CN103289029B - Flame retardant and acid and alkali-resistant plastic containing 1,4-pentadiene - Google Patents
Flame retardant and acid and alkali-resistant plastic containing 1,4-pentadiene Download PDFInfo
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- CN103289029B CN103289029B CN201310252560.1A CN201310252560A CN103289029B CN 103289029 B CN103289029 B CN 103289029B CN 201310252560 A CN201310252560 A CN 201310252560A CN 103289029 B CN103289029 B CN 103289029B
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- parts
- pentadiene
- alkali
- acid
- fire
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- 239000004033 plastic Substances 0.000 title claims abstract description 35
- 239000003063 flame retardant Substances 0.000 title claims abstract description 29
- 239000002253 acid Substances 0.000 title abstract description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 9
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 title abstract description 5
- 239000003513 alkali Substances 0.000 title abstract description 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004695 Polyether sulfone Substances 0.000 claims abstract description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000292 calcium oxide Substances 0.000 claims abstract description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920006393 polyether sulfone Polymers 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract description 4
- 239000006229 carbon black Substances 0.000 claims abstract description 4
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004568 cement Substances 0.000 claims description 15
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 8
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 238000001816 cooling Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a flame retardant and acid and alkali-resistant plastic containing 1, 4-pentadiene. The plastic comprises the following components: by weight, 40-50 parts of the 1, 4-pentadiene, 30-40 parts of isobutene, 30-40 parts of cellulose acetate, 10-20 parts of calcium oxide, 10-20 parts of boron oxide, 10-20 parts of polyethersulfone resin and 10-20 parts of carbon black. The prepared plastic containing the 1,4-pentadiene has good effects of flame retardance and acid and alkali resistance.
Description
Technical field
The present invention relates to a kind of fire-retardant acid-alkali-resisting plastic, particularly relate to a kind of fire-retardant acid-alkali-resisting plastic containing Isosorbide-5-Nitrae-pentadiene.
Background technology
In the evolution of industry, in the segmentation field relating to fire-retardant acid-alkali-resisting plastic, the requirement of user to fire-retardant acid and alkali-resistance shape glue is day by day increased, such as, pay close attention to more and more to the flame retardant properties of plastic cement, possess flame retardant properties and can solve very many technical problems, also the acid-proof alkaline of plastic cement is also concerned about very much simultaneously, the plastic cement purposes possessing good flame retardant properties and acid-proof alkaline is comparatively wide, but have fire-retardant considerably less with plastic cement kind that is acid and alkali-resistance effect at present on the market simultaneously, therefore develop a kind of plastic cement simultaneously with good flame-retardance and resistance to acids and bases and there are good market outlook.
Summary of the invention
The technical problem solved: the problem that conventional plastic is fire-retardant and acid and alkali-resistance effect is poor.
Technical scheme: the present invention is a kind of containing 1, the fire-retardant acid-alkali-resisting plastic of 4-pentadiene, be made up of according to weight ratio following composition: Isosorbide-5-Nitrae-pentadiene 40 ~ 50 parts, iso-butylene 30 ~ 40 parts, rhodia 30 ~ 40 parts, 10 ~ 20 parts, calcium oxide, boron oxide 10 ~ 20 parts, polyethersulfone resin 10 ~ 20 parts, carbon black 10 ~ 20 parts.At 60 ~ 80 DEG C, various composition is dropped into reaction vessel allotment, stir, be heated to 200 DEG C and keep 8 ~ 10h, the plastic cement with good fire-retardant acid and alkali-resistance effect after cooling, can be obtained.
Beneficial effect: the fire-retardant acid-alkali-resisting plastic flame retardant properties containing Isosorbide-5-Nitrae-pentadiene that the present invention makes can reach V-1 rank, has good flame retardant effect.Fire-retardant acid-alkali-resisting plastic in addition containing Isosorbide-5-Nitrae-pentadiene has good acid and alkali-resistance effect.
Embodiment
Containing 1, the preparation method of the fire-retardant acid-alkali-resisting plastic of 4-pentadiene is: first reaction vessel temperature is adjusted to 60 ~ 80 DEG C, get 1,4-pentadiene 40 ~ 50kg, iso-butylene 30 ~ 40kg, rhodia 30 ~ 40kg, calcium oxide 10 ~ 20kg, boron oxide 10 ~ 20kg, polyethersulfone resin 10 ~ 20kg, carbon black 10 ~ 20kg, added togetherly to mix, be heated to 200 DEG C and keep 8 ~ 10h, obtain the fire-retardant acid-alkali-resisting plastic containing Isosorbide-5-Nitrae-pentadiene.Following table is the Ingredients Weight proportioning of embodiment 1, embodiment 2, embodiment 3.
Embodiment 1
At 60 DEG C, the composition of embodiment described in table 11 is dropped in reaction vessel according to weight and allocates, stir, be heated to 200 DEG C and keep 8h, the plastic cement with good fire-retardant acid and alkali-resistance effect after cooling, can be obtained.
Embodiment 2
Be that initial heating temperature is 80 DEG C with the difference of embodiment 1.
