CN103319033A - Photocatalytic wastewater degradation reactor capable of actively preventing water inrush of quartz cavity - Google Patents

Abstract

The invention relates to a photocatalytic wastewater degradation reactor capable of actively preventing the water inrush of a quartz cavity, which belongs to the technical field of wastewater treatment. The technical scheme aims at solving the problems of the water inrush of the cavity of a quartz tube for shielding an electrodeless lamp, the loss of nano-photocatalyst, the energy waste of a microwave, the low single-tank wastewater treatment amount of a reactor, the difficultly-distinguished endpoint time of degradation reaction, incapacity of powerfully dissipating catalyst aggregates, incapacity of immediately detecting the occurrence of catalyst aggregation, the corrosion on a magnetron due to the reverse flow of secondary ozone, and the like in the existing related technologies,. According to the scheme, a micro diaphragm pump capable of running in a normal state with low power consumption is connected to a connection gas tube between an air pump and the tube cavity of the quartz tube by means of bypass, the micro diaphragm pump can be used for providing continuous low-flow-rate air supplementation for the tube cavity of the quartz tube, so as to prevent the water inrush of the tube cavity of the quartz cavity; the microwave is restrained by a metal cage, so as to realize large-amplitude expansion for the reactor; the other problems are also solved in the scheme.

Description

A kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water

Technical field

The present invention relates to a kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water, belong to the C02F technical field of waste water processing.

Background technology

Microwave and photo catalysis degradation treatment technology, effectively for the innoxious process for treating containing the organic pollutant trade effluent, quite concerned in recent years as a kind of.

About the microwave and photo catalysis degradation technique, as an example, the Chinese patent application case that can be CN102260003A referring to publication number.

The Chinese patent application case that the disclosure number is CN102260003A, to using microwave as excitaton source, excite electrodeless ultraviolet lamp emission ultraviolet ray, irradiate the suspension that is mixed with photocatalyst titanium dioxide in liquid internal, this electrodeless ultraviolet lamp is shrouded and is protecting by silica tube, there is pneumatic pump to continue to inject air to this silica tube inner chamber, the air overflowed by quartz cavity is via pipeline and the micro porous aeration head UNICOM that is positioned at reactor bottom, the lower zone of this inside reactor is aeration zone, the upper area of this inside reactor is the microwave and photo catalysis reaction zone, this scheme is the built-in membrane separation assemblies with reactor also, carry the water of analysing after purification, and realize that with this membrane separation assemblies holding back again of photocatalyst titanium dioxide fine particles use, this scheme is also set up dividing plate between non-polar ultraviolet light source and membrane separation assemblies, for preventing the radiation injury of ultraviolet ray to organic membrane separation assemblies, pass into the air of inside reactor, part is participated in the photocatalytic degradation reaction that relies on photocatalyst titanium dioxide directly, some air, under the direct irradiation of UV-light, generate a certain amount of ozone, the ozone of this generation is also being brought into play the direct oxidative degradation for organic pollutant certainly.

The disclosure is number for the Chinese patent application case of CN102260003A has certainly played very important pushing effect for the progress of microwave and photo catalysis wastewater degradation technology, and the work that its research staff launches in this field is admirable.

The meaning of the admiration based on sincere, and, common striving direction, what below us, will talk is problem.

The problem that below will speak of, have 16; These 16 problems are 16 problems arranged side by side; The priority of its sequence is only to consider for discussing easily.

One of problem:

The Chinese patent application case that the disclosure number is CN102260003A, it is to be placed in the reactor inner chamber for the membrane separation assemblies of tackling the catalyzer titanium dioxide fine particles, be immersed in and process among object liquid, and what rely on ascension washes away membrane separation assemblies containing ozone bubbles, removing by this its surface adsorbs, the catalyst particles be detained, reach the recovery of catalyst particles, the recycling purpose, simultaneously, membrane separation assemblies is also to rely on this mode self-cleaning and keep its separating power, so, based on this structure, can only select curtain formula hollow fiber film assembly or plate film assembly for business, and, this membrane separation assemblies is need to be immersed in the context of strong oxidizing property of ozone bubbles ascension, therefore, tolerance against oxidative power to membrane separation assemblies must have requirement, the organic membrane separation assembly of common material can not tolerate such environment for use, therefore can only select the membrane separation assemblies of PVDF material, this point clearly illustrates that in open the 0009th section word of text of this case and claim 3, its material cost of filter membrane of the tolerance against oxidative power that this kind of needs are special is higher, common organic micro-filtration membrane module that its commercially available price also requires higher than the non-oxidation tolerance certainly, in other words, the frame mode of this case, cause the material of membrane separation assemblies to be limited to more expensive PVDF material.Have again, UV-light possible in device is revealed, may touch the organic membrane assembly, this also the organic membrane assembly material in claimed apparatus can resist ultraviolet light irradiation, from this point, organization plan based on this device, the material of organic membrane separation assembly also can only be limited in more expensive PVDF material.

The organic membrane assembly, compared to the ceramic filter assemblies, has its apparent advantage; About this point, for the personage of filtering technique specialty, be known, here do not launch to repeat.

Can so, under the prerequisite of using the organic material membrane module, bypass this PVDF filter membrane material limitation? this is the problem that needs solve, and this one of is problem.

Two of problem:

Scouring force in view of described ascension bubble, cleaning capacity is more weak, therefore, can only select other filter opening aperture of larger micro-filtration level with its aperture of membrane separation assemblies that this cleaning mode is used in conjunction with, other filter opening aperture of this micro-filtration level is the 0.1-0.2 micron, about this point, have clearly and limit in open the 0009th section word of text of this case and claim 3 equally, this kind of filter opening aperture limits, the type selecting of such membrane separation assemblies from this case, built-in and soak use-pattern, the self-cleaning method of ascension bubble, be inevitable, can only limit its filter opening aperture in the micro-filtration rank.In other words, this its scouring force of the mode of washing away with the ascension bubble, clean power too a little less than, to such an extent as to can't tackle the more filter membrane of small-bore at all, thus, in this case device, the filter membrane aperture is limited between 0.1 micron-0.2 micron, is the inevitable choice of not discussing leeway.

The filter opening aperture of so-called 0.1-0.2 micron, if change a measure unit, corresponding is exactly the filter opening aperture of 100-200 nanometer; Is what concept that? with 100 nanometer filter opening apertures of its lower limit, its size of catalyst particles that it can be tackled must be more than 100 nanometers, and the catalyst particles that is less than 100 nanometers can't be blocked; In other words, the catalyst particles that is less than 100 nanometers will directly penetrate, by the filter opening of membrane module, sneak among the so-called water purification that the DeR device exports.

Particle diameter and the photocatalyst dosage form selection of the related photocatalyst of the ultraviolet catalytic DeR of need to having a talk now.

The professional person who is engaged in photocatalytic degradation research knows, with the photochemical degradation reaction of uv light induction, its catalyzer multiselect titanium dioxide fine particles catalyzer, at present, developed the photodegradation particle catalyst based on the optically catalytic TiO 2 characteristic various in style on laboratory level, certainly, the photodegradation catalyzer that these different preparation methods form, its particle diameter is also various, its particle diameter of photocatalyst that different preparation methods make is little of 20 nanometers, and greatly to 100000 nanometer also is 100 microns, has, and wherein is no lack of the photocatalyst kind of excellent performance, but due to the restriction of the evaluation of performance permanent stability, preparation cost and the market expansion etc. aspect factor, most its deliverabilities of described photocatalyst only are confined to laboratory level, and there is no to form extensive commercially available production level, at present known can make a big purchase in large quantities commercially available can actual a large amount of photocatalysts for the UV-light wave band that use be famous gas phase titanium dioxide P25, its concrete art-recognized meanings of gas phase titanium dioxide P25, the insider knows, does not here launch to repeat, the median size of gas phase titanium dioxide P25 is 21 nanometers, gas phase titanium dioxide P25 performance is not very optimum, but, its stable performance, key is to make a big purchase in large quantities and to obtain on market, and can on technical scale, use in a large number, therefore, in photochemical catalysis specialized laboratory also usually with the P25 catalyzer be used as weighing various self-made photocatalyst catalytic performances with reference to pointer or contrast pointer, in fact, characteristics in view of the ultraviolet catalytic DeR, the photocatalyst that dispersity is higher, the needs that are applicable to this type reaction, that is to say, median size is in its catalyst interfacial area that can provide of photocatalyst of 21 nanometer left and right, the anti-settling ability, catalytic performance permanent stability etc. aspect, comprehensive, optimal.Say simply, at present, good and cheap, the photocatalyst of the UV-light wave band of the ready-made commercially available commercial grade that can actually make a big purchase in large quantities, use, be exactly the gas phase titanium dioxide P25 catalyzer that median size is 21 nanometers; At plant-scale application, the photocatalyst that this median size is 21 nanometers is actual first-selection.

Above address, the Chinese patent application case that the disclosure number is CN102260003A, it is for tackling the membrane module of photocatalyst, that the stripping film assembly surface that washes away with the ascension bubble is adsorbed, the catalyst particles of deposition, yet, its scouring force of the mode that this kind washes away with the ascension bubble, clean power too a little less than, to such an extent as to can't tackle the more filter membrane of small-bore at all, therefore, in this case device, the filter membrane aperture is limited at micro-filtration filter opening rank between 0.1 micron-0.2 micron, change a measure unit, in this case device, the filter membrane aperture is limited at the micro-filtration filter opening rank between 100 nanometers-200 nanometer, this is the inevitable choice of not discussing leeway, this case can't tackle without the micro-filtration filter opening between selectable 100 nanometers-200 nanometer the gas phase titanium dioxide P25 particle that median size as above is 21 nanometers certainly, so, if use the P25 photocatalyst, this catalyzer will can't be tackled fully, and flows in so-called water purification, forms secondary pollution, certain heavy losses that also cause catalyzer and unrenewable, even if use other kind for this reason and the titanium dioxide optical catalyst of special large particle diameter, collide or collide with wall because of mutual in its use procedure, must also can produce a large amount of small particle size fragments, wherein particle diameter is less than the fragment of 100 nanometers, can not be tackled by the micro-filtration filter opening between 100 nanometers-200 nanometer equally, these small shredss also can see through its membrane module and enter among so-called water purification, form secondary pollution.

The Chinese patent application case visible, that the disclosure number is CN102260003A, the cleaning solution of its scheme of interception structure for the photocatalyst particulate and related film assembly is all undesirable.

Therefore, how, under the prerequisite of this case advantage of incorporating things of diverse nature, reaching meticulous interception and recycling for the photocatalyst particulate, is an important topic very worth thinking deeply about, and this is problem two.

Three of problem:

We know, liquid water body itself also can absorb the energy of microwave, and cause itself temperature-rise effect of processed liquid water body, and this temperature-rise effect of following wastewater treatment process and occurring, it not but the situation that we expect, in other words, microwave energy from magnetron is not used to excite electrodeless ultraviolet lamp fully, and have quite a few only to be dissipated in described temperature-rise effect for the microwave energy that excites electrodeless ultraviolet lamp, the temperature-rise effect that this kind is not fond of has caused unnecessary microwave energy to waste, the apparatus structure scheme of showing in view of the above-mentioned publication number Chinese patent application case that is CN102260003A, its rational approach, can only be that volume by reducing the microwave and photo catalysis reactor reduces in other words single tank processing capacity and reaches the purpose that weakens the unnecessary dissipation of microwave, about this point, clear suitable size of having expressed about this apparatus structure integral body in this its embodiment of CN102260003A application case, what its expressed preferred size was corresponding is exactly a device that profile is very little, so, thus, the distance of reactor wall and microwave radiation source is little, the wastewater flow rate contacted with microwave is little, the microwave energy that waste water absorbs is relatively also little, answer in contrast ground, the wastewater treatment capacity of single tank is therefore also little, more particularly, the corresponding internal capacity of device suitable size expressed in embodiment is 40 liters, be also that single tank wastewater treatment capacity is 40 liters, 0.04 cube, in other words, it is once a complete set of, substantial length of operation has only solved the trade effluent of 0.04 cube, so, just need to carry out the repetition to the complete set operation of tail by head many times, its treatment capacity cumulative just has plant-scale meaning, so to say, just individual analogy roughly, its preferred structure size of this case is 0.04 cube of such wastewater treatment capacity of single tank of correspondence roughly, need to repeat the complete set to tail by head of 1000 times, substantial length of operation, its accumulation amount, just can reach 40 cubes such one have industrial level wastewater treatment capacity, so excessively loaded down with trivial details repetitive operation will cause manpower, the serious waste of material resources, visible, its actual wastewater degradation processing efficiency of the scheme that this kind showed by CN102260003A may not be fully up to expectations.Therefore, how not cause more microwave energy wastes or to reduce under the prerequisite of microwave energy waste, increase single tank wastewater treatment capacity, reduce the unnecessary too many repetitive operation number of times to tail by head of this intermittent type wastewater treatment equipment, improve its waste water treatment efficiency, be a significant technical problem merited attention, this is problem three.

Four of problem:

The scheme that this kind showed by CN102260003A, the bubble of the inner dispersed ascension of its retort, for the cyclic motion of the relative big scale of driving a reaction tank internal liquid, contribute slightly inadequate; Certainly, this weak point, in fact corresponding small size, the low capacity device for the CN102260003A scheme as clear expression in its embodiment, the impact that almost has nothing observable.From plant-scale application demand, undersized device that can not the divergence process amount does not have great magnetism certainly; So, as a kind of possibility, if there is certain mode can realize the significantly expansion for the treatment of capacity, under this situation, its importance of the cyclic motion of the relative big scale of retort internal liquid will highlight naturally; Imagining the possibility that this treatment capacity is significantly expanded, so, how to strengthen the cyclic motion of the relative big scale of retort internal liquid, is exactly certainly an individual problem, and this is problem four.

Five of problem:

Photochemical catalysis oxidizing reaction for the UV-light wave band, there is following so several key element can have influence on the efficiency of this kinds of oxidation reaction, first ultraviolet wavelength, intensity, it two is particle diameters of photocatalyst, the usage quantity of photocatalyst in the unit volume reaction solution, himself catalytic performance etc. of photocatalyst, it three is that oxidized object is organic concentration in water body, oxidation complexity that the organic molecule structure determines himself etc., it four is sufficient degree of oxygen atmosphere, in the situation that other condition is identical, the sufficient degree of oxygen atmosphere, will become a very important key element that affects photochemical catalysis oxidative degradation ability.

