CN103282588A - Heat trace system including hybrid composite insulation - Google Patents

Heat trace system including hybrid composite insulation Download PDF

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Publication number
CN103282588A
CN103282588A CN2011800443752A CN201180044375A CN103282588A CN 103282588 A CN103282588 A CN 103282588A CN 2011800443752 A CN2011800443752 A CN 2011800443752A CN 201180044375 A CN201180044375 A CN 201180044375A CN 103282588 A CN103282588 A CN 103282588A
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CN
China
Prior art keywords
pipeline
heat
insulation system
isolation layer
external surface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2011800443752A
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Chinese (zh)
Inventor
F·查卡拉卡尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nvent Thermal LLC
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Tyco Thermal Controls LLC
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Publication date
Application filed by Tyco Thermal Controls LLC filed Critical Tyco Thermal Controls LLC
Publication of CN103282588A publication Critical patent/CN103282588A/en
Pending legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L53/00Heating of pipes or pipe systems; Cooling of pipes or pipe systems
    • F16L53/30Heating of pipes or pipe systems
    • F16L53/32Heating of pipes or pipe systems using hot fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L53/00Heating of pipes or pipe systems; Cooling of pipes or pipe systems
    • F16L53/30Heating of pipes or pipe systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L53/00Heating of pipes or pipe systems; Cooling of pipes or pipe systems
    • F16L53/30Heating of pipes or pipe systems
    • F16L53/35Ohmic-resistance heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L53/00Heating of pipes or pipe systems; Cooling of pipes or pipe systems
    • F16L53/30Heating of pipes or pipe systems
    • F16L53/35Ohmic-resistance heating
    • F16L53/38Ohmic-resistance heating using elongate electric heating elements, e.g. wires or ribbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/02Shape or form of insulating materials, with or without coverings integral with the insulating materials
    • F16L59/029Shape or form of insulating materials, with or without coverings integral with the insulating materials layered
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/6416With heating or cooling of the system

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Insulation (AREA)

Abstract

A fluid pipeline has a first end and a second end. An elongated heat trace element comprised of first and second heat tubes is aligned and coupled to at least a portion of an outer surface of the fluid pipeline. The outer surface of fluid pipeline carries a first insulation material covering a first portion of the outer surface. The outer surface of the fluid pipeline further carries a second insulation material covering a second portion of the outer surface and wherein the second portion of the outer surface is different than the first portion of the outer surface. The first and second insulation materials are configured to cover the outer surface of the fluid pipeline. The fluid pipeline further comprises a third insulation material carried over a second outer surface defined by the cooperation of the first and second insulation materials.

