CN103293274A - Coke oven gas impurity content detection pipeline system - Google Patents

Coke oven gas impurity content detection pipeline system Download PDF

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Publication number
CN103293274A
CN103293274A CN2013102186119A CN201310218611A CN103293274A CN 103293274 A CN103293274 A CN 103293274A CN 2013102186119 A CN2013102186119 A CN 2013102186119A CN 201310218611 A CN201310218611 A CN 201310218611A CN 103293274 A CN103293274 A CN 103293274A
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China
Prior art keywords
oven gas
coke oven
detection device
pipeline
impurity content
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Pending
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CN2013102186119A
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Chinese (zh)
Inventor
李一鸣
李欢
何锋
吴海波
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Guizhou University
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Guizhou University
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Priority to CN2013102186119A priority Critical patent/CN103293274A/en
Publication of CN103293274A publication Critical patent/CN103293274A/en
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Abstract

The invention discloses a coke oven gas impurity content detection pipeline system. The coke oven gas impurity content detection pipeline system comprises a main pipeline (1), a moisture detection device and a hydrogen sulfide detection device, wherein the main pipeline (1) is provided with a cushion gas bottle (18), a detecting branch line (2) is output from the main pipeline (1), and the detecting branch line (2) is connected in series with the moisture detection device and the hydrogen sulfide detection device and is connected with the cushion gas bottle (18); and a reentry purification pipeline (3) is output from the cushion gas bottle (18), each pipeline is provided with a block valve, and the block valves, the moisture detection devices and the hydrogen sulfide detection device are respectively connected with an electronic control unit (14). The coke oven gas impurity content detection pipeline system provided by the invention can convey coke oven gas, the content of sulfuretted hydrogen after purifying coke oven gas and water vapour is synchronously detected in on-line manner, the quality of an air source of coke oven gas for vehicles is largely improved, the corrosion of hydrogen sulfide and water vapor to an engine and an air supplying pipeline is reduced, the environment pollution caused by sulfur-containing tail gas discharge is reduced, and the service life of the engine is prolonged.

