CN103274764A - High and low-temperature resistant porcelain glaze for enamel - Google Patents
High and low-temperature resistant porcelain glaze for enamel Download PDFInfo
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- CN103274764A CN103274764A CN2013101663534A CN201310166353A CN103274764A CN 103274764 A CN103274764 A CN 103274764A CN 2013101663534 A CN2013101663534 A CN 2013101663534A CN 201310166353 A CN201310166353 A CN 201310166353A CN 103274764 A CN103274764 A CN 103274764A
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Abstract
The invention relates to porcelain glaze and in particular relates to high and low-temperature resistant porcelain glaze for enamel. According to the technical scheme, the highnd low-temperature resistant porcelain glaze for enamel is prepared from the following raw materials in parts by weight: 22-38 parts of sodium silicate with the modulus of 2-3.8, 11-19 parts of aluminum oxide, 10-20 parts of manganese dioxide, 6-9 parts of palladium oxide, 6-9 parts of high-boron calcium borate, 23-29 parts of lead sulfate, 2-4 parts of talc, 7-13 parts of calcium carbonate, 8-12 parts of barium sulfate, 12-19 parts of zinc sulfate and 2-9 parts of titanium oxide. The high and low-temperature resistant porcelain glaze has excellent ultralow-temperature resistance and high-temperature resistance.
Description
Technical field
The present invention relates to ceramic glaze, particularly a kind of enamel material of the anti-high and low-temp for enamel.
Background technology
The enamel goods are widely used in all respects of life, but the enamel of prior art such as application publication number are the disclosed a kind of enviroment protective ceramic glaze of application for a patent for invention of CN102372501A, comprise following composition, and its massfraction is: SiO
250-60%, A1
2O
35-10%, CaO3-8%, ZnO5-10%, K
2O2-4%, Na
2O1-4%, B
2O
32-7%, La
2O
30.3-2% also contains MgO, BaO and ZrO
2, its total addition≤15%, this kind ceramic glaze high-and low-temperature resistance degree poor performance, in winter, pottery is easily by bursting by freezing, and resistance to elevated temperatures is also relatively poor.
Summary of the invention
The purpose of this invention is to provide a kind of enamel material of the anti-high and low-temp for enamel, have anti-very low temperature performance well, and have resistance to elevated temperatures.
Above-mentioned technical purpose of the present invention is achieved by the following technical programs: a kind of enamel material of the anti-high and low-temp for enamel, and it is made by the raw material of following parts by weight: modulus is water glass 22-38 part, aluminum oxide 11-19 part, Manganse Dioxide 10-20 part, palladous oxide 6-9 part, high boron lime borate 6-9 part, lead sulfate 23-29 part, talcum 2-4 part of 2-3.8; Calcium carbonate 7-13 part, barium sulfate 8-12 part, zinc sulfate 12-19 part, titanium oxide 2-9 part.
As of the present invention preferred, water glass 25-30 part, aluminum oxide 15-17 part, Manganse Dioxide 13-16 part, palladous oxide 7-9 part, high boron lime borate 6-8 part, lead sulfate 25-28 part, talcum 2-3 part; Calcium carbonate 8-11 part, barium sulfate 10-11 part, zinc sulfate 15-18 part, titanium oxide 3-7 part.
As of the present invention preferred, the modulus of described water glass is 2.5-3.5.
As of the present invention preferred, described raw material all is the powder shape, and particle diameter is the 30-38 order.
In sum, the present invention has following beneficial effect: spend to 950 degree for-80 through testing normal working temperature scope of the present invention, thereby have good high and low temperature resistance, and the glaze slickness is good, the glaze slip performance is good, firing range is wide.
Embodiment
This specific embodiment only is explanation of the invention; it is not limitation of the present invention; those skilled in the art can make the modification that does not have creative contribution to present embodiment as required after reading this specification sheets, but as long as all are subjected to the protection of patent law in claim scope of the present invention.