Description

Comprise the tracing system that mixes compound heat-insulation spare
The cross reference of related application
The application requires the U.S. Provisional Patent Application No.61/383 in submission on September 15th, 2010,258 priority, and its full content is incorporated the present invention in the mode of quoting.
Technical field
The present invention relates to a kind of heating fluid line on the whole.More specifically, the present invention relates to a kind of heating fluid line that mixes heat insulation structure that comprises.
Background technology
Usually outer thermal insulation barriers is the vitals of water back, and described water back is including, but not limited to the sulphur transport pipeline.Usually, this thermal insulation barriers is used for earthward that pipeline provides enough heat insulating abilities and personnel are protected.Existing liquid conveying pipe such as liquid sulfur transport pipeline and/or pipe-line system uses high temperature resistant heat insulation material usually, and described high temperature resistant heat insulation material is including, but not limited to following material: (1) aerogel heat-insulating material; (2) perlite heat-barrier material; (3) mineral wool; (4) polyurethane heat-barrier material.
Aerogel heat-insulating material has advantageously provided low thermal conductivity with respect to high temperature resistant heat insulation material commonly used.And aerogel heat-insulating material has flexible and is easy to be applied to pipeline.Because aerogel heat-insulating material provides low thermal conductivity, so very thin one deck heat-barrier material just can be used for covering pipeline and be pipe insulation.Aeroge is comparatively expensive usually, and this makes the known heat insulation substitution material of itself and other compare the shortage economic competitiveness.
Perlite is another kind of known heat-barrier material.The perlite heat-barrier material is cheap and confirm it is the heat-barrier material with high compression-strength and bearing high temperature ability.Perlite is frangible and may be damaged in transit with in the installation process.Perlite provides low insulation value usually, thereby needs extra thickness/material to distribute with the heat of realizing ideal.
Mineral wool is another kind of known heat-barrier material.Mineral wool is the heat-barrier material for the economy of high-temperature use.Compare with perlite, mineral wool provides more good insulation value usually, but does not possess the high compression-strength that supports pipeline.
Another kind of known heat-barrier material is polyurethane, and it provides low thermal conductivity.Usually, the heat-proof quality of polyurethane only is inferior to aerogel heat-insulating material.The polyurethane heat-barrier material is worked under about 150 ℃ temperature condition usually and/or is heat insulation.Yet the polyurethane heat-barrier material can not directly bear high temperature usually, such as those high temperature that stand in the sulphur transportation pipeline.
It is desirable to provide a kind of system, the limitation of traditional insulation materials is provided when maximization is by each advantage that provides in these heat-barrier materials in described system.
Summary of the invention
Hot (heat trace) system of disclosed companion that comprises mixing compound heat-insulation spare of the present invention comprises fluid line, and described fluid line has first end and the second end.Elongated companion's thermal element alignment and be connected at least a portion in the external surface of fluid line.
The pipeline tracing system is known by those of skill in the art.This pipeline tracing system generally includes at least one cartridge element (such as, heat pipe for example), described cartridge element binding or be welded to carrier pipe.In order to produce high temperature, can manage the seamless this carrier pipe that is welded to many.In most applications, this welding is " unstructuredness " and the heat catalysis of strict demand conduct from cartridge element (a plurality of cartridge element) to carrier pipe.Although concrete mechanism and structure can change, heat pipe can comprise the heating element (a plurality of heating element) for generation of heat.
In addition, at least one fibre circuit also can be used for implementing various control and/or monitoring function.For example, described at least one fibre circuit can be used in the continuous monitoring pipeline temperature curve on its whole length substantially, thereby guarantees safety and the unfailing performance of system.
The external surface of fluid line carries first heat-barrier material, and wherein, described first heat-barrier material covers the first of the external surface of described pipeline.The external surface of fluid line also carries second heat-barrier material, and wherein, described second heat-barrier material covers the second portion of external surface, and wherein, the second portion of described external surface is different with the first of described external surface.First heat-barrier material and second heat-barrier material are configured to cooperate and the external surface of covering fluid pipeline.Fluid line also comprises the 3rd heat-barrier material, and described the 3rd heat-barrier material is carried on by first and second heat-barrier materials and cooperates on second external surface that limits.
Disclose other embodiment, and can use or be used in combination among the described embodiment each separately.In following the detailed description and the accompanying drawings, described the further feature of disclosed embodiment and advantage and will become apparent from further feature described in the described the detailed description and the accompanying drawings and advantage.
Description of drawings
