CN103294015B - Complete set optimization control method for ethylene cracking furnace - Google Patents

Complete set optimization control method for ethylene cracking furnace Download PDF

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Publication number
CN103294015B
CN103294015B CN201210055595.1A CN201210055595A CN103294015B CN 103294015 B CN103294015 B CN 103294015B CN 201210055595 A CN201210055595 A CN 201210055595A CN 103294015 B CN103294015 B CN 103294015B
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cracking
furnace
cot
cracking furnace
pyrolysis
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CN103294015A (en
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陈爱军
王福善
曹巍
肖春景
任丽丽
雷荣孝
杨斌武
张建涛
顾治波
李湛
颉刚
何启伟
钟英
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Petrochina Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/14Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P90/00Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
    • Y02P90/02Total factory control, e.g. smart factories, flexible manufacturing systems [FMS] or integrated manufacturing systems [IMS]

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The invention discloses a complete set optimization control method for an ethylene cracking furnace, which comprises the steps of establishing a cracking depth model, implementing COT advanced control, optimizing key process parameters, realizing integrated application, establishing a hearth flame diagnosis system and establishing a cracking furnace energy management system. The method of the invention improves the yield of ethylene and propylene (namely diene) and reduces the energy consumption of the cracking furnace. The method realizes the optimized control of the process, reduces the serious interference of frequent manual operation on COT, and weakens the fluctuation range of operation when events such as fuel gas pressure, dryer switching and the like occur, thereby ensuring that the COT stability of the whole device is maintained at a higher level. And a cracking depth model of the cracking furnace device is established, and the operating conditions are optimized under different cracking working conditions, so that the diene yield is maintained at a higher level, and the energy-saving optimization of the cracking furnace is realized.

Description

The complete optimal control method of ethane cracking furnace
Technical field
The present invention relates to a kind of control method, particularly the complete optimal control method of a kind of ethane cracking furnace.
Background technology
Ethane cracking furnace is the nucleus equipment of ethylene unit, different cracking stocks corresponds to the different type of furnaces and has different optimised process operating conditionss, for cracking stock and the specific type of furnace of certain character, under the prerequisite meeting target running period and product yield, there is its optimum cracking temperature, inlet amount and dilution ratio, cracking severity model is needed to evaluate raw material, to determine best process condition.
From cracking stock to ethene, the output of propylene, main qualitative change process all completes in pyrolysis furnace.Stable, long period, the production at high load of pyrolysis furnace are the guarantees that ethylene unit normally runs.Fuel gas fluctuates the hot-restriking die, the change of component of raw material, the process fluctuations of associative cell that cause, all can affect the quiet run of pyrolysis furnace.Ethylene unit has the features such as disturbing factor is many, production schedule conversion is frequent.
Realizing in process of the present invention, inventor finds that prior art at least exists following problem: the energy consumption of existing ethane cracking furnace control method pyrolysis furnace is high, normal running and when putting forward the amount of falling the flow rate fluctuation of pyrolysis furnace combined feed larger.
Summary of the invention
The object of the embodiment of the present invention is the defect for above-mentioned prior art, provides a kind of and reduces energy consumption, the complete optimal control method of the ethane cracking furnace that diene yield is high.