As the scheme that CN102260003A was showed, its numerous micro porous aeration head disperseds that are placed in reactor inner chamber bottom are in bottom, and by it alleged water distribution board, make the effect of this micro porous aeration head dispersed arrangement become more very, certainly, this is for the situation of the oarse-grained micron-sized photocatalyst that uses relatively easy sedimentation, really there is its favourable one side, but, from another side, the mode that this micro porous aeration head dispersed arranges, the supply of oxygen atmosphere too disperses, and in fact need most enhanced oxygen blowing zone be the effective area of photochemical catalysis oxidation, because the Effective depth penetration of short wave ultraviolet in liquid water body only has 20 centimetres of left and right, therefore, needing most enhanced oxygen blowing in fact is exactly the zone within peripheral approximately 20 cm distance of silica tube with the effective area that promotes photochemical catalysis oxidation process, in other words, zone within peripheral approximately 20 cm distance of silica tube is really to need enriched with oxygen atmosphere to supply with the zone ensured, this regional oxygen atmosphere is supplied with stronger, oxidizing reaction is also just carried out sooner, especially especially, produce electrodeless ultraviolet emission in the microwave excitation mode, its characteristics can be accomplished high-power, high strength exactly, this is the strong point of this lamp type of electrodeless ultraviolet lamp, yet, just because of the superpower of its uv-radiation, high strength just more need to be mated with powerful oxygen atmosphere supply capacity, otherwise, that powerful uv-radiation ability is really just that major part has been wasted.Above address, as the scheme that CN102260003A was showed, factors has limited its reactor size, limited its actual treatment capacity, just as clearly illustrated that in its specific embodiment, that can only be the little reactor that a single tank single treatment amount only has 40 liters of left and right, at so little reactor, in the situation of little inner chamber, because size itself is just very little, so, its shortcoming aspect photochemical catalysis oxidation effective area oxygen supply concentration degree, just can not be so obvious, even can ignore, can regard a non-existent problem at all more even fully as, in the face of such undersized little reactor, shortcoming problem about oxygen supply concentration degree aspect, not may float mind, but, imagine, if can overcome described many limiting factors, if can there be one of way actual implementation large-scale, the reactor of high throughput, within so above-mentioned silica tube periphery 20 cm distance, effective area oxygen supply strengthening problem will show especially out, especially for the situation of using electrodeless ultraviolet lamp as UV source, within above-mentioned silica tube periphery 20 cm distance, effective area oxygen supply strengthening problem is not allowed to despise more, therefore, how among the structure of possible large-scale photo-catalytical oxidation DeR device, strengthen the oxygen supply concentration degree of described effective area, improve the usefulness of wastewater degradation equipment, the problem that a needs is kept a close watch on exactly, this is five of problem.

Six of problem:

Within this CN102260003A scheme pumps air into the silica tube that includes electrodeless ultraviolet lamp, reach the aeration-cooling of electrodeless ultraviolet lamp, cooling purpose, and those flow through the air of silica tube, because being subject to ultraviolet irradiation, some air can change ozone into, therefore, the air flowed out from silica tube is exactly the air that contains some ozone certainly, this scheme should be transferred to and be positioned at reactor below micro porous aeration head containing ozone-air, and disengage from micro porous aeration head, at these, contain in ozone bubbles ascension process from bottom to top, wherein contained ozone can meet with and occur redox reaction with the organic molecule that runs among distance, this redox reaction can consume a part of ozone certainly, this be do not have doubt, but, above address, as the scheme that CN102260003A was showed, the many effects limit that can't ignore that certainly exist its reactor size, limited its actual treatment capacity, just as clearly illustrated that in its specific embodiment, that can only be the little reactor that a single tank single treatment amount only has 40 liters of left and right, at so little reactor, in the situation of little inner chamber, because overall dimension itself is just very little, so, the longitudinal size of its reactor inner chamber or regard that to contain the liquid degree of depth can only be also a very little size as with reckoning in every item, this size is as clearly illustrated that among its embodiment, only have about 40 centimetres, the Sheng that the reckons in every item liquid degree of depth also just only has 40 centimetres, in fact contain the liquid degree of depth and certainly be less than this number, just with the Sheng liquid degree of depth of 40 centimetres, analyze, so, is this Sheng liquid degree of depth of 40 centimetres what concept? that is to say, only have short 40 centimetres containing the ozone-air ascension by the path of waste water, this path is too short, pass through at a gallop and only only have 40 centimetres of dark water bodys containing the ozone-air bubble, too short duration of contact with water body, contained ozone in bubble, can only there is a very little part to be used to the oxidative degradation organism, and most ozone is in fact just passed by liquid simply, from liquid level effusion emptying through exhaust port, briefly, the oxygenizement potentiality major part of these ozone has been wasted, and, overflow, in fact the ozone be wasted can cause unnecessary atmospheric pollution, the main contriver of this case once squeezed into containing ozone-air via micro porous aeration head with the normal domestic use ozone machine in one meter dark tank, in the situation that the depth of water degree of depth reaches one meter, still can near the water surface, obviously smell the smell of ozone, visible, that 40 centimetres of dark Sheng liquid degree of depth are obviously to be not enough to utilize fully ozone, visible, for the such equipment of electrodeless ultraviolet light chemical catalysis wastewater degradation reactor, ozone utilizes incomplete problem also to need to pay close attention to, obviously, people more expect be the ozone utilization more fully, the contaminative exhaust emissions still less without extreme ultraviolet wastewater degradation reactor, this is problem six.

Seven of problem:

Its running of waste water catalytic degradation reaction device, require the expenditure of energy, and therefore, operator are bound to wish, when the wastewater degradation reaction proceeds to terminal, can impartially, immediately not stop too early continuing Implantation Energy to inside reactor only lately; If it is too early to stop the moment of Implantation Energy, wastewater degradation is incomplete; And if reach already reaction end, but still unceasingly to the inside reactor Implantation Energy, that is certainly at the valuable energy of waste.Its structure of CN102260003A scheme as this case technical background can not provide any instant information constantly to the wastewater degradation reaction end, so, just can only estimate by experience the terminal of wastewater degradation reaction; And estimate by experience the terminal that wastewater degradation reacts, that obviously can not be satisfactory; So, how for the wastewater degradation reaction end, constantly make neither in advance also undelayed instant information output, and immediately close the energy input to reactor in the just right moment, the technical threshold that can not despise exactly, this is problem seven.

Eight of problem:

Accept the described trade effluent of microwave and photo catalysis degradation treatment, the material that wherein is mingled with unavoidably some metal particles that originate from mechanical system abrasion process and carbon granules and so on, even if quantity is small, its existence almost is difficult to avoid, described organic membrane separation assemblies in the Chinese patent application case that the disclosure number is CN102260003A is installed in the microwave and photo catalysis reaction zone, being installed in wherein do not stop microwave certainly for intercepting ultraviolet dividing plate between silica tube and membrane separation assemblies, so, the practical function zone of microwave must cover zone that organic membrane separation assemblies is installed described in this scheme, working mechanism based on membrane separation assemblies, its accumulation process on the organic top layer of membrane separation assemblies of the particulate of metal particle as above and carbon granules and so on is difficult to avoid, and the particulate of this type of described metal particle and carbon granules and so on, the good absorption medium of microwave energy exactly, absorbed the particulate of the described metal particle of accumulation state of microwave energy and carbon granules and so on, the top layer of the organic membrane separation assemblies that can be close to it of nature produce based on heat penetration erosion mechanism continue pierce destruction, as mentioned above, due to the structures shape of this its device of CN102260003A application case can only select the polyvinylidene fluoride film material, approximately 140 degrees centigrade of this polyvinylidene fluoride film material heatproofs, really high more many than general film material heatproof, yet, the heat penetration erosion effect that its point-like of particulate that has absorbed the described metal particle of accumulation state of microwave energy and carbon granules and so on is pierced formula very easily breaks through the heatproof temperature limit of this polyvinylidene fluoride film material, for above-mentioned reasons, well imagine, pvdf membrane material in its device of this CN102260003A application case will be significantly less than expected desirable work-ing life its actual service life, the structure of this its device of CN102260003A application case, determined under this structural framing, the heat penetration erosion destruction problem that above-mentioned point-like is pierced formula can't be avoided, therefore, how to get around the heat penetration erosion destruction problem that this point-like is pierced formula, also need to consider, this is problem eight.

Nine of problem:

The Chinese patent application case that the disclosure number is CN102260003A, its specification sheets open text text the 0008th section word and claim the second, the applicable catalyst particle size scope for its device institute energy, have a restriction, and this particle size range is defined as 20 nanometers to 100 micron.We know, under some pH value is regulated not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles is easily reunited, and then affects its effective working interface area, affects its photochemical catalysis usefulness; Especially for the section of those less particle diameters among this particle size range, easily occur because of presetting not in place, the incorrect agglomeration traits caused of pH value of pH value especially; The situation of reuniting for this catalyst particles, be immediately to adopt an effective measure, and carries out the depolymerization running for coacervate; Yet we do not see that any contributing to immediately dissolve the structure of this problem or can immediately dissolve the scheme prompting of this problem among this CN102260003A scheme.For can only be the reactor of small scale structures because of factors restriction just like that as the CN102260003A scheme, still can manually directly mention reactor, toppled over and inspected in the reactor outside, process above-mentioned reunion situation, so, if likely expand its capacity, just so to say, if be several cubes of large-scale reactor or the huge reactors to dozens of cube, that is not obviously manual to have toppled over problem that its operation can tackle, so, the situation of mutually reuniting for this catalyst particles, how to realize instant original position disposal, it is exactly a technical problem, this is nine of problem.

Ten of problem:

In the expressed apparatus structure of the Chinese patent application case that is CN102260003A in the disclosure number, protect the silica tube of electrodeless ultraviolet lamp for screen, its outer wall, refer to the outer wall of silica tube, through for a long time with the contacting of processed trade effluent, incrustation gradually unavoidably, the long-pending material of dirt is mainly difficult by mineral-type impurity that light-catalyzed reaction touched certainly, incrustation phenomenon because this mechanism forms is easy to be observed after the equipment long-play; Be attached to the dirty lamination of described silica tube outer wall, although be very thin one deck, also be enough to ultraviolet radiation to electrodeless ultraviolet lamp and cause significantly and stop, this will cause the actual treatment effect of this microwave and photo catalysis reaction treating device significantly to reduce; In its reactor, the bubble of dispersed ascension is because too disperseing, wash away strength a little less than, if only rely on this bubble relatively disperseed to maintain the bright and clean of silica tube surface, really undertake to do what is apparently beyond one's ability, in other words, the bubble that this relatively disperses, it is weak washes away the incrustation process that strength still is not enough to stop fully this silica tube surface; In the use procedure of laboratory yardstick, above-mentioned incrustation problem is subtle, and still, on the industrial application yardstick, this incrustation problem certainly will highlight; Therefore, how, under the prerequisite of not tearing machine open, immediately, effectively remove the dirty lamination on this silica tube outer wall, maintain the lasting high-level efficiency of this microwave and photo catalysis treatment unit, this problem is also very important, and this is problem ten.

11 of problem:

Nine its derivative problems that this problem is the problem of above addressing.Front is spoken of, and under some pH value is regulated not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles is easily reunited, and then affects its effective working interface area, affects its photochemical catalysis usefulness; The section of those less particle diameters among its suitable catalyst particle size range of especially touching upon for this CN102260003A scheme, easily occur because of presetting not in place, the incorrect agglomeration traits caused of pH value of pH value especially; The situation of reuniting for this catalyst particles, be immediately to adopt an effective measure, and carries out the depolymerization running for coacervate; Based on this its framework of CN102260003A scheme, operator can't perceive the situation that described reunion occurs inside reactor immediately, thereby also can't make instant disposal, thus, this is subject to the factors restriction and can only is the further reduction of its limited usefulness of reactor of small scale structures; Therefore, among the application running of reactor, particularly, for example, among the application running of possible large-scale reactor or huge reactor, the main inducing parameter how immediately awareness inside reactor catalyst particles is reunited, be a key issue, this is problem 11.

12 of problem:

Based on this its framework of CN102260003A scheme, restriction due to the factors of having addressed, its reactor can only be the smaller reactor of undersized treatment capacity, the useful size of reactor inner chamber is certainly also smaller, can be used in the spatial altitude of settling curtain type film assembly among its structure of reactor inner chamber is approximately also 30 centimetres of left and right, so, even if just adopt the very curtain type film assembly of small breadth, also almost up and down two head on plug in reactor the inside, little treatment capacity due to reactor, small size, so, after its DeR completes, under the situation of getting rid of from inside to outside liquid, its curtain type film assembly is exposed in air unavoidably, although each time exposed can be not long, but, the accumulation result of often buying and selling, make exactly this curtain type film assembly contact with air too much, its normal service requirements of curtain type film assembly, under submerged state, to use fully, that is to say, must be that hygrometric state is used, if curtain type film assembly contacts with air too much, can make it more aging than more quickly, Performance Ratio is decayed more quickly, and the situation that this curtain type film assembly contacts with air too much, under this its framework of CN102260003A scheme, can't avoid, therefore, how to protect for tackling the membrane module of catalyzer, can use under nominal situation, can avoid too much the contacting with air, to safeguard its normal usage energy, guarantee its normal service life, a problem that needs are faced exactly, this is problem 12.

13 of problem:

Based on this its framework of CN102260003A scheme, among its running, the granules of catalyst of being tackled by curtain type film assembly, a part is at the curtain type film assembly surface deposition, and another part is trapped among liquid phase, causes thus granules of catalyst concentration in liquid phase progressively to raise along with progressively reducing of liquid phase volume, this is for follow-up membrane sepn, its membrane sepn load also can raise thereupon gradually, and before and after this membrane sepn load, the excessive problem of difference needs to solve, and this is problem 13.

14 of problem:

Based on this its framework of CN102260003A scheme, among its running, water pump to reactor inner chamber filling waste water, itself can't differentiate inside reactor water level height, operator can only rely on experience or range estimation to close in time the pump motor of this filling waste water, if experience error or range estimation response are not prompt enough, be easy to occur cause thus unnecessary trouble because of the excessive situation of overflowing reactor of waste water filling; On the other hand, after DeR finishes, need to be by inside via curtain type film assembly to extracardiac pumping, failing to know under the situation of inside reactor water level, fully can only rule of thumb or estimate and judge the opportunity of closing down water pump, and running like this, obviously unreliable, very easily because of experience, slip up or estimate response not in time, causing this to draw water can't shut down in time with water pump, and this dry tap, idle running are easy to cause this pump motor that draws water to burn, this problem can not be out in the cold, and this is problem 14.