Embodiment 1: a kind of enamel material of the anti-high and low-temp for enamel, and it is stirred by powder shape raw material mixed melting under 1350 degree temperature of following parts by weight and makes: modulus is 26 parts of 10 parts of 11 parts in 22 parts of water glass, aluminum oxide, Manganse Dioxide, palladous oxides, 6 parts of high boron lime borates, 23 parts of lead sulfates, 2 parts in talcum; 7 parts in calcium carbonate, 8 parts in barium sulfate, 12 parts in zinc sulfate, 2 parts of titanium oxide.
The particle diameter of all raw materials is the 30-32 order.
Through test, the performance of present embodiment is as follows, thermal expansivity 50, change point (degree) 580, expansion softening temperature (degree) 660, sintering point (degree) 680, softening temperature (degree) 950, ball point (degree) 1120, hemisphere point (degree) 1310; According to GB/T 7989-2003 " mensuration of the enamel for glassed steel hydrochloric acid of anti-boiling steam corrosion performance ", its mass loss rate is 2.8g/m
2* d.
Embodiment 2: a kind of enamel material of the anti-high and low-temp for enamel, and it is stirred by powder shape raw material mixed melting under 1300 degree temperature of following parts by weight and makes: modulus is 3.8 9 parts of 20 parts of 19 parts in 38 parts of water glass, aluminum oxide, Manganse Dioxide, palladous oxides, 9 parts of high boron lime borates, 29 parts of lead sulfates, 4 parts in talcum; 13 parts in calcium carbonate, 12 parts in barium sulfate, 19 parts in zinc sulfate, 9 parts of titanium oxide.
The particle diameter of all raw materials is the 35-38 order.
Through test, the performance of present embodiment is as follows, thermal expansivity 53, change point (degree) 589, expansion softening temperature (degree) 666, sintering point (degree) 675, softening temperature (degree) 948, ball point (degree) 1130, hemisphere point (degree) 1330; According to GB/T 7989-2003 " mensuration of the enamel for glassed steel hydrochloric acid of anti-boiling steam corrosion performance ", its mass loss rate is 3.0g/m
2* d.
Embodiment 3: a kind of enamel material of the anti-high and low-temp for enamel, and it is stirred by powder shape raw material mixed melting under 1400 degree temperature of following parts by weight and makes: modulus is 2.5 7 parts of 13 parts of 15 parts in 25 parts of water glass, aluminum oxide, Manganse Dioxide, palladous oxides, 6 parts of high boron lime borates, 25 parts of lead sulfates, 2 parts in talcum; 8 parts in calcium carbonate, 10 parts in barium sulfate, 15 parts in zinc sulfate, 3 parts of titanium oxide.
The particle diameter of all raw materials is the 32-36 order.
Through test, the performance of present embodiment is as follows, thermal expansivity 48, change point (degree) 600, expansion softening temperature (degree) 685, sintering point (degree) 692, softening temperature (degree) 945, ball point (degree) 1120, hemisphere point (degree) 1310; According to GB/T 7989-2003 " mensuration of the enamel for glassed steel hydrochloric acid of anti-boiling steam corrosion performance ", its mass loss rate is 3.2g/m
2* d.
Embodiment 4: a kind of enamel material of the anti-high and low-temp for enamel, and it is stirred by powder shape raw material mixed melting under 1280 degree temperature of following parts by weight and makes: modulus is 3.5 9 parts of 16 parts of 17 parts in 30 parts of water glass, aluminum oxide, Manganse Dioxide, palladous oxides, 8 parts of high boron lime borates, 28 parts of lead sulfates, 3 parts in talcum; 11 parts in calcium carbonate, 11 parts in barium sulfate, 18 parts in zinc sulfate, 7 parts of titanium oxide.
The particle diameter of all raw materials is the 33-37 order.
