CN1033059C - Anti-corrosion agent for solid long-term-effective dropping resistance - Google Patents

Anti-corrosion agent for solid long-term-effective dropping resistance Download PDF

Info

Publication number
CN1033059C
CN1033059C CN 90107273 CN90107273A CN1033059C CN 1033059 C CN1033059 C CN 1033059C CN 90107273 CN90107273 CN 90107273 CN 90107273 A CN90107273 A CN 90107273A CN 1033059 C CN1033059 C CN 1033059C
Authority
CN
China
Prior art keywords
oxide
resistance
lowering
preservative
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 90107273
Other languages
Chinese (zh)
Other versions
CN1059162A (en
Inventor
张维荣
郭淑君
米惠杰
蒋志超
史振鄞
王滨
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GANSU PROV ELECTRIC POWER DESIGN INST
Original Assignee
GANSU PROV ELECTRIC POWER DESIGN INST
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GANSU PROV ELECTRIC POWER DESIGN INST filed Critical GANSU PROV ELECTRIC POWER DESIGN INST
Priority to CN 90107273 priority Critical patent/CN1033059C/en
Publication of CN1059162A publication Critical patent/CN1059162A/en
Application granted granted Critical
Publication of CN1033059C publication Critical patent/CN1033059C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The present invention relates to a resistance-lowering preservative with a long-term effect, which is black-grey granular powder composed of silicon oxide, titanium oxide, aluminum oxide, iron oxide, ferrous oxide, calcium oxide, magnesium oxide, potassium oxide, sodium oxide, sodium sulfate, sodium chloride, sodium hydroxide, trisodium phosphate and carbon element. The power-frequency resistivity of the resistance-lowering preservative is only 0.2 ohm. M, the shock resistivity of the resistance-lowering preservative is 0.2 ohm. M, and the resistance-lowering preservative also has the good characteristic that the resistivity is lowered when the current density is increased. The resistance-lowering preservative has the stable resistivity characteristic, wherein the resistance-lowering rate can reach 50 to 85%, the lowering rate of contact voltage is about 85%, and the resistance-lowering preservative has a function of corrosion prevention for a metal grounding body. The resistance-lowering preservative has the advantages of no toxicity, no taste, no environment pollution, low cost and convenient use.

