CN103288262A - Photocatalytic wastewater degradation device with high-frequency ultrasonic-assisted separation membrane for removing attachments - Google Patents

Abstract

The invention relates to a photocatalytic wastewater degradation device with a high-frequency ultrasonic-assisted separation membrane for removing attachments and belongs to the technical field of wastewater treatment. The photocatalytic wastewater degradation device aims at solving the problems of microwave energy waste, low single-tank wastewater treatment capacity, difficultly-distinguished reaction endpoint time, incapacity of powerfully dissipating catalyst agglomerates in situ, incapacity of detecting the occurrence of catalyst agglomeration in time, difficulty in eliminating catalyst precipitates on a membrane module, and the like, existing in the existing related technologies. Via the structure of the photocatalytic wastewater degradation device, a microwave irradiation airspace is limited, and great capacity expansion for a reactor is allowed; a catalyst is intercepted by an external cascaded multi-stage backwash-type filter stage by stage; the catalyst agglomerates are dissipated by a low-frequency ultrasonic wave, and incidentally, a quartz tube is cleaned simultaneously; a related power supply is automatically and immediately turned off at a degradation endpoint; the tendency of catalyst agglomeration can be warned; and the running of the backwash procedure of a membrane module is assisted by a high-frequency ultrasonic wave.

Description

The auxiliary separatory membrane of high frequency ultrasound is except the photochemical catalysis waste water decomposition apparatus that adheres to

Technical field

The present invention relates to the auxiliary separatory membrane of a kind of high frequency ultrasound except the photochemical catalysis waste water decomposition apparatus that adheres to, belong to the C02F technical field of waste water processing.

Background technology

Microwave and photo catalysis degradation treatment technology, is quite paid close attention to effectively at the innoxious process for treating that contains the organic pollutant trade effluent in recent years as a kind of.

About the microwave and photo catalysis degradation technique, as an example, can be the Chinese patent application case of CN102260003A referring to publication number.

The disclosure number is the Chinese patent application case of CN102260003A, be as excitaton source with microwave, excite electrodeless ultraviolet lamp emission ultraviolet ray, be mixed with the suspension liquid of photocatalyst titanium dioxide in the liquid internal irradiation, this electrodeless ultraviolet lamp is shrouded by silica tube to be protected, there is pneumatic pump to continue to inject air to this silica tube inner chamber, the air that is overflowed by quartzy chamber is via pipeline and the micro porous aeration head UNICOM that is positioned at reactor bottom, the lower zone of this inside reactor is the aeration zone, the upper area of this inside reactor is the microwave and photo catalysis reaction zone, this scheme is also with the built-in membrane separation assemblies of reactor, carry the water of analysing after the purification, and realize that with this membrane separation assemblies holding back again of photocatalyst titanium dioxide fine particles use; This scheme is also set up dividing plate between electrodeless ultraviolet light source and membrane separation assemblies, be used for preventing that ultraviolet ray is to the radiation injury of the membrane separation assemblies of organic matter; Feed the air of inside reactor, part is participated in the photocatalytic degradation reaction that relies on photocatalyst titanium dioxide directly, some air, under the direct irradiation of UV-light, generate a certain amount of ozone, the ozone of this generation is also being brought into play the direct oxidative degradation at organic pollutant certainly.

The disclosure is number for the Chinese patent application case of CN102260003A has undoubtedly played very important pushing effect for the progress of microwave and photo catalysis waste water degradation technique, and the work that its research staff launches in this field is admirable.

Based on the meaning of sincere admiration, and, common striving direction, what will talk below us is problem.

Below the problem that will speak of has 14; These 14 problems are 14 problems arranged side by side; The priority of its ordering only is to consider for discussing easily.

One of problem;

The disclosure number is the Chinese patent application case of CN102260003A, its membrane separation assemblies that is used for interception catalyzer titanium dioxide fine particles is to be placed in the reactor inner chamber, be immersed in and handle among the object liquid, and rely on the ozone bubbles that contains of ascension to wash away membrane separation assemblies, it is adsorbed to remove its surface by this, the catalyst particles that is detained, reach the recovery of catalyst particles, the recycling purpose, simultaneously, membrane separation assemblies also is to rely on this mode self-cleaning and keep its separating power, so, based on this structure, can only select for use commercial with curtain formula hollow fiber film assembly or plate film assembly, and this membrane separation assemblies is need be immersed in the context of strong oxidizing property of ozone bubbles ascension, therefore, oxidation tolerance to membrane separation assemblies must have requirement, the organic membrane separation assembly of common material can not tolerate such environment for use, so can only select the membrane separation assemblies of PVDF material for use, this point clearly illustrates that in open the 0009th section literal of text of this case and claim 3; Its material cost of the filter membrane of the oxidation tolerance that this kind needs are special is higher, and its commercially available price also is higher than common organic micro-filtration membrane module of non-oxidation tolerance requirement certainly; In other words, the frame mode of this case causes the material of membrane separation assemblies to be limited to expensive PVDF material.Have again, UV-light possible in the device is revealed, may touch the organic membrane assembly, this also the organic membrane assembly material in the claimed apparatus can resist ultraviolet light irradiation, from this point, based on the organization plan of this device, the material of organic membrane separation assembly also can only be limited in expensive PVDF material.

The organic membrane assembly has its apparent advantage compared to the ceramic filter assemblies; About this point, for the personage of filtering technique specialty, be known, here do not launch to give unnecessary details.

Can so, under the prerequisite of using the organic material membrane module, bypass this PVDF filter membrane material limitation? this is the problem that needs solve, and this is one of problem.

Two of problem:

Scouring force in view of described ascension bubble, cleaning capacity is more weak, therefore, can only select other filter opening aperture of bigger micro-filtration level for use with its aperture of membrane separation assemblies that this cleaning mode is used, other filter opening aperture of this micro-filtration level is the 0.1-0.2 micron, about this point, in open the 0009th section literal of text of this case and claim 3, have clearly equally and limit, this kind filter opening aperture limits, type selecting from the such membrane separation assemblies of this case, built-in and soak use-pattern, the self-cleaning method of ascension bubble, be inevitable, can only limit its filter opening aperture in the micro-filtration rank.In other words, this its scouring force of mode that washes away with the ascension bubble, cleaning power too a little less than, to such an extent as to can't tackle the more filter membrane of small-bore at all, thus, in this case device, the filter membrane aperture is limited between 0.1 micron-0.2 micron, is the inevitable choice of not discussing leeway.

The filter opening aperture of so-called 0.1-0.2 micron, if change a measure unit, corresponding is exactly the filter opening aperture of 100-200 nanometer; Is what concept that? with 100 nanometer filter opening apertures of its lower limit, its size of catalyst particles that it can be tackled must be more than 100 nanometers, and can't be blocked less than the catalyst particles of 100 nanometers; In other words, less than the catalyst particles of 100 nanometers will directly penetrate, by the filter opening of membrane module, sneak among the so-called water purification that the DeR device exports.

Particle diameter and the photocatalyst dosage form selection of the related photocatalyst of the ultraviolet catalytic DeR of need having a talk now.

The professional person who is engaged in photocatalytic degradation research knows, with the photochemical degradation reaction of uv light induction, its catalyzer multiselect titanium dioxide fine particles catalyzer; At present, on laboratory level, developed the photodegradation particle catalyst based on the optically catalytic TiO 2 characteristic various in style, certainly, the photodegradation catalyzer that these different preparation methods form, its particle diameter also is various; Its particle diameter of photocatalyst that different preparation methods make is little of 20 nanometers, to also namely 100 microns of 100000 nanometers, has greatly, wherein is no lack of the photocatalyst kind of excellent performance; But because the restriction of the evaluation of performance permanent stability, preparation cost and market expansion etc. aspect factor, most its deliverabilities of described photocatalyst only are confined to laboratory level, and do not have to form extensive commercially available production level; The at present known commercially available photocatalysts that are used for the UV-light wave band that can actually use in a large number that can make a big purchase in large quantities be famous gas phase titanium dioxide P25; Its concrete art-recognized meanings of gas phase titanium dioxide P25, the insider knows, does not here launch to give unnecessary details; The median size of gas phase titanium dioxide P25 is 21 nanometers; Gas phase titanium dioxide P25 performance is not very optimum, but, its stable performance, key is can make a big purchase in large quantities in market to obtain, and can on technical scale, use in a large number, therefore, in the photochemical catalysis specialized laboratory also usually with the P25 catalyzer be used as weighing various self-made photocatalyst catalytic performances with reference to pointer or contrast pointer, in fact, characteristics in view of the ultraviolet catalytic DeR, the photocatalyst that dispersity is more high, be fit to the needs of this type reaction, that is to say, the photocatalyst of median size about 21 nanometers its catalyst interfacial area that can provide, anti-sedimentation capacity, catalytic performance permanent stability etc. aspect, comprehensive, be optimal.Say simply, at present good and cheap, the photocatalyst of the UV-light wave band of the ready-made commercially available commercial grade that can actually make a big purchase in large quantities, use, be exactly median size be the gas phase titanium dioxide P25 catalyzer of 21 nanometers; At plant-scale application, this median size is that the photocatalyst of 21 nanometers is actual first-selections.

Above address, the disclosure number is the Chinese patent application case of CN102260003A, it is used for the membrane module of interception photocatalyst, be to wash away the stripping film assembly surface adsorbed with the ascension bubble, the catalyst particles of deposition, yet, its scouring force of mode that this kind washes away with the ascension bubble, cleaning power too a little less than, to such an extent as to can't tackle the more filter membrane of small-bore at all, therefore, in this case device, the filter membrane aperture is limited at micro-filtration filter opening rank between 0.1 micron-0.2 micron, change a measure unit, in this case device, the filter membrane aperture is limited at the micro-filtration filter opening rank between 100 nanometers-200 nanometer, and this is the inevitable choice of not discussing leeway; The micro-filtration filter opening that this case does not have between selectable 100 nanometers-200 nanometer can't be tackled the gas phase titanium dioxide P25 particle that aforesaid median size is 21 nanometers certainly; So, if use the P25 photocatalyst, this catalyzer will can't be tackled fully, and flows in the so-called water purification, forms secondary pollution, certain heavy losses that also cause catalyzer and unrenewable; Even if use other kind for this reason and the titanium dioxide optical catalyst of special big particle diameter, collide because of mutual collision or with wall in its use, must also can produce a large amount of small particle size fragments, wherein particle diameter is less than the fragment of 100 nanometers, can not be tackled by the micro-filtration filter opening between 100 nanometers-200 nanometer equally, these small shredss also can see through its membrane module and enter among the so-called water purification, form secondary pollution.

As seen, the disclosure number is the Chinese patent application case of CN102260003A, and its cleaning scheme at the interception structure scheme of photocatalyst particulate and related film assembly is all undesirable.

Therefore, how under the prerequisite of this case advantage of incorporating things of diverse nature, reaching at the meticulous interception of photocatalyst particulate and reclaim usefulness again, is an important topic very worth thinking deeply about, and this is two of problem.

Three of problem:

We know, liquid water body itself also can absorb the energy of microwave, and cause itself temperature-rise effect of processed liquid water body, and this temperature-rise effect of following wastewater treatment process and occurring, it but not the situation that we expect, in other words, microwave energy from magnetron is not used to excite electrodeless ultraviolet lamp fully, and have quite a few only to be used for exciting the microwave energy of electrodeless ultraviolet lamp to be dissipated in described temperature-rise effect, the temperature-rise effect that this kind is not fond of has caused unnecessary microwave energy to waste, in view of above-mentioned publication number is the apparatus structure scheme that the Chinese patent application case of CN102260003A is showed, its rational approach, can only be to reduce the purpose that single jar of processing capacity is reached the unnecessary dissipation of reduction microwave in other words by the volume that reduces the microwave and photo catalysis reactor, about this point, clear suitable size of having expressed about this apparatus structure integral body in this its embodiment of CN102260003A application case, the preferred size correspondence that it is expressed be exactly a device that profile is very little, so, thus, the distance of reactor wall and microwave radiation source is little, the wastewater flow rate that contacts with microwave is little, waste water institute microwave energy absorbed is also little relatively, with it accordingly, single jar wastewater treatment capacity is therefore also little, more particularly, the corresponding internal capacity of device suitable size expressed in the embodiment is 40 liters, also be that single jar of wastewater treatment capacity is 40 liters, namely 0.04 cube, in other words, it is once a complete set of, substantial length of operation has only solved 0.04 cube trade effluent, so, just need carry out many times by the repetition of head to the operation of the complete set of tail, adding up of its treatment capacity just has plant-scale meaning, so to say, just individual analogy roughly, its preferred structure size of this case is single jar of 0.04 cube of such wastewater treatment capacity of correspondence roughly, need to repeat 1000 times by the complete set of head to tail, substantial length of operation, its accumulation amount, just can reach 40 cubes such one have industrial level wastewater treatment capacity, so excessively loaded down with trivial details repetitive operation will cause manpower, the serious waste of material resources, as seen, this kind its actual waste water degradation treatment efficient of scheme of being showed by CN102260003A may not be fully up to expectations.Therefore, how not cause more microwave energy wastes or to reduce under the prerequisite of microwave energy waste, increase single jar of wastewater treatment capacity, reduce the unnecessary too many by the repetitive operation number of times of head to tail of this intermittent type wastewater treatment equipment, improving its waste water treatment efficiency, is a significant technical problem that merits attention.

