CN103290710B - A kind of automatically cleaning rope and preparation method thereof - Google Patents
A kind of automatically cleaning rope and preparation method thereof Download PDFInfo
- Publication number
- CN103290710B CN103290710B CN201310212439.6A CN201310212439A CN103290710B CN 103290710 B CN103290710 B CN 103290710B CN 201310212439 A CN201310212439 A CN 201310212439A CN 103290710 B CN103290710 B CN 103290710B
- Authority
- CN
- China
- Prior art keywords
- rope
- titanium dioxide
- automatically cleaning
- matrix
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 40
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 28
- 239000011159 matrix material Substances 0.000 claims abstract description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 18
- 239000010936 titanium Substances 0.000 claims abstract description 18
- 239000000017 hydrogel Substances 0.000 claims abstract description 16
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 229960000583 acetic acid Drugs 0.000 claims description 14
- 239000008367 deionised water Substances 0.000 claims description 14
- 229910021641 deionized water Inorganic materials 0.000 claims description 14
- 239000012362 glacial acetic acid Substances 0.000 claims description 14
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 7
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 5
- 238000005286 illumination Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000001699 photocatalysis Effects 0.000 abstract description 2
- 238000007146 photocatalysis Methods 0.000 abstract description 2
- 239000004065 semiconductor Substances 0.000 abstract description 2
- 238000003980 solgel method Methods 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 239000003292 glue Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- DSCFFEYYQKSRSV-FEPQRWDDSA-N (1s,2s,4s,5r)-6-methoxycyclohexane-1,2,3,4,5-pentol Chemical compound COC1[C@@H](O)[C@@H](O)C(O)[C@H](O)[C@H]1O DSCFFEYYQKSRSV-FEPQRWDDSA-N 0.000 description 2
- 241000790917 Dioxys <bee> Species 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000007792 addition Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/16—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics
- D07B1/162—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics characterised by a plastic or rubber enveloping sheathing
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2083—Jackets or coverings
- D07B2201/2092—Jackets or coverings characterised by the materials used
Landscapes
- Catalysts (AREA)
- Silicon Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of automatically cleaning rope and preparation method thereof, is related to field of rope, including rope matrix 1 and automatic cleaning coating 2, and the automatic cleaning coating 2 is coated on the outside of the rope matrix 1.Automatically cleaning rope provided by the invention and preparation method thereof, it make use of titanium dioxide that there is photocatalysis performance as a N-type semiconductor, the characteristic of greasy filth can be decomposed well under illumination condition, top finish and processing will be carried out to rope matrix using titanium dioxide-silica hydrogel made from sol-gel processing, obtained rope automatically cleaning effect is good, avoid often damage of the washing to rope, extend the service life of rope, manufacture craft is simple, it is easy to operate, cost is cheap, suitable large-scale promotion application.
Description
Technical field
The present invention relates to field of rope, specifically a kind of automatically cleaning rope and preparation method thereof.
Background technology
At present, rope is in the extensive use of the entertainment fields such as household, open air, physical culture, leisure, its assembly and disassembly simplicity, carrying side
Just the characteristics of is it in numerous areas extensive use.Rope is easy to be stained with spot in use, though black rope
It can also so use, but appearance is no longer attractive in appearance, influences using effect.If rope is removed into cleaning, take time and effort, also make again
Into the loss of rope.
The content of the invention
To solve above-mentioned technical problem, the invention provides a kind of automatically cleaning rope and preparation method thereof, rope
Automatic cleaning coating outside matrix can decompose greasy filth, realize the self cleaning of rope, effect is good, and technique is simple, cost
It is low, rope service life length.
To reach above-mentioned purpose, the technical solution adopted by the present invention is as follows：
A kind of automatically cleaning rope, including rope matrix and automatic cleaning coating, the automatic cleaning coating are coated on the rope
The outside of matrix.
The rope matrix is chemical fibre class, the torsade of natural fiber class and Plastic and sennit.
A kind of preparation method of automatically cleaning rope, is achieved by the steps of：
1）It is 1 by volume ratio:6:6-1:12:6 positive four butyl ester of metatitanic acid, glacial acetic acid and deionized water mixing, prepares dioxy
Change the titanium hydrosol；
2）It is 1 by volume ratio:5:10-1:5:15 tetraethyl orthosilicate, glacial acetic acid and deionized water mixed preparing titanium dioxide
The silicon hydrosol；
3）By step 1）With 2）In obtained titania hydrosol and silica hydrosol according to titanium silicon mol ratio 30:
1-60:1 is configured to titanium dioxide-silica hydrogel；
4）Top finish is carried out to rope matrix with obtained titanium dioxide-silica hydrogel, then through 70-100
DEG C hot water treatment 5-30min, last drying.