To understand aforementioned summary and the following detailed description of preferred embodiment when read in conjunction with the accompanying drawings better.In order to explain the present invention, accompanying drawing shows specific preferred embodiment.Yet, should be understood that the present invention is not limited to disclosed specific method and device.And, just to illustrative purposes but not limitation provides size, material and component names.
Fig. 1 shows the phantom drawing of exemplary fluid-mixing pipe insulation spare constructed according to the invention.
Fig. 2 shows the sectional view of exemplary fluid-mixing pipe insulation spare constructed according to the invention.
Fig. 3 to Fig. 6 shows the heat analysis of the element of exemplary fluid-mixing pipe insulation spare of the present invention.
The specific embodiment
Tracing system of the present invention disclosed herein comprises conduit assembly 100, and described conduit assembly 100 is configured with and mixes the compound heat-insulation system, and described mixing compound heat-insulation system has skin effect (skin effect) heat generating member that is arranged in external surface peripheral.
Fig. 1 shows the phantom drawing of exemplary fluid-mixing pipe insulation spare constructed according to the invention.Conduit assembly 100 comprises pipeline 102, and described pipeline 102 can be for having one section pipe cylindraceous substantially of external surface 104 and the inside 106 of basic hollow.It should be noted that pipeline 102 can be used in many functions, including, but not limited to being used for transporting fluid along the hollow inside 106 of described pipeline 102.
Pipeline 102 comprises companion's thermal element, and described companion's thermal element preferably includes first heat pipe 108 and second heat pipe 110.Described heat pipe 108 and 110 can be for the heat pipe according to the known method supply heat of those of skill in the art.If desired, attention be that the layout of described heat pipe 108 and 110 can change with respect to pipeline 102, to adapt to concrete installation or design parameters.Pipeline 102 can also support fiber optic cables sleeve pipe 112, and described fiber optic cables sleeve pipe 112 is fixedly attached to the external surface 104 of pipeline 102 substantially between heat pipe 108 and 110.Can use described fiber optic cables sleeve pipe 112 according to the known method of those of skill in the art.
Still with reference to Fig. 1, the first rigidity heat-barrier material 118 with bearing high temperature ability and high bearing capacity can advantageously be arranged in around the part of pipeline 102.As hereinafter more fully as described in, second heat-barrier material 120 can be arranged in around another part of pipeline 102.Described second heat-barrier material 120 can comprise preformed groove, described preformed groove be suitable for first and second heat pipes 108,110 and ferrule 112 match.Metal interface wrap member 122 can cover or surround first heat-barrier material 118 and second heat-barrier material 120, and described first and second heat- barrier materials 118 and 120 are separated with outer isolation layer 126 respectively.High density polyethylene (HDPE) (HDPE) vapor barrier 128 can be wrapped up or otherwise be arranged in around the skin 126 of pipeline 102.
Fig. 2 shows the exemplary embodiment of pipeline 102 and mixes the sectional view of compound heat-insulation system 100.Pipeline 102 can be columnar substantially pipe, has the inside 106 of external surface 104 and basic hollow.Illustrate but non-limitation, it should be noted that pipeline 102 can be A106B level carbon steel tube, described carbon steel tube is configured to transport molten sulfur along the hollow inside 106 of described pipeline 102.
Pipeline 102 can comprise first heat pipe 108.As shown in Figure 2, heat pipe 108 is arranged in the approximately position of " 10:30 ".Pipeline 102 can also comprise second heat pipe 110, and described second heat pipe 110 is arranged in the approximately position of " 1:30 " as shown in Figure 2.Described first and second heat pipes 108 and 110 can comprise for example A106B level carbon steel sheath, are used for protecting.By this way, described first and second heat pipes 108,110 can weld or otherwise be fixed to the external surface 104 of pipeline 102.Pipeline 102 can also support fiber optic cables sleeve pipe 112, described fiber optic cables sleeve pipe 112 the fixed-site of about " 12:00 " clock be attached to the external surface 104 of pipeline 102.This reference by location of " 10:30 ", " 1:30 " and " 12:00 o'clock " is represented the reference standard clock dial with respect to the general location of pipeline 102 as used herein, wherein regards the central vertical position that is positioned on the described pipeline 102 12 o'clock as.
The external surface 104 of pipeline 102 can comprise first outer peripheral portion 114, and described first outer peripheral portion 114 is limited between radial line C and the radial line C ', comprises radial line C and radial line C '.The external surface 104 of pipeline 102 can also comprise second outer peripheral portion 116, and described second outer peripheral portion 116 is limited between radial line C and the radial line C ', does not comprise radial line C and radial line C '.In other words, in the embodiment shown in Fig. 2, described first outer peripheral portion 114 can be bottom (with respect to the position of heat pipe 108 and 110) quadrant.Described first outer peripheral portion 114 can carry the first rigidity heat-barrier material 118, and the described first rigidity heat-barrier material 118 has bearing high temperature ability and high-bearing capacity.Illustrate but not limit to, described rigidity heat-barrier material can be configured to the anti-pipe temperature that exceeds 235 ℃.The example of appropriate rigidity heat-barrier material can be including, but not limited to expanded perlite/high density silicic acid calcium/HITLIN TM
