CN103275424A - polyvinyl chloride (PVC) sole material with high wear resistance - Google Patents
polyvinyl chloride (PVC) sole material with high wear resistance Download PDFInfo
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- CN103275424A CN103275424A CN2013102130467A CN201310213046A CN103275424A CN 103275424 A CN103275424 A CN 103275424A CN 2013102130467 A CN2013102130467 A CN 2013102130467A CN 201310213046 A CN201310213046 A CN 201310213046A CN 103275424 A CN103275424 A CN 103275424A
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- Prior art keywords
- sole
- pvc
- pvc material
- wearing feature
- wear
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- 239000000463 material Substances 0.000 title claims abstract description 26
- 239000004800 polyvinyl chloride Substances 0.000 title abstract 5
- 239000000314 lubricant Substances 0.000 claims abstract description 9
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003381 stabilizer Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 8
- 239000004902 Softening Agent Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 229920001903 high density polyethylene Polymers 0.000 claims description 5
- 239000004700 high-density polyethylene Substances 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims description 4
- -1 Zinic stearas Chemical compound 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical group [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 claims description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000292 calcium oxide Substances 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical group O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 2
- 229960003656 ricinoleic acid Drugs 0.000 claims description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229960001866 silicon dioxide Drugs 0.000 claims description 2
- XJKVPKYVPCWHFO-UHFFFAOYSA-N silicon;hydrate Chemical compound O.[Si] XJKVPKYVPCWHFO-UHFFFAOYSA-N 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 3
- 239000012800 wear resistant modifier Substances 0.000 abstract 2
- 238000005452 bending Methods 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 238000005303 weighing Methods 0.000 description 4
- 238000004898 kneading Methods 0.000 description 3
- 230000001404 mediated effect Effects 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 206010016256 fatigue Diseases 0.000 description 1
- 210000004744 fore-foot Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a polyvinyl chloride (PVC) sole material with high wear resistance. The material comprises the following components in percentage by weight: 50-55 percent of PVC, 25-30 percent of plasticizer, 2-3 percent of stabilizer, 3-5 percent of wear-resistant modifier, 4-6 percent of CPE, 4-6 percent of kaolin and 4-5 percent of lubricating agent. According to the PVC sole material, due to the addition of the wear-resistant modifier the wear resistance of the surface of the PVC sole can be improved, the wear is reduced, and the bending fatigue resistance is improved, so that the service life of the sole is prolonged.
Description
Technical field:
The present invention relates to footwear material technical field, relate in particular to a kind of PVC material for sole of shoe.
Background technology:
As everyone knows, made in China footwear are all over the world.The footwear annual production of China surpasses 10,000,000,000 pairs, accounts for 45% of global footwear output.The footwear industry volume of retail sales reaches 3,000 hundred million yuans.In recent years because the rubber overshoes industry begins to pursue high quality, pay attention to rubber overshoes comfortable and easy to wear, attractive in appearance, anti-skidding, the life-span is long, and bigger variation is also arranged on materials.The sole flexibility of existing P VC footwear is poor, wears no resistance, and wears uncomfortablely, and in addition, sole is easier to wearing and tearing at forefoot and rear heel place, thereby shortens the work-ing life of PVC sole, has both caused waste, again environment is caused disadvantageous effect.
The wear-resisting properties-correcting agent of methyl siliconic acid salt is used for PVC sole anti-wear agent, silicone anti-wear agent, by and the wear-resisting oil base material of silicone and carrier polymer between react, effectively increase wear-resisting reinforcing property, processing characteristics and the avidity of PVC material for sole of shoe.
Summary of the invention:
The purpose of this invention is to provide a kind of high-wearing feature PVC material for sole of shoe, the PVC sole that is made by this material has good wear resistance.
Purpose of the present invention is achieved through the following technical solutions:
A kind of high-wearing feature PVC material for sole of shoe comprises following component by weight percentage:
PVC 50-55%；
Softening agent 25-30%;
Stablizer 2-3%;
Wear-resisting properties-correcting agent 3-5%;
CPE 4-6%；
Kaolin 4-6%;
Lubricant 4-5%.
Preferred as technique scheme, described softening agent is one or several mixtures in fatty acid butyl ester and the tributyl citrate.
Preferred as technique scheme, described stablizer is calcium zinc stabilizer, main component has calcium stearate, ricinolic acid calcium, Zinic stearas, zinc ricinate and epoxy soybean oil, UV light absorber.