On the other hand, according to the literature, some system, under the situation of the direct irradiation wastewater liquid of microwave, the photochemical catalysis degradation efficiency truly has raising, that is to say, in some system, between the direct irradiation wastewater liquid of microwave and the photochemical catalysis degraded, there is certain coupling.

Therefore, how to take into account under the prerequisite of described coupling, improving the processing efficiency of waste water decomposition apparatus, be worth inquiring into, this is three of problem.

Four of problem:

The scheme that this kind showed by CN102260003A, the bubble of the inner dispersed ascension of its retort for the cyclic motion of the relative big scale of driving a reaction jar internal liquid, is contributed inadequate slightly; Certainly, this weak point, in fact corresponding small size, the low capacity device of clear expression in CN102260003A scheme such as its embodiment, the influence that almost has nothing observable.From plant-scale application demand, undersized device that can not the divergence process amount does not have great magnetism certainly; So, as a kind of possibility, if there is certain mode can realize the significantly expansion for the treatment of capacity, under this situation, its importance of the cyclic motion of the relative big scale of retort internal liquid will highlight naturally; Imagining the possibility that this treatment capacity is significantly expanded, so, how to strengthen the cyclic motion of the relative big scale of retort internal liquid, is exactly an individual problem certainly, and this is four of problem.

Five of problem;

Photochemical catalysis oxidizing reaction for the UV-light wave band, there is following so several key element can have influence on the efficient of this kinds of oxidation reaction, first ultraviolet wavelength, intensity, it two is particle diameters of photocatalyst, the usage quantity of photocatalyst in the unit volume reaction solution, himself catalytic performance etc. of photocatalyst, it three is that oxidized object is organic concentration in the water body, oxidation complexity that the organic molecule structure determines himself etc., it four is sufficient degree of oxygen atmosphere, under the identical situation of other condition, the sufficient degree of oxygen atmosphere will become a very important key element that influences photochemical catalysis oxidative degradation ability.

The scheme of showing as CN102260003A, its numerous micro porous aeration head disperseds that are placed in reactor inner chamber bottom are in the bottom, and by its alleged water distribution board, make the effect of this micro porous aeration head dispersed arrangement become more very, certainly, this is for the situation of the oarse-grained micron-sized photocatalyst that uses relatively easy sedimentation, really there is its favourable one side, but, from another side, the mode that this micro porous aeration head dispersed is arranged, the supply of oxygen atmosphere too disperses, and in fact need most enhanced oxygen blowing the zone be the effective area of photochemical catalysis oxidation, because the Effective depth penetration of short wave ultraviolet in liquid water body has only about 20 centimetres, therefore, needing most enhanced oxygen blowing in fact is exactly zone within peripheral about 20 cm distance of silica tube with the effective area that promotes photochemical catalysis oxidation process, in other words, zone within about 20 cm distance of silica tube periphery is really to need enriched with oxygen atmosphere to supply with the zone that ensures, this regional oxygen atmosphere is supplied with more strong, and oxidizing reaction is also just carried out more soon; Especially especially, produce electrodeless ultraviolet emission in the microwave excitation mode, its characteristics can be accomplished high-power, high strength exactly, this is the strong point of this lamp type of electrodeless ultraviolet lamp, yet, just because of the superpower of its uv-radiation, high strength just more need mate with powerful oxygen atmosphere supply capacity, otherwise, that powerful uv-radiation ability is that major part has been wasted really just.Above address, the scheme of showing as CN102260003A, many effects limit its reactor size, limited its actual treatment capacity, just as clearly illustrating that in its specific embodiment, that can only be that one single jar single treatment amount has only the little reactor about 40 liters, at so little reactor, under the situation of little inner chamber, because size itself is just very little, so, its shortcoming aspect photochemical catalysis oxidation effective area oxygen supply concentration degree just can not be so obvious, even can ignore, more even fully can regard a non-existent problem at all as, in the face of such undersized little reactor, about the shortcoming problem of oxygen supply concentration degree aspect, not may float mind; But, imagine, if can overcome described many limiting factors, if can there be one of way actual implementation large-scale, the reactor of high throughput, effective area oxygen supply reinforcement problem will show especially out within so above-mentioned silica tube periphery 20 cm distance, especially for the situation of using electrodeless ultraviolet lamp as UV source, effective area oxygen supply reinforcement problem is not allowed to despise more within above-mentioned silica tube periphery 20 cm distance, therefore, how among the structure of possible large-scale electrodeless ultraviolet light catalysis oxidative degradation device, strengthen the oxygen supply concentration degree of described effective area, improve the usefulness of waste water degraded equipment, the problem that individual exactly needs are kept a close watch on, this is five of problem.

Six of problem:

This CN102260003A scheme pumps air within the silica tube that includes electrodeless ultraviolet lamp, reach the aeration-cooling of electrodeless ultraviolet lamp, cooling purpose, and those flow through the air of silica tube, because being subjected to ultraviolet irradiation, some air can change ozone into, therefore, the air that flows out from silica tube is exactly the air that contains some ozone certainly, this scheme contains ozone-air with this and is transferred to and is positioned at reactor below micro porous aeration head, and disengage from micro porous aeration head, contain in the ozone bubbles ascension process from bottom to top at these, wherein contained ozone can meet with and take place redox reaction with the organic molecule that runs among the distance, this redox reaction can consume a part of ozone certainly, this does not have query, but, above address, the scheme of showing as CN102260003A, the many effects limit that can't ignore that certainly exist its reactor size, limited its actual treatment capacity, just as clearly illustrating that in its specific embodiment, that can only be that one single jar single treatment amount has only the little reactor about 40 liters, at so little reactor, under the situation of little inner chamber, because overall dimension itself is just very little, so, the longitudinal size of its reactor inner chamber or regard that to contain the liquid degree of depth also can only be a very little size as with reckoning in every item, this size is as clearly illustrating that among its embodiment, have only about 40 centimetres, the Sheng that the reckons in every item liquid degree of depth also just has only 40 centimetres, in fact contain the liquid degree of depth and be less than this number certainly, just analyze with 40 centimetres the Sheng liquid degree of depth, so, is this Sheng liquid degree of depth of 40 centimetres what concept? that is to say, contain the ozone-air ascension and have only short 40 centimetres by the path of waste water, this path is too short, containing the ozone-air bubble passes through at a gallop and only has only 40 centimetres of dark water bodys, too short duration of contact with water body, contained ozone in the bubble, can only there be a very little part to be used to the oxidative degradation organism, and most ozone is in fact just passed by liquid simply, from the liquid level effusion and through the exhaust port emptying, briefly, the oxygenizement potentiality major part of these ozone has been wasted, and, effusion, in fact the ozone that is wasted can cause unnecessary atmospheric pollution; The main contriver of this case once squeezed in one meter dark tank via micro porous aeration head with the normal domestic use ozone machine and contained ozone-air, reach in the depth of water degree of depth under one meter the situation, still can near the water surface, obviously smell the smell of ozone, as seen, the sort of 40 centimetres of dark Sheng liquid degree of depth obviously are to be not enough to utilize fully ozone; As seen, for the such equipment of electrodeless ultraviolet light chemical catalysis waste water DeR device, ozone utilizes incomplete problem also to need to pay close attention to, obviously, what people more expected is that the ozone utilization is more complete, contaminative exhaust emissions no extreme ultraviolet waste water DeR device still less, and this is six of problem.

Seven of problem:

Its running of waste water catalytic degradation reaction device requires the expenditure of energy, and therefore, operator are bound to wish, when the waste water DeR proceeds to terminal point, can impartially, immediately not stop too early continuing to inject energy to inside reactor only lately; If it is too early to stop to inject the moment of energy, then the waste water degraded not exclusively; And if reach reaction end already, but still inject energy to inside reactor unceasingly, that undoubtedly is at the valuable energy of waste.Its structure of CN102260003A scheme as this case technical background can not provide any instant information constantly to waste water DeR terminal point, so, just can only estimate the terminal point of waste water DeR by experience; And estimate the terminal point of waste water DeR by experience, that obviously can not be satisfactory; So, how make neither also undelayed instant information output in advance constantly at waste water DeR terminal point, and immediately close energy input to reactor in the just right moment, the technical threshold that can not despise exactly, this is seven of problem.

Eight of problem:

Accept the described trade effluent of microwave and photo catalysis degradation treatment, the material that wherein is mingled with some metal particles that originate from mechanical system abrasion process and carbon granules and so on unavoidably, even if quantity is small, its existence almost is difficult to avoid, the disclosure number is installed in the microwave and photo catalysis reaction zone for the described organic membrane separation assemblies in the Chinese patent application case of CN102260003A, the ultraviolet dividing plate of obstruct that is used for that is installed between silica tube and the membrane separation assemblies does not wherein stop microwave certainly, so, the practical function zone of microwave must cover zone that organic membrane separation assemblies is installed described in this scheme, working mechanism based on membrane separation assemblies, its accumulation process on the organic top layer of membrane separation assemblies of the particulate of aforesaid metal particle and carbon granules and so on is difficult to avoid, and the particulate of this type of described metal particle and carbon granules and so on, the good absorption medium of microwave energy exactly, absorbed the particulate of the described metal particle of accumulation attitude of microwave energy and carbon granules and so on, nature can to the top layer of its organic membrane separation assemblies of being close to produce based on heat penetration erosion mechanism continue pierce destruction, as mentioned above, since the structures shape of this its device of CN102260003A application case can only select the polyvinylidene fluoride film material for use, about 140 degrees centigrade of this polyvinylidene fluoride film material heatproof, high really more many than general film material heatproof, yet, absorbed the heatproof temperature limit that its point-like of particulate of the described metal particle of accumulation attitude of microwave energy and carbon granules and so on is pierced very easy this polyvinylidene fluoride film material of breakthrough of heat penetration erosion effect of formula, for above-mentioned reasons, well imagine, pvdf membrane material in its device of this CN102260003A application case will be significantly less than the desirable work-ing life of expecting its actual service life, the structure of this its device of CN102260003A application case, determined that under this structural framing the heat penetration erosion destruction problem that above-mentioned point-like is pierced formula can't be avoided; Therefore, how to get around the heat penetration erosion destruction problem that this point-like is pierced formula, also need consider, this is eight of problem.

Nine of problem:

The disclosure number is the Chinese patent application case of CN102260003A, open the 0008th section literal of text text of its specification sheets and claim the second, for its device catalyst particle size scope that can be suitable for, a restriction is arranged, this particle size range is defined as 20 nanometers to 100 micron.We know, under some pH value was regulated not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles was reunited easily, and then influences its effective working interface area, influences its photochemical catalysis usefulness; Especially among this particle size range those relatively than the section of small particle size,, the pH value incorrect agglomeration traits that cause not in place because of pH value preset appears especially easily; For the situation that this catalyst particles is reunited, be immediately to adopt an effective measure, carry out the depolymerization running at coacervate; Yet we do not see that any helping immediately dissolve the structure of this problem or can immediately dissolve the scheme prompting of this problem among this CN102260003A scheme.For can only being the reactor of small scale structures just like that because of many effects limit as the CN102260003A scheme, still can manually directly mention reactor, topple over and inspect in the reactor outside, handle above-mentioned reunion situation, so, if might expand its capacity, just so to say, if be several cubes to large-scale reactor or the huge reactor of dozens of cube, that obviously be not manual topple over its operation the problem that can tackle, so, for the situation that this catalyst particles is reunited mutually, how to realize instant original position disposal, be exactly a technical problem, this is nine of problem.

Ten of problem:

Number be in the expressed apparatus structure of the Chinese patent application case of CN102260003A in the disclosure, be used for the silica tube that screen protects electrodeless ultraviolet lamp, its outer wall, refer to the outer wall of silica tube, through for a long time with the contacting of processed trade effluent, incrustation gradually unavoidably, the long-pending material of dirt mainly are difficult by mineral-type impurity that light-catalyzed reaction touched certainly, incrustation phenomenon because this mechanism forms is easy to be observed after the equipment long-play; Be attached to the dirty lamination of described silica tube outer wall, though be very thin one deck, also be enough to ultraviolet radiation to electrodeless ultraviolet lamp and cause significantly and stop, this will cause the actual treatment of this microwave and photo catalysis reaction treating device to be renderd a service significantly reducing; The bubble of dispersed ascension is because too disperseing in its reactor, wash away strength a little less than, keep the bright and clean of silica tube surface if only rely on this bubble that relatively disperses, really undertake to do what is apparently beyond one's ability, in other words, the bubble that this relatively disperses, it is more weak washes away the incrustation process that strength still is not enough to stop fully this silica tube surface; In the use of laboratory yardstick, above-mentioned incrustation problem is subtle, and still, on the industrial application yardstick, this incrustation problem undoubtedly will highlight; Therefore, how under the prerequisite of not tearing machine open, remove the dirty lamination on this silica tube outer wall immediately, effectively, keep the high-level efficiency that continues of this microwave and photo catalysis treatment unit, this problem is also very important, and this is ten of problem.

