CN103288181B - Thermal electron emission type anion water and ozone generator - Google Patents
Thermal electron emission type anion water and ozone generator Download PDFInfo
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- CN103288181B CN103288181B CN201210056907.0A CN201210056907A CN103288181B CN 103288181 B CN103288181 B CN 103288181B CN 201210056907 A CN201210056907 A CN 201210056907A CN 103288181 B CN103288181 B CN 103288181B
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Abstract
Thermal electron emission type anion water and ozone generator. Mainly formed by high and low pressure dc source, the transparent container being filled with water, small-power electric furnace, thermionic electron emitter (negative electrode), positive plate and bar-bell type insulated electric conductor etc. The top of the transparent container being filled with water is provided with thermionic electron emitter (negative electrode), is provided with positive plate in bottom. Underwater between cathode and anode, arranges a bar-bell type insulated electric conductor. Thermionic electron emitter (negative electrode) can be launched a large amount of thermoelectrons to the top of insulated electric conductor. These electronics, in the time leaping space, can produce ozone; After electronics enters in water again, generate hydrogen with hydrone effect. So the hydroxide ion in container in water just increases relatively gradually, pH value increases, and just can make the anion water through ozonization of required pH value. Anion water is not only effectively got rid of people's physical efficiency and the effect of deactivation free radical, makes free radical without poisoning, and reaches anti-disease, anti-aging old, and all biologies is had to the effect of " mystery ", and as for cultivation, survival rate is high, fosterly to obtain loose deliciousness; Be used for breeding and pour plant, percentage of seedgermination is high, and branch is healthy and strong, and result is many, and the speed of growth improves etc. Therefore, very worth research promotion and use.
Description
Affiliated technical field
The present invention relates to performance and high-voltage DC power supply that first family major element on the periodic table of elements easily loses outermost electron producesThe effect of raw electrostatic field, and reacting of occurring with water of electronics.
Background technology
Anion water is rich in electronics, can effectively get rid of with deactivation human body in the carcinogenic free radical that causes a disease, and all biologies are hadThe effect of " mystery ", as for cultivation, survival rate is high, support to obtain loose deliciousness; Be used for breeding and pour plant, seedGermination percentage is high, and branch is healthy and strong, and result is many, and the speed of growth improves etc. and therefore developing high-effect anion water generator becomesThe urgent need of society.
In physics, confirm that beyond suspicion cathode-ray is electron stream; In old-fashioned electron tube, for strengthening electron tubeThe emission measure of interior electron stream, has increased a metallic plate that can be subject to thermal electron filament (negative electrode) is other, makes heater-type electricitySon pipe; Utilize metal caesium (Cs) easily to lose an outermost electronics, found photoelectric effect, photoelectric tube was widely applied afterwards.
In electrochemistry, acquire again in addition: 2H2O+2e＝2OH-+H2. thereby to electron emission in water, can make hydrogen ion (H in water+)Constantly reduce, relatively hydroxide ion (OH-) be on the increase, pH value constantly increases. From this thinking, just design thermoelectricitySub-transmitting anion water generator.
Summary of the invention
Thermal electron emission type anion water and ozone generator, mainly by the transparent container being filled with water, high and low pressure dc source, littleThe formations such as load electric stove, thermionic electron emitter (negative electrode) and positive plate and bar-bell type insulated electric conductor.
Electron amount in the unit interval emitting from thermionic electron emitter, the electric current chapter in physics electrolyte and gasIn joint, indicating, is not defer to Ohm's law. Obviously, its emission measure of electronics within the unit interval be with emitter stage in easily transmittingElectronic metal content character size and the cathode and anode relative with temperature, emitter stage and the anode of number, emitter stageVoltage height between plate is relevant.