Automatically cleaning rope provided by the invention and preparation method thereof, titanium dioxide make use of to have as a N-type semiconductor
There is photocatalysis performance, the characteristic of greasy filth can be decomposed well under illumination condition, will utilize made from sol-gel processing
Titanium dioxide-silica hydrogel carries out top finish and processing to rope matrix, and obtained rope automatically cleaning effect is good,
Often damage of the washing to rope is avoided, extends the service life of rope, manufacture craft is simple, easy to operate, into
This cheap, suitable large-scale promotion application.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention.
In figure：1 is rope matrix；2 be automatic cleaning coating.
Embodiment
The present invention will be described in detail with specific embodiment below in conjunction with the accompanying drawings：
Include rope matrix 1 and automatic cleaning coating 2 as shown in Figure 1 for the specific embodiment of the present invention, the automatically cleaning rope,
The automatic cleaning coating 2 is coated on the outside of the rope matrix 1.
The rope matrix 1 is chemical fibre class, the torsade of natural fiber class and Plastic and sennit.
A kind of preparation method of automatically cleaning rope, is achieved by the steps of：
1）It is 1 by volume ratio:6:6-1:12:6 positive four butyl ester of metatitanic acid, glacial acetic acid and deionized water mixing, prepares dioxy
Change the titanium hydrosol；
2）It is 1 by volume ratio:5:10-1:5:15 tetraethyl orthosilicate, glacial acetic acid and deionized water mixed preparing titanium dioxide
The silicon hydrosol；
3）By step 1）With 2）In obtained titania hydrosol and silica hydrosol according to titanium silicon mol ratio 30:
1-60:1 is configured to titanium dioxide-silica hydrogel；
4）Top finish is carried out to rope matrix with obtained titanium dioxide-silica hydrogel, then through 70-100
DEG C hot water treatment 5-30min, last drying.
Illustrate the preparation method of automatically cleaning rope of the present invention below by several specific embodiments：
Embodiment 1：
1）It is 1 by volume ratio:6:6 positive four butyl ester of metatitanic acid, glacial acetic acid and deionized water mixes, and preparing titanium dioxide is water-soluble
Glue；
2）It is 1 by volume ratio:5:10 tetraethyl orthosilicate, glacial acetic acid and deionized water mixed preparing silica are water-soluble
Glue；
3）By step 1）With 2）In obtained titania hydrosol and silica hydrosol according to titanium silicon mol ratio 30:
1 is configured to titanium dioxide-silica hydrogel；
4）Top finish is carried out to rope matrix with obtained titanium dioxide-silica hydrogel, then through 70 DEG C
Hot water treatment 30min, last drying.
Embodiment 2：
1）It is 1 by volume ratio:12:6 positive four butyl ester of metatitanic acid, glacial acetic acid and deionized water mixing, preparing titanium dioxide water
Colloidal sol；
2）It is 1 by volume ratio:5:15 tetraethyl orthosilicate, glacial acetic acid and deionized water mixed preparing silica are water-soluble
Glue；
3）By step 1）With 2）In obtained titania hydrosol and silica hydrosol according to titanium silicon mol ratio 60:
1 is configured to titanium dioxide-silica hydrogel；
4）Top finish is carried out to rope matrix with obtained titanium dioxide-silica hydrogel, then through 100 DEG C
Hot water treatment 5min, last drying.
Embodiment 3：
1）It is 1 by volume ratio:10:6 positive four butyl ester of metatitanic acid, glacial acetic acid and deionized water mixing, preparing titanium dioxide water
Colloidal sol；
2）It is 1 by volume ratio:5:12 tetraethyl orthosilicate, glacial acetic acid and deionized water mixed preparing silica are water-soluble
Glue；
3）By step 1）With 2）In obtained titania hydrosol and silica hydrosol according to titanium silicon mol ratio 40:
1 is configured to titanium dioxide-silica hydrogel；
4）Top finish is carried out to rope matrix with obtained titanium dioxide-silica hydrogel, then through 85 DEG C
Hot water treatment 20min, last drying.