11 of problem:

This problem is nine its problems of deriving of the problem above addressed.The front is spoken of, and under some pH value was regulated not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles was reunited easily, and then influences its effective working interface area, influences its photochemical catalysis usefulness; Especially those among its suitable catalyst particle size range of touching upon for this CN102260003A scheme than the section of small particle size,, the pH value incorrect agglomeration traits that cause not in place because of pH value preset occur relatively especially easily; For the situation that this catalyst particles is reunited, be immediately to adopt an effective measure, carry out the depolymerization running at coacervate; Based on this its framework of CN102260003A scheme, operator can't perceive the situation that described reunion takes place inside reactor immediately, thereby also can't make instant disposal, thus, this is subjected to many effects limit and can only is the further reduction of its limited usefulness of reactor of small scale structures; Therefore, among the application running of reactor, particularly, for example, among the application of possible large-scale reactor or huge reactor running, the awareness inside reactor catalyst particles main inducing parameter of reuniting how immediately, be a key issue, this is 11 of problem.

12 of problem:

Based on this its framework of CN102260003A scheme, because all multifactor restriction of having addressed, its reactor can only be the smaller reactor of undersized treatment capacity, the useful size of reactor inner chamber is also smaller certainly, can be used in the spatial altitude of settling curtain type film assembly among its structure of reactor inner chamber approximately also is about 30 centimetres, so, even if just adopt the very curtain type film assembly of small breadth, also almost up and down two head on plug in the reactor the inside, because the little treatment capacity of reactor, small size, so, after its DeR is finished, under the situation of getting rid of liquid from inside to outside, its curtain type film assembly is exposed in the air unavoidably, though each time that exposes can be not long, but, the accumulation result of often buying and selling, make this curtain type film assembly contact with air too much exactly, its normal service requirements of curtain type film assembly, be to use under the submerged state fully, that is to say, must be that hygrometric state uses, if curtain type film assembly contacts with air too much, can make it than aging more quickly, performance is than decay more quickly, and the situation that this curtain type film assembly contacts with air too much under this its framework of CN102260003A scheme, can't be avoided; Therefore, how to protect the membrane module for the interception catalyzer, can enough under nominal situation, use; can enough avoid too much the contacting with air, to safeguard its normal use properties, guarantee its normal work-ing life; problem that needs are faced exactly, this is 12 of problem.

13 of problem:

Based on this its framework of CN102260003A scheme, among its running, the granules of catalyst of being tackled by curtain type film assembly, a part is at the curtain type film assembly surface deposition, and another part then is trapped among the liquid object phase, causes liquid object middle granules of catalyst concentration progressively rising along with progressively reducing of liquid phase volume mutually thus, this is for subsequent membrane separation, its membrane sepn load also can raise thereupon gradually, and the excessive problem of difference needs to solve before and after this membrane sepn load, and this is 13 of problem.

14 of problem:

Based on this its framework of CN102260003A scheme, among its running, water pump to reactor inner chamber filling waste water, itself can't differentiate inside reactor water level height, operator can only rely on experience or range estimation in time to close the pump motor of this filling waste water, if experience error or range estimation response are not prompt enough, be easy to occur cause unnecessary trouble thus because of the excessive situation of overflowing reactor of waste water filling; On the other hand, after DeR finishes, need be by inside via curtain type film assembly to extracardiac pumping, failing to know under the situation of inside reactor water level, fully can only rule of thumb or estimate and judge the opportunity of closing down water pump, and running like this, obviously unreliable, very easily untimely because of experience error or range estimation response, causing this to draw water can't in time shut down with water pump, and this dry tap, idle running be easy to cause this pump motor that draws water to burn, this problem can not be out in the cold, this is 14 of problem.

Summary of the invention

Technical problem to be solved by this invention is, at one of problem of above addressing, two, three, four, five, six, seven, eight, nine, ten, 11,12,13,14, and take into account microwave exposure and encourage collaborative, the coupling of degrading with photochemical catalysis, research and develop a kind of novel waste water microwave and photo catalysis degradation treatment device that can solve described serial problem totally.

The present invention solve the technical problem by following scheme, this scheme provides the auxiliary separatory membrane of a kind of high frequency ultrasound except the photochemical catalysis waste water decomposition apparatus that adheres to, the structure of this device comprises reactor, this reactor is the container of a hollow, its appearance profile of this reactor is cube shaped, cuboid, the cylinder bodily form, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form are equiped with many micro porous aeration heads at the lower region of this reactor inner chamber, and, silica tube, this silica tube is erected at the inner chamber position of described reactor, and the two ends of this silica tube are equiped with the shutoff headkerchief, lays respectively on the described shutoff headkerchief at silica tube two ends and all offers the ventilation interface, and, electrodeless ultraviolet lamp, this electrodeless ultraviolet lamp is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, the quantity of this electrodeless ultraviolet lamp are at least more than one, this quantity all is erected at the inside of described silica tube at least at more than one electrodeless ultraviolet lamp, and, pneumatic pump, this pneumatic pump is installed in the outside of reactor, ventilation interface on the described silica tube one end shutoff headkerchief connects with the air outlet of described pneumatic pump via the wall that breather line also sees through reactor, ventilation interface on its other end shutoff headkerchief of described silica tube connects with the micro porous aeration head that is positioned at reactor inner chamber lower region via another breather line, and, microwave generator, this microwave generator is installed in the outside of reactor, this microwave generator is magnetron, and, waveguide, this waveguide is the member for the transmission microwave, one end of this waveguide and described magnetron UNICOM, the other end of this waveguide sees through the inner chamber of the wall orientating reaction device of reactor, and, water pump, this water pump is positioned at the outside of reactor, and this water pump is used for the pending waste water of pumping, and its water outlet of this water pump leads to the inner chamber of this reactor, this reactor top offers exhaust port, emphasis is, that end of the wall that sees through reactor of this waveguide extends much further into the inner chamber of reactor, and, the structure of this reactor also comprises the microwave exposure spatial domain constrainer of the cage shape of metal material, be a mass of many holes or mesh in microwave exposure spatial domain its structure of constrainer of this cage shape, the function of the microwave exposure spatial domain constrainer of this cage shape is constraint microwave exposure spatial domain, and the microwave exposure spatial domain constrainer of the cage shape of this metal material is exactly a metal cage, this metal cage is installed in the inner chamber position of reactor, that port that gos deep into the reactor inner chamber of this waveguide and the inner chamber UNICOM of this metal cage, described UNICOM refers to connection and the perforation on the microwave channel meaning, and described silica tube is the inside that is erected at this metal cage, article two, described breather line all penetrates the wall of this metal cage, the locations of structures of the wall of this metal cage is the locations of structures between reactor wall and silica tube outer wall, and, topping-up pump, this topping-up pump is used for the degraded water afterwards that the supercharging pumping is mixed with a large amount of catalyst particles, its water-in of this topping-up pump connects with the inner chamber of described reactor via the wall that ventilating water pipe also sees through described reactor, and, the preposition prefilter of back flush type, its water-in of the preposition prefilter of this back flush type connects with the water outlet of described topping-up pump, and, back flush type tubular fibre membrane microfiltration strainer, its pure water inlet of the preposition prefilter of described back flush type connects via the water-in of first water purifying valve with this back flush type tubular fibre membrane microfiltration strainer, and, back flush type hollow-fibre membrane ultra filtration filter, described its pure water inlet of back flush type tubular fibre membrane microfiltration strainer connects via the water-in of second water purifying valve with this back flush type hollow-fibre membrane ultra filtration filter, and this its pure water inlet of back flush type hollow-fibre membrane ultra filtration filter connects with the entrance end of the 3rd water purifying valve, the water side of the 3rd water purifying valve is the water side of outlet terminal water purification, and, catalyst underflow transition jar, this catalyst underflow transition jar is the tank body of a hollow, this catalyst underflow transition jar is used for temporarily depositing the higher water body of catalyst concentration ratio that its backwashing procedures of described strainer discharges, be positioned at the catalyst underflow refluxing opening of this its intracavity bottom of catalyst underflow transition jar via the inner chamber of catalyst underflow reverse flow valve towards reactor, this catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control, and its sewage outlet of the preposition prefilter of described back flush type leads to the inner chamber of this catalyst underflow transition jar via first sewage valve, described its sewage outlet of back flush type tubular fibre membrane microfiltration strainer leads to the inner chamber of this catalyst underflow transition jar via second sewage valve, described its sewage outlet of back flush type hollow-fibre membrane ultra filtration filter leads to the inner chamber of this catalyst underflow transition jar via the 3rd sewage valve, and each described strainer is all be used to holding back catalyst particles, and each its sewage outlet of described strainer is all migrated and used delivery port again for the recovery of being held back catalyst particles, and, described many micro porous aeration heads are assembled formation cluster shape micro porous aeration head cluster mutually, and this cluster shape micro porous aeration head cluster is erected at the lower region of described reactor inner chamber vacantly, and the fore-and-aft distance of this cluster shape micro porous aeration head its bottom edge of cluster and described reactor inner chamber bottom surface is between 10 centimetres and 50 centimetres, the transverse distance of this cluster shape micro porous aeration head cluster edge and described reactor intracavity sidewall arround it is between 20 centimetres and 300 centimetres, this cluster shape micro porous aeration head its center of cluster or center of gravity be positioned at described silica tube under, and, ozone sensor, the sampling port of this its stopple coupon of ozone sensor is close to described exhaust port or probes into the inside of described exhaust port, and, the ozone content indicating meter, the composite structure of ozone attention device or ozone content indicating meter and ozone attention device, this ozone sensor is via article one cable and this ozone content indicating meter, ozone attention device or ozone content indicating meter connect with the composite structure of ozone attention device, and, power-supply controller of electric, its output electric signal of this ozone sensor connects with this power-supply controller of electric via the second cable, and this power-supply controller of electric connects with described magnetron via the 3rd cable, this power-supply controller of electric connects with described pneumatic pump via the 4th cable, this power-supply controller of electric is the power-supply controller of electric that can carry out the power switch action according to its described electric signal that receives, and, one group of ultrasonic transducer, this group of ultrasonic transducer contains a ultrasonic transducer individuality at least, this group of ultrasonic transducer is used for the radiation low-frequency ultrasonic waves, and this low-frequency ultrasonic waves refers to frequency in the ultrasonic wave of 20kHz-60kHz scope, and this reactor inner chamber bottom surface is hollow gradually to the central zone by periphery, described hollow its gradient is between 5 degree and 35 degree, this group of ultrasonic transducer is outer side position or the medial surface position that is installed in this its corresponding that part of reactor diapire in hollow innermost of reactor inner chamber bottom surface with attaching, and, HF oscillation electric signal transmission cable, one group of ultrasonic transducer of one end of this HF oscillation electric signal transmission cable and this connects, and, HF oscillation electric signal producer, the other end of described HF oscillation electric signal transmission cable connects with this HF oscillation electric signal producer, and, the pH probe, and, the pH analyser, this pH probe is coupled to each other with the pH analyser, this pH analyser and connect with warning horn, this warning horn is used for the pH value situation of transfiniting is given the alarm, and this pH probe stretches into the reactor inner chamber through the top of reactor, and, through the micropore stainless steel sleeve that powder sintering process is made, this micropore stainless steel sleeve is cap for brush shape, and this micropore stainless steel sleeve is positioned at the reactor inner chamber, this its blind end of micropore stainless steel sleeve down, this its opening end of micropore stainless steel sleeve up, this its opening end up of micropore stainless steel sleeve connects with reactor head via the buffering isolating pad, this pH its that part that stretches into the reactor inner chamber of popping one's head in probes within this micropore stainless steel sleeve, this its material of buffering isolating pad is viton or silicon rubber, and, two pairs of dry-reed type ball float level controllers, these two pairs of dry-reed type ball float level controllers all extend into the inner chamber of reactor through the top of reactor, a pair of dry-reed type ball float level controller wherein connects with the power cable of described water pump by a rly., wherein another connects with the power cable of described topping-up pump by another rly. the dry-reed type ball float level controller, and, tank, described back flush type tubular fibre membrane microfiltration strainer and the equal submergence of described back flush type hollow-fibre membrane ultra filtration filter are placed within this tank, be equiped with another group ultrasonic transducer at its sidewall of this tank or its bottom, this another group ultrasonic transducer contains a ultrasonic transducer individuality at least, and this another group ultrasonic transducer is used for the radiation high-frequency ultrasonic, this high-frequency ultrasonic refers to frequency in the ultrasonic wave of 100kHz-12MHz scope, and this another group ultrasonic transducer connects with another HF oscillation electric signal producer.

This catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control; The opening-closing valve of commercially available various fluid lines can be applicable to the needs of this locations of structures, and its concrete type selecting can determine as required.

Described dry-reed type ball float level controller, the art-recognized meanings of itself are known for the professional of fluid level controller manufacturing; Described dry-reed type ball float level controller market is on sale.

Described rly. market is on sale.

Valve body on all fluid passages of this case can select to use magnetic valve, selects to use under the situation of magnetic valve, is arranged on the control panel by long-range cable is concentrated, and so, can realize remote centralized control easily.