15 of problem:

Based on this its framework of CN102260003A scheme, among its running, the air pumped into to quartzy tube chamber, be subject to uviolizing, wherein a part can be converted into ozone, so form containing ozone-air, most of can release by force feed to micro porous aeration head place, but, we know, magnetron structures itself does not have vacuum-tightness, and, the junction of waveguide and magnetron does not generally have vacuum-tightness yet, therefore, what have a relative positive pressure describedly must have the sub-fraction reverse magnetron place structural region of scurrying in ground of can taking advantage of a situation containing ozone-air, and its structural member material of magnetron comprises that generally speaking its case material does not possess the ability of resisting the ozone corrosion yet, so, thus, reverse scurry into the magnetron structures zone must form the corrosive nature to the magnetron member containing ozone-air, the power of this corrosive nature may be subtle within the short period of time of laboratory yardstick, yet, time is slightly long, certainly manifest, should be containing the reverse channelling of ozone-air the problem of corroding the magnetron member, can not be avoided, this is 15 of problem.

16 of problem:

Based on this its framework of CN102260003A scheme, electrodeless ultraviolet lamp be placed in the tube chamber of silica tube within, normal luminous work in order to ensure this electrodeless ultraviolet lamp, it is clean to maintain the transparent performance to UV-light that its inwall of this silica tube must keep, and, requirement based on similar light penetrability aspect, himself lamp wall outer side of related electrodeless ultraviolet lamp also must keep clean; But this its framework of CN102260003A scheme is difficult to avoid this silica tube lumen area generation gushing water problem; The alleged gushing water of this case, the water referred in reactor is not treated that insight protrudes into the lumen area of this silica tube; Cause the reason of this gushing water situation to have haply following so two: first silica tube lumen area air expands with heat and contract with cold and causes the silica tube lumen area under-voltage, it two is that silica tube lumen area air is escaped and to cause the silica tube lumen area under-voltage, so, around under the promotion of the relative positive pressure of water body, the lumen area that water in reactor is progressively charged into this silica tube, form the gushing water situation; In the situation that pneumatic pump cuts off the power supply and the silica tube outer side partly is submerged by water or large section is submerged by water, described gushing water situation especially easily occurs; Specifically, this the most incidental period of gushing water problem, be following two periods, first period is to the pending waste water of filling in reactor and in pneumatic pump not yet starts, and second period is after pneumatic pump cuts out and in the water purification extraction procedure not yet completes; When described gushing water situation occurs, the water that is being mingled with many inorganic impurities of charging into this silica tube tube chamber is easy to pollute himself lamp wall outer side of this silica tube lumen wall and electrodeless ultraviolet lamp, cause its uv transmittance of relevant translucent construction position significantly to reduce, and then the overall waste water photodegradation treatment efficiency of the relevant wastewater degradation reactor of impact, therefore, this gushing water problem should not be avoided, and this is problem 16.

Summary of the invention

Technical problem to be solved by this invention is, for one of problem of above addressing, two, three, four, five, six, seven, eight, nine, ten, 11,12,13,14,15,16, research and develop a kind of novel waste water microwave and photo catalysis degradation treatment device that can solve described series of problems totally.

The present invention solve the technical problem by following scheme, this scheme provides a kind of photocatalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water, the structure of this reactor comprises a container, its appearance profile of described container is cube shaped, cuboid, cylindrical, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form, bottom position at described container intracavity is equiped with many micro porous aeration heads, and, quartz ampoule, this quartz ampoule is erected at the inner chamber position of described container, the two ends of this quartz ampoule are equiped with the shutoff headkerchief, lay respectively on the described shutoff headkerchief at quartz ampoule two ends and all offer the ventilation interface, and, electrodeless ultraviolet lamp, this electrodeless ultraviolet lamp is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, the quantity of this electrodeless ultraviolet lamp is at least more than one, this quantity at least all is erected at the inside of described quartz ampoule at more than one electrodeless ultraviolet lamp, and, air pump, this air pump is installed in the outside of described container, ventilation interface on described quartz ampoule one end shutoff headkerchief connects with the gas outlet of described air pump via breather line and through described wall of a container, ventilation interface on its other end shutoff headkerchief of described quartz ampoule connects with the micro porous aeration head that is positioned at described container intracavity bottom via another breather line, and, microwave generator, this microwave generator is installed in the outside of described container, this microwave generator is magnetron, and, waveguide, this waveguide is for transmitting the member of microwave, one end of this waveguide and described magnetron UNICOM, the other end of this waveguide sees through the inner chamber of described wall of a container towards described container, and, water pump, this water pump is positioned at the outside of described container, this water pump is for the pending waste water of pumping, its delivery port of this water pump leads to the inner chamber of described container, the top of described container offers exhaust port, emphasis is, that end that sees through described wall of a container of this waveguide extends much further into the inner chamber of described container, this gos deep into that end of waveguide of described container intracavity and the inside that a shutoff headkerchief further seeing through again described quartz ampoule probes into quartz ampoule, and, the structure of this reactor also comprises the microwave constrainer of the cage shape of metal material, contain many holes or mesh on the microwave constrainer of this cage shape, the function of the microwave constrainer of this cage shape is the constraint microwave, contain its unhelpful dissipation, simultaneously, allow most of ultraviolet light to penetrate, the installation position of the microwave constrainer of this cage shape is positioned at the inside of described quartz ampoule, that end UNICOM that probes into quartz ampoule of its inner chamber of microwave constrainer of this cage shape and described waveguide, the described electrodeless ultraviolet lamp that is erected at quartz ampoule inside all is rolled in wherein by the microwave constrainer of described cage shape, and, the circulation guide, the function of this circulation guide is the ascension path containing ozone-air bubble of pack from micro porous aeration head, and lead described internal tank liquid to make the shuttling movement of relative large scale by the strength that pulls of the bubble flow because being subject to the ascension that pack strengthens, this circulation guide is installed in the inner chamber position of described container, the simple and easy cone that its profile shape of this circulation guide connects like two ends, its osculum end of this circulation guide vertically upward, this its big opening end of circulation guide vertically downward, this its axis of circulation guide is mutually vertical with the inner chamber bottom surface of described container, its locations of structures of osculum end vertically upward of this circulation guide is under described quartz ampoule, its edge of big opening end vertically downward of this circulation guide and the lateral separation between described container inner wall are between 5 centimetres and 300 centimetres, its edge of big opening end vertically downward of this circulation guide and the fore-and-aft distance between described container intracavity bottom surface are between 5 centimetres and 100 centimetres, and, described many micro porous aeration heads be installed in the scope of drawing a circle to approve in the vertical projection of described container intracavity bottom surface at its big opening end edge of described circulation guide with gathering within, and, booster pump, this booster pump is mixed with the degraded water afterwards of a large amount of catalyst particles for the supercharging pumping, its water inlet of this booster pump connects with the inner chamber of described container via ventilating water pipe and through described wall of a container, and, the preposition prefilter of back flush type, its water inlet of the preposition prefilter of this back flush type connects with the delivery port of described booster pump, and, back flush type doughnut membrane microfiltration filter, its pure water inlet of the preposition prefilter of described back flush type connects with the water inlet of this back flush type doughnut membrane microfiltration filter via first water purifying valve, and, back flush type hollow-fibre membrane ultra filtration filter, described its pure water inlet of back flush type doughnut membrane microfiltration filter connects with the water inlet of this back flush type hollow-fibre membrane ultra filtration filter via second water purifying valve, this its pure water inlet of back flush type hollow-fibre membrane ultra filtration filter connects with the entrance point of the 3rd water purifying valve, the water side of the 3rd water purifying valve is the water side of outlet terminal water purification, and, catalyst underflow transition tank, this catalyst underflow transition tank is the tank body of a hollow, this catalyst underflow transition tank is for temporarily depositing the higher water body of catalyst concentration ratio that its backwashing procedures of described filter discharges, the catalyst underflow refluxing opening that is positioned at this its intracavity bottom of catalyst underflow transition tank leads to the inner chamber of described container via catalyst underflow return valve, this catalyst underflow return valve is to control the valve body of this catalyst return flow line for switch, its outlet of sewer of the preposition prefilter of described back flush type leads to the inner chamber of this catalyst underflow transition tank via first sewage valve, described its outlet of sewer of back flush type doughnut membrane microfiltration filter leads to the inner chamber of this catalyst underflow transition tank via second sewage valve, described its outlet of sewer of back flush type hollow-fibre membrane ultra filtration filter leads to the inner chamber of this catalyst underflow transition tank via the 3rd sewage valve, each described filter is all for holding back catalyst particles, each its outlet of sewer of described filter is all converted as being held back the recycling delivery outlet of catalyst particles, and, ozone sensor, the sampling port of this its probe tube of ozone sensor is close to described exhaust port or probes into the inside of described exhaust port, and, the ozone content display, the composite structure of ozone attention device or ozone content display and ozone attention device, this ozone sensor is via article one cable and this ozone content display, ozone attention device or ozone content display connect with the composite structure of ozone attention device, and, power-supply controller of electric, its output electric signal of this ozone sensor connects with this power-supply controller of electric via the second cable, this power-supply controller of electric connects with described magnetron via the 3rd cable, this power-supply controller of electric connects with described air pump via the 4th cable, this power-supply controller of electric is the power-supply controller of electric that the described electric signal that can receive according to it carries out the power switch action, and, one group of ultrasonic transducer, this group of ultrasonic transducer at least contains a ultrasonic transducer individuality, this group of ultrasonic transducer is for the radiation low-frequency ultrasonic waves, this low-frequency ultrasonic waves refers to the ultrasonic wave of frequency in the 20kHz-60kHz scope, this container intracavity bottom surface is hollow gradually to central area by periphery, described hollow its gradient is between 5 degree and 35 degree, this group of ultrasonic transducer is to be installed in lateral surface position or the medial surface position of its corresponding part vessel bottom wall in hollow bosom of this container intracavity bottom surface with attaching, and, higher-order of oscillation electric signal transmission cable, one group of ultrasonic transducer of one end of this higher-order of oscillation electric signal transmission cable and this connects, and, higher-order of oscillation electric signal generator, the other end of described higher-order of oscillation electric signal transmission cable connects with this higher-order of oscillation electric signal generator, and, the pH probe, and, the pH analyzer, this pH probe is coupled to each other with the pH analyzer, this pH analyzer and connecting with siren, this siren is for giving the alarm to the pH value situation of transfiniting, described container intracavity is stretched at the top that this pH probe sees through described container, and, the micropore stainless steel sleeve of making through powder sintering process, this micropore stainless steel sleeve is cap for brush shape, this micropore stainless steel sleeve is positioned at described container intracavity, this its blind end of micropore stainless steel sleeve down, this its openend of micropore stainless steel sleeve upward, this its openend upward of micropore stainless steel sleeve connects with described container top via the buffering isolating pad, this pH pops one's head within its that part that stretches into described container intracavity probes into this micropore stainless steel sleeve, this its material of buffering isolating pad is fluorubber or silicon rubber, and, two pairs of dry-reed type ball float level controllers, these two pairs of dry-reed type ball float level controllers all extend into the inner chamber of reactor through the top of reactor, a pair of dry-reed type ball float level controller wherein connects with the power cable of described water pump by a relay, wherein another connects with the power cable of described booster pump by another relay the dry-reed type ball float level controller, its part of going deep into this container intracavity of this waveguide is to consist of two sections stainless steel tubes, these two sections stainless steel tubes are docked with flange connection each other, connect part at this flange, use two-layer teflon gasket, and, the airtight partition panel of wave transparent, the airtight partition panel of this wave transparent is quartz glass plate, the ceramic wafer that polyfluortetraethylene plate or dense sintering form, the airtight partition panel of this wave transparent is for this waveguide of the cross-section separation of air-tightness, the board plane of the airtight partition panel of this wave transparent is mutually vertical with the axis that this flange of this waveguide is connected part, its periphery edge of the airtight partition panel of this wave transparent is wedged the locations of structures between two-layer teflon gasket, and, first check valve, this first check valve is installed in the position of contiguous described air pump gas outlet on its plenum duct of described air pump, and, quartz ampoule tube chamber malleation holding pump, this quartz ampoule tube chamber malleation holding pump be one lower powered for the low discharge pumped air and only take and maintain the miniature membrane pump that quartz ampoule tube chamber malleation is purpose, this its power of quartz ampoule tube chamber malleation holding pump is between 5 watts and 50 watts, this its gas outlet operating pressure of quartz ampoule tube chamber malleation holding pump is between 1 meter water column and 5 meter water columns, this its gas output of quartz ampoule tube chamber malleation holding pump is between 1 liter and 80 liters per minute per minute, this its gas outlet of quartz ampoule tube chamber malleation holding pump sees through second check valve and described air pump is connected in parallel, and, the 3rd check valve, the 3rd check valve is installed in connecting on gas circuit between this quartz ampoule tube chamber and described micro porous aeration head, this connects namely described another breather line of gas circuit.

Check valve market is on sale.

Miniature surge pump market is on sale.

This catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control; The opening-closing valve of commercially available various fluid lines, can be applicable to the needs of this locations of structures, and its concrete type selecting can determine as required.

Described dry-reed type ball float level controller, the art-recognized meanings of itself is known for the professional of fluid level controller manufacturing; Described dry-reed type ball float level controller market is on sale.

Described rly. market is on sale.Described rly. comprises high power relay certainly.The described rly. of this case is made a general reference function class together or some approaching circuit connection control device of function, and described circuit connection control device is rly., contactor, isolating switch etc. for example; Described circuit connection controller again for example rly. add the assembling device of contactor.Described rly., contactor, isolating switch etc. device market is all on sale.

Related stainless steel tube market is on sale.

Related quartz glass plate market is on sale.

The markets such as related polyfluortetraethylene plate and teflon gasket are all on sale.

The ceramic plate market that related dense sintering forms is on sale; This ceramic plate also can customize to Ceramics Majors producer.

Related flange connects itself art-recognized meanings of a word for the pipework technician, is known.

Valve body on all fluid passages of this case, can the choice for use magnetic valve, in the situation of choice for use magnetic valve, by the cable by long-range, concentrates and is arranged on a control panel, so, can realize easily long-distance centralized control.