Description

Anti-corrosion agent for solid long-term-effective dropping resistance
The present invention relates to Resistance of Grounding Grids, the reduction of ground surface contact potential, step voltage and the anticorrosion of earth electrode.Be mainly used in the system of electric power, railway, post and telecommunications, radar and other employing ground network.
Reducing earth resistance, make the electrical system earthing device under any circumstance all can reach specification requirement, is that people wish the problem that solves for a long time.Aspect solution reduction earth resistance, adopted the way that enlarges the ground network area to realize in the past; Along with science and technology development, chemical resistance-reducing agent had had bigger development afterwards.As: Japan, JP8114467; The U.S., US4001145; China's application number, 881058823 grades are chemical grounded resistance reducing agent.But above these resistance reducing agents have many deficiencies in some aspects.As: shock-resistant voltage, current capacity is poor, poisonous, cost is high, uses inconvenience, poor durability or the like.
It is good to the objective of the invention is to invent a kind of resistance-reducing performance, good endurance, and cost is low, on-the-spot long-term-effective dropping resistance anticorrisive agent easy to use.
The long-term-effective dropping resistance anticorrisive agent is a kind of grey black coloured particles sprills, and is tasteless, nontoxic, environmentally safe, and resistance reducing effect is remarkable.Under repeatedly power frequency, heavy impulse current effect, electrical resistivity property is stable, and the metal earth electrode is played the anti-corrosion protection effect.The present invention, the long-term-effective dropping resistance anticorrisive agent is made up of following composition: silicon dioxide, titanium oxide, aluminium powder, brown iron oxide, ferrous oxide powder, calcium oxide, manganese oxide, potassium oxide, sodium oxide molybdena, sodium sulphate, chlorate, NaOH, phosphoric acid hydrochlorate and carbon.Wherein, the percentage by weight of each composition is as shown in table 1.The effect of each composition is respectively: silica has extremely strong suction, water holding capacity, is mainly used in to store electrolyte and moisture content; Titanium oxide can also keep the stability of resistance reducing agent except that possessing electric action; Aluminium oxide, sodium oxide molybdena, potassium oxide, magnesium oxide are active metal oxide,
Table 1
Composition Silica Titanium oxide Aluminium oxide Iron oxide Ferrous oxide
Content (%) 20~60 ?0.5~4 ?10~20 ?2~5 ?0.1~3
Composition Calcium oxide Magnesium oxide Potassium oxide Sodium oxide molybdena Sodium sulphate
Content (%) 1~6 ?3~10 ?0.1~3 ?0.5~5 ?3~10
Composition Sodium chloride NaOH Sodium phosphate Carbon
Content (%) 2~10 ?0.15~3 ?0.15~4 ?3~15
Good electric conductivity is arranged, stable performance under the high current density effect; Calcium oxide can guarantee that the moisture content in the resistance reducing agent is difficult for evaporation, thereby makes electrolyte be difficult for running off; Iron oxide and ferrous oxide can reduce the corrosion rate of ground connection band iron; Also available other sulfate of sodium sulphate substitutes, and sulfate has extremely strong penetration capacity in soil, to improving the soil electrical characteristics remarkable result is arranged; Sodium chloride (or magnesium chloride) electric conductivity is extremely strong, can greatly reduce the industrial frequency electric resistance rate; NaOH and the phosphatic pH value that has the scalable resistance reducing agent make it be slightly larger than 7 and the ground connection band iron had good corrosion-resisting function; Carbon in the resistance reducing agent is crossed through 2500 ℃ of high-temperature process, its existence except that resistance reducing agent is possessed the excellent conducting performance, also has high temperature resistant, low temperature resistant characteristic, particularly when lightning impulse and cold district when using, its high temperature resistant, low temperature resistant performance is more outstanding.
The preparation of resistance-reducing anti-corrosion agent: at first, take by weighing each composition, then each composition is pulverized, fully mix, mix well and get final product in the described ratio of table 1.
Resistance-reducing anti-corrosion agent has and do to apply and add two kinds of usings method of water.
Do the method for applying: resistance-reducing anti-corrosion agent dry powder shape proportion is 1~1.2 kilogram/cubic decimeter, and the dried proportion of resistance reducing agent and every meter consumption calculate horizontal laying and vertical run tunnel size, gets final product around the earth electrode that then dry powder is laid in.
Water feeding method: a bigger container is prepared in the job site, resistance reducing agent is poured into, and be equipped with 60% water, stirs in container and trembles evenly, around the earth electrode that then resistance reducing agent is laid in.
Resistance-reducing anti-corrosion agent of the present invention is compared with similar products at home and abroad, and the industrial frequency electric resistance rate has only 0.2 Europe. rice; The impulse resistance rate is 0.2 Europe. rice; And also have with current density and increase the advantageous feature that reduces, in power frequency and 5 repeatedly KA, 10 KA, 20 KA, 40 KAUnder the heavy impulse current effect, electrical resistivity property is stable; Its resistance-reducing yield can reach 50~85%, and touch voltage reduction rate is about 85%; Can play the anti-corrosion protection effect to the metal earth electrode, corrosion rate can be reduced to 0.05739 millimeter/year, and tasteless, nontoxic; Environmentally safe, cost is low, and is easy to use.
The prescription of example of the present invention can be as shown in table 2.Take by weighing each composition by prescription, pulverize, fully mix and get final product.Wherein carbon is through 2500 ℃ of high-temperature process.The resistance reducing agent for preparing, visual job site is convenient, selects for use and does the method for applying or water feeding method.
Table 2
Composition Silica Titanium oxide Aluminium oxide Iron oxide Ferrous oxide
Content (%) 40.5 3 10 2.5 0.2
Composition Calcium oxide Magnesium oxide Potassium oxide Sodium oxide molybdena Sodium sulphate
Content (%) 3 3 5 5 8
Composition Sodium chloride NaOH Sodium phosphate Carbon
Content (%) 2.6 1 1.2 15

Claims (1)