On the periodic table of elements, the major element of first family has: lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), francium (Fr)Deng. on their outermost orbit, only have an electronics, easily depart from, the modern potassium (K) of selecting is as the material of manufacturing thermionic electron emitterMaterial, its reason is:
1) there is rareness at nature in rubidium (Rb), caesium (Cs), francium (Fr), is exactly to have on caesium (Cs) market, but the price utmost pointExpensive.
2) potassium (K) can be supplied in a large number on market, and price is relatively also cheap.
3) fusing point of these first family major elements, boiling point, dissociation energy, Noboru China's heat and ionization potential etc. are compared as follows mutually:
| Metal | Li | Na | K | Rb | Cs |
| Fusing point (DEG C) | 186 | 98 | 63 | 39 | 28 |
| Boiling point (DEG C) | 1336 | 890 | 770 | 680 | 670 |
| Dissociation energy (thousand card/gram molecule) | 26 | 18 | 12 | 11 | 10 |
| Noboru China's heat (thousand card/gram atom) | 36 | 26 | 22 | 21 | 19 |
| The ionization potential (volt) of atom | 5.4 | 5.1 | 4.3 | 4.2 | 3.9 |
Ionization potential is that atom loses electronics and becomes the needed minimum potential of cation.
Show from upper table: potassium (K) and its performance of caesium (Cs) are very approaching, price also can, be therefore the most desirable.
Because the activity of potassium (K) is larger than sodium (Na), all to burn with water or with air effect, for this reason, this just requires veryEmpty or be full of as in the closed unit of the gas such as nitrogen or carbon dioxide, potassium is taken out from kerosene, put between two metallic plates, closeAfter coming, seal again the crack of surrounding, made thermionic electron emitter.
This closed unit can be made like this, and above with glass plate, other position is that metal or timber can.. Side opening twoThe openning that individual left hand and right hand can stretch into, gets one pair of the plastic glove of long sleeves mouth, two opennings of handle sleeve and closed unit twoSeamless adhesion is made at the edge of openning, and making two hands have on this glove can operate in closed unit. First sheet metal and potassium andRequired closed material and instrument are put into closed unit, and then, available carbon dioxide closes device with air-discharging method Zhu Ru Mi upwards, close thereafterClose. The method of obtaining carbon dioxide is a lot, and calcium carbonate and hydrochloric acid effect are product in laboratory methods,2HCl+CaCO3＝CaCl2+H2O+CO2Can consult and use.
(E is electric-field intensity to definition from electric-field intensity: E=F/q, and F is placed on the upper suffered electric field of electric charge q of electric field pointActive force), derive thus F=qE. apparent, because of an electron is negatively charged lotus, obtain it is had to larger directed force F, necessaryStrengthen electric field strength E. and in the chapters and sections of physical basic electrostatic phenomenon, illustrate in detail:, the electric-field intensity between parallel-plateE, be to two-plate between voltage U be directly proportional, and distance d between two plates is inversely proportional to, it is at Guan Department formula: so E=U/d. justCan select on demand voltage and distance between the positive and negative pole plate of high-voltage DC power supply. design.
Brief description of the drawings
Below in conjunction with the bright Jin mono-of this Fa of drawings and Examples Dui Walk explanation.
Fig. 1 is that structure and the circuit of thermal electron emission type anion water and ozone generator connects schematic diagram.
Fig. 2 is structure and the profile schematic diagram of thermionic electron emitter.
Fig. 3 is structure and the profile schematic diagram of bar-bell type insulated electric conductor.
Fig. 4 is the profile schematic diagram of thermal electron emission type anion water and ozone generator.
In Fig. 1-4,1-timer, 2-rheostat, 3-primary coil, 4-low pressure output secondary coil, 5-primary coil, 6-High voltage output secondary coil, 7-rectifier, 8-electromagnetic relay, 9-spring, 10-armature, 11-the earth, 12-ground wire,The transparent container being filled with water of 13-, 14-positive plate, 15-insulating materials, 16-outlet pipe, 17-valve, 18-water, 19-Gap, 20-bar-bell type insulated electric conductor, the lid of the transparent water container of 21-, 22-thermionic electron emitter, 23-small power electricStove, 24-electricity Re Silk, 25-air bleeding valve, 26-water inlet pipe, 27-valve,, 28-turning handle switch, 29-electromagnet, 30Indicator lamp, 32-rectifier, the 33-high and low pressure dc source, 34 of-mono-indicator lamp that can glow, 31-energy green light-telegraph key, 35-plug, 36-metallic potassium, 37-metallic plate, 38-is high temperature resistant closed material, 39-metallic plate, 40-The insulation outer container of high and low pressure dc source.
In all multiple components, high and low pressure dc source (33), electromagnetic relay (8), small-power electric furnace (23), timer (1), rheostat (2), the indicator lamp (30) that can glow, can green light indicator lamp (31), telegraph key (34), plug (35) andValve (17), (27) etc., on market, all easily buying obtains.
The transparent container being filled with water (13) is made with glass or lucite, high temperature resistant machinery again for the lid (21) of transparent water containerThe ceramic material that intensity is good is made, and high and low pressure dc source outer container (40) must come with the good insulation preformance plastics that mechanical strength is good againManufacture.
Thermionic electron emitter (22) is by metallic plate (37) and metallic plate (39), metallic potassium (36) to be clipped in the middle, due to metallic potassium (K)Meet air just oxidized and burn, chance water and water effect releasing hydrogen gas also burn, and Jin No preserves in kerosene at ordinary times.Therefore must vacuum be full of nitrogen or the closed unit of carbon dioxide in, potassium is placed between two metallic plates (37), (39), closeAfter coming, high temperature resistant closed material (38) for periphery crack is sealed. Metallic sheet material can adopt stainless steel, copper or aluminium. and resistance toHigh temperature closure material (38) available water glass mixes and stirs with cement or other have the material of identical performance.
Bar-bell type insulated electric conductor (20) can adopt iron castings, and its outer surface must be used insulating materials (15) sealing, insulating materials (15)The toxic low-cost vinyon again of available good insulation preformance ， No.
Bar-bell type insulated electric conductor (20) is placed between thermionic electron emitter (22) and positive plate (14), is that to utilize it to occur quietThe phenomenon of electric induction. At this moment, or else the electric-field intensity between wish meter Suan yin, yang pole plate be application thermionic electron emitter (22) and anodeDistance between plate (14), but thermionic electron emitter (22) is to the distance at bar-bell type insulated electric conductor (20) top. ShortenThis segment distance of bar-bell type insulated electric conductor (20) height, electric-field intensity is significantly strengthened, and just makes thermionic electron emitter (22) send outThe ability of radio improves greatly.
In order to produce highfield, the distance from thermionic electron emitter (22) to bar-bell type insulated electric conductor (20), is the smaller the better, still,Too little will puncturing and produce electric arc, therefore this distance is limited. Electric current in General Physics electrolyte and gasChapters and sections in, show under atmospheric pressure, while puncturing between two electrodes of Different electrodes shape, two voltage across poles and two interpolarsDistance Guan Department table, make a copy of as follows:
If plane-shaped electrode is rough, exist on serration unevenly, just can not treat as plane.
Principle and the operation side that further describes thermal electron emission type anion water and ozone generator by embodiment belowMethod:
Open valve (27) and add water, exceed the top of bar-bell type insulated electric conductor (20) to the water surface, plug (35) is connected to 220 voltsCivil power, again timer (1) is arranged on the scale of the time that uses high voltage heat of emission electron institute need. Rheostat (2) canRegulate the voltage at primary coil (5) two ends, namely can regulate the High voltage output of output high pressure secondary coil (6), withControl emitter stage within the unit interval thermionic emission amount number.
Closed telegraph key (34), to being in heating wire (24), primary coil (4) and the primary coil in small-power electric furnace (23) in parallel(5) all led to electricity.