Through test, the performance of present embodiment is as follows, thermal expansivity 52, change point (degree) 598, expansion softening temperature (degree) 675, sintering point (degree) 683, softening temperature (degree) 940, ball point (degree) 1110, hemisphere point (degree) 1290; According to GB/T 7989-2003 " mensuration of the enamel for glassed steel hydrochloric acid of anti-boiling steam corrosion performance ", its mass loss rate is 2.9g/m
2* d.
Embodiment 5: a kind of enamel material of the anti-high and low-temp for enamel, and it is stirred by powder shape raw material mixed melting under 1450 degree temperature of following parts by weight and makes: modulus is 38 parts of 15 parts of 16 parts in 22 parts of water glass, aluminum oxide, Manganse Dioxide, palladous oxides, 7 parts of high boron lime borates, 26 parts of lead sulfates, 3 parts in talcum; 9 parts in calcium carbonate, 10 parts in barium sulfate, 16 parts in zinc sulfate, 6 parts of titanium oxide.
The particle diameter of all raw materials is the 35-38 order.
Through test, the performance of present embodiment is as follows, thermal expansivity 53, change point (degree) 596, expansion softening temperature (degree) 673, sintering point (degree) 686, softening temperature (degree) 950, ball point (degree) 1118, hemisphere point (degree) 1296; According to GB/T 7989-2003 " mensuration of the enamel for glassed steel hydrochloric acid of anti-boiling steam corrosion performance ", its mass loss rate is 2.9g/m
2* d.
Claims (4)
1. enamel material that is used for the anti-high and low-temp of enamel, it is characterized in that it is made by the raw material of following parts by weight: modulus is water glass 22-38 part, aluminum oxide 11-19 part, Manganse Dioxide 10-20 part, palladous oxide 6-9 part, high boron lime borate 6-9 part, lead sulfate 23-29 part, talcum 2-4 part of 2-3.8; Calcium carbonate 7-13 part, barium sulfate 8-12 part, zinc sulfate 12-19 part, titanium oxide 2-9 part.
2. the enamel material of a kind of anti-high and low-temp for enamel according to claim 1, it is characterized in that water glass 25-30 part, aluminum oxide 15-17 part, Manganse Dioxide 13-16 part, palladous oxide 7-9 part, high boron lime borate 6-8 part, lead sulfate 25-28 part, talcum 2-3 part; Calcium carbonate 8-11 part, barium sulfate 10-11 part, zinc sulfate 15-18 part, titanium oxide 3-7 part.
3. the enamel material of a kind of anti-high and low-temp for enamel according to claim 2 is characterized in that the modulus of described water glass is 2.5-3.5.
4. the enamel material of a kind of anti-high and low-temp for enamel according to claim 3 is characterized in that described raw material all is the powder shape, and particle diameter is the 30-38 order.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310166353.4A CN103274764B (en) | 2013-05-08 | 2013-05-08 | High and low-temperature resistant porcelain glaze for enamel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310166353.4A CN103274764B (en) | 2013-05-08 | 2013-05-08 | High and low-temperature resistant porcelain glaze for enamel |
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| CN103274764A true CN103274764A (en) | 2013-09-04 |
| CN103274764B CN103274764B (en) | 2014-06-04 |
Family
ID=49057423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310166353.4A Expired - Fee Related CN103274764B (en) | 2013-05-08 | 2013-05-08 | High and low-temperature resistant porcelain glaze for enamel |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103693848A (en) * | 2013-12-09 | 2014-04-02 | 常熟市永达化工设备厂 | High and low temperature resistant porcelain glaze for enamel |