Related pH probe market is on sale; Described pH probe also claims the pH sensor; Itself art-recognized meanings of pH probe or day pH sensor is known.

Related pH analyser market is on sale; Itself art-recognized meanings of pH analyser is known.The pH that can utilize that any model made a general reference in this case pH analyser one word detects, picks up, shows the pH value information, and can externally export the instrument of pH associated electrical signal, sell on market simple and easy or complicated but all meet the pH correlate meter of this basic demand it is various in style, can select as required.

Related its thickness of buffering isolating pad is not limit; But, a preferable range is arranged, the preferable range of this its thickness of buffering isolating pad is between 1 millimeter to 8 millimeters.

Their own art-recognized meanings of related viton and related silicon rubber are known; Related viton and related silicon rubber, market is all on sale.

Related its wall thickness of micropore stainless steel sleeve is not limit; But, an associated preferable range is also arranged, the preferable range of this its wall thickness of micropore stainless steel sleeve is between 3 millimeters to 30 millimeters.

A related powder sintered word, the art-recognized meanings of itself, for the professional of metallurgical technology field, is known.

Related micropore stainless steel sleeve, can be to the customization of relevant powder metallurgy specialized factory.

The sleeve-shaped micropore Stainless Steel Filter conversion that powder sintering process can be made is the described micropore stainless steel of this case sleeve; The sleeve-shaped micropore Stainless Steel Filter market that described powder sintering process is made is on sale.

The aperture of related its micropore of micropore stainless steel sleeve is not limit; But the aperture of this micropore is also that a preferable range is arranged, the preferable range of this micropore size is between 0.5 micron to 50 microns.

This its opening end upward of micropore stainless steel sleeve connects with described container top via the buffering isolating pad, refers to, and this connection is flexible connection, at this, connects part, has described buffer compartment to ask between it from pad.

Described warning horn be can be received according to it electric signal send the device of audio frequency warning message or optical frequency warning message; Itself art-recognized meanings of described warning horn is known; Described warning horn market is on sale.

Itself art-recognized meanings of ultrasonic transducer one word is known for the professional in ultrasonic technology field.

Itself art-recognized meanings of HF oscillation electric signal transmission cable one word is also known for the professional in ultrasonic technology field.

Ultrasonic transducer and HF oscillation electric signal transmission cable market are all on sale; Described ultrasonic transducer and HF oscillation electric signal transmission cable etc. also can be to ultrasonic transducer specialized factory and the customizations of cable specialized factory.

Itself art-recognized meanings of HF oscillation electric signal producer one word is also known for the professional in ultrasonic technology field; Various HF oscillation electric signal producer all has commercially available; Described HF oscillation electric signal producer also can customize to ultrasonic wave equipment specialized factory.

Related ozone sensor market is on sale; Also can to ozone sensor specialized factory, customize as required.

Related ozone content monitor market is on sale; Also can to ozone content indicating meter specialized factory, customize as required; Ozone sensor producer also sells matching used ozone content indicating meter usually.

Related ozone attention device, refer to warn sound or alarm flashing or warning sound combines with alarm flashing both mechanisms for warning of having both at the same time; Ozone attention device market is on sale; Also can customize to ozone attention device specialized factory; Ozone sensor producer also can sell matching used ozone attention device usually.

Related this power-supply controller of electric is the power-supply controller of electric that the described electric signal that can receive according to it carries out the power switch action; The power-supply controller of electric that the electric signal that can receive according to it carries out the power switch action only with regard to its circuit engineering itself, is ripe, known technology; Described power-supply controller of electric market is on sale; Also can utilize commercially available power-supply controller of electric to be changed a social system as required; Described power-supply controller of electric also can be to the customization of power-supply controller of electric specialty manufacturers; Its professional manufacturers of the electron device of power-supply controller of electric and so on spreads all over the world.

In this case statement, retort one word refer to implication and described container one word to refer to implication identical; Described container is also one of primary member of reactor simultaneously certainly.

Described metal material one word, the art-recognized meanings of itself, be known.

Described magnetron, and, waveguide device, its art-recognized meanings is known for the professional of microwave technical field.Described magnetron, and waveguide etc., all have commercially available; Described waveguide is self manufacture as required, and this making is for the professional of microwave technical field, and the making of waveguide device is simple.

Described silica tube, its art-recognized meanings is known; Described silica tube market is on sale.

Described electrodeless ultraviolet lamp, its art-recognized meanings is known for the professional of light sources technical field; Described electrodeless ultraviolet lamp market is on sale; Its shape of described electrodeless ultraviolet lamp, size, inner institute blanketing gas, lamp wall material, lamp wall thickness, etc., also can, according to the specific design needs, to electric light source manufacturing concern, customize.Certainly, also can self manufacture.The making of electrodeless ultraviolet lamp is for the professional who possesses electric light source expertise, and its manufacturing technology is simple.

Described water pump and topping-up pump, are all the pumps for delivery of clear or turbid all kinds of water, and certainly, its pumping pressure can be selected as required arbitrarily, and various pump market is all on sale; This case adopts different names, just for convenient statement, the convenient pump of distinguishing each different structure position.

Its material of microwave constrainer of this cage shape can be any selected metal, but, residing by the formed ozone gas mixture of strong ultraviolet radiation environment in view of it, and, for exporting to greatest extent considering of the UV-light of being launched by electrodeless ultraviolet lamp by complicated specular reflection mechanism as much as possible, the preferred metal material that is suitable for making the microwave constrainer of this cage shape is the punching stainless steel of processing through mirror polish.

Can make described microwave constrainer through welding, splicing or mould pressing process with bright finished punching stainless steel plate.

Can certainly make with bright finished Stainless Steel Wire braiding the microwave constrainer of this cage shape.

For convenience of runnings such as the cleaning of regularly carrying out for described internal tank and maintenance, can offer sewage draining exit in the bottom of described container, this sewage draining exit is used for deslagging, removes contamination, can be at this Location for Sewage installing wash water valve, and described wash water valve is the valve of controlling for blowdown; In case of necessity, can utilize this sewage draining exit that is positioned at described container bottom that described internal tank liquid is emptied completely.Described sewage draining exit and wash water valve are not necessarily.

Described water purifying valve, sewage valve, wash water valve, be all water valve, and various water valve market is all on sale; About water valve, itself art-recognized meanings of this word is known; This case adopts different titles, just for convenient statement, the convenient water valve of distinguishing each different structure position.

The material of described circulation conductor is not limit, and the material of described circulation conductor can be for example tetrafluoroethylene material, glass material, ceramic material, metal material, etc., still, its preferred material of circulation conductor is stainless steel.

In this case device, isolation and restriction by means of metal cage to the microwave exposure spatial domain, zone between metal cage outer wall and described container inner wall, a microwave zero irradiation zone or the weak irradiation zone of microwave have been formed, because microwave can't have influence on this zone basically, microwave is contained because the simple pyrogenicity of waste water absorbs the unhelpful dissipation of energy caused in this zone, like this, no matter how this zone volume enlarges, and all allows; Based on this, the structure of this case device, allow to expand significantly single tank designing treatment capacity of described reactor, allow to expand significantly the volume of reactor, certainly, be to limit the microwave exposure spatial domain by metal cage, and significantly the design volume in the spatial domain between expanded metal cage outer wall and described container inner wall realize.

In this case structure, described many micro porous aeration heads be installed in the scope of drawing a circle to approve in the vertical projection of described container intracavity bottom surface at its big opening end edge of described circulation conductor with gathering within.Be positioned at the described many micro porous aeration heads within the scope that described vertical projection draws a circle to approve, can be both within tiling ground is installed in bottom described container intracavity the scope of drawing a circle to approve, certainly, within this delineation scope, also can take another kind of more intensive installing mode, described more intensive installing mode, refer to, described many micro porous aeration heads can be folded and set up at the enterprising windrow of three-dimensional, they be gathered form the cluster-shaped micro porous aeration head cluster with three-dimensional stacked framework in this way; This kind of cluster-shaped micro porous aeration head cluster can hold the comparatively huge micro porous aeration head of quantity; This kind of mode can be carried larger air flux.

The preferable range in its filter opening aperture of the preposition prefilter of described back flush type is between 5 microns and 300 microns, and certainly, it is also that this case allows that the preposition pre-filtering of other outside this preferable range aperture is selected; The preferable range in its filter opening aperture of described back flush type tubular fibre membrane microfiltration strainer is between 25 nanometers and 1000 nanometers, and certainly, it is also that this case allows that other micro-filtration aperture outside this preferable range is selected; The preferable range in its filter opening aperture of described back flush type hollow-fibre membrane ultra filtration filter is between 15 nanometers and 2 nanometers, and certainly, it is also that this case allows that other ultrafiltration aperture outside this scope is selected.

The preposition prefilter of described back flush type also claims back flush type fore filter or back flush type prefilter, and itself art-recognized meanings of the preposition prefilter of described back flush type is known; The preposition prefilter of described back flush type market is on sale.

Described back flush type tubular fibre membrane microfiltration strainer is the strainer that is suitable for micro-filtration; Itself art-recognized meanings of described micro-filtration one word is known; Itself art-recognized meanings of described back flush type tubular fibre membrane microfiltration strainer, for the professional in membrane separation technique field, is known; Described back flush type tubular fibre membrane microfiltration strainer market is on sale.

Described back flush type hollow-fibre membrane ultra filtration filter is the strainer that is suitable for ultrafiltration; Itself art-recognized meanings of described ultrafiltration one word is known; Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter, for the professional in membrane separation technique field, is known; Described back flush type hollow-fibre membrane ultra filtration filter market is on sale.

In the ultrafiltration link, this back flush type hollow-fibre membrane ultra filtration filter can be the form that a back flush type hollow-fibre membrane ultra filtration filter monomer is only arranged; Certainly, this back flush type hollow-fibre membrane ultra filtration filter also can be comprised of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.

Express a related word in parallel, the art-recognized meanings itself referred to is clearly.

Express related monomer one word, refer to itself function and structure equipment individuality completely.

Similarly, in the micro-filtration link, this back flush type tubular fibre membrane microfiltration strainer can be the form that a back flush type tubular fibre membrane microfiltration strainer monomer is only arranged; Certainly, this back flush type tubular fibre membrane microfiltration strainer also can be comprised of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.

Can further install second topping-up pump on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration its pure water inlet of strainer and described back flush type hollow-fibre membrane ultra filtration filter, this second topping-up pump is for augmenting hydraulic pressure to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter; This second topping-up pump not necessarily.

Be a mass of hole or mesh in himself structure of described metal cage, the preferable range of described hole or its bore of mesh is between 0.5 centimetre and 3.0 centimetres; Certainly, if must select hole or the mesh of other bore outside this preferable range, that is also that this case allows.

The structure of this case device, can also comprise some annexes, described annex for example: the cooling water recirculation system or the air cooling system that with the magnetron cooling duct, are connected; Described annex is also for example for the fixed support within the microwave constrainer that electrodeless ultraviolet lamp is fixed on to described cage shape; Described annex for example is fixed on the support member within described silica tube for the microwave constrainer by described cage shape again; Described annex can certainly comprise described silica tube is fixed on to support or the anchor within described container; Described annex also for example carries out described circulation conductor anchor, bracing frame or the suspension bracket of unsettled location within described container; Described annex for example be installed in again reactor influent waste water end for tackling the strainer of impurity, etc.

Can also be on this case architecture basics, further develop this case scheme, for example, can be paid close attention to the charging characteristic of catalyst particles, and it is apt to add utilization, based on this, consider, its hollow fiber microfiltration membrane included of the described back flush type tubular fibre of this case membrane microfiltration strainer can be specified and be used bear electricity hollow fiber microfiltration membrane, its hollow fiber ultrafiltration membrane included of the described back flush type hollow-fibre membrane of this case ultra filtration filter can specify use bear electricity hollow fiber ultrafiltration membrane.In the situation that use the bear electrolemma, the coulombic repulsion effect can be given full play to, and its effect of this coulombic repulsion, be can suppress the intractable of catalyst particles on membrane module to adhere to, and facilitates the clean running of its backwashing procedures of membrane module.Only, with regard to itself art-recognized meanings of bear electricity hollow-fibre membrane one word, the researchist for the charged membrane field, know.Only, with regard to itself technology of preparing of bear electricity hollow-fibre membrane, the expert for the charged membrane field, know.

Its structure of this case can also allow further to comprise tank, within described back flush type tubular fibre membrane microfiltration strainer and the equal submergence of described back flush type hollow-fibre membrane ultra filtration filter are placed in this tank, be equiped with another group ultrasonic transducer at its sidewall of this tank or its bottom, this another group ultrasonic transducer at least contains a ultrasonic transducer individuality, this another group ultrasonic transducer is used for the radiation high-frequency ultrasonic, this high-frequency ultrasonic refers to the ultrasonic wave of frequency in the 100kHz-12MHz scope, this another group ultrasonic transducer connects with another HF oscillation electric signal producer, in this case membrane module back flushing operation procedure, by means of there is no the extremely weak described high-frequency ultrasonic of cavitation damage or cavitation damage, can more mildly assist backwashing procedures to remove those obstinate catalyst adhered on the membrane module working interface.

Advantage of the present invention is, microwave constrainer with the cage shape of the metal material that is placed in described silica tube inside, electrodeless ultraviolet lamp is wrapped among its inner chamber, its inner chamber of microwave constrainer of cage shape and with the waveguide UNICOM of going deep into described internal tank, described UNICOM refers to the UNICOM on the microwave channel meaning, by this structure, within the microwave that will come via the waveguide transmission constrains in its effective workspace, the containment microwave is to the unhelpful dissipation of peripheral waste water water body, this case structure allows reactor significantly to expand its design volume, allow reactor list tank wastewater treatment capacity significantly to promote, and need not worry again that microwave energy dissipates too much in unhelpful waste water water body temperature-rise effect.

Make the microwave constrainer in the situation that adopt bright finished punching stainless steel, and, in the situation that adopt bright finished Stainless Steel Wire cylinder mould as the microwave constrainer, via complicated specular reflection mechanism, both all can transfer out the UV-light from electrodeless ultraviolet lamp to greatest extent, and make up to greatest extent himself entity of described microwave constrainer light is blocked, absorbs caused loss.

Structure based on this case, the design volume of reactor is that single tank wastewater treatment capacity can be expanded to several cubes to dozens of cube; The volume that even single tank is hundreds of cubes, also allow; Based on this structure of this case, can reduce significantly the frequency of a complete set, substantial length of operation, be conducive to the saving of human and material resources.