The second outer peripheral portion 116(namely, all the other external surfaces 104 of the pipeline 102 in the exemplary embodiment shown in Fig. 2) can be besieged or cover in second heat-barrier material 120.Second heat-barrier material 120 can be high temperature elasticity and the higher density insulation material such as high density rock wool heat-barrier material, wherein, described high density rock wool heat-barrier material for example has the molded groove of factory, the molded groove of described factory be suitable for first and second heat pipes 108,110 and fiber optic cables sleeve pipe 112 match.
Metal interface wrap member 122 can cover or seal first and second outer peripheral portions 114,116 external surface.Described metal interface wrap member 122 can advantageously distribute heat around the circumference of pipeline 102.The combination of first heat-barrier material 118 and second heat-barrier material 120 defines first isolation layer.In a preferred embodiment, metal interface wrap member 122 surround first isolation layers 124 and make described first isolation layer 124 and second or outer isolation layer 126 separate.
Second or outer 126 can be high temperature polyurethane foam (PUF) thermal insulation barriers with adequate thickness and density, to reduce along the thermal losses of pipeline 102, provides the sufficient compressive strength of filling the weight of sulphur pipeline in order to support simultaneously.In one embodiment, can apply described polyurethane foam by " controlled spraying technology ", to cause producing concentric thermal insulation barriers, can also use other application process although notice.In addition, high density polyethylene (HDPE) (HDPE) vapor barrier 128 can be wrapped up or otherwise be arranged in around the second layer or outer 126 of pipeline 102.
Fig. 3 to Fig. 6 shows the thermoanalytical graphical presentation of the element of exemplary fluid-mixing pipe insulation of the present invention system.Especially, each in the accompanying drawing all is to represent that heat that pipeline 102 may stand is considered and/or the finite element analysis image of fuel factor.For example, can select or utilize every layer of homogeneity thermal losses that is created in the described thermal insulation barriers of thermal insulation barriers.The information of being determined by the finite element analysis image of Fig. 3 to Fig. 6 can be used for preventing from producing the thermal losses of difference to some extent at the isolation layer of sealing pipeline 102, thereby causes the inconsistent temperature at the interface between internal layer and the skin.
The thickness of two materials of the internal layer of thermal insulation barriers or first floor can be used for be analyzed and/or be determined to comprise to the finite element analysis image of Fig. 3 to Fig. 6.In two materials of first floor each all has the different k values and different compression coefficient with respect to another kind of material, makes that the individual material of selection is very important.And the temperature at the interface of control internal layer or first floor and skin or the second layer is very important, and reason is that the rated temperature of skin or foams is lower than the possible temperature that can stand at the interface described.Shorten the application life that makes the skin of thermal insulation barriers or the second layer be in to cause the foams thermal insulation barriers under the temperatures involved usually or reduce and finally cause producing unacceptable thermal losses.Just because of this, can select mixing heat-barrier material described here structure and be applied to pipeline 102 to prevent not desired temperatures condition.
In one embodiment of the invention, can rotatably support pipeline 102, to allow heat-barrier material to aim at the external surface of pipeline 102 and it is applied to the external surface of pipeline 102 with desirable position, amount and thickness.For example, can rotate along longitudinal center line at place, both ends support one segment pipe 102 and its.Under the condition of computer and/or analysis and Control, can use one or more spray nozzles heat-barrier material is applied to exact position and structure place.
The embodiment disclosed herein provides a kind of cost-efficient heat insulation skin effect heating system, and it is that the ducted fluid (including, but not limited to sulphur) that is included in that carries in the pipeline such as pipeline 102 provides safety and fusion more reliably with the melt-flow that produces sulphur that described heating system applies concentrated heat by the desirable part place at pipe.The melt-flow of " rat hole " or sulphur is along the length of pipeline 102 and adjoin first and second heat pipes 108 and 110 extend.Rat hole allows molten sulfur to flow in the dead band of pipeline 102, simultaneously in the possibility of eliminating excessive heat sulphur pipeline 102.Mix compound heat-insulation spare and also prevent the possibility of the air gap relevant with the hard heat-insulating spare of " fluting ", the compressive strength of the base section place need of pipe is provided simultaneously.
Foregoing invention has some special features, although under not departing from the prerequisite of scope of the present invention, can use each described some special feature separately, and described some special features of Combination application preferably.Although this illustrate and described preferred embodiment of the present invention, but should be understood that except implementing the present invention with the embodiment in this special diagram or description, can also be in the scope of basic conception of the present invention or principle to form and the arrangement of parts and put into practice ad hoc fashion of the present invention and make some change.

