CN103275458A - Polyether-ether-ketone cable material and manufacturing method thereof - Google Patents
Polyether-ether-ketone cable material and manufacturing method thereof Download PDFInfo
- Publication number
- CN103275458A CN103275458A CN201310246026XA CN201310246026A CN103275458A CN 103275458 A CN103275458 A CN 103275458A CN 201310246026X A CN201310246026X A CN 201310246026XA CN 201310246026 A CN201310246026 A CN 201310246026A CN 103275458 A CN103275458 A CN 103275458A
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- China
- Prior art keywords
- ether
- polyether
- forcing machine
- ketone
- temperature
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Insulating Materials (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a polyether-ether-ketone cable material and a manufacturing method thereof. According to the invention, the cable material is formed in a way that the components, by weight percent, of 80-85 parts of polyether-ether-ketone, 10-15 parts of polyester ether, 3-5 parts of polyphenyl ether, and 0.3-0.5 parts of carbimide are mixed according to a traditional mixing method. The method comprises the following steps: adding mixture to a mixer and mixing evenly by adopting the mixer directly; extruding out prillings through a extruder; and arranging the temperature of each section of the extruder to between 140-345 DEG C when extruding the prillings. The cable material manufactured by the method has higher strength, high wear resistance and oil resistance, and good electrical insulating property, has the characteristics of low smoke, zero halogen, inflaming retarding, and the like, is extremely suitable for the extruding of electric thin wall cable, can satisfy the processing technique and the product technical requirement of an ultra-thin wall insulated cable, and has convenience in manufacturing, and excellent economic benefit and promotion value.
Description
Technical field
The present invention relates to a kind of industrial chemicals, particularly a kind of polyether-ether-ketone CABLE MATERIALS and preparation method thereof.
Background technology
Because China Express Railway and urban track traffic Equipment Development are rapid, the requirement with cable develops towards ultra-thin-wall, high-temperature resistant, high oil resistant, high flame retardant direction to high ferro and city rail equipment in manufacturing concern.The insulating wall thickness of common thin-walled cable is more than 0.3mm, and the required ultra-thin-wall insulated cable insulation wall thickness of high-speed railway and urban track traffic equipment requires to be 0.18mm.At present, the main insulating material of cable industry production thin-walled cable is cross-linked polyolefin, owing to contain more fire retardant in this CABLE MATERIALS, insulation resistance is less, cable is breakdown easily, and there are many deficiencies in the physical and mechanical properties of cable, and insulating wall can not be realized ultra-thin, is difficult to satisfy the needs of manufacturing concern.Therefore, a gordian technique of the ultra-thin-wall insulated cable of production high-temperature resistant, high oil resistant, high flame retardant is exactly the suitable CABLE MATERIALS of research.
Summary of the invention
One of purpose of the present invention is the above-mentioned deficiency that overcomes prior art, and provides a kind of and have high-temperature resistant, high oil resistant, high flame retardant, high insulation resistance, easily characteristics such as extrudes, and is fit to the polyether-ether-ketone CABLE MATERIALS of the production of ultra-thin-wall cable.
The technical scheme that realizes above-mentioned purpose of the present invention is: a kind of polyether-ether-ketone CABLE MATERIALS, it is counted by weight percentage is to be formed according to traditional compounding process is mixing by following component: 80～85 parts of polyether-ether-ketones, 10～15 parts of polyester ethers, 3～5 parts of polyphenylene oxide, 0.3～0.5 part of carbimide; Above-mentioned component added to simultaneously by said ratio take direct mechanical to mix in the blender, and by the forcing machine extruding pelletization, each zone temperatures of forcing machine is set to 140～345 ℃ during extruding pelletization.
The further technical scheme of the present invention is: during extruding pelletization, the temperature in forcing machine one district is set to 140～150 ℃, the temperature in forcing machine two districts is set to 180～190 ℃, the temperature in forcing machine three districts is set to 240～250 ℃, the temperature in forcing machine four districts is set to 330～345 ℃, the temperature of forcing machine flange is set to 330～345 ℃, and the temperature of cross-head die orifice is set to 330～340 ℃.