On the other hand, described its existence of circulation conductor in this case apparatus structure, can guide the internal passages fast rise of the liquid stream of described internal tank along this circulation conductor, and after impacting, pass through silica tube periphery photocatalytic degradation conversion zone, spread to surrounding by top area, sink via neighboring area, arrive described container intracavity bottom section, converge to again the internal passages of circulation conductor through the hydraucone of circulation conductor, continue its circulation; Certainly, be subject to pack the ascension bubble flow pull the major impetus that strength is this circulation; The liquid systemic circulation campaign of this relative big scale guided, contribute to guarantee the homogenizing of described internal tank liquid degradation reaction process, and this,, for this case large-scale DeR device so, is necessary.

Its UV source of this case device is to rely on microwave excited electrodeless ultraviolet lamp, the uv-radiation characteristics of this lamp type can be accomplished high-power, high strength exactly, yet the Effective depth penetration of ultraviolet ray in liquid water body only had an appointment 20 centimetres, therefore, zone within peripheral approximately 20 cm distance of silica tube is effective area, and this zone is exactly the efficient zone of photochemical catalysis oxidative degradation; This case device is with described circulation conductor, pack is from the bubble flow of numerous micro porous aeration heads, its concentrated area is discharged towards silica tube periphery photochemical catalysis oxidation effective area, this mode contributes to the oxygen atmosphere that improves the described effective area of silica tube periphery to supply with intensity, contributes to accelerating ultraviolet catalyzing oxidizing degrading reaction process.

Based on this case structure, the capacity of reactor or treatment capacity can significantly be expanded, described significantly expansion, to realize by significantly expanding the design volume of irradiation zone a little less than microwave zero irradiation zone or microwave, so, from the appearance, the lateral dimension of reactor, longitudinal size is all significantly to expand certainly, therefore, inside reactor is contained the liquid degree of depth and can be deepened significantly similarly, for example, can deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc., in the situation that the Sheng liquid degree of depth is enough dark, containing ozone-air bubble ascension path sufficiently long, the time sufficiently long contacted with water body containing the ozone-air bubble, in its ascension process just can with abundant reducing substances fortune, and thoroughly or be close to and exhaust up hill and dale ozone contained in bubble, thus, containing ozone composition oxidation potential in the ozone-air bubble, utilize incomplete problem to be solved, and, because long ascension path causes ozone to exhaust, just can not be entrained with again the ozone that can cause environmental pollution in reactor tail gas.

This case with external multistage filter, reach the interception step by step to the collision fragment of the small scale from coacervate macrobead to ten number nanometers of catalyst particles, be close to recovery, reuse photocatalyst up hill and dale, be close to the secondary pollution of taking precautions against catalyst loss up hill and dale and causing; This is interception structure can protect secondary filter to make its filtration passage avoid the rigid obstruction of large particulate matter step by step; Wherein the pre-filtering aperture of the first step is between 5 microns and 300 microns, and its aperture of the micro-filtration of the second stage is between 25 nanometers and 1000 nanometers, and its aperture of the ultrafiltration of the third stage is between 15 nanometers and 2 nanometers; Such interception structure, can fully tackle nano level photocatalyst, and it certainly can be close to and tackle up hill and dale the catalyzer that this median size of gas phase titanium dioxide P25 is 21 nanometers; Address above, the gas phase titanium deoxide catalyst of nano level P25 and so on, it is the commercially available catalyzer that can buy in a large number, also weather resistance, stability, the known good photocatalyst of UV-light wave band photocatalysis performance, certainly, it is also in fact to pay the utmost attention to the photocatalyst of selecting in industrial scale applications; This case catalyzer interception structure is complementary with the virtual rating of catalyzer market supply, actual kind, merges mutually.

And, this case catalyzer interception mechanism is external, its filter core needn't be soaked in the liquid of the strong oxidation of inside reactor, strong uv irradiation, therefore, can needn't consider the tolerance to uv irradiation, strong oxidizing condition fully, like this, selecting of filter core material, just there is no the restriction aspect extraordinary tolerance, can on more vast optional material kind, be selected, and need not be confined to again the material of more expensive PVDF and so on fully.

Related strainer at different levels all has commercially available, commercially available strainers at different levels, the discharge outlet of draining-off sewage when its sewage draining exit is exactly back flushing, this class back flush type equipment is used in this case, for tackling step by step catalyst particles, originally the sewage draining exit of commercially available equipment is used as being held back the recycling delivery port of catalyst particles or refluxing and use delivery port again by conversion in this case.

Above address, based on this case structure, the capacity of reactor or treatment capacity can significantly be expanded, described significantly expansion, to realize by significantly expanding the design volume of irradiation zone a little less than microwave zero irradiation zone or microwave, so, from the appearance, the lateral dimension of reactor, longitudinal size is all significantly to expand certainly, therefore, inside reactor is contained the liquid degree of depth and can be deepened significantly similarly, for example, can deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc., in the situation that the Sheng liquid degree of depth is enough dark, containing ozone-air bubble ascension path sufficiently long, the time sufficiently long contacted with water body containing the ozone-air bubble, in its ascension process just can with abundant reducing substances fortune, and thoroughly or be close to and exhaust up hill and dale ozone contained in bubble, thus, containing ozone composition oxidation potential in the ozone-air bubble, utilize incomplete problem to be solved, and, because long ascension path causes ozone to exhaust, just can not be entrained with again the ozone that can cause environmental pollution in reactor tail gas, only ought be subject to processing reducing substances in water body is in organic pollutant is degraded totally, in water body, again without the organic pollutant that can supply ozone oxidation reaction, those unnecessary ozone just likely no longer consume and see through long ascension path effusion liquid level, front is spoken of, among some problems that this case solves simultaneously one, it is the circulation of the relative big scale of enhanced reactor internal liquid, this systemic circulation mechanism of having strengthened has been facilitated the uniformity of its contained organic pollutants DeR process of inside reactor liquid, thus, in this case structure, allow several cubes to dozens of cube even under the processing capacity framework of hundreds of cube volume, above the inside reactor liquid level, have in the ozone effusion, the DeR that shows inside reactor has reached terminal, and be the terminal that the whole uniformity of internal liquid ground reaches DeR, this terminal point determining factor is that the condition that can provide with this case organization plan is complementary, this case is at its exhaust port position installing ozone sensor of reactor, ozone detected in this locations of structures, just mean that the inside reactor DeR reaches home, ozone sensor and connecting with the composite structure of ozone content indicating meter with ozone attention device or ozone content indicating meter or ozone attention device, for to operator, providing indication information accurately, this case and the electric signal that ozone sensor is exported send power-supply controller of electric to by cable, this power-supply controller of electric also connects with magnetron and pneumatic pump respectively by cable, the power-supply controller of electric described electric signal received according to it carries out the power switch action, certainly, its function mode is, at power-supply controller of electric, receive in the signal that ozone that ozone sensor sends overflows, automatically close the power supply that leads to magnetron and pneumatic pump, this case is organization plan according to this, can know in time the terminal of inside reactor DeR process, and organization plan according to this, when reaction reaches terminal, automatically close the power supply of magnetron and pneumatic pump, stop in time, to the inside reactor Implantation Energy, so can avoiding unnecessary energy dissipation, and, this case is structure according to this, in DeR reaches home, can close in time the power supply of described magnetron and pneumatic pump, this power-off action is synchronous, the same generation process of ozone that stopped in a flash also, because ozone generation process is stopped in time, just do not have over a large amount of ozone that need and disengage from described exhaust port, thereby avoided unnecessary secondary pollution or day secondary pollution, its framework of this case has determined that it does not have ozone more than needed can supply discharge.

Among this case structure, the microwave exposure spatial domain of its inside reactor is subject to forcing to cut off, limit, this case and adopt the multistage backwash filter structure of external cascade to tackle subtly catalyst particles, back flush type hollow fiber microfiltration membrane assembly wherein and back flush type polysulfone hollow fiber ultrafiltration membrane system are all external and away from reactor core, microwave can not shine described membrane module fully, based on this structure of this case, got around described point-like fully and pierced the heat penetration erosion destruction problem of formula, this problem is settled properly thus.

This case reactor inner chamber bottom surface is hollow gradually to central zone by periphery, described hollow its gradient is between 5 degree and 35 degree, and this case ultrasonic transducer is to be installed in outer side position or the medial surface position of this its hollow innermost, reactor inner chamber bottom surface corresponding part reactor diapire with attaching, above address, this case structure and be beneficial to the cyclic motion that driving a reaction device internal liquid is made relative big scale, the mode of this liquid circulation campaign is that peripheral liquid sinks, middle liquid rises, and so constantly moves in circles, above address, under some pH value is regulated not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles is easily reunited, and then affects its effective working interface area, affects its photochemical catalysis usefulness, especially for the section of those less particle diameters among this particle size range, easily occur because of presetting not in place, the incorrect agglomeration traits caused of pH value of pH value especially, the situation of reuniting for this catalyst particles, be immediately to adopt an effective measure, and carries out the depolymerization running for coacervate, at catalyst particles, occur under serious situation of reuniting, the heavier macro aggregate of wherein some is due to action of gravity, tend to gradually to the sedimentation of reactor intracavity bottom, in this case structure, the reactor intracavity bottom is hollow structure, and, this case structure can driving a reaction device internal liquid be made the cyclic motion of described relative big scale, the effect of this systemic circulation campaign is together with the effect of ubiquitous natural gravity, the macro aggregate of sedimentation can be pushed away along the slope of described hollow structure and sweep to hollow innermost and make them be gathered in there, in this case structure, ultrasonic transducer is positioned at this hollow innermost locations of structures just, this hollow innermost zone, it is the final zone of assembling of described macro aggregate, also that ultrasonic wave can be damply minimum simultaneously, closest range ground, the most consumingly, carry out depolymerization running zone for macro aggregate most effectively, this structure of this case can allow with minimum ultrasonic energy loss, realizes maximized ultrasonic depolymerization effect, this case is structure according to this, can converge the coacervate sediment, and, in the most concentrated zone of coacervate sediment, implements the depolymerization running, the ultrasonic wave that is derived from reactor bottom certainly simultaneously also can be radiated other zone in inside reactor liquid, smallerly to those still in the coacervate of suspended state, is bringing into play unzipping, this case associated ultrasonic radiation mechanism is the mechanism that can start as required or close, this case has realized disposing for the instant original position of this catalyst particles agglomeration traits thus.

Protect the silica tube of electrodeless ultraviolet lamp in structure for screen, its outer wall, refer to the outer wall of silica tube, through for a long time with the contacting of processed trade effluent, incrustation gradually unavoidably, the long-pending material of dirt is mainly to be difficult for by the mineral-type impurity that light-catalyzed reaction touched certainly, and the incrustation phenomenon because this mechanism forms is easy to be observed after the equipment long-play; Be attached to the dirty lamination of described silica tube outer wall, although be very thin one deck, also be enough to ultraviolet radiation to electrodeless ultraviolet lamp and cause significantly and stop, this will cause the actual treatment effect of this microwave and photo catalysis reaction treating device significantly to reduce; Be positioned at the ultrasonic transducer of reactor bottom in this case structure, among the depolymerization running of carrying out in the irregular situation of seriously reuniting for accidental catalyst particles, the ultrasonic wave of its radiation, certainly also can arrive silica tube place locations of structures, this ultrasonic wave, when carrying out original position depolymerization running, is also being carried out the ultrasonic clean scale removal work for the long-pending thing of silica tube surface dirt in the lump; And, the installation position of ultrasonic transducer is away from silica tube place locations of structures, decay to some extent when ultrasonic radiation arrives the silica tube position, therefore, the suffered ultrasonic impact in silica tube surface is low intensive ultrasonic impact, this leniently scale removal of low intensive ultrasonic impact, can avoid again or significantly weaken its silica tube surface smoothness loss that may cause of ultrasonic cavitation; Based on this structure of this case, can under the prerequisite of not tearing machine open, immediately, effectively remove the dirty lamination on this silica tube outer wall, safeguard by this lasting high-level efficiency of this microwave and photo catalysis DeR device.

The pH value of wastewater degradation inside reactor water body is the key factor that affects the catalyst dispersion stabilization; PH probe and associated pH value display instrument and the warning horn be associated etc. in this case structure, installed, can be in the situation that the pH value exceeds catalyst stably dispersing scope, initiatively give the alarm, based on this structure of this case, relating operation personnel awareness immediately inside reactor catalyst is reunited and is inclined to, and makes instant disposal.Described micropore stainless steel sleeve and installing mode thereof in this case structure are the indispensable important components be complementary with this case principle and this case structure.

Membrane module in this case structure, among the operating mode of using in complete submergence all the time, the ingress of air of having no chance of membrane module wherein, the state that always keeps hygrometric state and complete submergence, therefore, there will be no the membrane module easily occurred in that background technology often to be exposed to airborne situation, its applying working condition of membrane module in this case structure meets itself intrinsic working conditions requirement of membrane module more, be more conducive to safeguard its normal usage energy of membrane module, be more conducive to guarantee its normal service life of membrane module.

Catalyst underflow transition tank is set in this case structure, for temporarily deposit from each its backwashing procedures of back flush type strainer wash away and come containing the higher liquid of catalyst concentration ratio, thereby avoid the liquid that this catalyst concentration ratio is higher directly to fill with back reactor, so, avoided the problem that in inside reactor liquid, catalyst concentration progressively raises along with the extraction process of water purification, this extracts to its follow-up water purification and reduce the heavy burdens, so catalyst underflow transition tank structure has been arranged, just can be after the water purification extraction procedure completes, within again the catalyst underflow being filled with back to reactor.

The a pair of dry-reed type ball float level controller connected with its power cable of water pump of described transport wastewater through rly. in this case structure, its existence, can automatically avoid excessive filling waste water to the reactor inner chamber, and avoid thus waste water to overflow reactor; The dry-reed type ball float level controller that another connects with its power cable of described topping-up pump seeing through another rly., its existence, can avoid the liquid of inside reactor to be caused this topping-up pump idle running, dry turning by excessive the extraction, so can avoid booster motor to burn.

Any valve body on all fluid channels in this case structure, can the choice for use magnetic valve, these cables can be concentrated and is routed on a panel, and this structure allows the corresponding valve body switch action of each program of long-distance centralized control.