Description

A kind of oven gas impurity content detector tube wire system
Technical field
The present invention relates to a kind of oven gas delivery line that can detect moisture and hydrogen sulfide content in the mixed gas.
Background technology
Oven gas is a kind of secondary product of coking industry, and 1 ton of coke of common every production can produce 430Nm 3About oven gas.China's coke output was 4.28 hundred million tons in 2011, surpassed 220 billion cubic meters with the direct oven gas that enters atmosphere that burns of the mode of " point day lamp ", had caused the significant wastage of environmental pollution and resource.Principal ingredient according to oven gas is hydrogen and methane, and according to its physicochemical property, oven gas can be used as vehicle fuel and uses, but oven gas impurity component complexity must be carried out purified treatment to it as vehicle fuel, reaches hydrogen sulfide content less than 15mgm -3, water dew point satisfies automobile-used less than-13 ℃ of ability.Owing to reasons such as the too fast and cleanser partial failures of gas flow rate, the oven gas after the purification does not often reach standard, need detect the oven gas after purifying and recycling again.
Summary of the invention
The technical problem to be solved in the present invention: at the frequent problem not up to standard of the oven gas after existing the purification, provide a kind of oven gas induction system that can detect moisture and hydrogen sulfide content in the mixed gas.
Technical solution of the present invention:
A kind of oven gas impurity content detector tube wire system, comprise Trunk Line, moisture content detection device and sulfuretted hydrogen pick-up unit, the buffering gas cylinder is installed on the Trunk Line, draw the detection branch line from Trunk Line, detect and contact moisture content detection device and sulfuretted hydrogen pick-up unit on the branch line and be connected into the buffering gas cylinder, draw on the buffering gas cylinder and return to purge lines, every pipeline is equipped with block valve, and block valve, moisture content detection device and sulfuretted hydrogen pick-up unit are connected electronic control unit respectively.
Moisture content detection device is by pressure transducer, molecular sieve dehydration device and dehydrate and jar forms, and the molecular sieve dehydration device is installed in and dehydrates in the jar, and pressure transducer is positioned at molecular sieve dehydration device below, pressure transducer connection electronic control unit.
Sulfuretted hydrogen pick-up unit and electromagnetism relay valve are connected in parallel on and detect on the branch line.
The sulfuretted hydrogen pick-up unit comprises baroceptor, pressure regulation device, sulfuretted hydrogen detection probe and sulfuretted hydrogen detection probe seat.
Beneficial effect of the present invention:
This oven gas delivery line system can be when carrying oven gas synchronous online inspection vehicle purify the content of after cure hydrogen and water vapor with oven gas, and be restored to underproof oven gas in the purification plant again, improve the source of the gas quality of automobile-used oven gas to a great extent, reduce sulfuretted hydrogen and water vapor to the corrosion of engine and supply air line, reduce the sulfur-bearing exhaust emissions to the pollution of environment, improve the serviceable life of engine.
Description of drawings:
Fig. 1 is structural representation of the present invention.
Embodiment:
As figure, buffering gas cylinder 18 is installed on the Trunk Line 1, draw detection branch line 2 from Trunk Line 1, detect and contact moisture content detection device and sulfuretted hydrogen pick-up unit on the branch line 2 and be connected into buffering gas cylinder 18, draw on the buffering gas cylinder 18 and return to purge lines 3, be equipped with block valve on every pipeline, all block valves, moisture content detection device and sulfuretted hydrogen pick-up unit are connected electronic control unit 14 respectively.Moisture content detection device is by pressure transducer 6, molecular sieve dehydration device 7 and dehydrate jars 8 and form, molecular sieve dehydration device 7 is installed in and dehydrates in the jar 8, pressure transducer 6 is positioned at molecular sieve dehydration device 7 belows, and pressure transducer 6 connects electronic control unit 14.Sulfuretted hydrogen pick-up unit and electromagnetism relay valve 13 are connected in parallel on and detect on the branch line 2, and the sulfuretted hydrogen pick-up unit comprises baroceptor 9, pressure regulation device 10, sulfuretted hydrogen detection probe 11 and sulfuretted hydrogen detection probe seat 12.
During work, block valve 5,16 is opened, the oven gas after the purification enters buffering gas cylinder 18 along Trunk Line 1, and a part of oven gas detects synchronously along detecting branch line 2 simultaneously.Oven gas at first enters in detecting branch line 2 and dehydrates jar 8, dehydrates in the jar 8 molecular sieve dehydration device 7 is housed, and there is the agent of 3A molecular sieve dehydration the inside, and pressure transducer 6 is arranged below, is 3*10 because the 3A molecular sieve can only adsorb diameter less than 3.2-3.3A -10The molecule of m is as H 2O, NH 3Deng, for CH 4, C 2H 6, H 2S etc. are big, and molecule is then got rid of, the quality of molecular sieve dehydration device 7 and the proportional relation of quality that absorbs water vapor, if moisture is less in the oven gas after purifying, then the slope of pressure transducer 6 pressures and time relationship line chart will reduce, if moisture is higher in the oven gas, then pressure transducer 6 pressures and time relationship line chart slope will increase, when slope increases to a certain setting value, illustrate that then moisture exceeds standard in the oven gas, close block valve 19 by electronic control unit 14, open block valve 17, oven gas is come back in the purification dehydration plant handle, when moisture reaches standard, open block valve 19 by electronic control unit 14 again, close block valve 17, oven gas up to standard enters the oven gas gas storage well along oven gas trunk line 4.
Hydrogen sulfide content detects: after oven gas gas comes out from dehydrate jar 8, be divided into two parts, a part is by entering cushion gas bottle 18 after the electromagnetism relay valve 13, a part is through baroceptor 9, pressure adjustment assembly 10, enter the sulfuretted hydrogen detection probe 11 that is fixed on the sulfuretted hydrogen detection probe seat 12, the hydrogen sulfide content in the oven gas is detected.Because present employed hydrogen sulfide gas detection probe can only be born the pressure of 0.12MPa, be used under normal pressure, detecting concentration of hydrogen sulfide, therefore must carry out pressure regulation before pipeline gas is used the sulfuretted hydrogen detection probe handles, detect in order to be implemented in line locking, when detecting sulfuretted hydrogen, the part oven gas enters buffering gas cylinder 18 by electromagnetism relay valve 13.Send signal by baroceptor 9 to electronic control unit 14,14 pairs of pressure adjustment assemblys 10 of electronic control unit and electromagnetism relay valve 13 are sent signal after treatment, the gaseous tension that enters the sulfuretted hydrogen detection probe is remained under the constant pressure of 0.12MPa, and all the other oven gas enter in the buffering gas cylinder 18 by electromagnetism relay valve 13 pipelines.If hydrogen sulfide content exceeds standard in the oven gas, close block valve 19 by electronic control unit 14, open block valve 17, oven gas is come back in the purification dehydration plant to be handled, when hydrogen sulfide content reaches standard, open block valve 19 by electronic control unit 14 again, close block valve 17, oven gas up to standard enters the oven gas gas storage well along oven gas trunk line 4.