Two of purpose of the present invention is the above-mentioned deficiencies that overcome prior art, and provides a kind of and have high-temperature resistant, high oil resistant, high flame retardant, high insulation resistance, easily characteristics such as extrudes, and is fit to the making method of polyether-ether-ketone CABLE MATERIALS of the production of ultra-thin-wall cable.
The technical scheme that realizes above-mentioned purpose of the present invention is: a kind of making method of polyether-ether-ketone CABLE MATERIALS, it is counted by weight percentage is to be formed according to traditional compounding process is mixing by following component: 80～85 parts of polyether-ether-ketones, 10～15 parts of polyester ethers, 3～5 parts of polyphenylene oxide, 0.3～0.5 part of carbimide; Above-mentioned component added to simultaneously by said ratio take direct mechanical to mix in the blender, and by the forcing machine extruding pelletization, each zone temperatures of forcing machine is set to 140～345 ℃ during extruding pelletization.
The further technical scheme of the present invention is: during extruding pelletization, the temperature in forcing machine one district is set to 140～150 ℃, the temperature in forcing machine two districts is set to 180～190 ℃, the temperature in forcing machine three districts is set to 240～250 ℃, the temperature in forcing machine four districts is set to 330～345 ℃, the temperature of forcing machine flange is set to 330～345 ℃, and the temperature of cross-head die orifice is set to 330～340 ℃.
Adopt the inventive method to make CABLE MATERIALS, compared with prior art, it is good that the CABLE MATERIALS of making not only has high strength, high abrasion, high oil resistant, electrical insulating property, have low cigarette, Halogen, characteristic such as fire-retardant simultaneously, can satisfy complete processing and the product technology requirement of ultra-thin-wall insulated cable, manufacture conveniently, have good economic benefit and promotional value.
Below in conjunction with embodiment detailed construction of the present invention is further described.
Embodiment
Embodiment one:
A kind of making method of polyether-ether-ketone CABLE MATERIALS, counting by weight percentage is to be formed according to traditional compounding process is mixing by following component: 80 parts of polyether-ether-ketones, 15 parts of polyester ethers, 4.5 parts of polyphenylene oxide, 0.5 part of carbimide; Mixture adds to takes direct mechanical to mix in the blender, and by the forcing machine extruding pelletization, each zone temperatures of forcing machine is set to during granulation: the temperature in forcing machine one district is set to 140～150 ℃, the temperature in forcing machine two districts is set to 180～190 ℃, the temperature in forcing machine three districts is set to 240～250 ℃, the temperature in forcing machine four districts is set to 330～345 ℃, and the temperature of forcing machine flange is set to 330～345 ℃, and the temperature of cross-head die orifice is set to 330～340 ℃.
The CABLE MATERIALS that adopts aforesaid method of the present invention to make, have that intensity is higher, high abrasion, high oil resistant, electrical insulating property be good, and have low cigarette, Halogen, characteristic such as fire-retardant, be fit to very much electric thin-walled cable extrude, can satisfy complete processing and the product technology requirement of ultra-thin-wall insulated cable.
Embodiment two:
A kind of making method of polyether-ether-ketone CABLE MATERIALS, counting by weight percentage is to be formed according to traditional compounding process is mixing by following component: 85 parts of polyether-ether-ketones, 12 parts of polyester ethers, 2.7 parts of polyphenylene oxide, 0.3 part of carbimide; Mixture adds to takes direct mechanical to mix in the blender, and by the forcing machine extruding pelletization, each zone temperatures of forcing machine is set to during granulation: the temperature in forcing machine one district is set to 140～150 ℃, the temperature in forcing machine two districts is set to 180～190 ℃, the temperature in forcing machine three districts is set to 240～250 ℃, the temperature in forcing machine four districts is set to 330～345 ℃, and the temperature of forcing machine flange is set to 330～345 ℃, and the temperature of cross-head die orifice is set to 330～340 ℃.
The CABLE MATERIALS that adopts aforesaid method of the present invention to make, it is good to have high strength, high abrasion, high oil resistant, electrical insulating property, and have low cigarette, Halogen, characteristic such as fire-retardant, the expressing technique better performances can satisfy complete processing and the product technology requirement of ultra-thin-wall insulated cable.
Claims (8)
1. polyether-ether-ketone CABLE MATERIALS, it is characterized in that counting by weight percentage is to be formed according to traditional compounding process is mixing by following component: 80～85 parts of polyether-ether-ketones, 10～15 parts of polyester ethers, 3～5 parts of polyphenylene oxide, 0.3～0.5 part of carbimide; Above-mentioned component added to simultaneously by said ratio take direct mechanical to mix in the blender, and by the forcing machine extruding pelletization, each zone temperatures of forcing machine is set to 140～345 ℃ during extruding pelletization.
2. polyether-ether-ketone CABLE MATERIALS according to claim 1, it is characterized in that counting by weight percentage is to be formed according to traditional compounding process is mixing by following component: polyether-ether-ketone 80%, polyester ether 15%, polyphenylene oxide 4.5%, carbimide 0.5%.
3. polyether-ether-ketone CABLE MATERIALS according to claim 1, it is characterized in that counting by weight percentage is to be formed according to traditional compounding process is mixing by following component: polyether-ether-ketone 85%, polyester ether 12%, polyphenylene oxide 2.7%, carbimide 0.3%.
4. according to the described polyether-ether-ketone CABLE MATERIALS of claim 1-3, each zone temperatures of forcing machine is set to when it is characterized in that granulation: the temperature in forcing machine one district is set to 140～150 ℃, the temperature in forcing machine two districts is set to 180～190 ℃, the temperature in forcing machine three districts is set to 240～250 ℃, the temperature in forcing machine four districts is set to 330～345 ℃, the temperature of forcing machine flange is set to 330～345 ℃, and the temperature of cross-head die orifice is set to 330～340 ℃.
5. the making method of a polyether-ether-ketone CABLE MATERIALS, it is characterized in that counting by weight percentage is to be formed according to traditional compounding process is mixing by following component: 80～85 parts of polyether-ether-ketones, 10～15 parts of polyester ethers, 3～5 parts of polyphenylene oxide, 0.3～0.5 part of carbimide; Mixture adds to takes direct mechanical to mix in the blender, and by the forcing machine extruding pelletization, each zone temperatures of forcing machine is set to 140～345 ℃ during extruding pelletization.
6. the making method of polyether-ether-ketone CABLE MATERIALS according to claim 5, it is characterized in that counting by weight percentage is to be formed according to traditional compounding process is mixing by following component: polyether-ether-ketone 80%, polyester ether 15%, polyphenylene oxide 4.5%, carbimide 0.5%.
7. the making method of polyether-ether-ketone CABLE MATERIALS according to claim 5, it is characterized in that counting by weight percentage is to be formed according to traditional compounding process is mixing by following component: polyether-ether-ketone 85%, polyester ether 12%, polyphenylene oxide 2.7%, carbimide 0.3%.