Heating wire (24) in small-power electric furnace (23) just the metallic plate (37) of composition thermionic electron emitter (22), (39) andMetallic potassium (36) heating, because the boiling point of metallic potassium (36) is 770 DEG C, becomes steam soon, in general chemistry, also refers toGo out, at this moment metallic potassium (36) is all monatomic state, and on its atom outermost orbit, only this electronics is just easy to loseGo.
On the loop forming at low pressure output secondary coil (4) and rectifier (32), there is electric current to pass through. So rectifier (32) and phaseIndicator lamp (30), indicator lamp (31) and electromagnet (29) in parallel can both become the loop that is electrified stream mutually. When turning handle leavesWhen pass (28) is placed in a point, the indicator lamp (30) that can glow is luminous, and the indicator lamp (31) of energy green light does not work, electricityCoil on magnet (29) has electric current to pass through Yin No, and armature (10) can not be attracted by electromagnet (29), in high tension loopA, A just can not connect. Therefore, the indicator lamp (30) that can glow is luminous, represents that thermionic electron emitter (22) is heated,But there is not thermionic emission. .
In the time that turning handle switch (28) is placed in b point, indicator lamp (31) and the electricity of rectifier (32) and parallel with one another energy green lightThe loop of magnet (29) composition just has electric current to pass through. At this moment, the indicator lamp (30) that can glow extinguishes, and the instruction of green lightLamp (31) is luminous, and the upper coil of electromagnet (29) has electric current to pass through simultaneously, and armature (10) is just attracted by electromagnet (29), spring(9) be elongated, A, 2 of A are switched on. So can export negative pole and armature (10) and the heat of the rectifier (7) of high voltage direct currentElectron emitter (22) becomes series connection to be connected, and because positive pole and the positive plate (14) of rectifier (7) are connected, is placed in transparent being filled with water againContainer (13) in bar-bell type insulated electric conductor (20), certainly will be subject to positive plate (14) induction effect and electrostatic induction occurs, at this moment,Electric-field intensity between thermionic electron emitter (22) and bar-bell type insulated electric conductor (20) top strengthens greatly. From metallic potassium (36) Off, under the effect of electric field force, just pass through metallic plate (39) and fly into space from electronics out, flying to bar-bell type insulated electric conductor (20)Top, result all drops in bar-bell type insulated electric conductor (20) water above, acquires electronics and water from " modern electrochemistry "Contact, reacts:
Water is weak electrolyte, is polar molecule, has more hydrone to be ionized under highfield effect, has produced more hydrogenIon (H+) and hydroxide ion (OH-), so hydrogen ion (H+) just must combine with the electronics that transmitting comes,
Illustrate from (1), (2) formula: the hydrogen ion (H water+) number and hydroxide ion (OH-) number, originally equated,See the growth in reaction time as Jin Sui, make hydrogen ion (H+) constantly reduce hydroxide ion (OH relatively-) count and be on the increase, inThe pH value that is water is just increasing, has just made anion water.
Metallic plate (37), (39) in thermionic electron emitter (22) are upper, must connect ground wire (12), be connected with the earth (11), becauseAfter thermionic electron emitter (22) electron emission, electromotive force own just raises, and as earth-free, thermionic emission is just of short duration. At this moment,Thermionic electron emitter (22) is because losing its electromotive force of a large amount of electronics just higher than the earth (11), and the earth (11) will pass through ground wire (12) conduction,Electronics is sent to thermionic electron emitter (22), and makes that electron emission is sustainable to carry out.
Because thermionic emission is passed through space, electronics has compared with macro-energy under highfield effect, the oxygen in its energy ionized air,Therefore, in the approach passing through at thermoelectron, certainly will can see Hyacinth corona, illustrate and constantly producing ozone,(be reversible reaction: being left exothermic reaction, is to the right the endothermic reaction. ) solubility of ozone is oxygen13 times, so soluble in water, it has the sterilization of utmost point Strong and eliminates the ability of the organic poison of tool carcinogenicity.
In the upper portion side wall of the transparent container being filled with water (13), have gap (19), for spilling water, prevent careless injected water volume mistakeMany, to protect thermionic electron emitter (22). also can play the effect of exhaust and air inlet simultaneously.
Lid (21) at transparent water container is upper, has an air bleeding valve (25), because need air in the time producing ozone, due to thermoelectronEmitter stage (22) is in continuous release heat, and on the water surface, gas is also heated, opens air bleeding valve (25), and hot-air is discharged thus, coldAir just enters from gap (19), has brought oxygen, for producing ozone.
At electronics and water and hydrogen ion (H+) in course of reaction, the hydrogen (H emitting2), also can be from air bleeding valve (25) or the spilling water of openingMouth (19) is discharged.
Through the effect of highfield, water, from 13～16 water clusters that hydrone is unified into of former cause, has become by 6 hydronesThe small water molecule group composition being even still less unified into, this water capacity is easily by the cell membrane of human body, multiple nutrient matter more can be entered carefullyBorn of the same parents discharge more waste materials simultaneously, and this just becomes the good health and a long life water that the World Health Organization of united state (WHO) confirms.
Finally, for operating and making to make good use of thermionic emission anion water generator, remake following some explanation:
The mensuration of 1.PH value, should adopt glass electrode method, to obtain more accurate data, does not use more rough test paper ratioColor method is measured.
If 2. the optimum pH value of pair human body is the anion water pH value > 7.6 that 7.4～7.6. makes, can be with commonWater mixes different substances together, and pH value is down to 7.4～7.6.
3. to pay attention to especially having laid ground wire (12), make earth resistance Jin Liang Minus little, ensure that the earth (11) is to thermionic electron emitter (22)The conduction of electronics is supplied with.
4. judge that whether ozone is discharged and caused contaminated environment from air bleeding valve (25), can place a slice in face of air-flow at exhaust outlet (25)Soaked the litmus red test paper of KI solution., if there is ozone to overflow, at this moment on litmus paper, there is chemical reaction:
2KI+O3+H2O＝2KOH+I2+O2
After reaction if make test paper become blue with contact starch and can make starch present bluish violet, just can confirm KOH and I2. alsoConfirm ozone effusion.
If 5. have ozone overflow, can:
1) pick out and pass in bottled water with leather hose, making is the ozone saturated solution of fine disinfectant.
Whether ozone passes in bottled water, reach capacity, and can be placed on bottleneck with the litmus red test paper that soaked KI solution equally and surveyFixed.
Under the status of criterion in every premium on currency solution, 0.65 liter of ozone of solubilized at most, its quality is 1392 milligrams, due to ozoneSterilization use amount, protecting special 0.045～0.45 mg/litre just has fine effect, Jing Ji Suan, this ozone saturated solution is to containerSterilization, it is just passable that every 1 liter capacity only need splash into 0.71 milliliter (containing 0.46 milligram), so be of great value.
2) can close air bleeding valve (25), the space in the transparent container being filled with water (13), does not just produce convection current, and air just can be from yetGap (19) enters, and the air in container is limited, and the ozone that just allows these air and make, dissolves in water or stay space.Because reaching approximately 1392 milligrams every liter, the ozone concentration in water just no longer dissolves. The half-life of ozone is 15 minutes 30～minutes again,So container includes the water that ozone concentration is higher, as long as ozone stops occurring, after a few hours, concentration just drops to adaptable journeyDegree.
6. control the high break-make of bribing that pushes back with turning handle switch (28) by electromagnetic relay (8), this is a safety device,Prevent that operating personnel from suffering high-voltage electric shock.
Reference
[general physics] (former Soviet Union) Fu Lisijimoliewa work Commercial Press
The alunite carat Suo Fuzhu Commercial Press of [general chemistry study course] (former Soviet Union)
The emerging Central South University of writing of [modern electrochemistry] Gong Zhuqing Wang Zhi goes out
Golden Shield publishing house is write by [water and human body's health] Li Junjie Marvin's China
Publishing house of [environmental protection and healthy new material---Tourmaline] Yao Dingshan chief editor China Textile University
[resource of water supply protection purifies with micropollutant water] Zhu Liang chief editor Chemical Industry Press and Environmental Science and Engineering publishing house
Claims (4)
1. a thermal electron emission type anion water and ozone generator, it is mainly by height, low-voltage direct source (33), electromagnetic relay (8), the transparent container being filled with water (13), small-power electric furnace (23), the lid (21) of transparent water container, high, the insulation outer container (40) of low-voltage dc power supply, thermionic electron emitter (22), positive plate (14), bar-bell type insulated electric conductor (20) and timer (1), rheostat (2), the indicator lamp (30) that can glow, the indicator lamp (31) of energy green light, telegraph key (34), plug (35) forms, wherein said thermionic electron emitter (22), to be formed by the metallic potassium (36) being placed between metallic plate (37) and metallic plate (39), and metallic plate (37, 39) high temperature resistant closed material (38) sealing for the crack at edge between.
2. thermal electron emission type anion water according to claim 1 and ozone generator, it is characterized in that positive plate (14) is arranged on the outside, bottom of the transparent container being filled with water (13), thermionic electron emitter (22) is arranged on below the central authorities of lid (21) of transparent water container, and with the water surface isolation of having living space.
3. thermal electron emission type anion water according to claim 1 and ozone generator, it is characterized in that the center position in the transparent container being filled with water (13), be provided with the bar-bell type insulated electric conductor (20) that is insulated material (15) sealing, the bottom of the transparent container being filled with water (13) is close in one end of bar-bell type insulated electric conductor (20), the other end is aimed at thermionic electron emitter (22), is placed under water (18) face.
4. thermal electron emission type anion water according to claim 1 and ozone generator, is characterized in that thermionic electron emitter (22) and the earth (11) have the ground wire that electric conductivity is good (12) to connect.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN200988797Y (en) * | 2006-12-20 | 2007-12-12 | 董晟荣 | Ozone water machine for producing large flow ozone water |
| CN101306854A (en) * | 2007-05-14 | 2008-11-19 | 三洋电机株式会社 | Water treatment device |
| CN101746850A (en) * | 2009-12-15 | 2010-06-23 | 青岛海德威船舶科技有限公司 | Multi-dimensional nanomaterial micro-current electron exciting electrode and preparation method thereof |
| CN101939261A (en) * | 2007-09-27 | 2011-01-05 | 生命之水有限责任公司 | Ultraviolet water purification system |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06106174A (en) * | 1992-09-28 | 1994-04-19 | Janome Sewing Mach Co Ltd | Purification device for hot bathtub water |
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- 2012-02-26 CN CN201210056907.0A patent/CN103288181B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN200988797Y (en) * | 2006-12-20 | 2007-12-12 | 董晟荣 | Ozone water machine for producing large flow ozone water |
| CN101306854A (en) * | 2007-05-14 | 2008-11-19 | 三洋电机株式会社 | Water treatment device |
| CN101939261A (en) * | 2007-09-27 | 2011-01-05 | 生命之水有限责任公司 | Ultraviolet water purification system |
| CN101746850A (en) * | 2009-12-15 | 2010-06-23 | 青岛海德威船舶科技有限公司 | Multi-dimensional nanomaterial micro-current electron exciting electrode and preparation method thereof |
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Effective date of registration: 20200925 Address after: Room 408, copper commodity market, Huaihe Road, Tongling City, Anhui Province Patentee after: Tongling Tiancheng Technology Development Co.,Ltd. Address before: 315033 Zhejiang province Ningbo Jiangbei Hongtang YJ 47 Park building 262, room 901 Patentee before: Gui Leizhu |