| CN104399419A (en) * | 2014-12-12 | 2015-03-11 | 常熟市永达化工设备厂 | Reaction still circularly heated by steam-heated heat transfer oil |
| CN104455923A (en) * | 2014-12-13 | 2015-03-25 | 常熟市华懋化工设备有限公司 | Glassed steel pipe fitting |
| CN104529163A (en) * | 2014-12-13 | 2015-04-22 | 常熟市华懋化工设备有限公司 | Closed glass lining storage tank |
| CN111333326A (en) * | 2020-03-05 | 2020-06-26 | 德化豪晟艺品有限公司 | Household environment-friendly high-temperature-resistant crack glaze with antifouling property and preparation method thereof |
| CN112661497A (en) * | 2018-07-20 | 2021-04-16 | 陆升(福建)集团有限公司 | Heat-resistant corrosion-resistant enamel-like ceramic product and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08165139A (en) * | 1994-12-09 | 1996-06-25 | Inax Corp | Low-temperature baking glaze |
| CN1169967A (en) * | 1996-07-08 | 1998-01-14 | 山东新华医药集团有限责任公司 | Low temperature firing acid-alkali resistant enamel and preparation thereof |
| CN1204627A (en) * | 1997-07-08 | 1999-01-13 | 包头市搪瓷厂 | Cast-iron porcelain enamel suitable for wet method production and its technology |
| KR20080044204A (en) * | 2005-05-09 | 2008-05-20 | 아메리칸 스탠다드 인터네쇼날 인코포레이티드 | Antimicrobial glaze and porcelain enamel via double layer glaze with high zinc content |
| CN101759366A (en) * | 2010-01-19 | 2010-06-30 | 方夕涛 | Porcelain glaze slurry |
-
2013
- 2013-05-08 CN CN201310166353.4A patent/CN103274764B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08165139A (en) * | 1994-12-09 | 1996-06-25 | Inax Corp | Low-temperature baking glaze |
| CN1169967A (en) * | 1996-07-08 | 1998-01-14 | 山东新华医药集团有限责任公司 | Low temperature firing acid-alkali resistant enamel and preparation thereof |
| CN1204627A (en) * | 1997-07-08 | 1999-01-13 | 包头市搪瓷厂 | Cast-iron porcelain enamel suitable for wet method production and its technology |
| KR20080044204A (en) * | 2005-05-09 | 2008-05-20 | 아메리칸 스탠다드 인터네쇼날 인코포레이티드 | Antimicrobial glaze and porcelain enamel via double layer glaze with high zinc content |
| CN101759366A (en) * | 2010-01-19 | 2010-06-30 | 方夕涛 | Porcelain glaze slurry |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103693848A (en) * | 2013-12-09 | 2014-04-02 | 常熟市永达化工设备厂 | High and low temperature resistant porcelain glaze for enamel |
| CN103693848B (en) * | 2013-12-09 | 2015-12-09 | 常熟市永达化工设备厂 | For the glaze of the anti-high and low-temp of enamel |
| CN104399419A (en) * | 2014-12-12 | 2015-03-11 | 常熟市永达化工设备厂 | Reaction still circularly heated by steam-heated heat transfer oil |
| CN104399419B (en) * | 2014-12-12 | 2016-06-22 | 常熟市永达化工设备厂 | Steam heating conduction oil circulating-heating reactor |
| CN104455923A (en) * | 2014-12-13 | 2015-03-25 | 常熟市华懋化工设备有限公司 | Glassed steel pipe fitting |
| CN104529163A (en) * | 2014-12-13 | 2015-04-22 | 常熟市华懋化工设备有限公司 | Closed glass lining storage tank |
| CN104455923B (en) * | 2014-12-13 | 2016-10-05 | 常熟市华懋化工设备有限公司 | Enamel pipe fitting |
| CN112661497A (en) * | 2018-07-20 | 2021-04-16 | 陆升(福建)集团有限公司 | Heat-resistant corrosion-resistant enamel-like ceramic product and preparation method thereof |
| CN111333326A (en) * | 2020-03-05 | 2020-06-26 | 德化豪晟艺品有限公司 | Household environment-friendly high-temperature-resistant crack glaze with antifouling property and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103274764B (en) | 2014-06-04 |
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Granted publication date: 20140604 Termination date: 20160508 |