CN103289347B - ABS/PC composite material and preparation method thereof - Google Patents
ABS/PC composite material and preparation method thereof Download PDFInfo
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- CN103289347B CN103289347B CN201310253348.7A CN201310253348A CN103289347B CN 103289347 B CN103289347 B CN 103289347B CN 201310253348 A CN201310253348 A CN 201310253348A CN 103289347 B CN103289347 B CN 103289347B
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Abstract
The invention discloses an ABS/PC composite material and a preparation method thereof. The composite material comprises following ingredients, by weight: 20 to 35 portions of ABS, 45 to 70 portions of PC, 6 to 8 portions of a compatilizer, 3 to 8 portions of an organosilicone flame retardant, 2 to 6 portions of a phosphorus based flame retardant, 0.2 to 1 portion of an antioxygen, 0.2 to 1 portion of an auxiliary antioxygen, 0.4 to 0.8 portion of a lubricant, 5 to 8 portions of a flexibilizer and 0.1 to 0.5 portion of a toner. The ABS/PC composite material has excellent physical properties, and can be applied to various material fields.
Description
Technical field
The invention discloses a kind of ABS/PC matrix material, belong to engineering plastics field.
Background technology
Polycarbonate (PC) is the polyester of carbonic acid, and it is a kind of Linear carbon acid polyester, is important Industrial products.PC has good shock resistance, resisting heat distortion performance, and good weatherability, hardness are high, is therefore applicable to this component producing automobile, as lighting system, dashboard, hot-plate etc.According to data presentation, PC is at electronic apparatus, and in automobile industry, usage ratio is more than 50%, and the ratio that China uses in this field only accounts for about 10%, electronic apparatus and automobile industry are the mainstay industries that China develops rapidly, and the demand of these fields following to PC is very huge.And PC is because having good light transmission, the dimensional stability of shock resistance, UV radiation and its goods and good moulding processability, make the unorganic glass of its use more traditional than construction industry have obvious technical feature advantage.
Summary of the invention
In order to overcome above the deficiencies in the prior art, the invention provides a kind of ABS/PC matrix material,
The present invention is achieved in the following ways:
A kind of ABS/PC matrix material, is made up of the component of following weight part:
ABS20-35 part;
PC45-70 part;
Compatilizer 6-8 part;
Organic silicon fibre retardant 3-8 part;
Phosphorus flame retardant 2-6 part;
Oxidation inhibitor 0.2-1 part;
Auxiliary antioxidant 0.2-1 part;
Lubricant 0.4-0.8 part;
Toughner 5-8 part;
Toner 0.1-0.5 part.
Described ABS/PC matrix material, compatilizer used can be SEBS-G-GMA.
Described ABS/PC matrix material, organic silicon fibre retardant can be silicon-resin flame retardant agent, silicon polyborane fire retardant.
Described ABS/PC matrix material, phosphorus flame retardant can be FRP-3010, phosphate toluene diphenyl ester, phosphotriester.
Described ABS/PC matrix material, oxidation inhibitor can be aromatic amine oxidation inhibitor, and auxiliary antioxidant can be three monooctyl esters, three certain herbaceous plants with big flowers ester or Lauryl Alcohols.
Described ABS/PC matrix material, lubricant can be TAF or EBS.
Described ABS/PC matrix material, toughner can be ABS, MBS, SBS.
Described ABS/PC matrix material, toner can be the mixture of one or more equal proportions of transparent red, transparent green, transparent blue, transparent yellow mixture.
The preparation method of described ABS/PC matrix material, comprises the following steps:
(1) take raw material according to each ingredients weight parts, each component is fully mixed;
(2) above mixture is put into twin screw extruder to extrude, obtain ABS/PC mixture.
Above-described ABS/PC matrix material applies in electrical type appliance field.
