CN103319842A - Flame-retardant acrylonitrile-butadiene-styrene plastic - Google Patents
Flame-retardant acrylonitrile-butadiene-styrene plastic Download PDFInfo
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- CN103319842A CN103319842A CN2013102444619A CN201310244461A CN103319842A CN 103319842 A CN103319842 A CN 103319842A CN 2013102444619 A CN2013102444619 A CN 2013102444619A CN 201310244461 A CN201310244461 A CN 201310244461A CN 103319842 A CN103319842 A CN 103319842A
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- butadiene
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- acrylonitrile
- styrene
- retardant
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Abstract
The invention relates to a plastic, and in particular relates to a flame-retardant acrylonitrile-butadiene-styrene plastic which contains the following components in parts by mass: 70 to 80 parts of acrylonitrile-butadiene-styrene, 2 to 6 parts of antimony trioxide and 20 to 30 parts of tetrabromobisphenol A. The plastic provided by the invention does not contain poly-brominated diphenyl ether, polybrominated diphenyl ether and other materials which are prohibited from being exported, and is moderate in cost.
Description
Technical field
The present invention relates to a kind of plastics, is a kind of fire-retardant acrylonitrile-butadiene diene-styrene plastic(s) specifically.
Background technology
The used fire retardant nearly 95% of present flame-proof ABS plastics is halogen containing flame-retardant, particularly the brominated flame-retardant efficient take polybromodiphenyl ether and polybrominated biphenyl material as representative is high, consumption is few, performance impact to material is little, and moderate, non-other fire retardants of its usefulness/cost ratio can be equal to, so 70%～80% all use this based flame retardant in China's electric series products for export.But bromide fire retardant is subject to the puzzlement of dioxin problem in recent years, use simultaneously its (bromo-antimony system) fire-retardant macromolecular material the time can generate a large amount of flue dust and corrosive gases in thermo-cracking and burning, at present European Union and Japan this based flame retardant of use of putting into effect in succession that it is forbidden by decree to.European Union will rise on July 1st, 2006 and implement in full the ROHS instruction, and the electronic and electrical equipment that this decree requires to throw in European Union must not contain poly-dibromodiphenyl ether, poly-bromo biphenyl, and this decree has seriously restricted the outlet of China's electronic and electrical equipment.
Summary of the invention
Technical problem to be solved by this invention is, a kind of fire-retardant acrylonitrile-butadiene diene-styrene plastic(s) is provided, and these plastics do not contain the materials such as poly-dibromodiphenyl ether, poly-bromo biphenyl, moderate cost.
The present invention solves the technical scheme of above technical problem:
A kind of fire-retardant acrylonitrile-butadiene diene-styrene plastic(s), the mass parts of the required proportioning component of plastics is: acrylonitrile-butadiene-styrene (ABS): 70-80 part, antimonous oxide: 2-6 part, tetrabromo-bisphenol: 20-30 part.
The technical scheme that the present invention further limits is:
Further, the mass parts of the required proportioning component of plastics is: acrylonitrile-butadiene-styrene (ABS): 72 parts, and antimonous oxide: 4 parts, tetrabromo-bisphenol: 24 parts.
The flame-proof ABS correlated performance that the plastics of fire-retardant acrylonitrile-butadiene diene-styrene plastic(s) provided by the invention gets: oxygen index 33.6%, notched Izod impact strength 80.1J/m, flexural strength 2.4MPa, stretching die formula weight 2.3GPa.
In a word, this plastics provided by the invention do not contain material, moderate costs such as exporting the poly-dibromodiphenyl ether of forbidding, poly-bromo biphenyl.
Embodiment
Embodiment 1
A kind of fire-retardant acrylonitrile-butadiene diene-styrene plastic(s), the mass parts of the required proportioning component of these plastics is: acrylonitrile-butadiene-styrene (ABS): 72 parts, antimonous oxide: 4 parts, tetrabromo-bisphenol: 24 parts.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.
Claims (2)
1. fire-retardant acrylonitrile-butadiene diene-styrene plastic(s), it is characterized in that: the mass parts of the required proportioning component of described plastics is: acrylonitrile-butadiene-styrene (ABS): 70-80 part, antimonous oxide: 2-6 part, tetrabromo-bisphenol: 20-30 part.
2. fire-retardant acrylonitrile-butadiene diene-styrene plastic(s) according to claim 1, it is characterized in that: the mass parts of the required proportioning component of described plastics is: acrylonitrile-butadiene-styrene (ABS): 72 parts, antimonous oxide: 4 parts, tetrabromo-bisphenol: 24 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102444619A CN103319842A (en) | 2013-06-20 | 2013-06-20 | Flame-retardant acrylonitrile-butadiene-styrene plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102444619A CN103319842A (en) | 2013-06-20 | 2013-06-20 | Flame-retardant acrylonitrile-butadiene-styrene plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103319842A true CN103319842A (en) | 2013-09-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102444619A Withdrawn CN103319842A (en) | 2013-06-20 | 2013-06-20 | Flame-retardant acrylonitrile-butadiene-styrene plastic |
Country Status (1)
| Country | Link |
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| CN (1) | CN103319842A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101003660A (en) * | 2006-01-20 | 2007-07-25 | 佛山市顺德区汉达精密电子科技有限公司 | Fire retardant modified ABS resin with high surface hardness |
| CN101061177A (en) * | 2005-12-19 | 2007-10-24 | Lg化学株式会社 | Acrylonitrile-butadiene-styrene resin composition having good weatherability and thermostability |
| CN101456995A (en) * | 2007-12-11 | 2009-06-17 | 天津德昊超微新材料有限公司 | Environmental protection flame retardant styrene resin |
| CN101875745A (en) * | 2010-03-30 | 2010-11-03 | 金发科技股份有限公司 | Flame-retardant styrene polymer compound containing smoke inhibitor and preparation method thereof |
| CN102372896A (en) * | 2010-08-13 | 2012-03-14 | 上海锦湖日丽塑料有限公司 | Low-odor flame retardant styrene-based resin composition and preparation method thereof |
-
2013
- 2013-06-20 CN CN2013102444619A patent/CN103319842A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101061177A (en) * | 2005-12-19 | 2007-10-24 | Lg化学株式会社 | Acrylonitrile-butadiene-styrene resin composition having good weatherability and thermostability |
| CN101003660A (en) * | 2006-01-20 | 2007-07-25 | 佛山市顺德区汉达精密电子科技有限公司 | Fire retardant modified ABS resin with high surface hardness |
| CN101456995A (en) * | 2007-12-11 | 2009-06-17 | 天津德昊超微新材料有限公司 | Environmental protection flame retardant styrene resin |
| CN101875745A (en) * | 2010-03-30 | 2010-11-03 | 金发科技股份有限公司 | Flame-retardant styrene polymer compound containing smoke inhibitor and preparation method thereof |
| CN102372896A (en) * | 2010-08-13 | 2012-03-14 | 上海锦湖日丽塑料有限公司 | Low-odor flame retardant styrene-based resin composition and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C04 | Withdrawal of patent application after publication (patent law 2001) | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20130925 |