ 700 DEG C;
11) heat-treat: adopt quenching+tempering processing mode, control normalizing Heating temperature at 920 DEG C ~ 950 DEG C, heat-up time was at 165 ~ 210 minutes; Control tempering Heating temperature at 630 DEG C ~ 670 DEG C, heat-up time was at 195 ~ 240 minutes.
12) stand-by.
The chemical composition value list (one) of table 1 various embodiments of the present invention and comparative example
The chemical composition value list (two) of table 1 various embodiments of the present invention and comparative example
The main technologic parameters list (one) of table 2 various embodiments of the present invention and comparative example
The main technologic parameters list (two) of table 2 various embodiments of the present invention and comparative example
The main technologic parameters list (three) of table 2 various embodiments of the present invention and comparative example
The main technologic parameters list (four) of table 2 various embodiments of the present invention and comparative example
The main technologic parameters list (five) of table 2 various embodiments of the present invention and comparative example
Table 3 is various embodiments of the present invention and comparative example mechanical properties test the results list
Note: comparative example 1 and 2 is the steel adopting converter smelting.
As everyone knows, steel plate thickness is larger, then mechanical property is more difficult to ensure.But as can be seen from Table 3, comparative example 1 and 2 is compared with the present invention, although mechanical property is more or less the same, thickness differs widely, the thicklyest reach 152 millimeters.This just illustrates, the present invention is under ensureing that mechanical property meets the prerequisite of the new market requirement, and meeting again user needs steel plate thickness to be greater than the new demand of more than 114 millimeters.
Above-described embodiment is only the best and exemplifies, and is not the restriction to embodiments of the present invention.