Preferred as technique scheme, described wear-resisting properties-correcting agent is the methyl siliconic acid salt compounds.
Preferred as technique scheme, described CPE is the macromolecular material that chlorinatedpolyethylene high density polyethylene(HDPE) (HDPE) makes through the chlorination substitution reaction.
Preferred as technique scheme, described kaolinic main component is aluminum oxide, silicon-dioxide and water also contain calcium oxide and ferric oxide.
Preferred as technique scheme, described lubricant is one or more mixtures in stearic acid, PE wax, fatty acid calcium, the polyvinyl alcohol.
Beneficial effect of the present invention is: the wear-resisting properties-correcting agent of its adding can improve the wear resistance of PVC sole surface, reduces wearing and tearing, improves anti-bent fatigability, thereby prolongs the life-span of sole.
Embodiment:
In order to deepen the understanding of the present invention, the invention will be further described below in conjunction with embodiment, and this embodiment only is used for explaining the present invention, does not constitute the restriction to protection domain of the present invention.
Embodiment 1:
Take by weighing PVC material 52g, softening agent 26g, stablizer 2.6g, wear-resisting properties-correcting agent 4.4g, CPE5.2g, kaolin 5.2g, lubricant 4.6g.The PVC that takes by weighing is added high speed to be mediated 5-7 minute, remove small amount of moisture among the PVC, treat that temperature reaches 60-70 ℃, with stablizer, wear-resisting properties-correcting agent, CPE, kaolin, lubricant drop into and carry out the high speed kneading in the high-speed mixer, treat that temperature reaches 80-90 ℃ and softening agent dropped into goes forward side by side that s is capable to be mediated at a high speed, discharging when temperature reaches 100 ℃, thus the PVC plastic hybrid obtained, again with the mixture that obtains, drop into extruding pelletization in the twin screw extruder, plasticizing forming obtains the PVC material for sole of shoe.Cutting diameter is 16mm, and thickness is that the circular specimen of 6mm is installed on the test machine and tests, and sets the friction number of times, and calculates the wearing and tearing quality.
Embodiment 2:
Take by weighing PVC material 52.5g, softening agent 25g, stablizer 2.5g, wear-resisting properties-correcting agent 5g, CPE5g, kaolin 5g, lubricant 5g.The PVC that takes by weighing is added high speed to be mediated 5-7 minute, remove small amount of moisture among the PVC, treat that temperature reaches 60-70 ℃, with stablizer, wear-resisting properties-correcting agent, CPE, kaolin, lubricant drop into and carry out the high speed kneading in the high-speed mixer, treat that temperature reaches 80-90 ℃ with the softening agent input and carries out the high speed kneading, discharging when temperature reaches 100 ℃, thus the PVC plastic hybrid obtained, again with the mixture that obtains, drop into extruding pelletization in the twin screw extruder, plasticizing forming obtains the PVC material for sole of shoe.Cutting diameter is 16mm, and thickness is that the circular specimen of 6mm is installed on the test machine and tests, and sets the friction number of times, and calculates the wearing and tearing quality.
Table 1 adds the analytical data of wear-resisting properties-correcting agent
| Embodiment | The friction number of times | Wearing and tearing quality/g |
| Embodiment 1 | 500 | 1.55 |
| Embodiment 2 | 500 | 1.12 |
Claims (7)
1. high-wearing feature PVC material for sole of shoe is characterized in that: comprise following component by weight percentage:
PVC 50-55%；
Softening agent 25-30%;
Stablizer 2-3%;
Wear-resisting properties-correcting agent 3-5%;
CPE 4-6%；
Kaolin 4-6%;
Lubricant 4-5%.
2. a kind of high-wearing feature PVC material for sole of shoe according to claim 1, it is characterized in that: described softening agent is one or several mixtures in fatty acid butyl ester and the tributyl citrate.
3. a kind of high-wearing feature PVC material for sole of shoe according to claim 1, it is characterized in that: described stablizer is calcium zinc stabilizer, and main component has calcium stearate, ricinolic acid calcium, Zinic stearas, zinc ricinate and epoxy soybean oil, UV light absorber.
4. a kind of high-wearing feature PVC material for sole of shoe according to claim 1, it is characterized in that: described wear-resisting properties-correcting agent is the methyl siliconic acid salt compounds.
5. a kind of high-wearing feature PVC material for sole of shoe according to claim 1, it is characterized in that: described CPE is the macromolecular material that the chlorinatedpolyethylene high density polyethylene(HDPE) makes through the chlorination substitution reaction.