Its part of going deep into this container intracavity of this waveguide in this case structure is to consist of two sections stainless steel tubes, these two sections stainless steel tubes are docked with flange connection each other, connect part at this flange, use two-layer teflon gasket, and, the airtight partition panel of wave transparent, the airtight partition panel of this wave transparent is quartz glass plate, the ceramic plate that polyfluortetraethylene plate or dense sintering form, the airtight partition panel of this wave transparent is for this waveguide of the cross-section separation of resistance to air loss, the board plane of the airtight partition panel of this wave transparent is mutually vertical with the axis that this flange of this waveguide is connected part, its periphery edge of the airtight partition panel of this wave transparent is wedged the locations of structures between two-layer teflon gasket, this structure enters the reverse channelling of ozone the Channel Perfect blocking-up in magnetron structures zone, the corrosion infringement that this structure has protected the magnetron structures member to make it avoid strong oxidizing power ozone effectively.

Described silica tube tube chamber malleation holding pump in this case structure, be one lower powered for the low flow pumped air and only take and maintain the miniature surge pump that silica tube tube chamber malleation is purpose, this its power of silica tube tube chamber malleation holding pump is between 5 watts and 50 watts, this its air outlet operating pressure of silica tube tube chamber malleation holding pump is between 1 meter water column and 5 meter water columns, this its air output of silica tube tube chamber malleation holding pump is between 80 liters of 1 liter of per minute and per minutes, this its air outlet of silica tube tube chamber malleation holding pump sees through second check valve and described pneumatic pump is connected in parallel, in other words, this its air outlet of silica tube tube chamber malleation holding pump is to access in described breather line with bypass mode, this silica tube tube chamber malleation holding pump in structure, its function, when relatively powerful described pneumatic pump quits work, this silica tube tube chamber malleation holding pump can start in good time, with relatively much lower power loss, relatively much lower air flow quantity and relatively much lower air outlet operating pressure, resist because of the silica tube tube chamber atmospheric pressure decay that air in the silica tube tube chamber expands with heat and contract with cold and the reason such as air escape may cause, prevent by this, check the generation of silica tube tube chamber gushing water situation, described first check valve, second check valve and the 3rd check valve and described silica tube tube chamber malleation holding pump cooperatively interact, and have formed the resulting structure of a strick precaution silica tube tube chamber gushing water, this silica tube tube chamber malleation holding pump, the relatively much lower power consumption based on it, in fact it can be also the state in normal open shop all the time, for prevention silica tube tube chamber gushing water provides the barrier of a normality.

In brief, the target that allows the reactor design capacity significantly to expand has been reached in this case; Simultaneously, its structure has also been strengthened the systemic circulation campaign of the relative big scale of inside reactor liquid; Its structure has solved the ozone oxidation potentiality simultaneously and has utilized incomplete problem; Its structure and reached for the nm-class catalyst particulate from the collision fragment of its coacervate macrobead to ten number nanometers widely, meticulous interception; The selection face of its filter core material is also because of this structure expanded; Its DeR endpoint information can be known in time; Can automatically close the energy input to reactor in its DeR terminal; In its DeR terminal, also automatically stop in time the generation process of ozone, avoided unnecessary secondary pollution; Its structure and immediately original position dispose the accidental catalyst particles situation of seriously reuniting, also, simultaneously incidentally with the described silica tube of the supersonic cleaning surface of the low intensive gentleness after weakening through the teletransmission appropriateness, keep its good UV-light transparent performance; Its structure also can initiatively be detected catalyst reunion tendency, and gives the alarm when correlation parameter exceeds standard; Its structure also is conducive to membrane module and is using among the submergence operating mode fully; Its structure and realize that by catalyst underflow transition tank structure the appropriate transition of catalyst underflow deposits, overcome the excessive problem of difference before and after the membrane sepn load; Its structure and can realize the automatic control of waste water perfusion water level; Its structure also can be extracted in restricted water supply position at water purification, closes automatically, in time the power supply of described topping-up pump, is beneficial to the protection of booster motor; The airtight partition-type structures of the wave transparent of its waveguide is conducive to the corrosion infringement of protecting the magnetron structures member to make it avoid reverse channelling ozone; The Miniature diaphragm pump of its bypass access, together with the check valve be used in conjunction with, can be stopped silica tube tube chamber gushing water.

This case structure has solved one of described problem, two, three, four, five, six, seven, eight, nine, ten, 11,12,13,14,15,16 totally.

The accompanying drawing explanation

Fig. 1 is the brief perspective diagram of this case structure of reactor.

Fig. 2 is the brief schematic diagram of its mutual flange connection profile form of two sections stainless steel tubes that forms waveguide.

In figure, the 1st, water pump, the 2nd, the circulation conductor, 3, 13 is respectively two breather lines that locations of structures is different, the 4th, the osculum end of circulation conductor, 5, 14 is respectively the shutoff headkerchief at silica tube two ends, the 6th, silica tube, the 7th, metal cage, it is also the microwave constrainer of the cage shape of metal material, the 8th, electrodeless ultraviolet lamp, the 9th, exhaust port, the 10th, waveguide, the 11st, magnetron, the 12nd, pneumatic pump, the 15th, described internal tank is not subject to the spatial domain of microwave exposure, the 16th, micro porous aeration head, the 17th, the big opening end of circulation conductor, the 18th, wash water valve, the 19th, sewage draining exit, the 20th, back flush type hollow-fibre membrane ultra filtration filter, the 21st, back flush type tubular fibre membrane microfiltration strainer, the 22nd, water purifying tank, the 23rd, the preposition prefilter of back flush type, the 24th, wastewater disposal basin, the 25th, topping-up pump, the 26th, the stopple coupon of ozone sensor, the 27th, the ozone content indicating meter, the composite structure of ozone attention device or ozone content indicating meter and ozone attention device, the 28th, ozone sensor, the 29th, power-supply controller of electric, the 30th, ultrasonic transducer, the 31st, HF oscillation electric signal transmission cable, the 32nd, warning horn, the 33rd, the cable that pH analyser and warning horn are linked up, the 34th, pH analyser, the 35th, the cable that pH analyser and pH probe is linked up, the 36th, pH probe, the 37th, micropore stainless steel sleeve, the 38th, catalyst underflow transition tank, the 39th, catalyst underflow reverse flow valve, 40, 46 is respectively the different stainless steel tube in two-stage structure position, 41, 45 is respectively two ring flanges that locations of structures is different, 42, 44 is respectively two teflon gaskets that locations of structures is different, the 43rd, the airtight partition panel of described wave transparent, some arrows in figure are indicated the liquid flow direction of its contiguous pipeline when in on-state.

Embodiment

In this case embodiment showed at Fig. 1, the structure of this reactor comprises a container, its appearance profile of described container is cube shaped, cuboid, cylindrical, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form, bottom position at described container intracavity is equiped with many micro porous aeration heads 16, and, quartz ampoule 6, this quartz ampoule 6 is erected at the inner chamber position of described container, the two ends of this quartz ampoule 6 are equiped with shutoff headkerchief 5, 14, lay respectively at the described shutoff headkerchief 5 at quartz ampoule 6 two ends, all offer the ventilation interface on 14, and, electrodeless ultraviolet lamp 8, this electrodeless ultraviolet lamp 8 is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, the quantity of this electrodeless ultraviolet lamp 8 is at least more than one, this quantity at least all is erected at the inside of described quartz ampoule 6 at more than one electrodeless ultraviolet lamp 8, and, air pump 12, this air pump 12 is installed in the outside of described container, ventilation interface on described quartz ampoule 6 one end shutoff headkerchieves 14 connects with the gas outlet of described air pump 12 via breather line 13 and through described wall of a container, ventilation interface on described quartz ampoule 6 its other end shutoff headkerchieves 5 connects with the micro porous aeration head 16 that is positioned at described container intracavity bottom via another breather line 3, and, microwave generator, this microwave generator is installed in the outside of described container, this microwave generator is magnetron 11, and, waveguide 10, this waveguide 10 is for transmitting the member of microwave, one end of this waveguide 10 and described magnetron 11 UNICOMs, the other end of this waveguide 10 sees through the inner chamber of described wall of a container towards described container, and, water pump 1, this water pump 1 is positioned at the outside of described container, this water pump is for the pending waste water of pumping, this water pump 1 its delivery port leads to the inner chamber of described container, the top of described container offers exhaust port 9, emphasis is, that end that sees through described wall of a container of this waveguide 10 extends much further into the inner chamber of described container, this gos deep into that end of waveguide 10 of described container intracavity and the inside that a shutoff headkerchief 14 further seeing through again described quartz ampoule 6 probes into quartz ampoule 6, and, the structure of this reactor also comprises the microwave constrainer 7 of the cage shape of metal material, contain many holes or mesh on the microwave constrainer 7 of this cage shape, the function of the microwave constrainer 7 of this cage shape is the constraint microwave, contain its unhelpful dissipation, simultaneously, allow most of ultraviolet light to penetrate, the installation position of the microwave constrainer 7 of this cage shape is positioned at the inside of described quartz ampoule 6, microwave constrainer 7 its inner chambers of this cage shape and that end UNICOM that probes into quartz ampoule 6 of described waveguide 10, the described electrodeless ultraviolet lamp 8 that is erected at quartz ampoule 6 inside all is rolled in wherein by the microwave constrainer 7 of described cage shape, the microwave constrainer 7 of this cage shape is exactly a metal cage 7, what label 7 referred to is same member, and, circulation guide 2, the function of this circulation guide 2 is pack ascension paths containing the ozone-air bubble from micro porous aeration head 16, and lead described internal tank liquid to make the shuttling movement of relative large scale by the strength that pulls of the bubble flow because being subject to the ascension that pack strengthens, this circulation guide 2 is installed in the inner chamber position of described container, the simple and easy cone that these circulation guide 2 its profile shapes connect like two ends, these circulation guide 2 its osculum ends vertically upward, these circulation guide 2 its big opening ends vertically downward, these circulation guide 2 its axis are mutually vertical with the inner chamber bottom surface of described container, 4 its locations of structures of osculum end vertically upward of this circulation guide 2 are under described quartz ampoule 6, 17 its edges of big opening end vertically downward of this circulation guide 2 and the lateral separation between described container inner wall are between 5 centimetres and 300 centimetres, any set point value within this lateral separation scope is all available enforcement value, this lateral separation can be for example 5 centimetres, 55 centimetres, 99 centimetres, 152.5 centimetre, 222 centimetres, 260 centimetres, 300 centimetres, etc., 17 its edges of big opening end vertically downward of this circulation guide 2 and the fore-and-aft distance between described container intracavity bottom surface are between 5 centimetres and 100 centimetres, any set point value within this fore-and-aft distance scope is all available enforcement value, this fore-and-aft distance can be for example 5 centimetres, 26 centimetres, 33 centimetres, 52.5 centimetre, 77 centimetres, 88 centimetres, 100 centimetres, etc., and, described many micro porous aeration heads 16 are within the scope that installing described circulation guide 2 its big opening end 17 edges are drawn a circle to approve in the vertical projection of described container intracavity bottom surface with gathering, and, booster pump 25, this booster pump 25 is mixed with the degraded water afterwards of a large amount of catalyst particles for the supercharging pumping, these booster pump 25 its water inlets connect with the inner chamber of described container via ventilating water pipe and through described wall of a container, and, the preposition prefilter 23 of back flush type, preposition prefilter 23 its water inlets of this back flush type connect with the delivery port of described booster pump 25, and, back flush type doughnut membrane microfiltration filter 21, preposition prefilter 23 its pure water inlets of described back flush type connect with the water inlet of this back flush type doughnut membrane microfiltration filter 21 via first water purifying valve, and, back flush type hollow-fibre membrane ultra filtration filter 20, described back flush type doughnut membrane microfiltration filter 21 its pure water inlets connect with the water inlet of this back flush type hollow-fibre membrane ultra filtration filter 20 via second water purifying valve, these back flush type hollow-fibre membrane ultra filtration filter 20 its pure water inlets connect with the entrance point of the 3rd water purifying valve, the water side of the 3rd water purifying valve is the water side of outlet terminal water purification, the water side of the 3rd water purifying valve can connect with water purifying tank 22, certainly, water purifying tank 22 is member not necessarily, the water side of the 3rd water purifying valve also can be directly via the past water purification water of device for cleaning pipeline mechanism, and, catalyst underflow transition tank 38, this catalyst underflow transition tank 38 is tank bodies of a hollow, this catalyst underflow transition tank 38 is for temporarily depositing described filter 20, 21, the higher water body of catalyst concentration ratio that 23 its backwashing procedures discharge, the catalyst underflow refluxing opening that is positioned at these catalyst underflow transition tank 38 its intracavity bottoms leads to the inner chamber of described container via catalyst underflow return valve 39, this catalyst underflow return valve is to control the valve body of this catalyst return flow line for switch, preposition prefilter 23 its outlets of sewer of described back flush type lead to the inner chamber of this catalyst underflow transition tank 38 via first sewage valve, described back flush type doughnut membrane microfiltration filter 21 its outlets of sewer lead to the inner chamber of this catalyst underflow transition tank 38 via second sewage valve, described back flush type hollow-fibre membrane ultra filtration filter 20 its outlets of sewer lead to the inner chamber of this catalyst underflow transition tank 38 via the 3rd sewage valve, each described filter 23, 21, 20 all for holding back catalyst particles, each described filter 23, 21, 20 its outlets of sewer are all converted as being held back the recycling delivery outlet of catalyst particles, and, ozone sensor 28, the sampling port of these ozone sensor 28 its probe tubes 26 is close to described exhaust port 9 or probes into the inside of described exhaust port 9, and, the ozone content display, the composite structure 27 of ozone attention device or ozone content display and ozone attention device, this ozone sensor 28 is via article one cable and this ozone content display, ozone attention device or ozone content display connect with the composite structure 27 of ozone attention device, and, power-supply controller of electric 29, these ozone sensor 28 its output electric signals connect with this power-supply controller of electric 29 via the second cable, this power-supply controller of electric 29 connects with described magnetron 11 via the 3rd cable, this power-supply controller of electric 29 connects with described air pump 12 via the 4th cable, this power-supply controller of electric 29 is power-supply controller of electric that the described electric signal that can receive according to it carries out the power switch action, and, one group of ultrasonic transducer 30, this group of ultrasonic transducer 30 at least contains a ultrasonic transducer individuality, this group of ultrasonic transducer 30 is for the radiation low-frequency ultrasonic waves, this low-frequency ultrasonic waves refers to the ultrasonic wave of frequency in the 20kHz-60kHz scope, this ultrasonic transducer 30 is bottom outside position or the bottom inside positions that are installed in this container, this container intracavity bottom surface is hollow gradually to central area by periphery, described hollow its gradient is between 5 degree and 35 degree, this ultrasonic transducer 30 is to be installed in lateral surface position or the medial surface position of its corresponding part vessel bottom wall in hollow bosom of this container intracavity bottom surface with attaching, what in legend, show is the example that is installed in the lateral surface position, there is no to show the example that is installed in the medial surface position in legend, and, higher-order of oscillation electric signal transmission cable 31, one group of ultrasonic transducer 30 of one end of this higher-order of oscillation electric signal transmission cable 31 and this connects, and, higher-order of oscillation electric signal generator, the other end of described higher-order of oscillation electric signal transmission cable 31 connects with this higher-order of oscillation electric signal generator, and, pH probe 36, and, pH analyzer 34, this pH probe 36 is coupled to each other with pH analyzer 34, this pH analyzer 34 and connecting with siren 32, this siren 32 is for giving the alarm to the pH value situation of transfiniting, described container intracavity is stretched at the top that this pH probe 36 sees through described container, and, the micropore stainless steel sleeve 37 of making through powder sintering process, this micropore stainless steel sleeve 37 is cap for brush shape, this micropore stainless steel sleeve 37 is positioned at described container intracavity, these micropore stainless steel sleeve 37 its blind ends down, these micropore stainless steel sleeve 37 its openends upward, these micropore stainless steel sleeve 37 its openends upward connect with described container top via the buffering isolating pad, do not draw described that buffering isolating pad in legend, within these pH probe 36 its those parts that stretch into described container intracavity probe into this micropore stainless steel sleeve 37, this its material of buffering isolating pad is fluorubber or silicon rubber, and, two pairs of dry-reed type ball float level controllers, these two pairs of dry-reed type ball float level controllers all extend into the inner chamber of reactor through the top of reactor, a pair of dry-reed type ball float level controller wherein connects with the power cable of described water pump 1 by a relay, wherein another connects with the power cable of described booster pump 25 by another relay the dry-reed type ball float level controller, these waveguide 10 its part of going deep into this container intracavity are by two sections stainless steel tubes 40, 46 form, these two sections stainless steel tubes 40, 46 are docked with flange connection each other, connect part at this flange, use two-layer teflon gasket 42, 44, and, the airtight partition panel 43 of wave transparent, the airtight partition panel 43 of this wave transparent is quartz glass plates, the ceramic wafer that polyfluortetraethylene plate or dense sintering form, the airtight partition panel 43 of this wave transparent is for this waveguide 10 of the cross-section separation of air-tightness, the board plane of the airtight partition panel 43 of this wave transparent is mutually vertical with the axis that these waveguide 10 these flanges are connected part, airtight partition panel 43 its periphery edges of this wave transparent are wedged two-layer teflon gasket 42, locations of structures between 44, and, first check valve, this first check valve is installed in the position of contiguous described air pump 12 gas outlets on described air pump 12 its plenum ducts 13, and, quartz ampoule tube chamber malleation holding pump, this quartz ampoule tube chamber malleation holding pump be one lower powered for the low discharge pumped air and only take and maintain the miniature membrane pump that quartz ampoule 6 tube chamber malleations are purpose, this its power of quartz ampoule tube chamber malleation holding pump is between 5 watts and 50 watts, this its gas outlet operating pressure of quartz ampoule tube chamber malleation holding pump is between 1 meter water column and 5 meter water columns, this its gas output of quartz ampoule tube chamber malleation holding pump is between 1 liter and 80 liters per minute per minute, this its gas outlet of quartz ampoule tube chamber malleation holding pump sees through second check valve and described air pump 12 is connected in parallel, in other words, this quartz ampoule tube chamber malleation holding pump is connected with described breather line 13 with bypass mode, and, the 3rd check valve, the 3rd check valve is installed in connecting on gas circuit between these quartz ampoule 6 tube chambers and described micro porous aeration head 16, this connects namely described another breather line 3 of gas circuit, do not draw described quartz ampoule tube chamber malleation holding pump and described first check valve in legend, second check valve and the 3rd check valve.