1. anti-corrosion agent for solid long-term-effective dropping resistance, it is characterized in that: contain silica, titanium oxide, aluminium oxide, iron oxide, ferrous oxide, calcium oxide, magnesium oxide, potassium oxide, sodium oxide molybdena in the resistance-reducing anti-corrosion agent, sodium sulphate, sodium chloride, NaOH, sodium phosphate and carbon; Its concrete weight percent content is:
Silica: 20~60%, titanium oxide: 0.5~4%, aluminium oxide: 10~20%
Iron oxide: 2~5%, ferrous oxide: 0.1~3%, calcium oxide: 1~6%
Magnesium oxide: 3~10%, potassium oxide: 0.1~3%, sodium oxide molybdena: 0.5~5%
Sodium sulphate: 3~10%, sodium chloride: 2~10%, NaOH: 0.15~3%
Sodium phosphate: 0.15~4%, carbon: 3~15%,
Wherein the carbon in this resistance-reducing anti-corrosion agent is through 2500 ℃ of high-temperature process.
CN 90107273 1990-08-24 1990-08-24 Anti-corrosion agent for solid long-term-effective dropping resistance Expired - Fee Related CN1033059C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 90107273 CN1033059C (en) 1990-08-24 1990-08-24 Anti-corrosion agent for solid long-term-effective dropping resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 90107273 CN1033059C (en) 1990-08-24 1990-08-24 Anti-corrosion agent for solid long-term-effective dropping resistance

Publications (2)

Publication Number Publication Date
CN1059162A CN1059162A (en) 1992-03-04
CN1033059C true CN1033059C (en) 1996-10-16

Family

ID=4880470

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 90107273 Expired - Fee Related CN1033059C (en) 1990-08-24 1990-08-24 Anti-corrosion agent for solid long-term-effective dropping resistance

Country Status (1)

Country Link
CN (1) CN1033059C (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062888C (en) * 1995-09-02 2001-03-07 龚循礼 Long service life, corrosion-proof, and electric resistance reducing agent for earthing
CN102354542B (en) * 2011-06-28 2013-04-24 成都桑莱特科技股份有限公司 Resistance-reducing agent with self-produced pressure
CN104356293B (en) * 2014-10-24 2016-11-30 广西电网公司电力科学研究院 A kind of grounding resistance-reducing agent prescription for mountain area rock and blasting construction method
CN107382124B (en) * 2017-09-15 2020-07-10 四川坤正新型材料有限公司 Autoclaved aerated concrete plate steel bar antirust agent and preparation method thereof
CN112447310B (en) * 2020-11-13 2022-06-14 广东电网有限责任公司 Resistance reducing agent and preparation method and application thereof

Also Published As

Publication number Publication date
CN1059162A (en) 1992-03-04

Similar Documents

Publication Publication Date Title
CN101752021B (en) Long-effective corrosion-prevention physical resistance-reducing agent
CN105907402A (en) Pole tower and transformer substation grounding calcium bentonite base resistance reducing agent
CN101882477B (en) Long-acting antiseptic resistance-reducing agent
CN104103334A (en) Novel high-efficiency anti-corrosive physical resistance reducing agent for galvanized steel grounding grid
CN105957577B (en) A kind of earthy calcium-base bentonite base friction reducer
CN106064907B (en) A kind of sulfonated polyaniline is modified Na-bentonite soil matrix friction reducer
CN1033059C (en) Anti-corrosion agent for solid long-term-effective dropping resistance
CN104403135B (en) A kind of liquid ground film and preparation method thereof
CN112447310B (en) Resistance reducing agent and preparation method and application thereof
CN104318973A (en) Novel bentonite resistance reducing agent modified by acrylic acid
CN100498978C (en) Modified grounding anti-corrosion resistance reduction agent
CN104449560A (en) Environment-friendly long-acting grounding device anticorrosive agent and preparation method of anticorrosive agent
CN101552385B (en) Graphite aluminum-magnesium alloy grounding material and preparing method thereof
CN1009683B (en) Inorganic-chemical solid reducer of ground resistance
CN102226089B (en) Soil improvement agent suitable for grounding works in high soil resistivity environments
CN104810631A (en) Ground connection resistance reduction composite padding for acid red soil
CN100552830C (en) A kind of ion resistance reducing agent
CN112680190B (en) Plant type composite high-efficiency corrosion inhibitor and preparation method and application thereof
CN103199349A (en) Grounding module
CN2845202Y (en) The prevention physical resistance-reducing agent earthing module
CN104966542A (en) Novel macromolecule resistance-reducing agent and preparation method thereof
CN1062888C (en) Long service life, corrosion-proof, and electric resistance reducing agent for earthing
CN105225769A (en) A kind of preparation method of basic soil ground network physics resistance reducing agent
CN101447242A (en) Grounding friction reducer
CN1050638A (en) Grounded resistance reducing agent

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee