CN103272990A - Molding sand comprising cyan sand as main material and manufacturing method thereof - Google Patents

Abstract

The invention discloses molding sand comprising cyan sand as a main material and a manufacturing method thereof. The molding sand comprises, by weight, 70 to 75 parts of cyan sand, 28 to 32 parts of nano-siliceous shale powder, 1.3 to 1.5 parts of water-soluble nano-silica sol, 0.55 to 0.65 parts of SP-60, 0.7 to 0.9 parts of glyceryl triglyceride, 1.1 to 1.3 parts of a silane coupling agent KH550, 30 to 35 parts of 2-ethyl-4-methylimidazole, 0.01 to 0.03 parts of calcined loess powder, 1.3 to 1.5 parts of oxalic acid and 2.0 to 3.5 parts of a film-forming agent. The molding sand has a reasonable formula, utilizes cyan sand as a main raw material, and comprises nano-siliceous shale powder. The size of the cyan sand is in a range of 200 to 250 meshes so that molding sand strength and heat resistance are improved. The 2-ethyl-4-methylimidazole as a curing agent is conducive to reduction of the roughness of a sand model composed of the molding sand. The molding sand has good heat resistance, small roughness and good permeability and avoids sand sticked to a casing.

Description

A kind of is the molding sand and preparation method thereof of major ingredient with blue or green sand

Technical field

The present invention relates to a kind of compound method of foundry sand, being specifically related to a kind of is the molding sand and preparation method thereof of major ingredient with blue or green sand.

Background technology

The effect of molding sand in Foundry Production is very important, the casting wasted product that causes because of the poor quality of molding sand accounts for 30～50% of the total waste product of foundry goods, usually the requirement to molding sand has intensity and heat endurance, flowability, plasticity, gas permeability and collapsibility, namely whether molding sand destroys easily behind casting solidification, the performance of whether removing from foundry goods easily.

At present, in the preparation process of molding sand, generally be mixed and made into by a certain percentage by fresh sand, old sand, binding agent and auxiliary material.

Summary of the invention

The object of the present invention is to provide a kind of is the molding sand and preparation method thereof of major ingredient with blue or green sand.

The present invention adopts following technical scheme:

Be the molding sand of major ingredient with blue or green sand, the weight portion of its constitutive material is: blue or green sand 70-75, the siliceous shale powder 28-32 of nanometer, water-soluble nano grade silica sol 1.3-1.5, sorbester p18 0.55-0.65, glycerine glycerinate 0.7-0.9, silane coupler KH550 1.1-1.3,2-ethyl-4 methylimidazole 30-35, calcining back loess powder 0.01-0.03, oxalic acid 1.3-1.5 and film forming agent 2.0-3.5.

Be the molding sand of major ingredient with blue or green sand, the weight portion of its constitutive material is: blue or green sand 72, the siliceous shale powder 30 of nanometer, water-soluble nano grade silica sol 1.4, sorbester p18 0.6, glycerine glycerinate 0.8, silane coupler KH550 1.2,2-ethyl-4 methylimidazole 32, calcining back loess powder 0.02, oxalic acid 1.4 and film forming agent 2.8.

Be the preparation method of the molding sand of major ingredient with blue or green sand, may further comprise the steps:

(1) at first blue or green sand and the siliceous shale powder of nanometer are crushed to the 200-250 order, in the roughing sand heater, blue or green sand and the siliceous shale powder of nanometer are heated to 200-240 ℃ then;

(2) the blue or green sand of step (1) and the siliceous shale powder of nanometer are poured in the puddle mixer stirred, naturally cool to 80-100 ℃, add other constitutive materials and constantly stirring then successively, it is 3-5s that control adds the stock yard interval, after treating that whole raw materials add, continue the nature cooling, fragmentation, sieve, namely get the molding sand finished product.

The preparation method of described film forming agent is as follows:

Prescription: water 20-25,3-aminopropyl trimethoxysilane 1-2, maleic anhydride 15-18, diethylene glycol butyl ether 5-8, boric acid 1-2, propane diols 8-12, polyvinylpyrrolidone 2-3, alum 1-2, urea 1-2, sodium peroxydisulfate 0.5-1;

The preparation method is as follows:

(1), heats water to 80-95 ℃, adding 3-aminopropyl trimethoxysilane, alum, sodium peroxydisulfate dissolving, stirring reaction 50-60 minute;

(2), the reaction system with step (1) is warming up to 140-145 ℃, adding diethylene glycol butyl ether, boric acid, polyvinylpyrrolidone, stirring reaction 40-50 minute;

(3), the reaction system with step (2) is cooled to 110-125 ℃, adding maleic anhydride, urea, propane diols, stirring reaction 40-50 minute; Obtain.

Beneficial effect of the present invention:

The present invention fills a prescription rationally, adopting blue or green sand is major ingredient, and the siliceous shale powder of adding nanometer, the granularity of blue or green sand is the 200-250 order, and the granularity of blue or green sand helps to improve intensity and the hear resistance of molding sand, and curing agent 2-ethyl-4 methylimidazole helps to reduce the roughness of the sand mold that molding sand makes up, and the present invention not only hear resistance is better, and roughness is less, and gas permeability is better, can avoid scab on foundry goods.