The technical scheme that the present invention takes to achieve these goals is:
The complete optimal control method of a kind of ethane cracking furnace, is characterized in that, comprise the following steps:
(1) cracking severity model is set up
Gather the cracking residence time under pyrolysis furnace steady operating mode, pyrolysis gas outlet temperature, pyrolysis gas top hole pressure, gas oil ratio, pyrolysis gas number of components according to this and cracking stock character, the method establishment cracking severity model combined with data-driven modeling by Analysis on Mechanism;
(2) COT (Coil Outlet Temperature, pyrolysis furnace outlet temperature) Dynamic matrix control is implemented
The dynamic hydrocarbon charging control technology based on DCS (Distributed Control System (DCS))/host computer is adopted to implement COT Dynamic matrix control;
(3) optimize key process parameter, realize integra-tion application
After setting up Energy consumption of cracking furnace optimization computation model, each variable is inputted by Optimized model demand, the physical parameter of raw material or process operation parameter by experiment room data base set procedure parameter real-time data base of unifying obtain in real time, if do not have corresponding Database Systems manually to input, running optimizatin program, at pyrolysis furnace turnout, boiler tube different phase COT calculates best dilution ratio and COT parameter under allowing cracking maximum temperature and cracking stock constraint condition, result of calculation is after process management personnel confirm, assign to operator as technology controlling and process index, setting value manually inputs pyrolysis furnace Dynamic matrix control device by operator, realize inlet amount, COT, the Optimum Operation of dilution ratio,
(4) furnace flame diagnostic system is set up
Utilize Microsoft Excel (the superior trial balance of Microsoft) and Matlab (Matrix Laboratory, matrix labotstory) technology, adopt VBA (Visual Basic for Applications, program language) and COM (the Component Object Model) mode of programming realize Excel (Microsoft's spreadsheet software) expansion functionally, realize data acquisition, graphic software platform and flame diagnostic analysis;
(5) pyrolysis furnace energy management system is set up
Online energy management system is used to set up pyrolysis furnace energy management system.
The embodiment of the described dynamic hydrocarbon charging control technology based on DCS/ host computer is: formerly control host computer development behavior hydrocarbon charging control strategy, according to first detection examination and put into operation effect real time modifying parameter or steering logic, reduce the risk first controlling implementation process; At DCS development logic interface, accept the instruction performing host computer, the instruction of executable operations personnel, and the security judging various instruction, if be judged as maloperation, then will not perform and point out.
The beneficial effect that the technical scheme that the embodiment of the present invention provides is brought is:
Method of the present invention is adopted to improve ethene and propylene (i.e. diene) yield.The optimal control of implementation procedure, reduces the severe jamming of frequent manual operation to COT, weakens the fluctuating range of operation when the event such as fuel gas pressure, exsiccator switching occurs, thus ensures that the steady rate of the COT of whole device maintains higher level.Set up the cracking severity model of cracking furnace installation, optimization of operating condition is carried out to different cracking operating modes, make diene yield maintain higher level, achieve the energy saving optimizing of pyrolysis furnace.After using the Optimized-control Technique method of ethane cracking furnace, COT controls steadily, to significantly increase the yield of high-value product.
Accompanying drawing explanation
Fig. 1 is the operation schematic diagram of the complete optimal control method of ethane cracking furnace of the present invention.
Embodiment
For making the object, technical solutions and advantages of the present invention clearly, below in conjunction with accompanying drawing, embodiment of the present invention is described further in detail.
See Fig. 1, according to explained hereafter present situation and demand, the data of laboratory information management system and DCS control system collected by cracking severity model, laboratory Data in Information Management System is analyzed from laboratory, the data of DCS control system are from field instrument, calculate pyrolysis furnace key operation index COT and gas oil ratio, its result and pyrolysis furnace coke cleaning, the data such as energy consumption input optimization computation model in the lump, be that optimization aim calculates best COT and gas oil ratio Con trolling index with energy consumption minimized, the data calculated are after process management personnel examination & verification, assign to pyrolysis furnace advanced control system, ' edge ' that realized these key operation indexs by pyrolysis furnace advanced control system operates.Simultaneously, real-time data base collection also preserves the related data of DCS control system, data required for furnace flame diagnostic system and Energy consumption of cracking furnace management system read from real-time data base, calculate and illustrate burning and the status of energy consumption of pyrolysis furnace furnace flame, instruct the proportioning of process technology management personnel adjustment burner hearth fuel gas and air, the unit abnormal to power consumption processes or overhauls, and reduces the energy consumption of pyrolysis furnace from technological operation aspect.