Related pH probe market is on sale; Described pH probe also claims the pH sensor; Itself art-recognized meanings of pH probe or day pH sensor is known.

Related pH analyser market is on sale; Itself art-recognized meanings of pH analyser is known.The pH that can utilize that any model made a general reference in this case pH analyser one word detects, picks up, shows the pH value information, and can externally export the instrument of pH associated electrical signal, sell on the market simple and easy or complicated but all meet the pH correlate meter of this basic demand it is various in style can be selected for use as required.

Related its thickness of buffering isolating pad is not limit; But, a preferable range is arranged, the preferable range of this its thickness of buffering isolating pad is between 1 millimeter to 8 millimeters.

Their own art-recognized meanings of related viton and related silicon rubber are known; Related viton and related silicon rubber, market is all on sale.

Related its wall thickness of micropore stainless steel sleeve is not limit; But, an associated preferable range is also arranged, the preferable range of this its wall thickness of micropore stainless steel sleeve is between 3 millimeters to 30 millimeters.

A related powder sintered word, the art-recognized meanings of itself is known for the professional of metallurgical technology field.

Related micropore stainless steel sleeve can be to the customization of relevant powder metallurgy specialized factory.

The cover tubular micropore Stainless Steel Filter that powder sintering process can be made is migrated and is the described micropore stainless steel of this case sleeve; The cover tubular micropore Stainless Steel Filter market that described powder sintering process is made is on sale.

The aperture of related its micropore of micropore stainless steel sleeve is not limit; But the aperture of this micropore also is that a preferable range is arranged, and the preferable range of this micropore size is between 0.5 micron to 50 microns.

This its opening end up of micropore stainless steel sleeve connects with described container top via the buffering isolating pad, refers to, and this connection is flexible connection, connects part at this, has described buffer compartment mediate from pad.

Described warning horn is the device that can send audio frequency caution message or optical frequency caution message according to its received electric signal; Itself art-recognized meanings of described warning horn is known; Described warning horn market is on sale.

Itself art-recognized meanings of ultrasonic transducer one word is known for the professional in ultrasonic technology field.

Itself art-recognized meanings of HF oscillation electric signal transmission cable one word also is known for the professional in ultrasonic technology field.

Ultrasonic transducer and HF oscillation electric signal transmission cable market are all on sale; Described ultrasonic transducer and HF oscillation electric signal transmission cable etc. also can be to ultrasonic transducer specialized factory and the customizations of cable specialized factory.

Itself art-recognized meanings of HF oscillation electric signal producer one word also is known for the professional in ultrasonic technology field; Various HF oscillation electric signal producer all has commercially available; Described HF oscillation electric signal producer also can customize to ultrasonic wave equipment specialized factory.

Related ozone sensor market is on sale; Also can customize to ozone sensor specialized factory as required.

Related ozone content monitor market is on sale; Also can customize to ozone content indicating meter specialized factory as required; Ozone sensor producer also sells matching used ozone content indicating meter usually.

Related ozone attention device refers to warn sound or caution flash of light or caution sound is combined with the caution flash phase mechanism that both being used for of having both at the same time warn; Ozone attention device market is on sale; Also can customize to ozone attention device specialized factory; Ozone sensor producer also can sell matching used ozone attention device usually.

Related this power-supply controller of electric is the power-supply controller of electric that can carry out the power switch action according to its described electric signal that receives; The power-supply controller of electric that can carry out power switch action according to its electric signal that receives is ripe, technique known only with regard to its circuit engineering itself; Described power-supply controller of electric market is on sale; Also can utilize commercially available power-supply controller of electric to change a social system as required; Described power-supply controller of electric also can be to the customization of power-supply controller of electric specialty manufacturers; Its professional manufacturers of the electron device of power-supply controller of electric and so on spreads all over the world.

Described metal material one word, the art-recognized meanings of itself is known.

Described magnetron, and, expression such as waveguide device, waveguide, waveguide are first-class, its art-recognized meanings is known for the professional of microwave technical field.Described magnetron, and waveguide etc. all have commercially available; Described magnetron, and waveguide etc. also can customize to specialized factory; Described waveguide is self manufacture as required, and this making is for the professional of microwave technical field, and the making of waveguide device is simple.

Described silica tube, its art-recognized meanings is known; Described silica tube market is on sale; Described silica tube also can customize to specialized factory.

Described electrodeless ultraviolet lamp, its art-recognized meanings are known for the professional of light sources technical field; Described electrodeless ultraviolet lamp market is on sale; Described its shape of electrodeless ultraviolet lamp, size, inner institute blanketing gas, lamp wall material, lamp wall thickness, etc., also can customize to electric light source manufacturing concern according to the specific design needs.Certainly, also can self manufacture.The making of electrodeless ultraviolet lamp is for the professional who possesses electric light source expertise, and its manufacturing technology is simple.

The described metal cage of this case can be the metal cage of being made by any metal material; But in view of the related strong oxidizing property condition of waste water degradation treatment, stainless steel is preferred material; The hole that spreads all in the metal cage self structure of this stainless steel or the preferable range of its bore of mesh are between 0.5 centimetre and 3.0 centimetres; Yet, if must select bore value outside this scope, also be that this case allows.

Preferred described metal cage can be through mold pressing, welding, riveted joint or complementary accessory splicing is made by screw, nut etc. metal cage by the stainless steel punched-plate.

Preferred described metal cage also can be the metal cage of being made by the Stainless Steel Wire braiding.

Use this case device, waste water in the reactor and by reactor inner chamber bottom bubbling on contain ozone-air and can see through numerous holes of metal cage or mesh and enter zone between metal cage and the silica tube, waste water with contain the photochemical catalysis oxidative degradation of ozone-air under this zone participates in the lump that microwave excitation is auxiliary and promotes, and be subjected to waste water after certain Degradation, numerous holes or the mesh that can freely see through metal cage are again outwards overflowed by metal cage is inner, so circularly, reciprocally, automatically constantly carrying out Degradation, the whole waste water until whole reactor inside all reach the degraded index.

Distance between the inwall of this case metal cage and the silica tube outer wall without limits, this distance can be distance arbitrarily; But the preferred value of the distance between the inwall of this metal cage and the outer wall of silica tube is between 3.0 centimetres and 30.0 centimetres.

The further preferred numerical range of the distance between the inwall of this metal cage and the outer wall of silica tube is between 10.0 centimetres and 20.0 centimetres.

In this case device, by means of isolation and the restriction of metal cage to the microwave exposure spatial domain, zone between metal cage outer wall and reactor wall, a microwave zero irradiation zone or the weak irradiation zone of microwave have been formed, because microwave can't have influence on this zone basically, microwave is contained because the simple pyrogenicity of waste water absorbs the unhelpful dissipation of energy that causes in this zone, and is like this, no matter should how to enlarge by the zone volume, all allow; Based on this, the structure of this case device, allow to expand significantly single jar of design capacity of described reactor, allow to expand significantly the volume of reactor, certainly, be to limit the microwave exposure spatial domain by metal cage, and significantly the design volume in the spatial domain between expanded metal cage and the reactor wall realize.Other factors, for example, itself particle diameter, preparation technology, catalysis efficiency etc. of the size of microwave exposure power, ultraviolet wavelength scope, UV-light light intensity, photochemical catalyst titanic oxide nano or employed various modified catalyst nano powder, all can have influence on the wastewater treatment ability of this case device, these are not the emphasis of this case yet.

Sewage draining exit can be offered in bottom at described reactor, and this sewage draining exit can be used for deslagging, remove contamination, and can install wash water valve in this sewage draining exit position, and described wash water valve is the valve for blowdown control.Described sewage draining exit and wash water valve are not necessarily.

Described water pump and topping-up pump all are the pumps for delivery of clear or turbid all kinds of water, and certainly, its pumping pressure can be selected as required arbitrarily, and various pump market is all on sale; Different titles are adopted in this case, just statement for convenience, the convenient pump of distinguishing each different structure position.

Described water purifying valve, sewage valve, wash water valve all are water valves, and various water valve market is all on sale; About water valve, itself art-recognized meanings of this word is known; Different titles is adopted in this case, just statement for convenience, the convenient water valve of distinguishing each different structure position.

The preferable range in its filter opening aperture of the preposition prefilter of described back flush type is between 5 microns and 300 microns, and certainly, it also is that this case allows that the preposition pre-filtering of other outside this preferable range aperture is selected; The preferable range in its filter opening aperture of described back flush type tubular fibre membrane microfiltration strainer is between 25 nanometers and 1000 nanometers, and certainly, it also is that this case allows that other micro-filtration aperture outside this preferable range is selected; The preferable range in its filter opening aperture of described back flush type hollow-fibre membrane ultra filtration filter is between 15 nanometers and 2 nanometers, and certainly, it also is that this case allows that other ultrafiltration aperture outside this scope is selected.

The preposition prefilter of described back flush type also claims back flush type fore filter or back flush type prefilter, and itself art-recognized meanings of the preposition prefilter of described back flush type is known; The preposition prefilter of described back flush type market is on sale.

Described back flush type tubular fibre membrane microfiltration strainer is the strainer that is suitable for micro-filtration; Itself art-recognized meanings of described micro-filtration one word is known; Itself art-recognized meanings of described back flush type tubular fibre membrane microfiltration strainer is known for the professional in membrane separation technique field; Described back flush type tubular fibre membrane microfiltration strainer market is on sale.

Described back flush type hollow-fibre membrane ultra filtration filter is the strainer that is suitable for ultrafiltration; Itself art-recognized meanings of described ultrafiltration one word is known; Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter is known for the professional in membrane separation technique field; Described back flush type hollow-fibre membrane ultra filtration filter market is on sale.

In the ultrafiltration link, this back flush type hollow-fibre membrane ultra filtration filter can be the form that a back flush type hollow-fibre membrane ultra filtration filter monomer is only arranged; Certainly, this back flush type hollow-fibre membrane ultra filtration filter also can be made up of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.

Express a related word in parallel, the art-recognized meanings that itself refers to is clearly.

Express related monomer one word, refer to itself function and structure equipment individuality completely.

Similarly, in the micro-filtration link, this back flush type tubular fibre membrane microfiltration strainer can be the form that a back flush type tubular fibre membrane microfiltration strainer monomer is only arranged; Certainly, this back flush type tubular fibre membrane microfiltration strainer also can be made up of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.

Can further install second topping-up pump on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration its pure water inlet of strainer and described back flush type hollow-fibre membrane ultra filtration filter, this second topping-up pump is used for augmenting hydraulic pressure to satisfy the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter; This second topping-up pump not necessarily.

The structure of this case device can also comprise some annexes, described annex for example: the cooling water recirculation system or the air cooling system that are connected with the magnetron cooling duct; Described annex is also for example for the fixed support that electrodeless ultraviolet lamp is fixed within the silica tube; Described annex for example is used for described metal cage is fixed on the support member within the reactor or hangs member again; Described annex can certainly comprise anchor or the suspension bracket that described silica tube is carried out unsettled location within described metal cage; Described annex for example is installed in the strainer that is used for interception impurity of reactor influent waste water end again, etc.

Advantage of the present invention is, with metal cage electrodeless ultraviolet lamp and screen thereof are protected with silica tube and to shroud in it, metal cage retrains the effect spatial domain of microwave simultaneously, so, spatial domain between silica tube outer wall and metal cage inwall has formed a microwave excitation fill-in light chemical catalysis waste water degraded areas, and, the multiple hole of metal cage or the structure of many meshes, do not influence waste water and reactor the below bubbling and on the air freedom into and out of this spatial domain; And the spatial domain between metal cage and reactor wall, the waste water water body is contained the unhelpful dissipation of the microwave energy that significantly weakened thus to the simple pyrogenicity absorption of microwave; By significantly expanding the design volume in irradiation spatial domain a little less than this microwave zero irradiation spatial domain or the microwave, can realize the significantly expansion of single jar of reactor volume, allow single jar of wastewater treatment capacity of reactor significantly to promote, and need not worry again that microwave energy dissipates too much in unhelpful waste water water body temperature-rise effect.

Based on this case structure, the Design of device volume is that single jar of wastewater treatment capacity can be expanded to several cubes to dozens of cube; Even single jar hundreds of cubes volume, also allow; Based on this structure of this case, can reduce the frequency of a complete set, substantial length of operation significantly, be conducive to the saving of human and material resources.

This case has been reached the target that photochemical catalysis waste water DeR device design capacity is significantly expanded taking into account under the auxiliary prerequisite of described microwave excitation.

This case device is among its operation, its high-density ascension bubble flow that discharges of described cluster shape micro porous aeration head cluster, in the ascension that makes progress, and wrapped folder, carry, guided liquid-flow, form a kind of motion that is similar to the fountain form, in this kind motion, the high-density bubble flow wrapped folder that is derived from described cluster shape micro porous aeration head cluster liquid to the metal cage region gush and on, and then relatively the concentrated area is impacted in the metal cage, outer close position, be subjected to described high-density bubble flow wrapped folder, the liquid stream that carries is impacting, in metal cage, after the outer close position, by the liquid layer of top area to around diffusion, sink via the neighboring area, arrive reactor intracavity bottom zone, again through the wrapped folder of described its high-density ascension bubble flow that discharges of cluster shape micro porous aeration head cluster, carry, continue the motion that it is similar to the fountain form, so circulation endlessly; The liquid circulation campaign of this relative big scale that is guided helps to guarantee the homogenizing of inside reactor liquid degradation reaction process, and this is necessary for large-scale electrodeless ultraviolet light catalysis DeR device.