Embodiment 3
When cooling after being to stir with the difference of embodiment 1, the time is 10h.
Performance test
Use the flame retardant resistance of UL94 standard to plastic cement to test, acid and alkali-resistance experiment alkali lye is the sodium hydroxide solution of 2mol/L, and acid solution is the phosphoric acid solution of 2mol/L, and the time is 15 ~ 30 days.Reference examples plastic cement used is common plastic cement.Result is as following table.
Flame retardant properties: embodiment 1-V1 rank, embodiment 2-V1 rank, embodiment 3-V1 rank
Phenomenon without exception in acid and alkali-resistance effect: embodiment 1-17 days; Phenomenon without exception in embodiment 2-15 days; Phenomenon without exception in embodiment 3-20 days.
Claims (2)
1. one kind contains 1, the fire-retardant acid-alkali-resisting plastic of 4-pentadiene, it is characterized in that: be made up of according to weight ratio following composition: Isosorbide-5-Nitrae-pentadiene 40 ~ 50 parts, iso-butylene 30 ~ 40 parts, rhodia 30 ~ 40 parts, 10 ~ 20 parts, calcium oxide, boron oxide 10 ~ 20 parts, polyethersulfone resin 10 ~ 20 parts, carbon black 10 ~ 20 parts.
2. a kind of fire-retardant acid-alkali-resisting plastic containing Isosorbide-5-Nitrae-pentadiene according to claim 1, is characterized in that: in plastic cement composition, Isosorbide-5-Nitrae-pentadiene is 40 parts.
3. a kind of fire-retardant acid-alkali-resisting plastic containing Isosorbide-5-Nitrae-pentadiene according to claim 1, is characterized in that: in plastic cement composition, iso-butylene is 30 parts.
4. a kind of fire-retardant acid-alkali-resisting plastic containing Isosorbide-5-Nitrae-pentadiene according to claim 1, is characterized in that: in plastic cement composition, rhodia is 30 parts.
5. a kind of fire-retardant acid-alkali-resisting plastic containing Isosorbide-5-Nitrae-pentadiene according to claim 1, is characterized in that: in plastic cement composition, calcium oxide is 10 parts.
6. a kind of fire-retardant acid-alkali-resisting plastic containing Isosorbide-5-Nitrae-pentadiene according to claim 1, is characterized in that: in plastic cement composition, polyethersulfone resin is 10 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310252560.1A CN103289029B (en) | 2013-06-24 | 2013-06-24 | Flame retardant and acid and alkali-resistant plastic containing 1,4-pentadiene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310252560.1A CN103289029B (en) | 2013-06-24 | 2013-06-24 | Flame retardant and acid and alkali-resistant plastic containing 1,4-pentadiene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103289029A CN103289029A (en) | 2013-09-11 |
| CN103289029B true CN103289029B (en) | 2015-04-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310252560.1A Expired - Fee Related CN103289029B (en) | 2013-06-24 | 2013-06-24 | Flame retardant and acid and alkali-resistant plastic containing 1,4-pentadiene |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103289029B (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101212990A (en) * | 2005-07-01 | 2008-07-02 | 金文申有限公司 | Medical devices comprising a reticulated composite material |
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2013
- 2013-06-24 CN CN201310252560.1A patent/CN103289029B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101212990A (en) * | 2005-07-01 | 2008-07-02 | 金文申有限公司 | Medical devices comprising a reticulated composite material |
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| CN103289029A (en) | 2013-09-11 |
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Effective date of registration: 20171229 Address after: 215002 754 room, No. 379, No. 1, Tower Park Road, Suzhou high tech Zone, Jiangsu Patentee after: SUZHOU NIUMAITIAN NEW MATERIAL TECHNOLOGY CO.,LTD. Address before: High tech Zone Fengqiao town Suzhou city Jiangsu province 215129 Bridge Village Patentee before: SUZHOU NEW DISTRICT JIAHE PLASTIC Co.,Ltd. |
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Effective date of registration: 20181228 Address after: 211000 Workshop 07-3, 51 Space, 33 Dongji Road, Dongshan Street, Jiangning District, Nanjing City, Jiangsu Province Patentee after: NANJING YOUGU NEW MATERIAL TECHNOLOGY CO.,LTD. Address before: Room 754, Building 379, Tayuan Road, Suzhou High-tech Zone, Jiangsu Province Patentee before: SUZHOU NIUMAITIAN NEW MATERIAL TECHNOLOGY CO.,LTD. |
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Effective date of registration: 20210301 Address after: 211111 p556, building 1, 12 mozhou East Road, Jiangning District, Nanjing City, Jiangsu Province Patentee after: NANJING YOUGU INTELLECTUAL PROPERTY SERVICE Co.,Ltd. Address before: 211000 Workshop 07-3, 51 Space, 33 Dongji Road, Dongshan Street, Jiangning District, Nanjing City, Jiangsu Province Patentee before: NANJING YOUGU NEW MATERIAL TECHNOLOGY Co.,Ltd. |
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Granted publication date: 20150429 |