Method of the present invention is applied at Lanzhou Petrochemical 460,000 tons/year of ethylene units, and the pyrolysis furnace of this device adopts the SC-1 type tube cracking furnace of KBR and ExxonMobil joint development.The technological process of pyrolysis furnace can be divided into several parts such as raw material preheating, convection section, radiation section, Pintsch process cold-peace heat recovery out of breath.
Pyrolysis furnace has five kinds of different raw materials: LPG, propane, two kinds of different naphtha feed, hydrogenation tail oil, cycle ethane/propane.Control for Pyrolysis Furnace Area comprises 5 SCORE SC-1 type pyrolysis furnaces, and the ethene designed capacity of every platform pyrolysis furnace is 16.25 tons/hour, enter the process fluid of pyrolysis furnace parallel be divided into 8 groups, and 5 different groups of pyrolysis furnace can cracking two kinds of raw materials.Each group of pyrolysis furnace can coke cleaning online when other group carries out cracking operation.The project organization of three (101B, 102B, 103B) is had to be applicable to cracking mixing naphtha and/or hydrogenation tail oil in five SC-1 pyrolysis furnaces.In these pyrolysis furnaces, the feeding line of every platform pyrolysis furnace is divided into Liang Geban district (each halfth district has four groups), and each halfth district can cracking naphtha or hydrogenation tail oil.Other two pyrolysis furnaces (104B, 105B) are used for cracking mixing naphtha, LPG and (or) ethane/propane.
The ethane cracking furnace complete optimal control method specific implementation process of the embodiment of the present invention is as follows:
1, cracking severity model is set up
For specific ethane cracking furnace, by the cracking residence time under a harvester period steady operating mode, pyrolysis gas outlet temperature, pyrolysis gas top hole pressure, gas oil ratio, pyrolysis gas number of components according to this and cracking stock character, with the method establishment pyrolysis furnace model of data-driven modeling.
According to mixed material character, pyrolysis furnace design and pyrolysis furnace service data, calculate one group of pyrolysis furnace service data and 56 kinds of (virtual) component pyrolysis furnace yields, laboratory is analyzed to the physical data that can not provide, need to set up this physical parameter regression model by the knowledge of chemical process and system modelling.Simultaneously with these data and cracking furnace pipe coking rate measured value, set up the coking rate model of gas phase and liquid-phase pyrolysis stove, being converted by coking rate by commutation factor is pyrolysis furnace coke cleaning period energy consumption.
Then use pilot scale data or field data calibration model, make the result of model prediction consistent with plant running data, meet the demand of pyrolysis furnace analog computation.Application-aware analytical approach sets up dilution ratio, correlation model between COT and yield of ethene.
2, COT Dynamic matrix control is implemented
Adopt the dynamic hydrocarbon charging control technology based on DCS/ host computer, its embodiment is: formerly control host computer development behavior hydrocarbon charging control strategy, according to first detection examination and put into operation effect real time modifying parameter or steering logic, reduce the risk first controlling implementation process; At DCS development logic interface, accept the instruction performing host computer, the instruction of executable operations personnel, and the security judging various instruction, if be judged as maloperation, then will not perform and point out.
The algorithm of host computer Dynamic matrix control is primarily of compositions such as COT deviation branch balance control technology, combined feed control technologys between average COT control technology, each bypass duct.This system combines with pyrolysis furnace depth model and tentatively forms ethane cracking furnace COT Optimized-control Technique, has defined necessarily integra-tion application.