Beneficial effect
ABS/PC composite property obtained by the present invention is excellent, wherein tensile strength can reach more than 19.5MPa, elongation can reach more than 196%, modulus in flexure can reach more than 1580MPa, flexural strength can reach more than 160MPa, melting index can reach more than 16g/10min, and notched Izod impact strength can reach more than 175J/M.
Embodiment:
Embodiment 1
A kind of ABS/PC matrix material, is made up of the component of following weight part:
ABS20 part, PC45 part, compatilizer SEBS-G-GMA6 part, silicon-resin flame retardant agent 3 parts, phosphotriester 4 parts, Ursol D 0.2 part, three monooctyl esters 0.2 part, TAF0.4 part, ABS5 part, 0.2 part, the equal proportion mixture of transparent red and transparent blue
This matrix material has following steps to be prepared from:
(1) take raw material according to each ingredients weight parts, each component is fully mixed;
(2) above mixture is put into twin screw extruder to extrude, obtain ABS/PC mixture.
Embodiment 2
A kind of ABS/PC matrix material, is made up of the component of following weight part:
ABS23 part, PC50 part, compatilizer SEBS-G-GMA6 part, silicon-resin flame retardant agent 4 parts, FRP-30103 part, dihydroquinoline 03 part, three monooctyl esters 0.3 part, EBS0.5 part, MBS5 part, 0.3 part, the equal proportion mixture of transparent yellow and transparent blue
This matrix material has following steps to be prepared from:
(1) take raw material according to each ingredients weight parts, each component is fully mixed;
(2) above mixture is put into twin screw extruder to extrude, obtain ABS/PC mixture.
Embodiment 3
A kind of ABS/PC matrix material, is made up of the component of following weight part:
ABS28 part, PC55 part, compatilizer SEBS-G-GMA7 part, silicon polyborane 6 parts, phosphate toluene diphenyl ester 4 parts, Ursol D 0.4 part, Lauryl Alcohol 0.6 part, TAF0.6 part, ABS5 part, 0.3 part, the equal proportion mixture of transparent red and transparent yellow
This matrix material has following steps to be prepared from:
(1) take raw material according to each ingredients weight parts, each component is fully mixed;
(2) above mixture is put into twin screw extruder to extrude, obtain ABS/PC mixture.
Embodiment 4
A kind of ABS/PC matrix material, is made up of the component of following weight part:
ABS31 part, PC63 part, compatilizer SEBS-G-GMA7 part, silicon polyborane 7 parts, phosphate toluene diphenyl ester 5 parts: pentanoic 0.7 part, three certain herbaceous plants with big flowers esters 0.8 part, TAF0.7 part, SBS7 part, 0.4 part, the equal proportion mixture of transparent green and transparent blue
This matrix material has following steps to be prepared from:
(1) take raw material according to each ingredients weight parts, each component is fully mixed;
(2) above mixture is put into twin screw extruder to extrude, obtain ABS/PC mixture.
Embodiment 5
A kind of ABS/PC matrix material, is made up of the component of following weight part:
ABS35 part, PC70 part, compatilizer SEBS-G-GMA8 part, silicon-resin flame retardant agent 8 parts, FRP-30106 part, Ursol D 1 part, three monooctyl esters 1 part, EBS0.8 part, MBS8 part, 0.5 part, the equal proportion mixture of transparent yellow and transparent blue
This matrix material has following steps to be prepared from:
(1) take raw material according to each ingredients weight parts, each component is fully mixed;
(2) above mixture is put into twin screw extruder to extrude, obtain ABS/PC mixture.
Carry out performance test to the matrix material obtained by above embodiment, acquired results is in table 1.
Table 1 embodiment obtains composite property test
As can be seen from above testing data, the matrix material properties obtained by the present invention is all very excellent, can be applied in the fields such as electronic material completely.