Embodiment 4
1）It is 1 by volume ratio:8:6 positive four butyl ester of metatitanic acid, glacial acetic acid and deionized water mixes, and preparing titanium dioxide is water-soluble
Glue；
2）It is 1 by volume ratio:5:14 tetraethyl orthosilicate, glacial acetic acid and deionized water mixed preparing silica are water-soluble
Glue；
3）By step 1）With 2）In obtained titania hydrosol and silica hydrosol according to titanium silicon mol ratio 50:
1 is configured to titanium dioxide-silica hydrogel；
4）Top finish is carried out to rope matrix with obtained titanium dioxide-silica hydrogel, then through 80 DEG C
Hot water treatment 10min, last drying.
The automatically cleaning rope that method for sorting obtains according to the method described above is still clean such as new, 48 Zhou Houbiao after using 24 weeks
Face shows light soil vestige.
The automatically cleaning rope solves the problems, such as that rope becomes easily infected by spot in use, using titanium dioxide in light
The characteristic of greasy filth is decomposed according under the conditions of, automatically cleaning effect is good, and the simple cost of technique is low.
Certainly, described above is not limitation of the present invention, and the present invention is also not limited to the example above, this technology neck
The variations, modifications, additions or substitutions that the technical staff in domain is made in the essential scope of the present invention, it should also belong to the present invention's
Protection domain.
Claims (1)
1. a kind of preparation method of automatically cleaning rope, it is characterised in that be achieved by the steps of：
1）It is 1 by volume ratio:6:6-1:12:6 positive four butyl ester of metatitanic acid, glacial acetic acid and deionized water mixing, preparing titanium dioxide
The hydrosol；
2）It is 1 by volume ratio:5:10-1:5:15 tetraethyl orthosilicate, glacial acetic acid and deionized water mixed preparing silica water
Colloidal sol；
3）By step 1）With 2）In obtained titania hydrosol and silica hydrosol according to titanium silicon mol ratio
30:1-60:1 is configured to titanium dioxide-silica hydrogel；
4）Top finish is carried out to rope matrix with obtained titanium dioxide-silica hydrogel, then through 70-100 DEG C
Hot water treatment 5-30min, last drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310212439.6A CN103290710B (en) | 2013-05-31 | 2013-05-31 | A kind of automatically cleaning rope and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310212439.6A CN103290710B (en) | 2013-05-31 | 2013-05-31 | A kind of automatically cleaning rope and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103290710A CN103290710A (en) | 2013-09-11 |
| CN103290710B true CN103290710B (en) | 2018-03-20 |
Family
ID=49092203
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310212439.6A Active CN103290710B (en) | 2013-05-31 | 2013-05-31 | A kind of automatically cleaning rope and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103290710B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103726302B (en) * | 2013-12-06 | 2016-01-20 | 南京工业大学 | Preparation method of multifunctional super-hydrophobic hybrid material |
| CN107142723A (en) * | 2017-05-10 | 2017-09-08 | 闽江学院 | Nano antifouling automatically cleaning vamp material and its method for sorting |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100531898C (en) * | 2006-06-12 | 2009-08-26 | 中国科学院理化技术研究所 | Preparation method of nano titanium dioxide/silicon dioxide composite photocatalytic sol and transparent photocatalytic film |
| GB2460686B (en) * | 2008-06-05 | 2012-05-16 | Tyco Electronics Ltd Uk | High performance, high temperature wire or cable |
| CN100594270C (en) * | 2008-09-17 | 2010-03-17 | 北京航材百慕新材料技术工程股份公司 | Sealing and protecting method by pressure injection of bridge rope corrosion inhibitor |
| CN102718411B (en) * | 2012-06-12 | 2015-03-11 | 华南理工大学 | Natural super-hydrophilic porous TiO2/SiO2 composite thin film and preparation method thereof |
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- 2013-05-31 CN CN201310212439.6A patent/CN103290710B/en active Active
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| Publication number | Publication date |
|---|---|
| CN103290710A (en) | 2013-09-11 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A self-cleaning rope and its production method Effective date of registration: 20230828 Granted publication date: 20180320 Pledgee: Taian Taishan Rural Commercial Bank Co.,Ltd. Pledgor: SHANDONG ROPE TECHNOLOGY Co.,Ltd. Registration number: Y2023980054032 |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20180320 Pledgee: Taian Taishan Rural Commercial Bank Co.,Ltd. Pledgor: SHANDONG ROPE TECHNOLOGY Co.,Ltd. Registration number: Y2023980054032 |