Its UV source of this case structure is to rely on microwave excited electrodeless ultraviolet lamp, the uv-radiation characteristics of this lamp type can be accomplished high-power, high strength exactly, yet the Effective depth penetration of ultraviolet ray in liquid water body has only about 20 centimetres, therefore, zone within about 20 cm distance of silica tube periphery is the effective area of photochemical catalysis oxidative degradation, and this zone also is simultaneously the efficient zone of microwave excitation promotion and the coupling of photochemical catalysis oxidative degradation; Partly or entirely being coated by permeable, the ventilative also metal cage of printing opacity of this effective area; This case method is to be positioned at the described cluster shape micro porous aeration head cluster under the metal cage, come the concentrated area to discharge highdensity ascension bubble flow, make its as concentrated area as the fountain towards as described in the effective area discharge, the oxygen atmosphere that this method helps to improve described effective area is supplied with intensity, helps the accelerated degradation reaction process.

Based on this case structure, the capacity of reactor or treatment capacity can significantly be expanded, described significantly expansion, be that the design volume of irradiation zone realizes a little less than microwave zero irradiation zone or the microwave by significantly expanding, so, the lateral dimension of reactor, longitudinal size all is significantly to expand certainly, therefore, inside reactor is contained the liquid degree of depth and can be deepened significantly similarly, for example, can deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc., containing the liquid degree of depth enough under the dark situation, contain ozone-air bubble ascension path sufficiently long, contain the time sufficiently long that the ozone-air bubble contacts with water body, in its ascension process just can with abundant reducing substances fortune, and thoroughly or be close to and exhaust ozone contained in the bubble up hill and dale, thus, contain that ozone composition oxidation potential utilizes incomplete problem to be solved in the ozone-air bubble, and, because long ascension path causes ozone to exhaust, just can not be entrained with the ozone that can cause environmental pollution again in the reactor tail gas.

This case structure is with external multistage filter, reach the interception step by step from the collision fragment of the small scale of coacervate macrobead to ten number nanometers to catalyst particles, be close to recovery, reuse photocatalyst up hill and dale, be close to the secondary pollution of taking precautions against catalyst loss up hill and dale and causing; This is tackled scheme step by step and can protect secondary filter to make its filtration passage avoid the rigid obstruction of large particulate matter; Wherein the pre-filtering aperture of the first step is between 5 microns and 300 microns, and its aperture of partial micro-filtration is between 25 nanometers and 1000 nanometers, and its aperture of the ultrafiltration of the third stage is between 15 nanometers and 2 nanometers; Such interception scheme can fully be tackled nano level photocatalyst, and it can be close to certainly and tackle this median size of gas phase titanium dioxide P25 up hill and dale is the catalyzer of 21 nanometers; Preamble is addressed, the gas phase titanium deoxide catalyst of nano level P25 and so on, it is the commercially available catalyzer that to buy in a large number, also be weather resistance, stability, the known good photocatalyst of UV-light wave band photocatalysis performance, certainly, it also is in fact to pay the utmost attention to the photocatalyst of selecting for use in the industrial scale applications; This case catalyzer interception scheme is complementary with the virtual rating of catalyzer market supply, actual kind, merges mutually.

And, in this case, catalyzer interception mechanism is external mechanism, and based on this structure, its filter core needn't be soaked in the liquid of the strong oxidation of inside reactor, strong uv irradiation, therefore, can needn't consider the tolerance to uv irradiation, strong oxidizing condition fully, like this, just not have restriction aspect the extraordinary tolerance selecting for use of filter core material, can select in more vast optional material kind, and need not be confined to the material of the PVDF and so on of comparison costliness fully again.

Related strainer at different levels all has commercially available, commercially available strainers at different levels, the discharge outlet of draining-off sewage when its sewage draining exit is exactly back flushing, this class back flush type equipment is used in this case, be to tackle catalyst particles step by step, originally the sewage draining exit of commercially available relevant device, the recovery that is used as being held back catalyst particles in this case by migrating are again with delivery port or reflux and use delivery port again.

Above address, based on this case structure, the capacity of reactor or treatment capacity can significantly be expanded, described significantly expansion, be that the design volume of irradiation zone realizes a little less than microwave zero irradiation zone or the microwave by significantly expanding, so, from in appearance, the lateral dimension of reactor, longitudinal size all is significantly to expand certainly, therefore, inside reactor is contained the liquid degree of depth and can be deepened significantly similarly, for example, can deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc., containing the liquid degree of depth enough under the dark situation, contain ozone-air bubble ascension path sufficiently long, contain the time sufficiently long that the ozone-air bubble contacts with water body, in its ascension process just can with abundant reducing substances fortune, and thoroughly or be close to and exhaust ozone contained in the bubble up hill and dale, thus, contain that ozone composition oxidation potential utilizes incomplete problem to be solved in the ozone-air bubble, and, because long ascension path causes ozone to exhaust, just can not be entrained with the ozone that can cause environmental pollution again in the reactor tail gas; Only ought be subject to processing that reducing substances is in organic pollutant is degraded totally in the water body, not had in the water body can be for the organic pollutant of ozone oxidation reaction again, and those redundant ozone just might no longer consume and see through long ascension path effusion liquid level; The front is spoken of, among some problems that this case solves simultaneously one, it is the circulation of the relative big scale of enhanced reactor internal liquid, this systemic circulation mechanism of having strengthened has been facilitated the uniformity of inside reactor liquid its contained organic pollutant degradation reaction process, thus, at several cubes that this case structure allows to the processing capacity framework of dozens of cube even hundreds of cube volume, above the inside reactor liquid level, have in the ozone effusion, the DeR that namely shows inside reactor has reached terminal point, and be the terminal point that the whole uniformity of internal liquid ground reaches DeR, this terminal point determining factor is that the condition that can provide with this case organization plan is complementary; This case is at its exhaust port position installing ozone sensor of reactor, detect ozone in this locations of structures, just mean that the inside reactor DeR reaches home, ozone sensor and connect with the composite structure of ozone content indicating meter with ozone attention device or ozone content indicating meter or ozone attention device, be used for providing indication information accurately to operator, this case and the electric signal that ozone sensor is exported send power-supply controller of electric to by cable, this power-supply controller of electric also connects with magnetron and pneumatic pump respectively by cable, power-supply controller of electric carries out the power switch action according to its received described electric signal, certainly, its function mode is, receive in the signal that ozone that ozone sensor sends overflows at power-supply controller of electric, close the power supply that leads to magnetron and pneumatic pump automatically; This case is organization plan according to this, can in time know the terminal point of inside reactor DeR process; And organization plan according to this, when reaction reaches terminal point, close the power supply of magnetron and pneumatic pump automatically, in time stop to inject energy to inside reactor, so can avoid unnecessary energy dissipation; And, this case is structure according to this, in DeR reaches home, can in time close the power supply of described magnetron and pneumatic pump, this power-off action has also stopped the generation process of ozone synchronously, together in a flash, because ozone generation process is in time stopped, just do not have above a large amount of ozone that need and disengage from described exhaust port, thereby avoided unnecessary secondary pollution or day secondary pollution; Its framework of this case has determined it not have ozone more than needed can supply discharging.

Among this case structure, the microwave exposure spatial domain of its inside reactor is subjected to forcing to cut off, limit, this case and adopt the multistage backwash filter structure of external cascade to tackle catalyst particles subtly, back flush type hollow fiber microfiltration membrane assembly wherein and back flush type polysulfone hollow fiber ultrafiltration membrane system are all external and away from reactor core, microwave can not shine described membrane module fully, based on this structure of this case, got around described point-like fully and pierced the heat penetration erosion destruction problem of formula, this problem is settled properly thus.

This case reactor inner chamber bottom surface is hollow gradually to the central zone by periphery, described hollow its gradient is between 5 degree and 35 degree, and this case ultrasonic transducer is outer side position or the medial surface position that is installed in this its corresponding that part of reactor diapire in hollow innermost of reactor inner chamber bottom surface with attaching; Above address, this case structure and be beneficial to the cyclic motion that driving a reaction device internal liquid is made relative big scale, the mode of this liquid circulation campaign are that peripheral liquid sinks, and middle liquid rises, and so constantly moves in circles; Above address, under some pH value was regulated not in place, the inappropriate situation of pH value in advance, titanium dioxide fine particles was reunited easily, and then influences its effective working interface area, influences its photochemical catalysis usefulness; Especially among this particle size range those relatively than the section of small particle size,, the pH value incorrect agglomeration traits that cause not in place because of pH value preset appears especially easily; For the situation that this catalyst particles is reunited, be immediately to adopt an effective measure, carry out the depolymerization running at coacervate; Take place under the serious situation of reuniting at catalyst particles, the macro aggregate that wherein some are heavier is because action of gravity, tend to gradually to the sedimentation of reactor intracavity bottom, in this case structure, the reactor intracavity bottom is hollow structure, and, this case structure can driving a reaction device internal liquid be made the cyclic motion of described relative big scale, the effect of this systemic circulation campaign is together with the effect of ubiquitous natural gravity, the macro aggregate of sedimentation pushes away along the slope of described hollow structure and sweeps to hollow innermost and make them accumulate in the there, ultrasonic transducer is positioned at this hollow innermost locations of structures just in this case structure, this hollow innermost zone, being the final zone of assembling of described macro aggregate, also is that ultrasonic wave can be damply minimum simultaneously, closest range ground, the most consumingly, carry out depolymerization running zone at macro aggregate most effectively; This structure of this case can allow the ultrasonic energy loss with minimum, realizes maximized ultrasonic depolymerization effect; This case is structure according to this, can converge the coacervate sediment, and in the most concentrated zone of coacervate sediment, implements the depolymerization running; Be derived from certain other zone that also can be radiated simultaneously in the inside reactor liquid of ultrasonic wave of reactor bottom, those smaller coacervates that still are in suspended state are being brought into play unzipping; This case associated ultrasonic radiation mechanism is the mechanism that can start as required or close; This case has realized disposing at the instant original position of this catalyst particles agglomeration traits thus.

Be used for the silica tube that screen protects electrodeless ultraviolet lamp in the structure, its outer wall, refer to the outer wall of silica tube, through for a long time with the contacting of processed trade effluent, incrustation gradually unavoidably, the long-pending material of dirt mainly is to be difficult for by the mineral-type impurity that light-catalyzed reaction touched certainly, and the incrustation phenomenon because this mechanism forms is easy to be observed after the equipment long-play; Be attached to the dirty lamination of described silica tube outer wall, though be very thin one deck, also be enough to ultraviolet radiation to electrodeless ultraviolet lamp and cause significantly and stop, this will cause the actual treatment of this microwave and photo catalysis reaction treating device to be renderd a service significantly reducing; Be positioned at the ultrasonic transducer of reactor bottom in this case structure, among the depolymerization running that the irregular situation of seriously reuniting at accidental catalyst particles is carried out, the ultrasonic wave of its radiation, certainly also can arrive silica tube place locations of structures, this ultrasonic wave is also being carried out the ultrasonic clean scale removal work at the long-pending thing of silica tube surface dirt in the lump when carrying out original position depolymerization running; And, the installation position of ultrasonic transducer is away from silica tube place locations of structures, decay to some extent when ultrasonic radiation arrives the silica tube position, therefore, the suffered ultrasonic impact in silica tube surface is low intensive ultrasonic impact, this low intensive ultrasonic impact scale removal leniently, can avoid again or significantly weaken ultrasonic cavitation its silica tube surface smoothness loss that may cause; Based on this structure of this case, can under the prerequisite of not tearing machine open, remove the dirty lamination on this silica tube outer wall immediately, effectively, safeguard the high-level efficiency that continues of this microwave and photo catalysis DeR device by this.

The pH value of the inner water body of waste water DeR device is the key factor that influences the catalyst dispersion stabilization; PH probe and related pH value display instrument and the warning horn that is associated etc. installed in this case structure, can exceed under the situation of catalyst stably dispersing scope in the pH value, initiatively give the alarm, based on this structure of this case, relating operation personnel awareness immediately inside reactor catalyst is reunited and is inclined to, and makes instant disposal.Described micropore stainless steel sleeve and installing mode thereof in this case structure are the indispensable important components that is complementary with this case principle and this case structure.

Membrane module in this case structure, be to be in all the time among the operating mode of complete submergence use, the ingress of air of having no chance of membrane module wherein, the state that always keeps hygrometric state and complete submergence, therefore, do not have again the membrane module that occurs easily in the sort of background technology often to be exposed to airborne situation, its applying working condition of membrane module in this case structure meets itself intrinsic working conditions requirement of membrane module more, be more conducive to safeguard its normal use properties of membrane module, be more conducive to guarantee membrane module its normal work-ing life.