8. according to the making method of the described polyether-ether-ketone CABLE MATERIALS of claim 5-7, each zone temperatures of forcing machine is set to when it is characterized in that granulation: the temperature in forcing machine one district is set to 140～150 ℃, the temperature in forcing machine two districts is set to 180～190 ℃, the temperature in forcing machine three districts is set to 240～250 ℃, the temperature in forcing machine four districts is set to 330～345 ℃, the temperature of forcing machine flange is set to 330～345 ℃, and the temperature of cross-head die orifice is set to 330～340 ℃.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510769477.0A CN105219019A (en) | 2013-06-20 | 2013-06-20 | A kind of Polyether-ether-ketocable cable material and preparation method thereof |
| CN201310246026.XA CN103275458B (en) | 2013-06-20 | 2013-06-20 | A kind of Polyether-ether-ketocable cable material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310246026.XA CN103275458B (en) | 2013-06-20 | 2013-06-20 | A kind of Polyether-ether-ketocable cable material and preparation method thereof |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510769477.0A Division CN105219019A (en) | 2013-06-20 | 2013-06-20 | A kind of Polyether-ether-ketocable cable material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN103275458A true CN103275458A (en) | 2013-09-04 |
| CN103275458B CN103275458B (en) | 2016-07-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510769477.0A Pending CN105219019A (en) | 2013-06-20 | 2013-06-20 | A kind of Polyether-ether-ketocable cable material and preparation method thereof |
| CN201310246026.XA Active CN103275458B (en) | 2013-06-20 | 2013-06-20 | A kind of Polyether-ether-ketocable cable material and preparation method thereof |
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| CN201510769477.0A Pending CN105219019A (en) | 2013-06-20 | 2013-06-20 | A kind of Polyether-ether-ketocable cable material and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103928150A (en) * | 2014-04-26 | 2014-07-16 | 芜湖航天特种电缆厂 | Waterproof control cable |
| CN107674377A (en) * | 2017-11-13 | 2018-02-09 | 安徽省康利亚股份有限公司 | A kind of motor train unit wheel is to velocity sensor cable |
| CN109851730A (en) * | 2018-12-29 | 2019-06-07 | 福建师范大学 | One kind containing DOPO side group Polyether-ether-ketocable cable material and preparation method thereof |
| CN117757248A (en) * | 2023-12-08 | 2024-03-26 | 杭州普天乐电缆有限公司 | Wear-resistant impact-resistant material for coaxial cable and preparation process thereof |
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| CN101130616A (en) * | 2007-09-28 | 2008-02-27 | 深圳市科聚新材料有限公司 | Low-smoke halogen-freeflame-proof polyphenylene oxide electric wire and cable material, and method for producing the same |
| CN102660103A (en) * | 2012-03-13 | 2012-09-12 | 大连路阳科技开发有限公司 | Antistatic polyether-ether-ketone composite material and preparation method thereof |
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| CN101157796A (en) * | 2007-09-30 | 2008-04-09 | 南京金紫鑫工程塑料有限公司 | Polyetheretherketone steel bar and preparation method and uses thereof |
| CN201698809U (en) * | 2010-06-30 | 2011-01-05 | 四川川泰线缆有限公司 | Polyether-ether-ketone (PEEK) high-flame-retardant low-carbon flexible fire-resistant wire cable |
| CN102332334A (en) * | 2011-06-02 | 2012-01-25 | 江苏恒神纤维材料有限公司 | Composite material cable reinforcing mandrel for power transmission cable |
| CN202662323U (en) * | 2012-05-22 | 2013-01-09 | 安徽省高沟电缆有限公司 | High-temperature-resisting cable |
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2013
- 2013-06-20 CN CN201510769477.0A patent/CN105219019A/en active Pending
- 2013-06-20 CN CN201310246026.XA patent/CN103275458B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130616A (en) * | 2007-09-28 | 2008-02-27 | 深圳市科聚新材料有限公司 | Low-smoke halogen-freeflame-proof polyphenylene oxide electric wire and cable material, and method for producing the same |
| CN102660103A (en) * | 2012-03-13 | 2012-09-12 | 大连路阳科技开发有限公司 | Antistatic polyether-ether-ketone composite material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103928150A (en) * | 2014-04-26 | 2014-07-16 | 芜湖航天特种电缆厂 | Waterproof control cable |
| CN107674377A (en) * | 2017-11-13 | 2018-02-09 | 安徽省康利亚股份有限公司 | A kind of motor train unit wheel is to velocity sensor cable |
| CN109851730A (en) * | 2018-12-29 | 2019-06-07 | 福建师范大学 | One kind containing DOPO side group Polyether-ether-ketocable cable material and preparation method thereof |
| CN117757248A (en) * | 2023-12-08 | 2024-03-26 | 杭州普天乐电缆有限公司 | Wear-resistant impact-resistant material for coaxial cable and preparation process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103275458B (en) | 2016-07-06 |
| CN105219019A (en) | 2016-01-06 |
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Address after: 421008 123 Huang Bai Road, Yanfeng District, Hengyang, Hunan Patentee after: Hang Fei cable Limited by Share Ltd Address before: 421008 123 Huang Bai Road, Yanfeng District, Hengyang, Hunan Patentee before: Hengyang Hengfei Cable Co., Ltd. |
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