Claims (1)
1. an ABS/PC matrix material, is characterized in that, is made up of the component of following weight part:
ABS 20-35 part;
PC 45-70 part;
Compatilizer 6-8 part;
Organic silicon fibre retardant 3-8 part;
Phosphorus flame retardant 2-6 part;
Oxidation inhibitor 0.2-1 part;
Auxiliary antioxidant 0.2-1 part;
Lubricant 0.4-0.8 part;
Toughner 5-8 part;
Toner 0.1-0.5 part;
Wherein compatilizer used is SEBS-G-GMA; Organic silicon fibre retardant is silicon-resin flame retardant agent or silicon polyborane fire retardant; Phosphorus flame retardant is FRP-3010 or phosphate toluene diphenyl ester or phosphotriester; Oxidation inhibitor is aromatic amine oxidation inhibitor, and auxiliary antioxidant is three monooctyl esters, three certain herbaceous plants with big flowers ester or Lauryl Alcohols; Lubricant is TAF or EBS; Toughner is ABS, MBS or SBS; Toner is the mixture of one or more equal proportions of transparent red, transparent green, transparent blue, transparent yellow mixture;
The preparation method of described ABS/PC matrix material, comprises the following steps:
(1) take raw material according to each ingredients weight parts, each component is fully mixed;
(2) above mixture is put into twin screw extruder to extrude, obtain ABS/PC mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310253348.7A CN103289347B (en) | 2013-06-24 | 2013-06-24 | ABS/PC composite material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310253348.7A CN103289347B (en) | 2013-06-24 | 2013-06-24 | ABS/PC composite material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103289347A CN103289347A (en) | 2013-09-11 |
| CN103289347B true CN103289347B (en) | 2015-03-11 |
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| CN201310253348.7A Expired - Fee Related CN103289347B (en) | 2013-06-24 | 2013-06-24 | ABS/PC composite material and preparation method thereof |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104479321A (en) * | 2014-11-20 | 2015-04-01 | 苏州新区佳合塑胶有限公司 | Anti-oxidative ABS/PC plastic for automobile instruments/meters |
| CN104530675B (en) * | 2014-11-20 | 2016-05-25 | 苏州新区佳合塑胶有限公司 | A kind of automobile lamp plastics |
| CN104479319A (en) * | 2014-11-20 | 2015-04-01 | 苏州新区佳合塑胶有限公司 | Antioxidant PC/GF (polycarbonate/glass fiber) plastic for automobile tailboards |
| CN104479320A (en) * | 2014-11-20 | 2015-04-01 | 苏州新区佳合塑胶有限公司 | Anti-oxidation ABS/PC plastic for automobile upholstery |
| CN104479323B (en) * | 2014-12-08 | 2016-01-20 | 苏州新区佳合塑胶有限公司 | A kind of electronic product casing flame retardant plastics |
| CN105968770A (en) * | 2016-06-24 | 2016-09-28 | 上海轶峰新材料股份有限公司 | Low-smoke halogen-free flame-retardant non-ferrous alloy material for extrusion and stamping and processing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101418118B (en) * | 2008-12-05 | 2011-04-27 | 北京化工大学 | Halogen-free flame retardant PC/ABS alloy and preparation method thereof |
| CN101967274A (en) * | 2010-10-11 | 2011-02-09 | 余林华 | Permanent antistatic polycarbonate (PC)/acrylonitrile-butadiene-styrene (ABS) composite material and preparation method thereof |
| CN102649872A (en) * | 2011-02-23 | 2012-08-29 | 苏州汉扬精密电子有限公司 | Modified PC (Poly Carbonate)/ABS (Acrylonitrile Butadiene Styrene) alloy |
| CN102516738A (en) * | 2011-12-14 | 2012-06-27 | 深圳市科聚新材料有限公司 | Halogen-free flame-retardant and cold-resistant PC/ABS (Poly Carbonate/Acrylonitrile Butadiene Styrene) material and preparation method thereof |
| CN102532888B (en) * | 2012-02-03 | 2014-09-17 | 杭州福膜新材料科技有限公司 | Solar cell frame and preparation method thereof |
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