3, optimize key process parameter, realize integra-tion application
With cracking severity model, Energy consumption of cracking furnace computation model, pyrolysis furnace coke cleaning period model for constraint, optimization aim is minimised as with Energy consumption of cracking furnace, after setting up Energy consumption of cracking furnace optimization computation model, each variable is inputted by Optimized model demand, the physical parameter of raw material or process operation parameter can room Database Systems (as LIMS) and procedure parameter real-time data base (as Honeywell PHD) obtain, if do not have corresponding Database Systems manually to input by experiment in real time.Running optimizatin program, best dilution ratio and COT parameter is calculated under allowing cracking maximum temperature and cracking stock constraint condition at pyrolysis furnace turnout, boiler tube different phase COT, result of calculation is after process management personnel confirm, assign to operator as technology controlling and process index, setting value manually inputs pyrolysis furnace Dynamic matrix control device by operator, realizes ' edge ' operation of inlet amount, COT, dilution ratio;
4, pyrolysis furnace furnace flame diagnostic system is set up
Utilize Microsoft Excel and Matlab technology, adopt the mode of VBA and COM programming to realize Excel expansion functionally, realize data acquisition, graphic software platform and flame diagnostic analysis;
In data acquisition function module, the main com interface technology adopting Excel.Utilize the data transmission interface that real-time data base provides, according to parameters set and the instruction of user of service, input the time period of data to be analyzed, sample frequency and PHD database item, click and obtain, read the historical data (each cracking furnace pipe COT temperature) of corresponding technique item, and being kept in Excel list, these data not only can be used for furnace flame temperature diagnostic, can also be used for the daily form of technologist, statistics or industrial analysis.
In graphic software platform and analytic function module, main employing Matlab and Excel Mixed-Programming Technology.Under Matlab programmed environment, realize the functions such as interactive interface, data transmission, data analysis, data 2D/3D display, data dependence one by one, compiling of application is Com file by application Matlab compiler; Under Excel programmed environment, quote the Com class that Matlab generates, patterned data message then will be needed to be transmitted by standardized class function, finally realize diagnostic software.
The stability of pyrolysis furnace furnace flame is very large on the impact of COT, and flame instability can cause the cracking furnace pipe temperature temperature runaway of local, greatly have impact on the energy consumption (showing as coke cleaning period to shorten) of pyrolysis furnace.Exploitation fire box temperature diagnostic system, the impact that graphic software platform nozzles air door fluctuates on COT, the correlativity between each data of theory calculate, instructs technologists how to adjust nozzles air door, solves pyrolysis furnace COT quiet run problem, realizes energy-saving and cost-reducing.
5, Energy consumption of cracking furnace management system is set up
Use online energy management system (EMS), to reach long-term energy-conservation object.The main technological route of EMS system is: 1) determine that the key parameter of energy unit input end and output terminal respectively used by pyrolysis furnace; 2) pyrolysis furnace battery limit (BL) key energy driving factors are determined; 3) energy object of pyrolysis furnace battery limit (BL) is set; 4) Key Performance Indicator is defined; 5) data acquisition, fail-safe analysis, data filtering, compensation data, Energy Conversion is carried out; 6) the operational objective value of pyrolysis furnace battery limit (BL) key energy driving factors is determined; 7) weigh energy consumption efficiency, quantize energy management index.Pyrolysis furnace EMS management system can adopt C/S and B/S framework, for different user provides consumption information, server end realizes automatic data collection, energy consumption calculation and result and stores, and administration and supervision authorities user can check ethylene unit service data and energy consumption data by client or browser.
Energy consumption monitoring and evaluation system are established to 5 pyrolysis furnaces of ethylene unit, quenching oil column, quenching water column and relevant heat interchanger, the energy consumption of detail display and tracking equipment and data, the technology platform of combined mathematical module and energy-optimised instrument, carry out operation to improve and technological transformation, finally achieve the target reducing comprehensive energy consumption.
After adopting technology of the present invention, according to ethylene unit state of art and Production requirement, pyrolysis furnace key operation index can be optimized, utilizes furnace flame diagnostic techniques to instruct the technological operation of pyrolysis furnace, realize pyrolysis furnace even running, improve diene yield.And energy-optimised management system, then monitor the energy consumption of pyrolysis furnace, instruct process operator to carry out improving and transforming, finally realize the target that cracker comprehensive energy consumption reduces.