Implement related check valve market on sale.

Implement related miniature surge pump market on sale.

This catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control; The opening-closing valve of commercially available various fluid lines, can be applicable to the needs of this locations of structures, and its concrete type selecting can determine as required.

Described dry-reed type ball float level controller, the art-recognized meanings of itself is known for the professional of fluid level controller manufacturing; Described dry-reed type ball float level controller market is on sale.

Described rly. market is on sale.Described rly. comprises high power relay certainly.The described rly. of this case is made a general reference function class together or some approaching circuit connection control device of function, and described circuit connection control device is rly., contactor, isolating switch etc. for example; Described circuit connection controller again for example rly. add the assembling device of contactor.Described rly., contactor, isolating switch etc. device market is all on sale.

Related stainless steel tube market is on sale.

Related quartz glass plate market is on sale.

The markets such as related polyfluortetraethylene plate and teflon gasket are all on sale.

The ceramic plate market that related dense sintering forms is on sale; This ceramic plate also can customize to Ceramics Majors producer.

Related flange connects itself art-recognized meanings of a word for the pipework technician, is known.

Valve body on all fluid passages of this case, can the choice for use magnetic valve, in the situation of choice for use magnetic valve, by the cable by long-range, concentrates and is arranged on a control panel, so, can realize easily long-distance centralized control.

Do not draw described dry-reed type ball float level controller in legend.

Do not draw this HF oscillation electric signal producer in legend.

Related pH probe market is on sale; Described pH probe also claims the pH sensor; Itself art-recognized meanings of pH probe or day pH sensor is known.

Related pH analyser market is on sale; Itself art-recognized meanings of pH analyser is known.The pH that can utilize that any model made a general reference in this case pH analyser one word detects, picks up, shows the pH value information, and can externally export the instrument of pH associated electrical signal, sell on market simple and easy or complicated but all meet the pH correlate meter of this basic demand it is various in style, can select as required.

Related its thickness of buffering isolating pad is not limit; But, a preferable range is arranged, the preferable range of this its thickness of buffering isolating pad is between 1 millimeter to 8 millimeters.

Their own art-recognized meanings of related viton and related silicon rubber are known; Related viton and related silicon rubber, market is all on sale.

Related its wall thickness of micropore stainless steel sleeve is not limit; But, an associated preferable range is also arranged, the preferable range of this its wall thickness of micropore stainless steel sleeve is between 3 millimeters to 30 millimeters.

A related powder sintered word, the art-recognized meanings of itself, for the professional of metallurgical technology field, is known.

Related micropore stainless steel sleeve, can be to the customization of relevant powder metallurgy specialized factory.

The sleeve-shaped micropore Stainless Steel Filter conversion that powder sintering process can be made is the described micropore stainless steel of this case sleeve; The sleeve-shaped micropore Stainless Steel Filter market that described powder sintering process is made is on sale.

The aperture of related its micropore of micropore stainless steel sleeve is not limit; But the aperture of this micropore is also that a preferable range is arranged, the preferable range of this micropore size is between 0.5 micron to 50 microns.

This its opening end upward of micropore stainless steel sleeve connects with described container top via the buffering isolating pad, refers to, and this connection is flexible connection, at this, connects part, has described buffer compartment mediate from pad.

Described warning horn be can be received according to it electric signal send the device of audio frequency warning message or optical frequency warning message; Itself art-recognized meanings of described warning horn is known; Described warning horn market is on sale.

Described hollow its gradient enforcement value is that any set point value within this gradient scope is all the operable enforcement value that this case allows between 5 degree and 35 degree; This hollow its gradient enforcement value can be for example 5 degree, 8 degree, 10 degree, 15 degree, 20 degree, 25 degree, 30 degree, 35 degree, etc.

Itself art-recognized meanings of related ultrasonic transducer one word is known for the professional in ultrasonic technology field.

Itself art-recognized meanings of related HF oscillation electric signal transmission cable one word is also known for the professional in ultrasonic technology field.

Related ultrasonic transducer and HF oscillation electric signal transmission cable market are all on sale; Described ultrasonic transducer and HF oscillation electric signal transmission cable etc. also can be to ultrasonic transducer specialized factory and the customizations of cable specialized factory.

Itself art-recognized meanings of related HF oscillation electric signal producer one word is also known for the professional in ultrasonic technology field; Various HF oscillation electric signal producer all has commercially available; Described HF oscillation electric signal producer also can customize to ultrasonic wave equipment specialized factory.

Related ozone sensor 28 markets are on sale; Also can to ozone sensor specialized factory, customize as required.

Related ozone content monitor market is on sale; Also can to ozone content indicating meter specialized factory, customize as required; Ozone sensor producer also sells matching used ozone content indicating meter usually.

Related ozone attention device, refer to warn sound or alarm flashing or warning sound combines with alarm flashing both mechanisms for warning of having both at the same time; Ozone attention device market is on sale; Also can customize to ozone attention device specialized factory; Ozone sensor producer also can sell matching used ozone attention device usually.

Related this power-supply controller of electric 29 is power-supply controller of electric that the described electric signal that can receive according to it carries out the power switch action; The power-supply controller of electric that the electric signal that can receive according to it carries out the power switch action only with regard to its circuit engineering itself, is ripe, known technology; Described power-supply controller of electric market is on sale; Also can utilize commercially available power-supply controller of electric to be changed a social system as required; Described power-supply controller of electric also can be to the customization of power-supply controller of electric specialty manufacturers; Its professional manufacturers of the electron device of power-supply controller of electric and so on spreads all over the world.

Described circulation conductor 2 its outline shapes or also can be described as the profile shape like the cooling tower in fuel-burning power plant.

Described metal material one word, the art-recognized meanings of itself, be known.

The microwave constrainer 7 of this cage shape is that its material of metal cage can be any selected metal, but, residing by the formed ozone gas mixture of strong ultraviolet radiation environment in view of it, and, for exporting to greatest extent considering of the UV-light of being launched by electrodeless ultraviolet lamp 8 by complicated specular reflection mechanism as much as possible, the preferred metal material that is suitable for making the microwave constrainer 7 of this cage shape is the stainless steel of processing through mirror polish.

Itself art-recognized meanings of described punching stainless steel one word, for stainless steel industry, is known.

Can make described microwave constrainer 7 through welding, splicing or mould pressing process with bright finished punching stainless steel plate.

Also can make with bright finished Stainless Steel Wire braiding the microwave constrainer 7 of this cage shape.

For convenience of routine preventive maintenance or the cleaning of equipment, can offer sewage draining exit 19 in the bottom of described container, certainly can install wash water valve 18 in the position of sewage draining exit 19.Described sewage draining exit 19 and wash water valve 18 are not necessarily.

The material of described circulation conductor 2 is not limit, and the material of described circulation conductor 2 can be for example tetrafluoroethylene material, glass material, ceramic material, metal material, etc., still, circulation conductor 2 its preferred materials are stainless steels.

The wastewater disposal basin 24 occurred in legend not necessarily because pending waste water also can be selected directly to lead to described container without wastewater disposal basin as the case may be.

In this this case example structure, described many micro porous aeration heads 16 be installed in the scope of drawing a circle to approve in the vertical projection of described container intracavity bottom surface at described circulation conductor 2 its big opening end 17 edges with gathering within.Be positioned at the described many micro porous aeration heads 16 within the scope that described vertical projection draws a circle to approve, can be both within tiling ground is installed in bottom described container intracavity the scope of drawing a circle to approve, certainly, within this delineation scope, also can take another kind of more intensive installing mode, described more intensive installing mode, refer to, described many micro porous aeration heads can be folded and set up at the enterprising windrow of three-dimensional, they be gathered form the cluster-shaped micro porous aeration head cluster with three-dimensional stacked framework in this way; This kind of cluster-shaped micro porous aeration head cluster can hold the comparatively huge micro porous aeration head of quantity; This kind of mode can be carried larger air flux.What in this case legend, show is exactly the structural feature of above-mentioned this cluster-shaped micro porous aeration head cluster; It is that the level showed than legend is more that the level of its actual stacked architecture can also allow certainly, and at this, in multi-level stacked architecture, each micro porous aeration head can be arranged each other with staggering, can not block mutually each other, certainly, even if there is part mutually to block, also without prejudice.

The preferable range in the preposition prefilter of described back flush type 23 its filter opening apertures is between 5 microns and 300 microns, and certainly, it is also that this case allows that the preposition pre-filtering of other outside this preferable range aperture is selected; The preferable range in described back flush type tubular fibre membrane microfiltration strainer 21 its filter opening apertures is between 25 nanometers and 1000 nanometers, and certainly, it is also that this case allows that other micro-filtration aperture outside this preferable range is selected; The preferable range in described back flush type hollow-fibre membrane ultra filtration filter 20 its filter opening apertures is between 15 nanometers and 2 nanometers, and certainly, it is also that this case allows that other ultrafiltration aperture outside this scope is selected.

The preposition prefilter 23 of described back flush type also claims back flush type fore filter or back flush type prefilter, and itself art-recognized meanings of the preposition prefilter of described back flush type 23 is known; The preposition prefilter of described back flush type 23 markets are on sale.

Described back flush type tubular fibre membrane microfiltration strainer 21 is the strainers that are suitable for micro-filtration; Itself art-recognized meanings of described micro-filtration one word is known; Itself art-recognized meanings of described back flush type tubular fibre membrane microfiltration strainer 21, for the professional in membrane separation technique field, is known; Described back flush type tubular fibre membrane microfiltration strainer 21 markets are on sale.

Described back flush type hollow-fibre membrane ultra filtration filter 20 is the strainers that are suitable for ultrafiltration; Itself art-recognized meanings of described ultrafiltration one word is known; Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter 20, for the professional in membrane separation technique field, is known; Described back flush type hollow-fibre membrane ultra filtration filter 20 markets are on sale.

In the ultrafiltration link, this back flush type hollow-fibre membrane ultra filtration filter 20 can be the form that a back flush type hollow-fibre membrane ultra filtration filter monomer is only arranged; Certainly, this back flush type hollow-fibre membrane ultra filtration filter also can be comprised of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.In legend, do not show the structural form of this kind of parallel connection.

Express a related word in parallel, the art-recognized meanings itself referred to is clearly.

Express related monomer one word, refer to itself function and structure equipment individuality completely.