Catalyst underflow transition jar is set in this case structure, be used for temporarily depositing from each its backwashing procedures of back flush type strainer wash away and come contain the higher liquid of catalyst concentration ratio, thereby avoid the liquid that this catalyst concentration ratio is higher directly to irritate back reactor, so, avoided the problem that catalyst concentration progressively raises along with the extraction process of water purification in the inside reactor liquid, this extracts for its follow-up water purification and reduce the heavy burdens, so catalyst underflow transition jar structure has been arranged, just can after finishing, the water purification extraction procedure again the catalyst underflow be irritated back within the reactor.

A pair of in this case structure sees through the dry-reed type ball float level controller that rly. connects with its power cable of water pump of described transport wastewater, and its existence can be avoided excessive filling waste water to the reactor inner chamber automatically, and avoid waste water to overflow reactor thus; Another is to seeing through the dry-reed type ball float level controller that another rly. connects with its power cable of described topping-up pump, its existence, can avoid the liquid of inside reactor to be caused this topping-up pump idle running, the dried commentaries on classics by excessive the extraction, so can avoid booster motor to burn.

Any valve body on all fluid channels in this case structure can select to use magnetic valve, these cables can be concentrated to be routed on the panel, and this structure allows remote centralized to control the corresponding valve body switch motion of each program.

In this case structure, described back flush type tubular fibre membrane microfiltration strainer and described back flush type hollow-fibre membrane ultra filtration filter all are submerged and are placed within the described tank, be equiped with another group ultrasonic transducer at its sidewall of described tank or its bottom, this another group ultrasonic transducer is used for the radiation high-frequency ultrasonic, this high-frequency ultrasonic refers to frequency in the ultrasonic wave of 100kHz-12MHz scope, and this another group ultrasonic transducer connects with another HF oscillation electric signal producer; In this case membrane module back flushing operation procedure, by means of there not being the extremely weak described high-frequency ultrasonic of cavitation damage or cavitation damage, can more mildly assist backwashing procedures to remove those obstinate catalyst that adheres on the membrane module working interface.

In brief, this case utilizes metal cage to retrain microwave more closely, has reached the target that allows the reactor design capacity significantly to expand; Simultaneously, its scheme has also been strengthened the cyclic motion of the relative big scale of inside reactor liquid; This scheme and to be set up in described its highdensity bubble flow that is discharged of cluster shape micro porous aeration head cluster under the metal cage realizes the significantly lifting at the oxygen supply concentration degree in emphasis DeR district; This scheme and reached at the nm-class catalyst particulate from the collision fragment of its coacervate macrobead to ten number nanometers widely, meticulous interception; Based on this organization plan, its filter core Material Selection face also thereby enlarged; Its DeR endpoint information can in time be known; Can close the energy input to reactor in its DeR terminal point automatically; In its DeR terminal point, also automatically in time stop the generation process of ozone, avoided unnecessary secondary pollution; Its structure and immediately original position dispose the accidental catalyst particles situation of seriously reuniting, also incidentally clean described silica tube surface with the ultrasonic wave through the low intensive gentleness after the reduction of teletransmission appropriateness simultaneously, keep its good UV-light transparent performance; Its structure also can initiatively be detected catalyst reunion tendency, and gives the alarm when correlation parameter exceeds standard; Its structure also is conducive to membrane module and is using among the submergence operating mode fully; Its structure and realize that by catalyst underflow transition jar structure the appropriate transition of catalyst underflow deposits has overcome the excessive problem of difference before and after the membrane sepn load; Its structure and can realize the automatic control of waste water perfusion water level; Its structure also can be extracted in the institute position of restricting water supply at water purification, closes the power supply of described topping-up pump automatically, in time, is beneficial to the protection of booster motor; Its structure and the catalyst that adheres to stubbornness on the low cavitation high-frequency ultrasonic assistance backwashing procedures releasing membrane interface.

This case has solved described serial problem totally.

Description of drawings

Fig. 1 is the brief perspective diagram of this case apparatus structure.

Among the figure, the 1st, reactor, the 2nd, the microwave exposure spatial domain constrainer of cage shape, it is exactly a metal cage, the 3rd, silica tube, the 4th, electrodeless ultraviolet lamp, 5,12 is respectively two shutoff headkerchieves of silica tube, the 6th, exhaust port, the 7th, waveguide, the 8th, magnetron, the 9th, pneumatic pump, 10,14 is respectively the different breather line in two-strip structure position, the rough position of inner waste water liquid level when 11 sign reactors are contained the liquid operation, the 13rd, irradiation zone a little less than zero irradiation zone of the microwave between metal cage outer wall and the reactor wall or microwave, the 15th, micro porous aeration head, the 16th, wash water valve, the 17th, sewage draining exit, the 18th, back flush type hollow-fibre membrane ultra filtration filter, the 19th, back flush type tubular fibre membrane microfiltration strainer, the 20th, the preposition prefilter of back flush type, the 21st, topping-up pump, the 22nd, water pump, the 23rd, the stopple coupon of ozone sensor, the 24th, the ozone content indicating meter, the composite structure of ozone attention device or ozone content indicating meter and ozone attention device, the 25th, ozone sensor, the 26th, power-supply controller of electric, the 27th, ultrasonic transducer, the 28th, HF oscillation electric signal transmission cable, the 29th, warning horn, the 30th, with the cable that pH analyser and warning horn link up, the 31st, pH analyser, the 32nd, the cable that pH analyser and pH probe is linked up, the 33rd, pH probe, the 34th, micropore stainless steel sleeve, the 35th, catalyst underflow transition jar, the 36th, catalyst underflow reverse flow valve, the some arrows among the figure are indicated the liquid flow direction of its contiguous pipeline when being in on-state.

Embodiment

In this case embodiment that Fig. 1 shows, the structure of this example device comprises reactor 1, and this reactor 1 is the container of a hollow, this reactor 1 its appearance profile is cube shaped, cuboid, the cylinder bodily form, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form are equiped with many micro porous aeration heads 15 at the lower region of this reactor 1 inner chamber, and mark 15 only is to indicate the micro porous aeration head individuality, 15 only indicate the individual morphology of micro porous aeration head, and, silica tube 3, this silica tube 3 is erected at the inner chamber position of described reactor, and the two ends of this silica tube 3 are equiped with shutoff headkerchief 5,12, lay respectively at the described shutoff headkerchief 5 at silica tube 3 two ends, all offer the ventilation interface on 12, and, electrodeless ultraviolet lamp 4, this electrodeless ultraviolet lamp 4 is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, the quantity of this electrodeless ultraviolet lamp 4 is at least more than one, and this quantity all is erected at the inside of described silica tube 3 at least at more than one electrodeless ultraviolet lamp 4, and, pneumatic pump 9, this pneumatic pump 9 is installed in the outside of reactor 1, and the ventilation interface on the described silica tube 3 one end shutoff headkerchieves 5 connects with the air outlet of described pneumatic pump 9 via the wall that breather line 10 also sees through reactor 1, ventilation interface on described silica tube 3 its other end shutoff headkerchieves 12 connects with the micro porous aeration head 15 that is positioned at reactor 1 inner chamber lower region via another breather line 14, and, microwave generator, this microwave generator is installed in the outside of reactor 1, this microwave generator is magnetron 8, and waveguide 7, this waveguide 7 are the members for the transmission microwave, one end of this waveguide 7 and described magnetron 8 UNICOMs, the other end of this waveguide 7 sees through the inner chamber of the wall orientating reaction device 1 of reactor 1, and, water pump 22, this water pump 22 is positioned at the outside of reactor 1, this water pump 22 is used for the pending waste water of pumping, and these water pump 22 its water outlets lead to the inner chamber of this reactor 1, and this reactor 1 top offers exhaust port 6, emphasis is, that end of the wall that sees through reactor 1 of this waveguide 7 extends much further into the inner chamber of reactor 1, and the structure of this reactor 1 also comprises the microwave exposure spatial domain constrainer 2 of the cage shape of metal material, be a mass of many holes or mesh in microwave exposure spatial domain constrainer 2 its structures of this cage shape, the function of the microwave exposure spatial domain constrainer 2 of this cage shape is constraint microwave exposure spatial domain, and the microwave exposure spatial domain constrainer 2 of the cage shape of this metal material is exactly a metal cage, and this metal cage 2 is installed in the inner chamber position of reactor 1, that port that gos deep into reactor 1 inner chamber of this waveguide 7 and the inner chamber UNICOM of this metal cage 2, described UNICOM refers to connection and the perforation on the microwave channel meaning, and described silica tube 3 is the inside that is erected at this metal cage 2, two described breather lines 10,14 all penetrate the wall of this metal cage 2, the locations of structures of the wall of this metal cage 2 is the locations of structures between reactor 1 inwall and silica tube 3 outer walls, and, topping-up pump 21, this topping-up pump 21 is used for the degraded water afterwards that the supercharging pumping is mixed with a large amount of catalyst particles, these topping-up pump 21 its water-ins connect with the inner chamber of described reactor 1 via the wall that ventilating water pipe also sees through described reactor 1, and, the preposition prefilter 20 of back flush type, preposition prefilter 20 its water-ins of this back flush type connect with the water outlet of described topping-up pump 21, and, back flush type tubular fibre membrane microfiltration strainer 19, preposition prefilter 20 its pure water inlets of described back flush type connect via the water-in of first water purifying valve with this back flush type tubular fibre membrane microfiltration strainer 19, and, back flush type hollow-fibre membrane ultra filtration filter 18, described back flush type tubular fibre membrane microfiltration strainer 19 its pure water inlets connect via the water-in of second water purifying valve with this back flush type hollow-fibre membrane ultra filtration filter 18, and these back flush type hollow-fibre membrane ultra filtration filter 18 its pure water inlets connect with the entrance end of the 3rd water purifying valve, and the water side of the 3rd water purifying valve is the water side of outlet terminal water purification, and, catalyst underflow transition jar 35, this catalyst underflow transition jar 35 is tank bodies of a hollow, this catalyst underflow transition jar 35 is used for temporarily depositing described strainer 18,19, the higher water body of catalyst concentration ratio that 20 its backwashing procedures discharge, the catalyst underflow refluxing opening that is positioned at these catalyst underflow transition jar 35 its intracavity bottoms leads to the inner chamber of reactor 1 via catalyst underflow reverse flow valve 36, this catalyst underflow reverse flow valve 36 is the valve bodies for this catalyst return flow line of on-off control, and preposition prefilter 20 its sewage outlet of described back flush type are via first sewage valve and the inner chamber that leads to this catalyst underflow transition jar 35, and described back flush type tubular fibre membrane microfiltration strainer 19 its sewage outlet lead to the inner chamber of this catalyst underflow transition jar 35 via second sewage valve, described back flush type hollow-fibre membrane ultra filtration filter 18 its sewage outlet lead to the inner chamber of this catalyst underflow transition jar 35 via the 3rd sewage valve, each described strainer is all be used to holding back catalyst particles, each described strainer 20,19,18 its sewage outlet are all migrated and are used delivery port again for the recovery of being held back catalyst particles, and, described many micro porous aeration heads 15 are assembled formation cluster shape micro porous aeration head cluster mutually, this cluster shape micro porous aeration head cluster is erected at the lower region of described reactor 1 inner chamber vacantly, and the fore-and-aft distance of this cluster shape micro porous aeration head its bottom edge of cluster and described reactor 1 inner chamber bottom surface is between 10 centimetres and 50 centimetres, and any set point value within this fore-and-aft distance scope all is available enforcement value, for example this fore-and-aft distance can be 10 centimetres, 20 centimetres, 30 centimetres, 40 centimetres, 50 centimetres, etc., the transverse distance of this cluster shape micro porous aeration head cluster edge and described reactor intracavity sidewall arround it is between 20 centimetres and 300 centimetres, and any set point value within this transverse distance scope all is available enforcement value, for example this transverse distance can be 20 centimetres, 60 centimetres, 100 centimetres, 160 centimetres, 250 centimetres, 300 centimetres, etc., this cluster shape micro porous aeration head its center of cluster or center of gravity be positioned at described silica tube under, and, ozone sensor 25, the sampling port of these ozone sensor 25 its stopple coupons 23 is close to described exhaust port 6 or probes into the inside of described exhaust port 6, and, the ozone content indicating meter, the composite structure 24 of ozone attention device or ozone content indicating meter and ozone attention device, this ozone sensor 25 is via article one cable and this ozone content indicating meter, ozone attention device or ozone content indicating meter connect with the composite structure 24 of ozone attention device, and, power-supply controller of electric 26, these ozone sensor 25 its output electric signals connect with this power-supply controller of electric 26 via the second cable, this power-supply controller of electric 26 connects with described magnetron 8 via the 3rd cable, this power-supply controller of electric 26 connects with described pneumatic pump 9 via the 4th cable, and this power-supply controller of electric 26 is the power-supply controller of electric that can carry out the power switch action according to its described electric signal that receives, and, one group of ultrasonic transducer 27, this group of ultrasonic transducer 27 contains a ultrasonic transducer individuality at least, and this one group of ultrasonic transducer 27 is used for the radiation low-frequency ultrasonic waves, and this low-frequency ultrasonic waves refers to frequency in the ultrasonic wave of 20kHz-60kHz scope, this reactor 1 inner chamber bottom surface is hollow gradually to the central zone by periphery, described hollow its gradient is between 5 degree and 35 degree, and this group of ultrasonic transducer 27 is outer side position or the medial surface positions that are installed in this its corresponding that part of reactor diapire in hollow innermost of reactor 1 inner chamber bottom surface with attaching, and what the ground of meaning shown in the legend was showed is the situation that is installed in the outer side position, there is not to show the situation that is installed in the medial surface position in the legend, and, HF oscillation electric signal transmission cable 28, one group of ultrasonic transducer 27 of an end of this HF oscillation electric signal transmission cable 28 and this connects, and, HF oscillation electric signal producer, the other end of described HF oscillation electric signal transmission cable 28 connects with this HF oscillation electric signal producer, and, pH probe 33, and, pH analyser 31, this pH probe 33 is coupled to each other with pH analyser 31, this pH analyser 31 and connect with warning horn 29, this warning horn 29 is used for the pH value situation of transfiniting is given the alarm, and reactor 1 inner chamber is stretched at the top that this pH probe 33 sees through reactor 1, and, the micropore stainless steel sleeve of making through powder sintering process 34, this micropore stainless steel sleeve 34 is cap for brush shape, and this micropore stainless steel sleeve 34 is positioned at reactor 1 inner chamber, and these micropore stainless steel sleeve 34 its blind ends down, these micropore stainless steel sleeve 34 its opening ends up, these micropore stainless steel sleeve 34 its opening ends are not up drawn that described buffering isolating pad via buffering isolating pad and reactor 1 top attachment in the legend, these pH probe 33 its those parts that stretch into reactor 1 inner chamber probe within this micropore stainless steel sleeve 34, this its material of buffering isolating pad is viton or silicon rubber, and, two pairs of dry-reed type ball float level controllers, these two pairs of dry-reed type ball float level controllers all extend into the inner chamber of reactor 1 through the top of reactor 1, a pair of dry-reed type ball float level controller wherein connects with the power cable of described water pump 22 by a rly., wherein another connects with the power cable of described topping-up pump 21 by another rly. the dry-reed type ball float level controller, and, tank, described back flush type tubular fibre membrane microfiltration strainer 19 and the 18 equal submergences of described back flush type hollow-fibre membrane ultra filtration filter are placed within this tank, be equiped with another group ultrasonic transducer at its sidewall of this tank or its bottom, this another group ultrasonic transducer contains a ultrasonic transducer individuality at least, and this another group ultrasonic transducer is used for the radiation high-frequency ultrasonic, this high-frequency ultrasonic refers to frequency in the ultrasonic wave of 100kHz-12MHz scope, and this another group ultrasonic transducer connects with another HF oscillation electric signal producer.