One of ordinary skill in the art will appreciate that all or part of step realizing above-described embodiment can have been come by hardware, the hardware that also can carry out instruction relevant by program completes, described program can be stored in a kind of computer-readable recording medium, the above-mentioned storage medium mentioned can be ROM (read-only memory), disk or CD etc.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (2)

1. the complete optimal control method of ethane cracking furnace, is characterized in that, comprise the following steps:
(1) cracking severity model is set up
Gather the cracking residence time under pyrolysis furnace steady operating mode, pyrolysis gas outlet temperature, pyrolysis gas top hole pressure, gas oil ratio, pyrolysis gas number of components according to this and cracking stock character, the method establishment cracking severity model combined with data-driven modeling by Analysis on Mechanism;
(2) COT Dynamic matrix control is implemented
The dynamic hydrocarbon charging control technology based on DCS/ host computer is adopted to implement COT Dynamic matrix control;
(3) optimize key process parameter, realize integra-tion application
With cracking severity model, Energy consumption of cracking furnace computation model, pyrolysis furnace coke cleaning period model for constraint, be minimised as optimization aim with Energy consumption of cracking furnace, set up Energy consumption of cracking furnace and optimize computation model, after setting up Energy consumption of cracking furnace optimization computation model, optimize computation model demand by Energy consumption of cracking furnace and input each variable, the physical parameter of raw material or process operation parameter by experiment room data base set procedure parameter real-time data base of unifying obtain in real time, if do not have corresponding Database Systems manually to input, running optimizatin program, at pyrolysis furnace turnout, boiler tube different phase COT calculates best dilution ratio and COT parameter under allowing cracking maximum temperature and cracking stock constraint condition, result of calculation is after process management personnel confirm, assign to operator as technology controlling and process index, setting value manually inputs pyrolysis furnace Dynamic matrix control device by operator, realize inlet amount, COT, the Optimum Operation of dilution ratio,
(4) furnace flame diagnostic system is set up
Utilize Microsoft Excel and Matlab technology, adopt the mode of VBA and COM programming to realize Excel expansion functionally, realize data acquisition, graphic software platform and flame diagnostic analysis;
(5) pyrolysis furnace energy management system is set up
Online energy management system is used to set up pyrolysis furnace energy management system.
2. the complete optimal control method of ethane cracking furnace according to claim 1, it is characterized in that, the embodiment of the described dynamic hydrocarbon charging control technology based on DCS/ host computer is: formerly control host computer development behavior hydrocarbon charging control strategy, according to first detection examination and put into operation effect real time modifying parameter or steering logic, reduce the risk first controlling implementation process; At DCS development logic interface, accept the instruction performing host computer, the instruction of executable operations personnel, and the security judging various instruction, if be judged as maloperation, then will not perform and point out.
CN201210055595.1A 2012-03-05 2012-03-05 Complete set optimization control method for ethylene cracking furnace Active CN103294015B (en)

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CN103713604B (en) * 2013-12-26 2016-01-13 东北大学 A kind of industrial pyrolysis furnace real time operation optimizing based on data-driven and control method
KR102396612B1 (en) * 2016-06-30 2022-05-12 엑손모빌 케미칼 패턴츠 인코포레이티드 Method and system for operation of high pressure ethylene polymerization unit
CN107450314B (en) * 2017-07-28 2024-02-20 中国寰球工程有限公司 System and method for controlling full-operation period cracking depth of ethylene cracking furnace
CN107958137B (en) * 2017-11-27 2021-10-26 中国石油化工股份有限公司 Matlab and Excel-based catalytic cracking yield prediction method
TWI831864B (en) * 2018-12-27 2024-02-11 美商Bl科技公司 System and method for dynamic monitoring and control of a process gas compressor
TR201902986A2 (en) * 2019-02-27 2020-09-21 Petkim Petrokimya Holding Anonim Sirketi Production optimization method for ethylene furnaces.
CN118311864B (en) * 2024-06-11 2024-08-16 成都格莱精密仪器有限公司 Cracking control method and device, electronic equipment and storage medium

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