Similarly, in the micro-filtration link, this back flush type tubular fibre membrane microfiltration strainer 21 can be the form that a back flush type tubular fibre membrane microfiltration strainer monomer is only arranged; Certainly, this back flush type tubular fibre membrane microfiltration strainer also can be comprised of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.Do not show this kind of parallel-connection structure situation in legend.

Can further install second topping-up pump on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration strainer 21 its pure water inlets and described back flush type hollow-fibre membrane ultra filtration filter 20, this second topping-up pump is for augmenting hydraulic pressure to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter; This second topping-up pump not necessarily.Do not show second supercharging pump structure situation of this kind of use in legend.

Described metal cage is to be a mass of hole or mesh in himself structure of microwave constrainer 7 of described cage shape, and the preferable range of described hole or its bore of mesh is between 0.5 centimetre and 3.0 centimetres; Certainly, if must select hole or the mesh of other bore outside this preferable range, that is also that this case allows.

Among enforcement, can also be on this case architecture basics, further develop this case scheme, for example, can be paid close attention to the charging characteristic of catalyst particles, and it is apt to add utilization, based on this consideration, its hollow fiber microfiltration membrane included of the described back flush type tubular fibre of this case membrane microfiltration strainer can be specified and be used bear electricity hollow fiber microfiltration membrane, its hollow fiber ultrafiltration membrane included of the described back flush type hollow-fibre membrane of this case ultra filtration filter can specify use bear electricity hollow fiber ultrafiltration membrane.In the situation that use the bear electrolemma, the coulombic repulsion effect can be given full play to, and its effect of this coulombic repulsion, be can suppress the intractable of catalyst particles on membrane module to adhere to, and facilitates the clean running of its backwashing procedures of membrane module.Only, with regard to itself art-recognized meanings of bear electricity hollow-fibre membrane one word, the researchist for the charged membrane field, know.Only, with regard to itself technology of preparing of bear electricity hollow-fibre membrane, the expert for the charged membrane field, know.

Among enforcement, its structure of this case can also allow further to comprise tank, within described back flush type tubular fibre membrane microfiltration strainer and the equal submergence of described back flush type hollow-fibre membrane ultra filtration filter are placed in this tank, be equiped with another group ultrasonic transducer at its sidewall of this tank or its bottom, this another group ultrasonic transducer at least contains a ultrasonic transducer individuality, this another group ultrasonic transducer is used for the radiation high-frequency ultrasonic, this high-frequency ultrasonic refers to the ultrasonic wave of frequency in the 100kHz-12MHz scope, this another group ultrasonic transducer connects with another HF oscillation electric signal producer, in this case membrane module back flushing operation procedure, by means of there is no the extremely weak described high-frequency ultrasonic of cavitation damage or cavitation damage, can more mildly assist backwashing procedures to remove those obstinate catalyst adhered on the membrane module working interface.

Implement not draw described other annex in legend.

The embodiment of this case is not limited to the legend mode.

Claims (10)

1. a photocatalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water, the structure of this reactor comprises a container, its appearance profile of described container is cube shaped, cuboid, cylindrical, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form, bottom position at described container intracavity is equiped with many micro porous aeration heads, and, quartz ampoule, this quartz ampoule is erected at the inner chamber position of described container, the two ends of this quartz ampoule are equiped with the shutoff headkerchief, lay respectively on the described shutoff headkerchief at quartz ampoule two ends and all offer the ventilation interface, and, electrodeless ultraviolet lamp, this electrodeless ultraviolet lamp is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, the quantity of this electrodeless ultraviolet lamp is at least more than one, this quantity at least all is erected at the inside of described quartz ampoule at more than one electrodeless ultraviolet lamp, and, air pump, this air pump is installed in the outside of described container, ventilation interface on described quartz ampoule one end shutoff headkerchief connects with the gas outlet of described air pump via breather line and through described wall of a container, ventilation interface on its other end shutoff headkerchief of described quartz ampoule connects with the micro porous aeration head that is positioned at described container intracavity bottom via another breather line, and, microwave generator, this microwave generator is installed in the outside of described container, this microwave generator is magnetron, and, waveguide, this waveguide is for transmitting the member of microwave, one end of this waveguide and described magnetron UNICOM, the other end of this waveguide sees through the inner chamber of described wall of a container towards described container, and, water pump, this water pump is positioned at the outside of described container, this water pump is for the pending waste water of pumping, its delivery port of this water pump leads to the inner chamber of described container, the top of described container offers exhaust port, it is characterized in that, that end that sees through described wall of a container of this waveguide extends much further into the inner chamber of described container, this gos deep into that end of waveguide of described container intracavity and the inside that a shutoff headkerchief further seeing through again described quartz ampoule probes into quartz ampoule, and, the structure of this reactor also comprises the microwave constrainer of the cage shape of metal material, contain many holes or mesh on the microwave constrainer of this cage shape, the function of the microwave constrainer of this cage shape is the constraint microwave, contain its unhelpful dissipation, simultaneously, allow most of ultraviolet light to penetrate, the installation position of the microwave constrainer of this cage shape is positioned at the inside of described quartz ampoule, that end UNICOM that probes into quartz ampoule of its inner chamber of microwave constrainer of this cage shape and described waveguide, the described electrodeless ultraviolet lamp that is erected at quartz ampoule inside all is rolled in wherein by the microwave constrainer of described cage shape, and, the circulation guide, the function of this circulation guide is the ascension path containing ozone-air bubble of pack from micro porous aeration head, and lead described internal tank liquid to make the shuttling movement of relative large scale by the strength that pulls of the bubble flow because being subject to the ascension that pack strengthens, this circulation guide is installed in the inner chamber position of described container, the simple and easy cone that its profile shape of this circulation guide connects like two ends, its osculum end of this circulation guide vertically upward, this its big opening end of circulation guide vertically downward, this its axis of circulation guide is mutually vertical with the inner chamber bottom surface of described container, its locations of structures of osculum end vertically upward of this circulation guide is under described quartz ampoule, its edge of big opening end vertically downward of this circulation guide and the lateral separation between described container inner wall are between 5 centimetres and 300 centimetres, its edge of big opening end vertically downward of this circulation guide and the fore-and-aft distance between described container intracavity bottom surface are between 5 centimetres and 100 centimetres, and, described many micro porous aeration heads be installed in the scope of drawing a circle to approve in the vertical projection of described container intracavity bottom surface at its big opening end edge of described circulation guide with gathering within, and, booster pump, this booster pump is mixed with the degraded water afterwards of a large amount of catalyst particles for the supercharging pumping, its water inlet of this booster pump connects with the inner chamber of described container via ventilating water pipe and through described wall of a container, and, the preposition prefilter of back flush type, its water inlet of the preposition prefilter of this back flush type connects with the delivery port of described booster pump, and, back flush type doughnut membrane microfiltration filter, its pure water inlet of the preposition prefilter of described back flush type connects with the water inlet of this back flush type doughnut membrane microfiltration filter via first water purifying valve, and, back flush type hollow-fibre membrane ultra filtration filter, described its pure water inlet of back flush type doughnut membrane microfiltration filter connects with the water inlet of this back flush type hollow-fibre membrane ultra filtration filter via second water purifying valve, this its pure water inlet of back flush type hollow-fibre membrane ultra filtration filter connects with the entrance point of the 3rd water purifying valve, the water side of the 3rd water purifying valve is the water side of outlet terminal water purification, and, catalyst underflow transition tank, this catalyst underflow transition tank is the tank body of a hollow, this catalyst underflow transition tank is for temporarily depositing the higher water body of catalyst concentration ratio that its backwashing procedures of described filter discharges, the catalyst underflow refluxing opening that is positioned at this its intracavity bottom of catalyst underflow transition tank leads to the inner chamber of described container via catalyst underflow return valve, this catalyst underflow return valve is to control the valve body of this catalyst return flow line for switch, its outlet of sewer of the preposition prefilter of described back flush type leads to the inner chamber of this catalyst underflow transition tank via first sewage valve, described its outlet of sewer of back flush type doughnut membrane microfiltration filter leads to the inner chamber of this catalyst underflow transition tank via second sewage valve, described its outlet of sewer of back flush type hollow-fibre membrane ultra filtration filter leads to the inner chamber of this catalyst underflow transition tank via the 3rd sewage valve, each described filter is all for holding back catalyst particles, each its outlet of sewer of described filter is all converted as being held back the recycling delivery outlet of catalyst particles, and, ozone sensor, the sampling port of this its probe tube of ozone sensor is close to described exhaust port or probes into the inside of described exhaust port, and, the ozone content display, the composite structure of ozone attention device or ozone content display and ozone attention device, this ozone sensor is via article one cable and this ozone content display, ozone attention device or ozone content display connect with the composite structure of ozone attention device, and, power-supply controller of electric, its output electric signal of this ozone sensor connects with this power-supply controller of electric via the second cable, this power-supply controller of electric connects with described magnetron via the 3rd cable, this power-supply controller of electric connects with described air pump via the 4th cable, this power-supply controller of electric is the power-supply controller of electric that the described electric signal that can receive according to it carries out the power switch action, and, one group of ultrasonic transducer, this group of ultrasonic transducer at least contains a ultrasonic transducer individuality, this group of ultrasonic transducer is for the radiation low-frequency ultrasonic waves, this low-frequency ultrasonic waves refers to the ultrasonic wave of frequency in the 20kHz-60kHz scope, this container intracavity bottom surface is hollow gradually to central area by periphery, described hollow its gradient is between 5 degree and 35 degree, this group of ultrasonic transducer is to be installed in lateral surface position or the medial surface position of its corresponding part vessel bottom wall in hollow bosom of this container intracavity bottom surface with attaching, and, higher-order of oscillation electric signal transmission cable, one group of ultrasonic transducer of one end of this higher-order of oscillation electric signal transmission cable and this connects, and, higher-order of oscillation electric signal generator, the other end of described higher-order of oscillation electric signal transmission cable connects with this higher-order of oscillation electric signal generator, and, the pH probe, and, the pH analyzer, this pH probe is coupled to each other with the pH analyzer, this pH analyzer and connecting with siren, this siren is for giving the alarm to the pH value situation of transfiniting, described container intracavity is stretched at the top that this pH probe sees through described container, and, the micropore stainless steel sleeve of making through powder sintering process, this micropore stainless steel sleeve is cap for brush shape, this micropore stainless steel sleeve is positioned at described container intracavity, this its blind end of micropore stainless steel sleeve down, this its openend of micropore stainless steel sleeve upward, this its openend upward of micropore stainless steel sleeve connects with described container top via the buffering isolating pad, this pH pops one's head within its that part that stretches into described container intracavity probes into this micropore stainless steel sleeve, this its material of buffering isolating pad is fluorubber or silicon rubber, and, two pairs of dry-reed type ball float level controllers, these two pairs of dry-reed type ball float level controllers all extend into the inner chamber of reactor through the top of reactor, a pair of dry-reed type ball float level controller wherein connects with the power cable of described water pump by a relay, wherein another connects with the power cable of described booster pump by another relay the dry-reed type ball float level controller, its part of going deep into this container intracavity of this waveguide is to consist of two sections stainless steel tubes, these two sections stainless steel tubes are docked with flange connection each other, connect part at this flange, use two-layer teflon gasket, and, the airtight partition panel of wave transparent, the airtight partition panel of this wave transparent is quartz glass plate, the ceramic wafer that polyfluortetraethylene plate or dense sintering form, the airtight partition panel of this wave transparent is for this waveguide of the cross-section separation of air-tightness, the board plane of the airtight partition panel of this wave transparent is mutually vertical with the axis that this flange of this waveguide is connected part, its periphery edge of the airtight partition panel of this wave transparent is wedged the locations of structures between two-layer teflon gasket, and, first check valve, this first check valve is installed in the position of contiguous described air pump gas outlet on its plenum duct of described air pump, and, quartz ampoule tube chamber malleation holding pump, this quartz ampoule tube chamber malleation holding pump be one lower powered for the low discharge pumped air and only take and maintain the miniature membrane pump that quartz ampoule tube chamber malleation is purpose, this its power of quartz ampoule tube chamber malleation holding pump is between 5 watts and 50 watts, this its gas outlet operating pressure of quartz ampoule tube chamber malleation holding pump is between 1 meter water column and 5 meter water columns, this its gas output of quartz ampoule tube chamber malleation holding pump is between 1 liter and 80 liters per minute per minute, this its gas outlet of quartz ampoule tube chamber malleation holding pump sees through second check valve and described air pump is connected in parallel, and, the 3rd check valve, the 3rd check valve is installed in connecting on gas circuit between this quartz ampoule tube chamber and described micro porous aeration head, this connects namely described another breather line of gas circuit.

2. a kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water according to claim 1, is characterized in that, its material of microwave constrainer of this cage shape is the punching stainless steel of processing through mirror polish.

3. a kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water according to claim 1, is characterized in that, the microwave constrainer of this cage shape is to be made by the braiding of mirror polish Stainless Steel Wire.

4. a kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water according to claim 1, it is characterized in that, described many micro porous aeration heads are to fold and set up at the enterprising windrow of three-dimensional, gather in this way and form the cluster-shaped micro porous aeration head cluster with three-dimensional stacked framework.

5. a kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water according to claim 1, is characterized in that, its material of circulation conductor of the simple and easy speaking trumpet that this profile shape connects like two ends is stainless steel.

6. a kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water according to claim 1, it is characterized in that, its filter opening aperture of the preposition prefilter of described back flush type is between 5 microns and 300 microns, its filter opening aperture of described back flush type tubular fibre membrane microfiltration strainer is between 25 nanometers and 1000 nanometers, and its filter opening aperture of described back flush type hollow-fibre membrane ultra filtration filter is between 15 nanometers and 2 nanometers.

7. a kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water according to claim 1, it is characterized in that, this back flush type hollow-fibre membrane ultra filtration filter is comprised of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.

8. a kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water according to claim 1, it is characterized in that, this back flush type tubular fibre membrane microfiltration strainer is comprised of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.

9. a kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water according to claim 1, it is characterized in that, be equiped with second topping-up pump on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration its pure water inlet of strainer and described back flush type hollow-fibre membrane ultra filtration filter, this second topping-up pump is for augmenting hydraulic pressure to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter.

10. a kind of photochemical catalysis wastewater degradation reactor that initiatively prevents the quartz cavity gushing water according to claim 1, is characterized in that, its bore scope of the hole spread all in this metal cage self structure or mesh is between 0.5 centimetre and 3.0 centimetres.

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