6. a kind of high-wearing feature PVC material for sole of shoe according to claim 1, it is characterized in that: described kaolinic main component is aluminum oxide, silicon-dioxide and water also contain calcium oxide and ferric oxide.
7. a kind of high-wearing feature PVC material for sole of shoe according to claim 1, it is characterized in that: described lubricant is one or more mixtures in stearic acid, PE wax, fatty acid calcium, the polyvinyl alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102130467A CN103275424A (en) | 2013-05-31 | 2013-05-31 | polyvinyl chloride (PVC) sole material with high wear resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102130467A CN103275424A (en) | 2013-05-31 | 2013-05-31 | polyvinyl chloride (PVC) sole material with high wear resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103275424A true CN103275424A (en) | 2013-09-04 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102130467A Pending CN103275424A (en) | 2013-05-31 | 2013-05-31 | polyvinyl chloride (PVC) sole material with high wear resistance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103275424A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104262821A (en) * | 2014-09-04 | 2015-01-07 | 苏州市景荣科技有限公司 | High wear-resistant PVC foamed sole material and preparation method thereof |
| CN104262823A (en) * | 2014-09-04 | 2015-01-07 | 苏州市景荣科技有限公司 | High-wear-resistance polyvinyl chloride foamed shoe sole material and manufacturing method thereof |
| CN106084634A (en) * | 2016-06-30 | 2016-11-09 | 嘉兴市哈妮鞋业有限公司 | Preparation rubber soles is with lubricator |
| CN106084635A (en) * | 2016-06-30 | 2016-11-09 | 嘉兴市哈妮鞋业有限公司 | Rubber soles preparation method with lubricator |
| CN104262823B (en) * | 2014-09-04 | 2017-01-04 | 苏州市景荣科技有限公司 | The foam polyvinyl chloride material for sole of shoe of a kind of high abrasion and manufacture method thereof |
| CN107200958A (en) * | 2017-06-13 | 2017-09-26 | 合肥远科服装设计有限公司 | A kind of high performance plastic sole and preparation method thereof |
| CN107254121A (en) * | 2017-07-28 | 2017-10-17 | 合肥布竹梦依服装贸易有限公司 | A kind of high performance plastic sole and preparation method thereof |
| CN110885516A (en) * | 2019-12-17 | 2020-03-17 | 含山县仁盛鞋业有限公司 | Preparation method of wear-resistant plastic sandal material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323693A (en) * | 2008-08-05 | 2008-12-17 | 沈阳化工学院 | A kind of dynamically vulcanized thermoplastic elastomer and preparation method thereof |
-
2013
- 2013-05-31 CN CN2013102130467A patent/CN103275424A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323693A (en) * | 2008-08-05 | 2008-12-17 | 沈阳化工学院 | A kind of dynamically vulcanized thermoplastic elastomer and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104262821A (en) * | 2014-09-04 | 2015-01-07 | 苏州市景荣科技有限公司 | High wear-resistant PVC foamed sole material and preparation method thereof |
| CN104262823A (en) * | 2014-09-04 | 2015-01-07 | 苏州市景荣科技有限公司 | High-wear-resistance polyvinyl chloride foamed shoe sole material and manufacturing method thereof |
| CN104262823B (en) * | 2014-09-04 | 2017-01-04 | 苏州市景荣科技有限公司 | The foam polyvinyl chloride material for sole of shoe of a kind of high abrasion and manufacture method thereof |
| CN106084634A (en) * | 2016-06-30 | 2016-11-09 | 嘉兴市哈妮鞋业有限公司 | Preparation rubber soles is with lubricator |
| CN106084635A (en) * | 2016-06-30 | 2016-11-09 | 嘉兴市哈妮鞋业有限公司 | Rubber soles preparation method with lubricator |
| CN107200958A (en) * | 2017-06-13 | 2017-09-26 | 合肥远科服装设计有限公司 | A kind of high performance plastic sole and preparation method thereof |
| CN107254121A (en) * | 2017-07-28 | 2017-10-17 | 合肥布竹梦依服装贸易有限公司 | A kind of high performance plastic sole and preparation method thereof |
| CN110885516A (en) * | 2019-12-17 | 2020-03-17 | 含山县仁盛鞋业有限公司 | Preparation method of wear-resistant plastic sandal material |
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Application publication date: 20130904 |