Do not draw this tank in the legend.

This catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control; The opening-closing valve of commercially available various fluid lines can be applicable to the needs of this locations of structures, and its concrete type selecting can determine as required.

Described dry-reed type ball float level controller, the art-recognized meanings of itself are known for the professional of fluid level controller manufacturing; Described dry-reed type ball float level controller market is on sale.

Described rly. market is on sale.

Valve body on all fluid passages of this case can select to use magnetic valve, selects to use under the situation of magnetic valve, is arranged on the control panel by long-range cable is concentrated, and so, can realize remote centralized control easily.

Do not draw described dry-reed type ball float level controller in the legend.

Do not draw this HF oscillation electric signal producer and described another HF oscillation electric signal producer in the legend.

Related pH probe market is on sale; Described pH probe also claims the pH sensor; Itself art-recognized meanings of pH probe or day pH sensor is known.

Related pH analyser market is on sale; Itself art-recognized meanings of pH analyser is known.The pH that can utilize that any model made a general reference in this case pH analyser one word detects, picks up, shows the pH value information, and can externally export the instrument of pH associated electrical signal, sell on the market simple and easy or complicated but all meet the pH correlate meter of this basic demand it is various in style can be selected for use as required.

Related its thickness of buffering isolating pad is not limit; But, a preferable range is arranged, the preferable range of this its thickness of buffering isolating pad is between 1 millimeter to 8 millimeters.

Their own art-recognized meanings of related viton and related silicon rubber are known; Related viton and related silicon rubber, market is all on sale.

Related its wall thickness of micropore stainless steel sleeve is not limit; But, an associated preferable range is also arranged, the preferable range of this its wall thickness of micropore stainless steel sleeve is between 3 millimeters to 30 millimeters.

A related powder sintered word, the art-recognized meanings of itself is known for the professional of metallurgical technology field.

Related micropore stainless steel sleeve can be to the customization of relevant powder metallurgy specialized factory.

The cover tubular micropore Stainless Steel Filter that powder sintering process can be made is migrated and is the described micropore stainless steel of this case sleeve; The cover tubular micropore Stainless Steel Filter market that described powder sintering process is made is on sale.

The aperture of related its micropore of micropore stainless steel sleeve is not limit; But the aperture of this micropore also is that a preferable range is arranged, and the preferable range of this micropore size is between 0.5 micron to 50 microns.

This its opening end up of micropore stainless steel sleeve connects with described container top via the buffering isolating pad, refers to, and this connection is flexible connection, connects part at this, has described buffer compartment mediate from pad.

Described warning horn is the device that can send audio frequency caution message or optical frequency caution message according to its received electric signal; Itself art-recognized meanings of described warning horn is known; Described warning horn market is on sale.

Described hollow its gradient enforcement value is that any set point value within this gradient scope all is the operable enforcement value that this case allows between 5 degree and 35 degree; This hollow its gradient enforcement value for example can be 5 degree, 8 degree, 10 degree, 15 degree, 20 degree, 25 degree, 30 degree, 35 degree, etc.

Itself art-recognized meanings of related ultrasonic transducer one word is known for the professional in ultrasonic technology field.

Itself art-recognized meanings of related HF oscillation electric signal transmission cable one word also is known for the professional in ultrasonic technology field.

Related ultrasonic transducer and HF oscillation electric signal transmission cable market are all on sale; Described ultrasonic transducer and HF oscillation electric signal transmission cable etc. also can be to ultrasonic transducer specialized factory and the customizations of cable specialized factory.

Itself art-recognized meanings of related HF oscillation electric signal producer one word also is known for the professional in ultrasonic technology field; Various HF oscillation electric signal producer all has commercially available; Described HF oscillation electric signal producer also can customize to ultrasonic wave equipment specialized factory.

Related ozone sensor 25 markets are on sale; Also can customize to ozone sensor specialized factory as required.

Related ozone content monitor market is on sale; Also can customize to ozone content indicating meter specialized factory as required; Ozone sensor producer also sells matching used ozone content indicating meter usually.

Related ozone attention device refers to warn sound or caution flash of light or caution sound is combined with the caution flash phase mechanism that both being used for of having both at the same time warn; Ozone attention device market is on sale; Also can customize to ozone attention device specialized factory; Ozone sensor producer also can sell matching used ozone attention device usually.

Related this power-supply controller of electric 26 is the power-supply controller of electric that can carry out the power switch action according to its described electric signal that receives; The power-supply controller of electric that can carry out power switch action according to its electric signal that receives is ripe, technique known only with regard to its circuit engineering itself; Described power-supply controller of electric market is on sale; Also can utilize commercially available power-supply controller of electric to change a social system as required; Described power-supply controller of electric also can be to the customization of power-supply controller of electric specialty manufacturers; Its professional manufacturers of the electron device of power-supply controller of electric and so on spreads all over the world.

Described metal material one word, the art-recognized meanings of itself is known.

Metal cage 2 can be the metal cage of being made by any metal material; But in view of the related strong oxidizing property condition of waste water degradation treatment, stainless steel is preferred material.

The hole that spreads all in these metal cage 2 self structure or its bore preferable range of mesh are between 0.5 centimetre and 3.0 centimetres, any set point value within this preferable range all is preferred available enforcement value, for example, its bore value can be 0.5 centimetre, 1.0 centimetres, 1.75 centimetres, 2.0 centimetres, 3.0 centimetres, etc.; If must select to use the bore value outside this preferable range, that also is that this case allows.

Preferred described metal cage 2 can be through mold pressing, welding, riveted joint or complementary accessory splicing is made by screw, nut etc. metal cage by the stainless steel punched-plate.

Preferred described metal cage 2 also can be the metal cage of being made by the Stainless Steel Wire braiding.

Distance between the inwall of metal cage 2 and silica tube 3 outer walls without limits, this distance can be distance arbitrarily; But, the preferred value of the distance between the outer wall of the inwall of this metal cage 2 and silica tube 3 is between 3.0 centimetres and 30.0 centimetres, any numerical value within this scope all is the preferred value that allows enforcement, for example, the numerical value of this distance can be 3.0 centimetres, 8.0 centimetres, 16.5 centimetres, 22 centimetres, 30 centimetres, etc.

The further preferred numerical range of the distance between the outer wall of the inwall of metal cage 2 and silica tube 3 is between 10.0 centimetres and 20.0 centimetres, any numerical value within this scope all is the further preferred numerical value that allows enforcement, for example this distance value can be 10 centimetres, 15 centimetres, 18 centimetres, 20 centimetres, etc.

Sewage draining exit 17 can be offered in bottom at described reactor 1, and this sewage draining exit 17 can be used for deslagging, remove contamination, and can install wash water valve 16 in these sewage draining exit 17 positions, and described wash water valve 16 is the valves for blowdown control.Described sewage draining exit 17 and wash water valve 16 are not necessarily.

Described water pump 22 and topping-up pump 21 all are the pumps for delivery of clear or turbid all kinds of water, and certainly, its pumping pressure can be selected as required arbitrarily, and various pump market is all on sale; Different titles are adopted in this case, just statement for convenience, the convenient pump of distinguishing each different structure position.

Described water purifying valve, sewage valve, wash water valve all are water valves, and various water valve market is all on sale; About water valve, itself art-recognized meanings of this word is known; Different titles is adopted in this case, just statement for convenience, the convenient water valve of distinguishing each different structure position.

The preferable range in the preposition prefilter of described back flush type 20 its filter opening apertures is between 5 microns and 300 microns, any set point value within this scope all is preferred available enforcement value, certainly, other the preposition pre-filtering aperture selection outside this preferable range also is that this case allows; The preferable range in described back flush type tubular fibre membrane microfiltration strainer 19 its filter opening apertures is between 25 nanometers and 1000 nanometers, any set point value within this preferable range all is preferred available enforcement value, certainly, other micro-filtration aperture selection outside this preferable range also is that this case allows; The preferable range in described back flush type hollow-fibre membrane ultra filtration filter 18 its filter opening apertures is between 15 nanometers and 2 nanometers, any set point value within this preferable range all is preferred available enforcement value, certainly, other ultrafiltration aperture selection outside this scope also is that this case allows.

The preposition prefilter 20 of described back flush type also claims back flush type fore filter or back flush type prefilter, and itself art-recognized meanings of the preposition prefilter of described back flush type 20 is known; The preposition prefilter of described back flush type 20 markets are on sale.

Described back flush type tubular fibre membrane microfiltration strainer 19 is the strainers that are suitable for micro-filtration; Itself art-recognized meanings of described micro-filtration one word is known; Itself art-recognized meanings of described back flush type tubular fibre membrane microfiltration strainer 19 is known for the professional in membrane separation technique field; Described back flush type tubular fibre membrane microfiltration strainer 19 markets are on sale.

Described back flush type hollow-fibre membrane ultra filtration filter 18 is the strainers that are suitable for ultrafiltration; Itself art-recognized meanings of described ultrafiltration one word is known; Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter 18 is known for the professional in membrane separation technique field; Described back flush type hollow-fibre membrane ultra filtration filter 18 markets are on sale.

In the ultrafiltration link, this back flush type hollow-fibre membrane ultra filtration filter 18 can be the form that a back flush type hollow-fibre membrane ultra filtration filter monomer is only arranged; Certainly, this back flush type hollow-fibre membrane ultra filtration filter also can be made up of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.

Express a related word in parallel, the art-recognized meanings that itself refers to is clearly.

Express related monomer one word, refer to itself function and structure equipment individuality completely.

Similarly, in the micro-filtration link, this back flush type tubular fibre membrane microfiltration strainer 19 can be the form that a back flush type tubular fibre membrane microfiltration strainer monomer is only arranged; Certainly, this back flush type tubular fibre membrane microfiltration strainer also can be made up of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.

Can further install second topping-up pump on the connecting pipeline of the water-in of described back flush type tubular fibre membrane microfiltration strainer 19 its pure water inlets and described back flush type hollow-fibre membrane ultra filtration filter 18, this second topping-up pump is used for augmenting hydraulic pressure to satisfy the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter; This second topping-up pump not necessarily.

Its structure of this case device embodiment can also comprise some annexes, described annex for example: the cooling water recirculation system or the air cooling system that are connected with magnetron 8 cooling ducts; Described annex is also for example for the fixed support that electrodeless ultraviolet lamp 4 is fixed within the silica tube 3; Described annex for example is used for described metal cage is fixed on the support member within the reactor 1 or hangs member again; Described annex can certainly comprise anchor or the suspension bracket that described silica tube 3 is carried out unsettled location within described metal cage 2; Described annex for example is used for bracing frame or anchor or the suspension bracket of unsettled location described cluster shape micro porous aeration head cluster again; Described annex for example is installed in the strainer that is used for interception impurity of reactor 1 influent waste water end again, etc.