Claims (4)

1. oven gas impurity content detector tube wire system, comprise Trunk Line (1), moisture content detection device and sulfuretted hydrogen pick-up unit, it is characterized in that: Trunk Line (1) is gone up buffering gas cylinder (18) is installed, draw detection branch line (2) from Trunk Line (1), detecting branch line (2) goes up polyphone moisture content detection device and sulfuretted hydrogen pick-up unit and is connected into buffering gas cylinder (18), draw on the buffering gas cylinder (18) and return to purge lines (3), every pipeline is equipped with block valve, block valve, moisture content detection device is connected electronic control unit (14) respectively with the sulfuretted hydrogen pick-up unit.
2. oven gas impurity content detector tube wire system according to claim 1, it is characterized in that: moisture content detection device is by pressure transducer (7), molecular sieve dehydration device (8) and dehydrate jar (6) and form, molecular sieve dehydration device (8) is installed in and dehydrates in jar (6), pressure transducer (7) is positioned at molecular sieve dehydration device (8) below, and pressure transducer (7) connects electronic control unit (14).
3. oven gas impurity content detector tube wire system according to claim 1 is characterized in that: sulfuretted hydrogen pick-up unit and electromagnetism relay valve (13) are connected in parallel on and detect on the branch line (2).
4. oven gas impurity content detector tube wire system according to claim 1, it is characterized in that: the sulfuretted hydrogen pick-up unit comprises baroceptor (9), pressure regulation device (10), sulfuretted hydrogen detection probe (11) and sulfuretted hydrogen detection probe seat (12).
CN2013102186119A 2013-06-04 2013-06-04 Coke oven gas impurity content detection pipeline system Pending CN103293274A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2013102186119A CN103293274A (en) 2013-06-04 2013-06-04 Coke oven gas impurity content detection pipeline system

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Application Number Priority Date Filing Date Title
CN2013102186119A CN103293274A (en) 2013-06-04 2013-06-04 Coke oven gas impurity content detection pipeline system

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112649461A (en) * 2020-09-16 2021-04-13 山西晋神沙坪煤业有限公司 Device and method for measuring volatilization amount of hydrogen sulfide in pulverized coal
CN113686719A (en) * 2021-09-08 2021-11-23 淮北矿业股份有限公司涡北选煤厂 Coal moisture detection and drying cooling workstation

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4435644A (en) * 1980-07-15 1984-03-06 Tokyo Shibaura Denki Kabushiki Kaisha Radioactive effluent gas monitoring apparatus
US20060059901A1 (en) * 2004-09-21 2006-03-23 Denso Corporation Exhaust gas purifying device for internal combustion engine
CN101564601A (en) * 2008-04-23 2009-10-28 许培圣 Method for absorbing tail gas from chemical production and device for preparing polyester resin by using same
CN201732085U (en) * 2010-05-11 2011-02-02 任源峰 Detection device for hydrogen sulfide in natural gas pipeline
CN101980016A (en) * 2010-10-29 2011-02-23 云南大红山管道有限公司 Device for online detecting quality of oil
CN201867326U (en) * 2010-11-17 2011-06-15 郑州光力科技股份有限公司 Sulfur hexafluoride (SF6) gas sampling detection device
CN203299074U (en) * 2013-06-04 2013-11-20 贵州大学 Gas impurity detection device

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4435644A (en) * 1980-07-15 1984-03-06 Tokyo Shibaura Denki Kabushiki Kaisha Radioactive effluent gas monitoring apparatus
US20060059901A1 (en) * 2004-09-21 2006-03-23 Denso Corporation Exhaust gas purifying device for internal combustion engine
CN101564601A (en) * 2008-04-23 2009-10-28 许培圣 Method for absorbing tail gas from chemical production and device for preparing polyester resin by using same
CN201732085U (en) * 2010-05-11 2011-02-02 任源峰 Detection device for hydrogen sulfide in natural gas pipeline
CN101980016A (en) * 2010-10-29 2011-02-23 云南大红山管道有限公司 Device for online detecting quality of oil
CN201867326U (en) * 2010-11-17 2011-06-15 郑州光力科技股份有限公司 Sulfur hexafluoride (SF6) gas sampling detection device
CN203299074U (en) * 2013-06-04 2013-11-20 贵州大学 Gas impurity detection device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112649461A (en) * 2020-09-16 2021-04-13 山西晋神沙坪煤业有限公司 Device and method for measuring volatilization amount of hydrogen sulfide in pulverized coal
CN113686719A (en) * 2021-09-08 2021-11-23 淮北矿业股份有限公司涡北选煤厂 Coal moisture detection and drying cooling workstation

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Application publication date: 20130911