The specific embodiment

Embodiment 1: be the molding sand of major ingredient with blue or green sand, the weight portion of its constitutive material (kg) is: blue or green sand 72, the siliceous shale powder 30 of nanometer, water-soluble nano grade silica sol 1.4, sorbester p18 0.6, glycerine glycerinate 0.8, silane coupler KH550 1.2,2-ethyl-4 methylimidazole 32, calcining back loess powder 0.02, oxalic acid 1.4 and film forming agent 2.8.

Be the preparation method of the molding sand of major ingredient with blue or green sand, may further comprise the steps:

(1) at first blue or green sand and the siliceous shale powder of nanometer are crushed to the 200-250 order, in the roughing sand heater, blue or green sand and the siliceous shale powder of nanometer are heated to 220-240 ℃ then;

(2) the blue or green sand of step (1) and the siliceous shale powder of nanometer are poured in the puddle mixer stirred, naturally cool to 80-100 ℃, add other constitutive materials and constantly stirring then successively, it is 3-5s that control adds the stock yard interval, after treating that whole raw materials add, continue the nature cooling, fragmentation, sieve, namely get the molding sand finished product.

The preparation method of described film forming agent is as follows:

Prescription (weight portion): water 22,3-aminopropyl trimethoxysilane 1.5, maleic anhydride 17, diethylene glycol butyl ether 6.5, boric acid 1.5, propane diols 10, polyvinylpyrrolidone 2.5, alum 1, urea 1.5, sodium peroxydisulfate 0.8;

The preparation method is as follows:

(1), heats water to 80-95 ℃, adding 3-aminopropyl trimethoxysilane, alum, sodium peroxydisulfate dissolving, stirring reaction 50-60 minute;

(2), the reaction system with step (1) is warming up to 140-145 ℃, adding diethylene glycol butyl ether, boric acid, polyvinylpyrrolidone, stirring reaction 40-50 minute;

(3), the reaction system with step (2) is cooled to 110-125 ℃, adding maleic anhydride, urea, propane diols, stirring reaction 40-50 minute; Obtain.

The performance data of the molding sand that makes by above-described embodiment:

High temperature compression strength is more than 0.87Mpa, gas forming amount is lower than below the 15.0ml/g, heat-resistant time 178-185 second, room temperature tensile strength is greater than 3.85Mpa, hot-drawn intensity is greater than 128Mpa, not only hear resistance is better in the present invention, roughness is less, and gas permeability is better, can produce the complicated precision casting of various materials.

Claims (4)

1. one kind is the molding sand of major ingredient with blue or green sand, it is characterized in that the weight portion of its constitutive material is: blue or green sand 70-75, the siliceous shale powder 28-32 of nanometer, water-soluble nano grade silica sol 1.3-1.5, sorbester p18 0.55-0.65, glycerine glycerinate 0.7-0.9, silane coupler KH550 1.1-1.3,2-ethyl-4 methylimidazole 30-35, calcining back loess powder 0.01-0.03, oxalic acid 1.3-1.5 and film forming agent 2.0-3.5.

2. according to claim 1 is the molding sand of major ingredient with blue or green sand, it is characterized in that the weight portion of its constitutive material is: blue or green sand 72, the siliceous shale powder 30 of nanometer, water-soluble nano grade silica sol 1.4, sorbester p18 0.6, glycerine glycerinate 0.8, silane coupler KH550 1.2,2-ethyl-4 methylimidazole 32, calcining back loess powder 0.02, oxalic acid 1.4 and film forming agent 2.8.

One kind as claimed in claim 1 be the preparation method of the molding sand of major ingredient with blue or green sand, it is characterized in that may further comprise the steps:

(1) at first blue or green sand and the siliceous shale powder of nanometer are crushed to the 200-250 order, in the roughing sand heater, blue or green sand and the siliceous shale powder of nanometer are heated to 200-240 ℃ then;

(2) the blue or green sand of step (1) and the siliceous shale powder of nanometer are poured in the puddle mixer stirred, naturally cool to 80-100 ℃, add other constitutive materials and constantly stirring then successively, it is 3-5s that control adds the stock yard interval, after treating that whole raw materials add, continue the nature cooling, fragmentation, sieve, namely get the molding sand finished product.

4. according to claim 1 is the preparation method of the molding sand of major ingredient with blue or green sand, and it is characterized in that: the preparation method of described film forming agent is as follows:

Prescription: water 20-25,3-aminopropyl trimethoxysilane 1-2, maleic anhydride 15-18, diethylene glycol butyl ether 5-8, boric acid 1-2, propane diols 8-12, polyvinylpyrrolidone 2-3, alum 1-2, urea 1-2, sodium peroxydisulfate 0.5-1;

The preparation method is as follows:

(1), heats water to 80-95 ℃, adding 3-aminopropyl trimethoxysilane, alum, sodium peroxydisulfate dissolving, stirring reaction 50-60 minute;

(2), the reaction system with step (1) is warming up to 140-145 ℃, adding diethylene glycol butyl ether, boric acid, polyvinylpyrrolidone, stirring reaction 40-50 minute;

(3), the reaction system with step (2) is cooled to 110-125 ℃, adding maleic anhydride, urea, propane diols, stirring reaction 40-50 minute; Obtain.