Can also be on this case architecture basics, further develop this case scheme, for example, can be paid close attention to the charging characteristic of catalyst particles, and it kind is added utilization, consider that based on this its hollow fiber microfiltration membrane that includes of described back flush type tubular fibre of this case membrane microfiltration strainer can be specified and be used bear electricity hollow fiber microfiltration membrane, its hollow fiber ultrafiltration membrane that includes of the described back flush type hollow-fibre membrane of this case ultra filtration filter can specify use bear electricity hollow fiber ultrafiltration membrane.Under the situation of using the bear electrolemma, the coulombic repulsion effect can be given full play to, and its effect of this coulombic repulsion is can suppress the intractable of catalyst particles on membrane module to adhere to, and makes things convenient for the cleaning running of its backwashing procedures of membrane module.Only with regard to itself art-recognized meanings of bear electricity hollow-fibre membrane one word, the researchist for the charged membrane field knows.Only with regard to itself technology of preparing of bear electricity hollow-fibre membrane, the expert for the charged membrane field knows.

Implement not draw described annex in the legend.

The embodiment of this case is not limited to the legend mode.

Claims (10)

1. the auxiliary separatory membrane of high frequency ultrasound is except the photochemical catalysis waste water decomposition apparatus that adheres to, the structure of this device comprises reactor, this reactor is the container of a hollow, its appearance profile of this reactor is cube shaped, cuboid, the cylinder bodily form, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form, lower region at this reactor inner chamber is equiped with many micro porous aeration heads, and silica tube, this silica tube are erected at the inner chamber position of described reactor, the two ends of this silica tube are equiped with the shutoff headkerchief, lay respectively on the described shutoff headkerchief at silica tube two ends and all offer the ventilation interface, and, electrodeless ultraviolet lamp, this electrodeless ultraviolet lamp is bar-shaped, ring-type, spherical, starfish shape or sea urchin shape, the quantity of this electrodeless ultraviolet lamp is at least more than one, and this quantity all is erected at the inside of described silica tube at least at more than one electrodeless ultraviolet lamp, and, pneumatic pump, this pneumatic pump is installed in the outside of reactor, and the ventilation interface on the described silica tube one end shutoff headkerchief connects with the air outlet of described pneumatic pump via the wall that breather line also sees through reactor, and the ventilation interface on its other end shutoff headkerchief of described silica tube connects with the micro porous aeration head that is positioned at reactor inner chamber lower region via another breather line, and, microwave generator, this microwave generator is installed in the outside of reactor, and this microwave generator is magnetron, and, waveguide, this waveguide are the members for the transmission microwave, an end of this waveguide and described magnetron UNICOM, the other end of this waveguide sees through the inner chamber of the wall orientating reaction device of reactor, and, water pump, this water pump is positioned at the outside of reactor, this water pump is used for the pending waste water of pumping, its water outlet of this water pump leads to the inner chamber of this reactor, and this reactor top offers exhaust port, it is characterized in that, that end of the wall that sees through reactor of this waveguide extends much further into the inner chamber of reactor, and the structure of this reactor also comprises the microwave exposure spatial domain constrainer of the cage shape of metal material, is a mass of many holes or mesh in microwave exposure spatial domain its structure of constrainer of this cage shape, the function of the microwave exposure spatial domain constrainer of this cage shape is constraint microwave exposure spatial domain, the microwave exposure spatial domain constrainer of the cage shape of this metal material is exactly a metal cage, and this metal cage is installed in the inner chamber position of reactor, that port that gos deep into the reactor inner chamber of this waveguide and the inner chamber UNICOM of this metal cage, described UNICOM refers to connection and the perforation on the microwave channel meaning, described silica tube is the inside that is erected at this metal cage, and two described breather lines all penetrate the wall of this metal cage, and the locations of structures of the wall of this metal cage is the locations of structures between reactor wall and silica tube outer wall, and, topping-up pump, this topping-up pump are used for the degraded water afterwards that the supercharging pumping is mixed with a large amount of catalyst particles, and its water-in of this topping-up pump connects with the inner chamber of described reactor via the wall that ventilating water pipe also sees through described reactor, and, the preposition prefilter of back flush type, its water-in of the preposition prefilter of this back flush type connects with the water outlet of described topping-up pump, and, back flush type tubular fibre membrane microfiltration strainer, its pure water inlet of the preposition prefilter of described back flush type connects via the water-in of first water purifying valve with this back flush type tubular fibre membrane microfiltration strainer, and, back flush type hollow-fibre membrane ultra filtration filter, described its pure water inlet of back flush type tubular fibre membrane microfiltration strainer connects via the water-in of second water purifying valve with this back flush type hollow-fibre membrane ultra filtration filter, this its pure water inlet of back flush type hollow-fibre membrane ultra filtration filter connects with the entrance end of the 3rd water purifying valve, and the water side of the 3rd water purifying valve is the water side of outlet terminal water purification, and, catalyst underflow transition jar, this catalyst underflow transition jar is the tank body of a hollow, and this catalyst underflow transition jar is used for temporarily depositing the higher water body of catalyst concentration ratio that its backwashing procedures of described strainer discharges, and the catalyst underflow refluxing opening that is positioned at this its intracavity bottom of catalyst underflow transition jar leads to the inner chamber of reactor via catalyst underflow reverse flow valve, this catalyst underflow reverse flow valve is the valve body for this catalyst return flow line of on-off control, its sewage outlet of the preposition prefilter of described back flush type is via the inner chamber of first sewage valve towards this catalyst underflow transition jar, and described its sewage outlet of back flush type tubular fibre membrane microfiltration strainer is via the inner chamber of second sewage valve towards this catalyst underflow transition jar, and described its sewage outlet of back flush type hollow-fibre membrane ultra filtration filter leads to the inner chamber of this catalyst underflow transition jar via the 3rd sewage valve, each described strainer is all be used to holding back catalyst particles, each its sewage outlet of described strainer is all migrated and is used delivery port again for the recovery of being held back catalyst particles, and described many micro porous aeration heads are assembled mutually and formed cluster shape micro porous aeration head cluster, this cluster shape micro porous aeration head cluster is erected at the lower region of described reactor inner chamber vacantly, the fore-and-aft distance of this cluster shape micro porous aeration head its bottom edge of cluster and described reactor inner chamber bottom surface between 10 centimetres and 50 centimetres, the transverse distance of this cluster shape micro porous aeration head cluster edge and described reactor intracavity sidewall arround it between 20 centimetres and 300 centimetres, this cluster shape micro porous aeration head its center of cluster or center of gravity be positioned at described silica tube under, and, ozone sensor, the sampling port of this its stopple coupon of ozone sensor are close to described exhaust port or probe into the inside of described exhaust port, and, the ozone content indicating meter, the composite structure of ozone attention device or ozone content indicating meter and ozone attention device, this ozone sensor is via article one cable and this ozone content indicating meter, ozone attention device or ozone content indicating meter connect with the composite structure of ozone attention device, and, power-supply controller of electric, its output electric signal of this ozone sensor connects with this power-supply controller of electric via the second cable, this power-supply controller of electric connects with described magnetron via the 3rd cable, and this power-supply controller of electric connects with described pneumatic pump via the 4th cable, and this power-supply controller of electric is the power-supply controller of electric that can carry out the power switch action according to its described electric signal that receives, and, one group of ultrasonic transducer, this group of ultrasonic transducer contains a ultrasonic transducer individuality at least, and this group of ultrasonic transducer is used for the radiation low-frequency ultrasonic waves, this low-frequency ultrasonic waves refers to frequency in the ultrasonic wave of 20kHz-60kHz scope, this reactor inner chamber bottom surface is hollow gradually to the central zone by periphery, and described hollow its gradient is between 5 degree and 35 degree, and this group of ultrasonic transducer is outer side position or the medial surface position that is installed in this its corresponding that part of reactor diapire in hollow innermost of reactor inner chamber bottom surface with attaching, and, HF oscillation electric signal transmission cable, one group of ultrasonic transducer of an end of this HF oscillation electric signal transmission cable and this connects, and, HF oscillation electric signal producer, the other end of described HF oscillation electric signal transmission cable connects with this HF oscillation electric signal producer, and, the pH probe, and, the pH analyser, this pH probe is coupled to each other with the pH analyser, this pH analyser and connect with warning horn, this warning horn is used for the pH value situation of transfiniting is given the alarm, this pH probe sees through the top of reactor and stretches into the reactor inner chamber, and, the micropore stainless steel sleeve of making through powder sintering process, this micropore stainless steel sleeve is cap for brush shape, this micropore stainless steel sleeve is positioned at the reactor inner chamber, this its blind end of micropore stainless steel sleeve down, this its opening end of micropore stainless steel sleeve is up, this its opening end up of micropore stainless steel sleeve connects with reactor head via the buffering isolating pad, this pH its that part that stretches into the reactor inner chamber of popping one's head in probes within this micropore stainless steel sleeve, and this its material of buffering isolating pad is viton or silicon rubber, and, two pairs of dry-reed type ball float level controllers, these two pairs of dry-reed type ball float level controllers all extend into the inner chamber of reactor through the top of reactor, a pair of dry-reed type ball float level controller wherein connects with the power cable of described water pump by a rly., and wherein another connects with the power cable of described topping-up pump by another rly. the dry-reed type ball float level controller, and, tank, described back flush type tubular fibre membrane microfiltration strainer and the equal submergence of described back flush type hollow-fibre membrane ultra filtration filter are placed within this tank, are equiped with another group ultrasonic transducer at its sidewall of this tank or its bottom, this another group ultrasonic transducer contains a ultrasonic transducer individuality at least, this another group ultrasonic transducer is used for the radiation high-frequency ultrasonic, and this high-frequency ultrasonic refers to frequency in the ultrasonic wave of 100kHz-12MHz scope, and this another group ultrasonic transducer connects with another HF oscillation electric signal producer.

2. the auxiliary separatory membrane of high frequency ultrasound according to claim 1 is except the photochemical catalysis waste water decomposition apparatus that adheres to, it is characterized in that, its material of this metal cage is stainless steel, and its bore scope of the hole that spreads all in this metal cage self structure or mesh is between 0.5 centimetre and 3.0 centimetres.

3. the auxiliary separatory membrane of high frequency ultrasound according to claim 1 is characterized in that except the photochemical catalysis waste water decomposition apparatus that adheres to the distance between the inwall of this metal cage and the outer wall of silica tube is between 3.0 centimetres and 30.0 centimetres.

4. the auxiliary separatory membrane of high frequency ultrasound according to claim 3 is characterized in that except the photochemical catalysis waste water decomposition apparatus that adheres to the distance between the inwall of this metal cage and the outer wall of silica tube is between 10.0 centimetres and 20.0 centimetres.

5. the auxiliary separatory membrane of high frequency ultrasound according to claim 1 is except the photochemical catalysis waste water decomposition apparatus that adheres to, it is characterized in that, its filter opening aperture of the preposition prefilter of described back flush type is between 5 microns and 300 microns, its filter opening aperture of described back flush type tubular fibre membrane microfiltration strainer is between 25 nanometers and 1000 nanometers, and its filter opening aperture of described back flush type hollow-fibre membrane ultra filtration filter is between 15 nanometers and 2 nanometers.

6. the auxiliary separatory membrane of high frequency ultrasound according to claim 1 is except the photochemical catalysis waste water decomposition apparatus that adheres to, it is characterized in that this back flush type hollow-fibre membrane ultra filtration filter is made up of in the connection parallel with one another of more than one back flush type hollow-fibre membrane ultra filtration filter monomer quantity.

7. the auxiliary separatory membrane of high frequency ultrasound according to claim 1 is except the photochemical catalysis waste water decomposition apparatus that adheres to, it is characterized in that this back flush type tubular fibre membrane microfiltration strainer is made up of in the connection parallel with one another of more than one back flush type tubular fibre membrane microfiltration strainer monomer quantity.

8. the auxiliary separatory membrane of high frequency ultrasound according to claim 1 is except the photochemical catalysis waste water decomposition apparatus that adheres to, it is characterized in that, connecting pipeline at the water-in of described back flush type tubular fibre membrane microfiltration its pure water inlet of strainer and described back flush type hollow-fibre membrane ultra filtration filter is equiped with second topping-up pump, and this second topping-up pump is used for augmenting hydraulic pressure to satisfy the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter.

9. the auxiliary separatory membrane of high frequency ultrasound according to claim 1 is except the photochemical catalysis waste water decomposition apparatus that adheres to, it is characterized in that, bottom at described reactor offers sewage draining exit, this sewage draining exit is used for deslagging, removes contamination, be equiped with wash water valve in this sewage draining exit position, described wash water valve is the valve for blowdown control.

10. the auxiliary separatory membrane of high frequency ultrasound according to claim 1 is except the photochemical catalysis waste water decomposition apparatus that adheres to, it is characterized in that, this its wall thickness of micropore stainless steel sleeve is between 3 millimeters to 30 millimeters, this its micropore size of micropore stainless steel sleeve is between 0.5 micron to 50 microns, and this its thickness of buffering isolating pad is between 1 millimeter to 8 millimeters.

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