Claims (9)

1. one kind is mixed insulation system, comprising:
A) pipeline, described pipeline has: hollow inside, described hollow is constructed inside into the fluid bearings material; With at least one heating element, described at least one heating element is carried by the external surface of described pipeline;
B) first isolation layer, described first isolation layer comprises:
I) first insulating portion is carried first insulating portion along first outer peripheral portion of the external surface of described pipeline, and wherein, described first insulating portion is arranged to relative substantially by described at least one heating element of described external surface carrying;
Ii) second insulating portion is carried described second insulating portion along second outer peripheral portion of the external surface of described pipeline;
C) second isolation layer, described second isolation layer are sealed described first isolation layer and are configured to and extend along the external surface of described pipeline.
2. mixing insulation system according to claim 1, described mixing insulation system also comprises the metal interface wrap member, described metal interface wrap member surrounds described first isolation layer.
3. mixing insulation system according to claim 1, described mixing insulation system also comprises vapor barrier, described vapor barrier is surrounded described second isolation layer.
4. mixing insulation system according to claim 3, wherein, described vapor barrier is high density polyethylene (HDPE) (HDPE) vapor barrier.
5. mixing insulation system according to claim 1, wherein, described pipeline is carbon steel tube.
6. mixing insulation system according to claim 1, described mixing insulation system also comprises optical fiber tube, adjoins described at least one heating element substantially and carries described optical fiber tube.
7. mixing insulation system according to claim 1, wherein, described first insulating portion is the expanded perlite thermal insulation barriers.
8. mixing insulation system according to claim 1, wherein, described second insulating portion is high density rock wool thermal insulation barriers.
9. mixing insulation system according to claim 1, wherein, described second isolation layer is polyurethane foam (PUF).
CN2011800443752A 2010-09-15 2011-09-15 Heat trace system including hybrid composite insulation Pending CN103282588A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US38325810P 2010-09-15 2010-09-15
US61/383,258 2010-09-15
PCT/US2011/051799 WO2012037374A1 (en) 2010-09-15 2011-09-15 Heat trace system including hybrid composite insulation

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CN103282588A true CN103282588A (en) 2013-09-04

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US (1) US9719623B2 (en)
EP (1) EP2616605A4 (en)
KR (1) KR20130118869A (en)
CN (1) CN103282588A (en)
BR (1) BR112013006285A2 (en)
CA (1) CA2811549C (en)
CL (1) CL2013000700A1 (en)
RU (1) RU2598500C2 (en)
WO (1) WO2012037374A1 (en)

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CN101663527A (en) * 2006-11-14 2010-03-03 普拉德研究及开发股份有限公司 Dispose the method and system of one or more optical fiber waveguides in conjunction and pipeline
CN201116473Y (en) * 2007-11-13 2008-09-17 煤炭科学研究总院南京研究所 Wet-type concrete spraying units
CN101469793A (en) * 2008-01-08 2009-07-01 张征年 Multi-wall interlayer hollow plastic heat preserving and cold insulating pipeline
US20090293350A1 (en) * 2008-05-27 2009-12-03 Fountainhead, Llc Raised bed planter with biomimetic exoskeleton

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CN103883834A (en) * 2014-03-07 2014-06-25 江阴市华能电热器材有限公司 Single-core series-connection electric heat tracing system
CN106535371A (en) * 2016-11-28 2017-03-22 中国石油大学(华东) Grid type electric blanket tube bundle heater
CN106535371B (en) * 2016-11-28 2019-08-02 中国石油大学(华东) A kind of grating electric blanket tube bundle heater
CN106598098B (en) * 2016-12-16 2019-04-16 中广核工程有限公司 Intelligent nuclear power plant technique pipeline tracing device
CN113819334A (en) * 2021-10-09 2021-12-21 济南睿达物联网有限公司 Heat-insulation water pipe capable of being heated
CN113819334B (en) * 2021-10-09 2023-01-13 济南睿达物联网有限公司 Heat-insulation water pipe capable of being heated
CN114458838A (en) * 2022-01-22 2022-05-10 巩义市泛锐熠辉复合材料有限公司 Heat-insulation composite pipe and preparation method thereof
CN114458838B (en) * 2022-01-22 2023-11-03 巩义市泛锐熠辉复合材料有限公司 Heat-insulating composite pipe and preparation method thereof

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RU2013116744A (en) 2014-10-20
EP2616605A4 (en) 2014-09-03
RU2598500C2 (en) 2016-09-27
KR20130118869A (en) 2013-10-30
CL2013000700A1 (en) 2014-03-07
EP2616605A1 (en) 2013-07-24
CA2811549C (en) 2018-10-23
US9719623B2 (en) 2017-08-01
US20130248013A1 (en) 2013-09-26
WO2012037374A1 (en) 2012-03-22
BR112013006285A2 (en) 2017-07-04

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